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At least 1,423 records · Page 79

Derivation and assessment of regional electricity generation emission factors in the USA

Electricity production is one of the largest sources of environmental emissions - especially greenhouse gases (GHGs) - in the USA. Emission factors (EFs) vary from region to region, which requires the use of spatially relevant EF data for electricity production while performing life cycle assessments (LCAs). Uncertainty information, which is sought by LCA practitioners, is rarely supplied with available life cycle inventories (LCIs). To address these challenges, we present a method for collecting data from different sources for electricity generation and environmental emissions; discuss the challenges involved in agglomerating such data; provide relevant suggestions and solutions to merge the information; and calculate EFs for electricity generation processes from various fuel sources for different spatial regions and spatial resolutions. The EFs from the US 2016 Electricity Life Cycle Inventory (eLCI) are analyzed and explored in this study. We also explore the method of uncertainty information derivation for the EFs. We explore the EFs from different technologies across Emissions & Generation Resource Integrated Database (eGRID) regions in the USA. We find that for certain eGRID regions, the same electricity production technology may have worse emissions. This may be a result of the age of the plants in the region, the quality of fuel used, or other underlying factors. Region-wise life cycle impact assessment (LCIA) ISO 14040 impacts for total generation mix activities provide an overview of the total sustainability profile of electricity production in a particular region, rather than only global warming potential (GWP). We also find that, for different LCIA impacts, several eGRID regions are consistently worse than the US average LCIA impact for every unit of electricity generated. Here this work describes the development of an electricity production LCI at different spatial resolutions by combining and harmonizing information from several databases. The inventory consists of emissions, fuel inputs, and electricity and steam outputs from different electricity production technologies located across various regions of the USA. This LCI for electricity production in the USA will prove to be an enormous resource for all LCA researchers - considering the detailed sources of the information and the breadth of emissions covered by it.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Mapping Environmental Contaminants at Ray Mine, AZ

Airborne Visible and InfraRed Imaging Spectrometer (AVIRIS) data was collected over Ray Mine as part of a demonstration project for the Environmental Protection Agency (EPA) through the Advanced Measurement Initiative (AMI). The overall goal of AMI is to accelerate adoption and application of advanced measurement technologies for cost effective environmental monitoring. The site was selected to demonstrate the benefit to EPA in using advanced remote sensing technologies for the detection of environmental contaminants due to the mineral extraction industry. The role of the Jet Propulsion Laboratory in this pilot study is to provide data as well as performing calibration, data analysis, and validation of the AVIRIS results. EPA is also interested in developing protocols that use commercial software to perform such work on other high priority EPA sites. Reflectance retrieval was performed using outputs generated by the MODTRAN radiative transfer model and field spectra collected for the purpose of calibration. We are presenting advanced applications of the ENVI software package using n-Dimensional Partial Unmixing to identify image-derived endmembers that best match target materials reference spectra from multiple spectral libraries. Upon identification of the image endmembers the Mixture Tuned Match Filter algorithm was applied to map the endmembers within each scene. Using this technique it was possible to map four different mineral classes that are associated with mine generated acid waste.

McCubbin, Ian↗

Machine Intelligence-Centered System for Automated Characterization of Functional Materials and Interfaces

Classic design of experiment relies on a time-intensive workflow that requires planning, data interpretation, and hypothesis building by experienced researchers. Here, in this paper, we describe an integrated, machine-intelligent experimental system which enables simultaneous dynamic tests of electrical, optical, gravimetric, and viscoelastic properties of materials under a programmable dynamic environment. Specially designed software controls the experiment and performs on-the-fly extensive data analysis and dynamic modeling, real-time iterative feedback for dynamic control of experimental conditions, and rapid visualization of experimental results. The system operates with minimal human intervention and enables time-efficient characterization of complex dynamic multifunctional environmental responses of materials with simultaneous data processing and analytics. The system provides a viable platform for artificial intelligence (AI)-centered material characterization, which, when coupled with an AI-controlled synthesis system, could lead to accelerated discovery of multifunctional materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Building a genome-based understanding of bacterial pH preferences

The environmental preferences of many microbes remain undetermined. This is the case for bacterial pH preferences, which can be difficult to predict a priori despite the importance of pH as a factor structuring bacterial communities in many systems. We compiled data on bacterial distributions from five datasets spanning pH gradients in soil and freshwater systems (1470 samples), quantified the pH preferences of bacterial taxa across these datasets, and compiled genomic data from representative bacterial taxa. While taxonomic and phylogenetic information were generally poor predictors of bacterial pH preferences, we identified genes consistently associated with pH preference across environments. We then developed and validated a machine learning model to estimate bacterial pH preferences from genomic information alone, a model that could aid in the selection of microbial inoculants, improve species distribution models, or help design effective cultivation strategies. More generally, we demonstrate the value of combining biogeographic and genomic data to infer and predict the environmental preferences of diverse bacterial taxa.

59 BASIC BIOLOGICAL SCIENCES↗

TT and C - First TDRSS, Then Commercial GEO and Big LEO and Now through LEO

The advent of low earth orbit (LEO) commercial communications satellites provides an opportunity to dramatically reduce Telemetry Tracking and Control (TT&C) costs of launch vehicles and Unpiloted Aerial Vehicles (UAVs) by reducing or eliminating ground infrastructure. Personnel from the Goddard Space Flight Center Wallops Flight Facility (GSFC/WFF) in Virginia have successfully used commercial GEO & Big LEO communications satellites for Long Duration Balloon flight TT&C. In addition, TDRSS capability for these balloons has been developed by WFF for the Ultra Long Duration Balloons with the first test flight launch in January 2001 for one global circumnavigation at 120,000 feet altitude launched from Alice Springs. Australia. Numerous other low cost applications can new utilize the commercial LEO satellites for TT&C. The Flight Modern became a GSFC/WFF Advanced Range Technology Initiative (ARTI) in an effort to streamline TT&C capability to the user community at low cost. Phase I ground tests of The Flight Modem verified downlink communications quality of service and measured transmission latencies. These tests were completed last year, Phase II consisting of aircraft flight tests provide much of the data presented in this paper. Phase III of the Flight Modern baseline test program is a demonstration of the ruggedized version of the WFF Flight Modem flown on one sounding rocket launched from Sweden. Flights of opportunity have been and are being actively pursued with other centers, ranges and users at universities. The WFF goal is to reduce TT&C costs by providing a low cost COTS Flight Modem with a User Handbook containing system capability and limitation descriptions. Additionally, since data transmission is by packetized Internet Protocol (IP), data can be received and commands initialed from practically any location with no infrastructure. The WFF, like most ranges, has been using GPS receivers on sounding rockets and long duration balloons for several years, The WFF Flight Modem contains a GPS receiver to provide vehicle position for tracking and vehicle recovery. The system architecture which integrates antennas, GPS receiver, commercial satellite packet data modem. and a single board computer with custom software is described and a number of technical challenges are discussed along with the plan for their resolution. These include antenna development, high Doppler rates, reliability, environmental ruggedness, hand over between satellites and data security. An aggressive test plan is included which in addition to environmental Testing measures bit error rate latency and antenna patterns. Additional flight tests are planned far the near future on aircraft, long duration balloons and sounding rockets and these results as well as the current status of the project arc reported. Use of the WFF Flight Modem on small satellites is also being pursued. The LEO satellite constellation altitude above 1400 km is not an obstacle because most spacecraft do not require continuous Communications. The challenge is scheduling where store and forward techniques for command are required and downlink when the communications link allows connection (above 60 percent of the time depending on the satellite altitude). Sophisticated scheduling techniques utilizing 2-line orbital element sets available on the NASA/NORAD Internet site could be implemented for rare special cases. The current 9600 baud rate of the LEO communications link may be increased With special techniques that are planned for development in the WFF Flight Modem project.

Morgan, Dwayne↗

Ultrahigh performance LC/FT-MS non-targeted screening for biomass burning organic aerosol with MZmine2 and MFAssignR

In recent years, ultrahigh performance liquid chromatography Fourier transform mass spectrometry (LC/FT-MS) based non-targeted screening (NTS) methods have become increasingly popular for comprehensive analysis of complex organic mixtures. However, applying these methods for environmental complex mixture analysis is challenging due to the extreme complexity of natural samples and a lack of standard samples or surrogates for environmental complex mixtures. Furthermore, limited molecular markers in the databases and insufficient data processing software workflows make the application of these methods more challenging for environmental complex mixtures. In this work, we implement a new NTS data processing workflow to process data collected from ultrahigh performance liquid chromatography and Fourier transform Orbitrap Elite Mass Spectrometry (LC/FT-MS) by combining MZmine2 and MFAssignR, two opensource data processing tools and commercial Mesquite liquid smoke as a surrogate for biomass burning organic aerosol. MZmine2.53 data extraction followed MFAssignR molecular formula assignment offered noise free and highly accurate 1733 individual molecular formulas presented in liquid smoke with 4906 molecular species, including isomers. The results of this new approach were consistent with the results of direct infusion FT-MS analysis confirming its reliability. Over 90% of the molecular formulas presented in mesquite liquid smoke were matched with the molecular formulas of ambient biomass burning organic aerosol. This suggests the potential use of commercial liquid smoke as a surrogate for biomass burning organic aerosol research. Furthermore, the presented method significantly improves the identification of the molecular composition of biomass burning organic aerosol by successfully addressing some of the limitations related to the data analysis and giving a semi quantitative insight into the analysis.

54 ENVIRONMENTAL SCIENCES↗

AmeriFlux FLUXNET-1F US-OPE Optimizing Production Inputs for Economic and Environmental Enhancement (OPE3)

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-OPE Optimizing Production Inputs for Economic and Environmental Enhancement (OPE3). This is the FLUXNET version of the carbon flux data for the site US-OPE Optimizing Production Inputs for Economic and Environmental Enhancement (OPE3) produced by applying the standard ONEFlux (1F) software. Site Description - The Optimizing Production Inputs for Economic and Environmental Enhancement (OPE3) site is located at the Beltsville Agricultural Research Center in Prince George's County, MD, and consists of a 22-ha production field, with an adjacent riparian wetland and first-order stream. Scientists from several U.S. Federal agencies, universities (foreign and domestic), and private industry have conducted multidisciplinary research at this location since 1998.

Alfieri, Joe [USDA-ARS Hydrology and Remote Sensin↗

Uinta Basin CarbonSAFE II: Storage Complex Feasibility (Final Report)

The primary objective of this CarbonSAFE Phase II project was to establish the technical and commercial feasibility of a commercial-scale CO 2 geological storage complex for Deseret Power Electric Cooperative Bonanza Power Plant and other CO 2 sources in the northeast Uinta Basin, Utah, with the goal to securely store at least 50 million metric tons of captured CO 2 and accelerate CO 2 capture, utilization, and storage (CCUS) deployment. The project team established high-potential technical and commercial feasibility for a storage site within the east Uinta Basin (Utah), in the Cretaceous sandstones (Frontier, Dakota, and Buckhorn), Entrada Sandstone, Nugget Sandstone, and/or Weber Sandstone southwest of the Bonanza coal-fired power plant. This project collected and analyzed state-of-the-art data to characterize the storage complex consistent with Environmental Protection Agency (EPA) permitting standards. The team conducted extensive analog studies, outcrop mapping, and data sampling, which largely contributed to understanding the subsurface lithology and facies. Existing data were obtained and assessed from Utah Division of Oil, Gas, and Mining (DOGM), Utah Geological Survey (UGS), Colorado Geological Survey (CGS), U.S. Geological Survey (USGS), and EPA. These data were analyzed using state-of-the-art CCUS technologies for Societal Considerations, Site Characterization, Modeling and Simulations, Risk Assessment, Management and Monitoring, potential Underground Injection Control (UIC) Class VI Well Permitting, and Technical/Economic Feasibility. Through these high-resolution data collection and feasibility studies, this project was expected to provide a reference for initiating Underground Injection Control (UIC) and other commercial-scale geological storage permitting processes in the Western United States, ultimately contributing to the nation's decarbonization goals through low-risk, cost-effective commercial-scale carbon capture, utilization, and storage (CCUS) projects.

42 ENGINEERING↗

AOT_data_repo

Data repo for ocean test case testing new data assimilation algorithm in an idealized setting.

54 ENVIRONMENTAL SCIENCES↗

In-situ ETEM study of plasma-facing tungsten nanofuzz oxidation at atmospheric pressure: Microstructure evolution and substrate-free oxidation kinetics

To enable sustainable carbon-free fusion energy, managing reactor structural material degradation during normal operation as well as accident scenarios is vital. Tungsten (W) plasma-facing materials (PFMs) are susceptible to aggressive high-temperature oxidation during air-ingress fusion reactor accidents, yet there's a lack of oxidation kinetic data for irradiated tungsten. Here, in this study, we utilize atmospheric environmental transmission electron microscopy (ETEM) to present the first kinetic data for substrate-free W nanofuzz oxidation at 400 ºC and 500 ºC in 1 bar dry air. Comparison with pristine bulk W during the early parabolic stage suggests an irradiationdecelerated oxidation for W nanofuzz. Our time-resolved in-situ characterization reveals a durable amorphous surface oxide, likely promoted by high-flux He + irradiation-induced surface defects, serving as an effective passivating layer that impedes nanofuzz oxidation onset. This surface oxide layer also interfaces well with newly formed orthorhombic WO 3 , facilitated by stress relief through He bubble shrinkage, providing lasting passivating protection throughout the nanofuzz parabolic oxidation. This new finding challenges conventional notions of irradiation's negative impact on metal oxidation, and calls for advanced characterization to enhance our understanding of fusion energy materials degradation, informed by further accident modeling.

36 MATERIALS SCIENCE↗

Hanford Site Ground Squirrel Monitoring Report for Calendar Year 2021

The U.S. Department of Energy, Richland Operations Office (DOE-RL) conducts ecological monitoring on the Hanford Site to collect and track data needed to ensure compliance with an array of environmental laws, regulations, and policies governing U.S. Department of Energy (DOE) activities. Ecological monitoring data provide baseline information about the plants, animals, and habitat under DOE-RL stewardship at the Hanford Site required for accurate ecological impact assessment decision making under the National Environmental Policy Act and Comprehensive Environmental Response, Compensation, and Liability Act. In addition, ecological monitoring helps ensure that DOE-RL, its contractors, and other entities conducting activities on the Hanford Site are in compliance with DOE/EIS- 0222-F, Hanford Site Comprehensive Land Use Plan (CLUP). DOE-RL places priority on monitoring those plant and animal species or habitats with specific regulatory protections or requirements; that are rare and/or declining (federal or state listed endangered, threatened, or sensitive species); or of significant interest to federal, state, or Tribal governments or the public.

54 ENVIRONMENTAL SCIENCES↗

Assessing Marginal Land Availability Based on Land Use Change Information in the Contiguous United States

Utilization of marginal land for growing dedicated bioenergy crops for second-generation biofuels is appealing to avoid conflicts with food production. This study develops a novel framework to quantify marginal land for the Contiguous United States (CONUS) based on a history of satellite-observed land use change (LUC) over the 2008–2015 period. Frequent LUC between crop and noncrop is assumed to be an indicator of economically marginal land; this land is also likely to have a lower opportunity cost of conversion from food crop to bioenergy crop production. We first present an approach to identify cropland in transition using the time series of Cropland Data Layer (CDL) land cover product and determine the amount of land that can be considered marginal with a high degree of confidence vs with uncertainty across the CONUS. We find that the biophysical characteristics of this land and its productivity and environmental vulnerability vary across the land and lie in between that of permanent cropland and permanent natural vegetation/bare areas; this land also has relatively low intrinsic value and agricultural profit but a high financial burden and economic risk. We find that the total area of marginal land with confidence vs with uncertainty is 10.2 and 58.4 million hectares, respectively, and mainly located along the 100th meridian. Only a portion of this marginal land (1.4–2.2 million hectares with confidence and 14.8–19.4 million hectares with uncertainty) is in the rainfed region and not in crop production and, thus, suitable for producing energy crops without diverting land from food crops in 2016. These estimates are much smaller than the estimates obtained by previous studies, which consider all biophysically low-quality land to be marginal without considering economical marginality. The estimate of marginal land for bioenergy crops obtained in this study is an indicator of the availability of economically marginal land that is suitable for bioenergy crop production; whether this land is actually converted to bioenergy crops will depend on the market conditions. Here, we note the inability to conduct field-level validation of cropland in transition and leave it to future advances in technology to ground-truth land use change and its relationship to economically marginal land.

54 ENVIRONMENTAL SCIENCES↗

2022 Annual Site Environmental Report for Sandia National Laboratories, Livermore, California

Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy’s National Nuclear Security Administration. The National Nuclear Security Administration’s Sandia Field Office administers the contract and oversees contractor operations at Sandia National Laboratories, California. Activities at this multiprogram engineering and science laboratory support the nuclear weapons stockpile program, energy and environmental research, homeland security, micro- and nanotechnologies, and basic science and engineering research. The U.S. Department of Energy and its management and operating contractor are committed to safeguarding the environment, assessing sustainability practices, and ensuring the validity and accuracy of the monitoring data presented in this annual site environmental report. This report provides a summary of environmental monitoring information and compliance activities that occurred at Sandia National Laboratories, California during calendar year 2022 unless noted otherwise. General site and environmental program information is also included. This report was prepared in accordance with DOE O 231.1B, Environment, Safety and Health Reporting.

54 ENVIRONMENTAL SCIENCES↗

Monitoring of ground water table depth and soil moisture at the Point Reyes field site

Ground water table (GWT) depth and soil moisture (SM) have been monitored at several locations at the Point Reyes field site (Californian coastal grassland) from 2021 to 2024. Monitoring is still on-going and data may be added to this archive at later time. The SM data have been acquired using Teros 12 Meter soil moisture sensors placed at 10, 30, 60 and 90 cm depth at 5 locations along a small hillslope. These sensors also collect soil temperature and bulk conductance. In addition, some collocated sensors provide pore pressure and Photochemical Reflectance Index (PRI). The GWT depth has been inferred from various type of Onset pressure transducers. The pressure measurements have been corrected for atmospheric pressure variations and sensor position relative to the ground surface to infer GWT depth, as well as with RTK GPS data to infer GWT elevation. The GWT data have been acquired at 5 distinct locations from 2020 to 2024 with the sensors placed at about 4 m depth. In addition, GWT data has been acquired for the 2023-2024 period with sensors located in 1 m deep shallow wells installed near each deeper well. This data is intended to evaluate possibly different dynamic in shallow (perched) and deep aquifer. The datasets are all provided in csv format. Please note that the interpretation of the GWT data needs to be done with consideration of environmental and well characteristics at the site and uncertainty in various variables. For more information on GWT and SM data, please contact the author.

54 ENVIRONMENTAL SCIENCES↗

Space qualification of optical instruments using the NASA Long-Duration Exposure Facility

The NASA Long-Duration Exposure Facility (LDEF), designed for the in situ testing of optical instrumentation in the space environment is described. The LDEF is basically a reusable structure which is three-axis gravity-gradient stabilized when flying free in space. The structure weighs about 8,000 lbs. and accommodates experiment trays weighing about 10,000 lbs. A vacuum exposure control canister is being designed for controlled exposure experiments. The LDEF will have an experiment power and data system and a shuttle bay environmental measurements system is being designed for measuring parameters such as acoustics, vibration, acceleration. The induced environment contamination monitor will evaluate the contamination levels of shuttle payloads. Experiments currently under development include the evaluation of active optical components and the study of fiber optic data transmission.

Clark, L. G.↗

Effects of spatial variability in vegetation phenology, climate, landcover, biodiversity, topography, and soil property on soil respiration across a coastal ecosystem

Coastal terrestrial-aquatic interfaces (TAIs) are crucial contributors to global biogeochemical cycles and carbon exchange. A systematic evaluation of the interaction between coastal catchment properties and carbon dioxide (CO2) emission by soil respiration is significant for assessing carbon dynamics and predicting the future trajectory of atmospheric CO2 concentrations in coastal TAIs. The soil CO2 efflux in these transition zones is however poorly understood due to the high spatiotemporal dynamics of TAIs, as various sub-ecosystems in this region are compressed and expanded by complex influences of tides, changes in river levels, climate, and land use. We focus on the Chesapeake Bay region to (i) investigate the spatial heterogeneity of the coastal ecosystem and identify spatial zones with similar environmental characteristics based on the spatial data layers, including vegetation index (kNDVI), climate, landcover, diversity, topography, soil property, and relative tidal elevation; (ii) understand the primary driving factors affecting soil respiration within sub-ecosystems of the coastal ecosystem. Specifically, we employed hierarchical clustering analysis to identify spatial regions with distinct environmental characteristics, followed by the determination of main driving factors using Random Forest regression and SHapley Additive exPlanations. Maximum and minimum temperature are the main drivers common to all sub-ecosystems, while each region also has additional unique major drivers that differentiate them from one another. Precipitation exerts an influence on vegetated lands, while soil pH value holds importance specifically in forested lands. In croplands characterized by high clay content and low sand content, the significant role is attributed to bulk density. Wetlands demonstrate the importance of both elevation and sand content, with clay content being more relevant in non-inundated wetlands than in inundated wetlands. The topographic wetness index significantly contributes to the mixed vegetation areas, including shrub, grass, pasture, and forest. Additionally, our research reveals that dense vegetation land covers and urban/developed areas exhibit distinct soil property drivers. Overall, there is no one-size-fits-all approach to modeling carbon fluxes in coastal TAIs, and our study highlights the importance of further research and monitoring practices to improve our understanding of carbon dynamics and promote the sustainable management of coastal TAIs.

54 ENVIRONMENTAL SCIENCES↗

Cuticle development and the underlying transcriptome–metabolome associations during early seedling establishment

Abstract The plant cuticle is a complex extracellular lipid barrier that has multiple protective functions. This study investigated cuticle deposition by integrating metabolomics and transcriptomics data gathered from six different maize seedling organs of four genotypes, the inbred lines B73 and Mo17, and their reciprocal hybrids. These datasets captured the developmental transition of the seedling from heterotrophic skotomorphogenic growth to autotrophic photomorphogenic growth, a transition that is highly vulnerable to environmental stresses. Statistical interrogation of these data revealed that the predominant determinant of cuticle composition is seedling organ type, whereas the seedling genotype has a smaller effect on this phenotype. Gene-to-metabolite associations assessed by integrated statistical analyses identified three gene networks associated with the deposition of different elements of the cuticle: cuticular waxes; monomers of lipidized cell wall biopolymers, including cutin and suberin; and both of these elements. These gene networks reveal three metabolic programs that appear to support cuticle deposition, including processes of chloroplast biogenesis, lipid metabolism, and molecular regulation (e.g. transcription factors, post-translational regulators, and phytohormones). This study demonstrates the wider physiological metabolic context that can determine cuticle deposition and lays the groundwork for new targets for modulating the properties of this protective barrier.

Plant Sciences↗

Hanford Site Mule Deer Monitoring Report for Fiscal Years 2024 and 2026

The U.S. Department of Energy, Hanford Field Office (HFO) conducts ecological monitoring on the Hanford Site to collect and track data needed to ensure compliance with environmental laws, regulations, and policies governing Department of Energy activities. The vision for the HFOmanaged portion of the Hanford Site, hereby referred to as Central Hanford, focuses not only on the cleanup of nuclear facilities and waste sites but on the protection and restoration of the Hanford Site lands. As the HFO moves toward accomplishing this vision, understanding of the ecological resources present and the need for conservation and/or protection of those resources will be critical for making informed decisions for responsible site stewardship. Ecological monitoring data provides baseline information about the plants, animals, and habitats under HFO stewardship at Central Hanford required for decision-making under the National Environmental Policy Act of 1969 (NEPA) and Comprehensive Environmental Response, Compensation, and Liability Act of 1980.

54 ENVIRONMENTAL SCIENCES↗