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At least 1,405 records · Page 78

Chemical Composition and Flow Velocity as a Function of Operating Conditions for an Arc Jet Heater

We have used laser-induced fluorescence (LIF) to carry out a detailed, systematic survey of the properties of the free stream of the 20 Megawatt Aerodynamic Heating Facility at NASA/Ames Research Center. In both air and nitrogen flows we have measured the atomic nitrogen absolute number density and flow velocity at each operating condition. In air flows we have also measured the atomic oxygen absolute number density and rotational/translational temperature at each operating condition. These results have been used to provide, for the first time, a direct, nonintrusive measurement of the enthalpy on the centerline of the flow. In addition, the observed arc jet properties can be used to test and improve computer simulations of the arc jet flow which include detailed chemical rate processes (especially nitrogen atom recombination) taking place during the supersonic expansion.

Bamford, Douglas J.↗

SiC/SiC Leading Edge Turbine Airfoil Tested Under Simulated Gas Turbine Conditions

Silicon-based ceramics have been proposed as component materials for use in gas turbine engine hot-sections. A high pressure burner rig was used to expose both a baseline metal airfoil and ceramic matrix composite leading edge airfoil to typical gas turbine conditions to comparatively evaluate the material response at high temperatures. To eliminate many of the concerns related to an entirely ceramic, rotating airfoil, this study has focused on equipping a stationary metal airfoil with a ceramic leading edge insert to demonstrate the feasibility and benefits of such a configuration. Here, the idea was to allow the SiC/SiC composite to be integrated as the airfoil's leading edge, operating in a "free-floating" or unrestrained manner. and provide temperature relief to the metal blade underneath. The test included cycling the airfoils between simulated idle, lift, and cruise flight conditions. In addition, the airfoils were air-cooled, uniquely instrumented, and exposed to the same internal and external conditions, which included gas temperatures in excess of 1370 C (2500 F). Results show the leading edge insert remained structurally intact after 200 simulated flight cycles with only a slightly oxidized surface. The instrumentation clearly suggested a significant reduction (approximately 600 F) in internal metal temperatures as a result of the ceramic leading edge. The object of this testing was to validate the design and analysis done by Materials Research and Design of Rosemont, PA and to determine the feasibility of this design for the intended application.

Robinson, R. Craig↗

Application of a radiometric method to the measurement of temperature in self-absorbing gases

A radiometric method for the measurement of gas temperature in self-absorbing gases has been applied in the study of shock-tube-generated flows. This method involves making two absolute-intensity measurements at the same wavelength in a specified gas sample, but using two different path lengths. Experimental results are presented for reflected shock waves in air and in xenon at conditions corresponding to shock velocities from 4 to 10 km/sec and an initial driven tube pressure of 1 torr. These results indicate that, with the technique, temperature measurements with an accuracy of 5% can be carried out. The measurements in air suggest certain facility-related problems, and results obtained in the application of this measurement technique to the investigation of these problems and to the study of radiative cooling phenomena in both air and xenon are presented.

Nerem, R. M.↗

Flight evaluation of a stagnation detection hot-film sensor

Results are presented of flight evaluation tests of a stagnation detection hot-film sensor. Experiments were conducted at steady level-flight conditions over a range of altitudes, angles of attack, and air speeds, as well as quasi-steady conditions during level-flight velocity acceleration and deceleration maneuvers. The results demonstrate the ability of a hot-film sensor to provide an accurate, reliable, and relatively nonintrusive measurement of the stagnation region in a flight environment. Stagnation could be identified within 0.1 inches.

Scott, Michael A.↗

Man-Made Closed Ecological Systems as Model of Natural Ecosystems and as Means to Provide High Quality of Human Life in Adverse Environment

For its more than thirty year long history, the experimental creation of closed ecological systems has from its very sources been distinctly and strongly motivated by the development of human life-support systems for space. As the trend developed its fundamental significance and broad opportunities of terrestrial applications of the technologies under development were coming to the foreground. Nowadays, it can be argued that development of closed ecosystems is experimental foundation of a new branch of ecology biospherics, the goal of which is to comprehend the regularities of existence of the biosphere as a unique in the Universe (in that part of it that we know, at least) closed ecosystem. Closed technologies can be implemented in life-support systems under adverse conditions of life on the Earth - in Arctic and Antarctic latitudes, deserts, high mountains or deep in the ocean, as well as under the conditions of polluted water and air. In space where the environment is hostile for life all around the cell of life should be sealed and the life-support system as close to the ideally closed cyclic turnover of the matter as possible. Under terrestrial conditions designers should strive for maximum closure of the limiting factor: water - in deserts, oxygen - in high mountains, energy - in polar latitudes, etc. Essential closure of a life-support systems withstands also pollution of the environment by the wastes of human vital activity. This is of particular importance for the quarantine of visited planets, and on the Earth under the conditions of deficient heat in high latitudes and water in and areas. The report describes experimental ecosystem 'BIOS' and exohabitats being designed on its basis, which are adapted to various conditions, described capacities of the Center for Closed Ecosystems in Drasnoyarsk for international collaboration in research and education in this field.

Gitelson, I. I.↗

The behavior of fuel-lean premixed flames in a standard flammability limit tube under controlled gravity conditions

Fuel-lean flames in methane-air mixtures from 4.90 to 6.20 volume percent fuel and propane-air mixtures from 1.90 to 3.00 volume percent fuel were studied in the vicinity of the limit for a variety of gravity conditions. The limits were determined and the behavior of the flames studied for one g upward, one g downward, and zero g propagation. Photographic records of all flammability tube firings were obtained. The structure and behavior of these flames were detailed including the variations of the curvature of the flame front, the skirt length, and the occurrence of cellular instabilities with varying gravity conditions. The effect of ignition was also discussed. A survey of flame speeds as a function of mixture strength was made over a range of lean mixture compositions for each of the fuels studied. The results were presented graphically with those obtained by other researchers. The flame speed for constant fractional gravity loadings were plotted as a function of gravity loadings from 0.0 up to 2.0 g's against flame speeds extracted from the transient gravity flame histories for corresponding gravity loadings. The effects of varying gravity conditions on the extinguishment process for upward and downward propagating flames were investigated.

Wherley, B. L.↗

Mass transfer coefficients, kL, and air-CO2 ingassing rates in 3.4 m2 and 1-acre raceway ponds.

The US DOE 2016 Billion Ton Update (Langholtz 2016) projected that CO2 in flue-gas from power plants or similar sources would limit U.S. algal biofuel potential to under 5 billion gallons gasoline equivalent (gge) per year, due to lack of sufficient land, water and other requirements near such flue gas sources. 2nd generation carbon capture technologies are proposed to overcome this constraint (Davis 2017), and could expand this resource potential nearly 10-fold, assuming CO2 costs near the future, 2025 DOE NETL, goal of $40/metric ton CO2. An alternative pathway is the direct uptake of air CO2 into the algal ponds through an increase in the air-CO2 transfer rate resulting from the reaction of CO2 with hydroxide ions. However, such a ‘chemical enhancement’ in mass transfer depends on a high pH in the culture, and, by extension, the ability of microalgae to maintain high rates of carbon assimilation under such conditions. Abiotic experiments characterized the air-CO2 mass-transfer rate in 1-acre and 3.4 m2 raceway ponds as a function of pH, with rates approaching 10 g C/m2-day at pH 12 in the brackish water tested, equivalent to a biomass productivity potential of near 20 g AFDW/m2-day (@ 0.47 g C/g AFDW). The mass transfer rate was found to be nearly independent of the mass-transfer coefficient, indicating that at turbulence levels achievable in typical raceway ponds, the system is reaction rate, rather than diffusion limited. In biotic trials with an unknown green microalga, biomass productivity in ponds receiving CO2 from only direct surface air-CO2 exchange averaged 5 +/- 0.5 g AFDW/m2-day in August - September central California conditions, about half-that of experimental controls fertilized with supplemental CO2. pH in the air-only treatment reached a maximum of 10.5, supporting a model predicted air-CO2 ingassing rate between 2-3 g C/m2-day, consistent with the observed biomass carbon assimilation rate. Results suggest that unique alkaliphilic strains are required if reliant on direct in-pond air-CO2 transfer for algal inorganic carbon supply, and that reaching an economically viable biomass productivity will require strains that thrive at pH 11 and above.

09 BIOMASS FUELS↗

Variability Analysis of FMVSS-121 Air Brake Systems: 60-mi/hr Service Brake System Performance Data for Truck Tractors

In support of the Federal Motor Carrier Safety Administration’s (FMCSA’s) ongoing interest in connected and automated commercial vehicles, this report summarizes analyses conducted to quantify variability in stopping distance tests conducted on commercial truck tractors. The data used were retrieved from tests performed under the controlled conditions specified for FMVSS-121 air brake system compliance testing. The report explores factors affecting the variability of the service brake stopping distance as defined by 49 CFR 571.121, S5.3.1 Stopping Distance—trucks and buses stopping distance. Variables examined in this analysis include brake type, weight, wheelbase, and tractor antilock braking system (ABS). This analysis uses existing test data collected between 2010 and 2019. Several of the examined parameters affected both tractor stopping distance and stopping distance variability. First, the average stopping distance for disc/disc brakes was shorter than either drum/drum or disc/drum brakes, but brake type did not have a statistically significant effect on stopping distance variability. Second, tractors with a gross vehicle weight rating (GVWR) of 45,000-50,000 lb had shorter stopping distances than any other examined weight category. Weight was found to have a significant effect on stopping distance variability; the 50,000-55,000-lb GVWR range had more variability than both the next lower (45,000-50,000 lb) and next higher (55,000-60,000 lb) range.

Lascurain, Mary Beth↗

Flame Shapes of Nonbuoyant Laminar Jet Diffusion Flames

The shapes (flame-sheet and luminous-flame boundaries) of steady nonbuoyant round hydrocarbon-fueled laminar-jet diffusion flames in still and coflowing air were studied both experimentally and theoretically. Flame-sheet shapes were measured from photographs using a CH optical filter to distinguish flame-sheet boundaries in the presence of blue CO2 and OH emissions and yellow continuum radiation from soot. Present experimental conditions included acetylene-, methane-, propane-, and ethylene-fueled flames having initial reactant temperatures of 300 K, ambient pressures of 4-50 kPa, jet exit Reynolds number of 3-54, initial air/fuel velocity ratios of 0-9 and luminous flame lengths of 5-55 mm; earlier measurements for propylene- and 1,3-butadiene-fueled flames for similar conditions were considered as well. Nonbuoyant flames in still air were observed at micro-gravity conditions; essentially nonbuoyant flames in coflowing air were observed at small pressures to control effects of buoyancy. Predictions of luminous flame boundaries from soot luminosity were limited to laminar smokepoint conditions, whereas predictions of flame-sheet boundaries ranged from soot-free to smokepoint conditions. Flame-shape predictions were based on simplified analyses using the boundary layer approximations along with empirical parameters to distinguish flame-sheet and luminous flame (at the laminar smoke point) boundaries. The comparison between measurements and predictions was remarkably good and showed that both flame-sheet and luminous-flame lengths are primarily controlled by fuel flow rates with lengths in coflowing air approaching 2/3 lengths in still air as coflowing air velocities are increased. Finally, luminous flame lengths at laminar smoke-point conditions were roughly twice as long as flame-sheet lengths at comparable conditions due to the presence of luminous soot particles in the fuel-lean region of the flames.

Xu, F.↗

Time-Resolved OH-PLIF Assessment of Deflagrations Levels in a CH4-O2 Rotating Detonation Rocket Combustor

The parasitic loss incurred by deflagrative pre-burning is considered to be one of the key challenges to the effective implementation of rotating detonation engine (RDE) systems. Thus far, there have been relatively limited high fidelity, spatio-temporally resolved measurements of the pre-burning process as a function of the reactant conditions and composition within an RDE. In this work, simultaneous high-repetition-rate broadband OH* chemiluminescence and OH planar laser-induced fluorescence (PLIF) imaging are employed to investigate deflagrative burning dynamics in a fully optically accessible CH4-O2 RDE as compared to a H2-air systems under the same conditions. A custom-built optical parametric oscillator (OPO) is coupled with a high-repetition-rate burst-mode laser to generate the 284 nm source for the excitation of the Q1(9) transition of the OH radical. Significant deflagrative burning is observed throughout the chamber as a consequence of the oxygen-rich environment. Trailing wave systems that consume unburned reactants in the region immediately following the primary detonation wave are observed. The formation of a product gas recirculation zone that entrains and combusts incoming reactants is observed, and quantitative analysis is performed to gain valuable insight into deflagration characteristics. At an oxidizer mass flux of Gox ≈ 350kg/m2/s, it is found that the levels of pre-wave burning in CH4-O2 are a factor of ∼2-3 times higher than in H2-air in the region directly ahead of the detonation wave at a global equivalence ratio Φ ≈ 1.0. This study highlights the key roles of ignition delay and turbulent mixing of the combustion product and reactant fields on the levels of pre-burning and establishes a methodology for further investigation, such as for the effects of various RDE inlet configurations.

Propulsion↗

Flame Shapes of Nonbuoyant Laminar Jet Diffusion Flames

The shapes (flame-sheet and luminous-flame boundaries) of steady nonbuoyant round hydrocarbon-fueled laminar-jet diffusion flames in still and coflowing air were studied both experimentally and theoretically. Flame-sheet shapes were measured from photographs using a CH optical filter to distinguish flame-sheet boundaries in the presence of blue C02 and OH emissions and yellow continuum radiation from soot. Present experimental conditions included acetylene-, methane-, propane-, and ethylene-fueled flames having initial reactant temperatures of 300 K, ambient pressures of 4-50 kPa, jet exit Reynolds number of 3-54, initial air/fuel velocity ratios of 0-9 and luminous flame lengths of 5-55 mm; earlier measurements for propylene- and 1,3-butadiene-fueled flames for similar conditions were considered as well. Nonbuoyant flames in still air were observed at micro-gravity conditions; essentially nonbuoyant flames in coflowing air were observed at small pressures to control effects of buoyancy. Predictions of luminous flame boundaries from soot luminosity were limited to laminar smoke-point conditions, whereas predictions of flame-sheet boundaries ranged from soot-free to smoke-point conditions. Flame-shape predictions were based on simplified analyses using the boundary layer approximations along with empirical parameters to distinguish flame-sheet and luminous-flame (at the laminar smoke point) boundaries. The comparison between measurements and predictions was remarkably good and showed that both flame-sheet and luminous-flame lengths are primarily controlled by fuel flow rates with lengths in coflowing air approaching 2/3 lengths in still air as coflowing air velocities are increased. Finally, luminous flame lengths at laminar smoke-point conditions were roughly twice as long as flame-sheet lengths at comparable conditions due to the presence of luminous soot particles in the fuel-lean region of the flames.

Xu, F.↗

Interactions between Per- and Polyfluoroalkyl Substances (PFAS) at the Water–Air Interface

Per- and polyfluoroalkyl substances (PFAS)--so-called “forever chemicals”--contaminate the drinking water of about 100 million people in the U.S. alone and are inefficiently removed by standard treatment techniques. A key property of these compounds that underlies their fate and transport and the efficacy of several promising remediation approaches is that they accumulate at the water−air interface. This phenomenon remains incompletely understood, particularly under conditions relevant to natural and treatment systems where water−air interfaces often carry significant loads of other organic contaminants or natural organic matter. To understand the impact of organic loading on PFAS adsorption, we carried out molecular dynamics simulations of PFAS at varying interfacial densities. We find that adsorbed PFAS form strong mutual interactions (attraction between perfluoroalkyl chains and electrostatic interactions among charged head groups) that give rise to ordered interfacial coatings. Furthermore, these interactions often involve near-cancellation of hydrophobic attraction and Coulomb repulsion. Our findings explain an apparent paradox whereby PFAS adsorption isotherms often suggest minimal mutual interactions while simultaneously displaying a high sensitivity to the composition and density of interfacial coatings. Consideration of the compounds present with PFAS at the interface has the potential to allow for more accurate predictions of fate and transport and the design of more efficient remediation approaches.

54 ENVIRONMENTAL SCIENCES↗

Operational Concept for the Smart Landing Facility (SLF)

The purpose of this document is to describe an operational concept for the Smart Landing Facility (SLF). The SLF is proposed as a component of the Small Aircraft Transportation System (SATS) and is envisioned to utilize Communication, Navigation, Surveillance and Air Traffic Management (CNS/ATM) technologies to support higher-volume air traffic operations in a wider variety of weather conditions than are currently possible at airports without an Air Traffic Control Tower (ATCT) or Terminal Radar Approach Control (TRACON). In order to accomplish this, the SLF will provide aircraft sequencing and separation within its terminal airspace (the SLF traffic area) and on the airport surface. The approach taken in this report is to first define and describe the SLF environment and the type of operations and aircraft that must be supported. Services currently provided by an ATCT and TRACON are reviewed and assembled into a set of high-level operational functions. A description of the applicable CNS/ATM technologies that have been deployed in the NAS (National Airspace System) or have been demonstrated to be operationally feasible is presented. A candidate SLF system concept that employs the CNS/ATM technologies is described. This is followed by SLF operational scenarios for minimally-equipped aircraft and for aircraft fully-equipped to make full use of SLF services. An assessment is made of the SLF technology and key research issues are identified.

Thompson, S. D.↗

Exhaust emissions survey of a turbofan engine for flame holder swirl type augmentors at simulated altitude flight conditions

Emissions of carbon dioxide, total oxides of nitrogen, unburned hydrocarbons, and carbon monoxide from an F100 afterburning two spool turbofan engine at simulated flight conditions are reported. Tests were run at Mach 0.8 at altitudes of 10.97 and 13.71 km (36,000 and 45,000 ft), and at Mach 1.2 at 13.71 km (45,000 ft). Emission measurements were made from intermediate power (nonafterburning) through maximum afterburning, using a single point gas sample probe traversed across the horizontal diameter of the exhaust nozzle. The data show that emissions vary with flight speed, altitude, power level, and radial position across the nozzle. Carbon monoxide emissions were low for intermediate and partial afterburning power. Unburned hydrocarbons were near zero for most of the simulated flight conditions. At maximum afterburning, there were regions of NOx deficiency in regions of high CO. The results suggest that the low NOx levels observed in the tests are a result of interaction with high CO in the thermal converter. CO2 emissions were proportional to local fuel air ratio for all test conditions.

Moss, J. E., Jr.↗

Infrared Signature Masking by Air Plasma Radiation

Detailed measurements and modeling of the spectral emission of an atmospheric pressure air plasma at temperatures up to -3400 K have been made. The cold gas injected in the plasma torch contained an estimated mole fraction of water vapor of approximately 4.5 x 10(exp -3) and an estimated carbon dioxide mole fraction of approximately 3.3 x 10(exp -4). Under these conditions, the minimum level of air plasma emission is found to be between 3.9 and 4.15 microns. Outside this narrow region, significant spectral emission is detected that can be attributed to the fundamental and overtone bands of NO and OH, and to the v(sub 3) and the (v(sub 1)+v(sub 3)) bands Of CO2. Special attention was paid to the effects of ambient air absorption in the optical path between the plasma and the detector. Excellent quantitative agreement is obtained between the measured and simulated spectra, which are both on absolute intensity scales, thus lending confidence in the radiation models incorporated into NEQAIR2-IR over the course of this research program.

Kruger, C. H.↗

Improving AIRS Radiance Spectra in High Contrast Scenes Using MODIS

The Atmospheric Infrared Sounder (AIRS) on the EOS Aqua Spacecraft was launched on May 4, 2002. AIRS acquires hyperspectral infrared radiances in 2378 channels ranging in wavelength from 3.7-15.4 microns with spectral resolution of better than 1200, and spatial resolution of 13.5 km with global daily coverage. The AIRS is designed to measure temperature and water vapor profiles for improvement in weather forecast accuracy and improved understanding of climate processes. As with most instruments, the AIRS Point Spread Functions (PSFs) are not the same for all detectors. When viewing a non-uniform scene, this causes a significant radiometric error in some channels that is scene dependent and cannot be removed without knowledge of the underlying scene. The magnitude of the error depends on the combination of non-uniformity of the AIRS spatial response for a given channel and the non-uniformity of the scene, but is typically only noticeable in about 1% of the scenes and about 10% of the channels. The current solution is to avoid those channels when performing geophysical retrievals. In this effort we use data from the Moderate Resolution Imaging Spectroradiometer (MODIS) instrument to provide information on the scene uniformity that is used to correct the AIRS data. For the vast majority of channels and footprints the technique works extremely well when compared to a Principal Component (PC) reconstruction of the AIRS channels. In some cases where the scene has high inhomogeneity in an irregular pattern, and in some channels, the method can actually degrade the spectrum. Most of the degraded channels appear to be slightly affected by random noise introduced in the process, but those with larger degradation may be affected by alignment errors in the AIRS relative to MODIS or uncertainties in the PSF. Despite these errors, the methodology shows the ability to correct AIRS radiances in non-uniform scenes under some of the worst case conditions and improves the ability to match AIRS and MODIS radiances in non-uniform scenes.

spatial↗

Selected contribution: redistribution of pulmonary perfusion during weightlessness and increased gravity

To compare the relative contributions of gravity and vascular structure to the distribution of pulmonary blood flow, we flew with pigs on the National Aeronautics and Space Administration KC-135 aircraft. A series of parabolas created alternating weightlessness and 1.8-G conditions. Fluorescent microspheres of varying colors were injected into the pulmonary circulation to mark regional blood flow during different postural and gravitational conditions. The lungs were subsequently removed, air dried, and sectioned into approximately 2 cm(3) pieces. Flow to each piece was determined for the different conditions. Perfusion heterogeneity did not change significantly during weightlessness compared with normal and increased gravitational forces. Regional blood flow to each lung piece changed little despite alterations in posture and gravitational forces. With the use of multiple stepwise linear regression, the contributions of gravity and vascular structure to regional perfusion were separated. We conclude that both gravity and the geometry of the pulmonary vascular tree influence regional pulmonary blood flow. However, the structure of the vascular tree is the primary determinant of regional perfusion in these animals.

short duration↗

In-Operando XRD Study of the Effects of Water Vapor on Phase Formation in LSM/YSZ SOFC Cathodes

Here, in-operando XRD was conducted on anode supported SOFC button cells with LSM-YSZ cathodes operated at varying cathode air compositions under constant current conditions for over 1000 h. 1-hour XRD scans were continuously collected throughout the entire operation duration. By taking the sum of measured intensities from all of the collected patterns, the resulting cumulative XRD count times allowed the identification of minor phases present at concentrations as low as <0.1 wt%. In dry air with no contaminants, the cathode exhibited improving power output during the first couple of hundred hours, followed by stable operation. The effect of 3% H 2 O + 12% CO 2 on the LSM-YSZ cathode was very similar to the effect of 3% H 2 O alone, exhibiting performance degradation. Increasing contaminants in the cathode air were found to decrease the performance of the cells. In-operando XRD discovered an increase in MnO concentration and decrease in La 2 O 3 . A gradual expansion of the LSM lattice resulting from loss of Sr or O was discovered in the LSM/YSZ cathodes tested in humid cathode air. The inverse relationship between the unit cell volume and operating voltage suggests a possible correlation between Sr segregation and performance degradation in the LSM/YSZ cathodes.

25 ENERGY STORAGE↗