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At least 1,405 records · Page 78

Detection of Forced Change Within Combined Climate Fields Using Explainable Neural Networks

Abstract Assessing forced climate change requires the extraction of the forced signal from the background of climate noise. Traditionally, tools for extracting forced climate change signals have focused on one atmospheric variable at a time, however, using multiple variables can reduce noise and allow for easier detection of the forced response. Following previous work, we train artificial neural networks to predict the year of single‐ and multi‐variable maps from forced climate model simulations. To perform this task, the neural networks learn patterns that allow them to discriminate between maps from different years—that is, the neural networks learn the patterns of the forced signal amidst the shroud of internal variability and climate model disagreement. When presented with combined input fields (multiple seasons, variables, or both), the neural networks are able to detect the signal of forced change earlier than when given single fields alone by utilizing complex, nonlinear relationships between multiple variables and seasons. We use layer‐wise relevance propagation, a neural network explainability tool, to identify the multivariate patterns learned by the neural networks that serve as reliable indicators of the forced response. These “indicator patterns” vary in time and between climate models, providing a template for investigating inter‐model differences in the time evolution of the forced response. This work demonstrates how neural networks and their explainability tools can be harnessed to identify patterns of the forced signal within combined fields.

54 ENVIRONMENTAL SCIENCES↗

Earth-system-model evaluation of cloud and precipitation occurrence for supercooled and warm clouds over the Southern Ocean's Macquarie Island

Abstract. Over the remote Southern Ocean (SO), cloud feedbacks contribute substantially to Earth system model (ESM) radiative biases. The evolution of low Southern Ocean clouds (cloud-top heights < ∼ 3 km) is strongly modulated by precipitation and/or evaporation, which act as the primary sink of cloud condensate. Constraining precipitation processes in ESMs requires robust observations suitable for process-level evaluations. A year-long subset (April 2016–March 2017) of ground-based profiling instrumentation deployed during the Macquarie Island Cloud and Radiation Experiment (MICRE) field campaign (54.5∘ S, 158.9∘ E) combines a 95 GHz (W-band) Doppler cloud radar, two lidar ceilometers, and balloon-borne soundings to quantify the occurrence frequency of precipitation from the liquid-phase cloud base. Liquid-based clouds at Macquarie Island precipitate ∼ 70 % of the time, with deeper and colder clouds precipitating more frequently and at a higher intensity compared to thinner and warmer clouds. Supercooled cloud layers precipitate more readily than layers with cloud-top temperatures > 0 ∘C, regardless of the geometric thickness of the layer, and also evaporate more frequently. We further demonstrate an approach to employ these observational constraints for evaluation of a 9-year GISS-ModelE3 ESM simulation. Model output is processed through the Earth Model Column Collaboratory (EMC2) radar and lidar instrument simulator with the same instrument specifications as those deployed during MICRE, therefore accounting for instrument sensitivities and ensuring a coherent comparison. Relative to MICRE observations, the ESM produces a smaller cloud occurrence frequency, smaller precipitation occurrence frequency, and greater sub-cloud evaporation. The lower precipitation occurrence frequency by the ESM relative to MICRE contrasts with numerous studies that suggest a ubiquitous bias by ESMs to precipitate too frequently over the SO when compared with satellite-based observations, likely owing to sensitivity limitations of spaceborne instrumentation and different sampling methodologies for ground- versus space-based observations. Despite these deficiencies, the ESM reproduces the observed tendency for deeper and colder clouds to precipitate more frequently and at a higher intensity. The ESM also reproduces specific cloud regimes, including near-surface clouds that account for ∼ 25 % of liquid-based clouds during MICRE and optically thin, non-precipitating clouds that account for ∼ 27 % of clouds with bases higher than 250 m. We suggest that the demonstrated framework, which merges observations with appropriately constrained model output, is a valuable approach to evaluate processes responsible for cloud radiative feedbacks in ESMs.

54 ENVIRONMENTAL SCIENCES↗

Description of historical and future projection simulations by the global coupled E3SMv1.0 model as used in CMIP6

Abstract. This paper documents the experimental setup and general features of the coupled historical and future climate simulations with the first version of the US Department of Energy (DOE) Energy Exascale Earth System Model (E3SMv1.0). The future projected climate characteristics of E3SMv1.0 at the highest emission scenario (SSP5-8.5) designed in the Scenario Model Intercomparison Project (ScenarioMIP) and the SSP5-8.5 greenhouse gas (GHG) only forcing experiment are analyzed with a focus on regional responses of atmosphere, ocean, sea ice, and land. Due to its high equilibrium climate sensitivity (ECS of 5.3 K), E3SMv1.0 is one of the Coupled Model Intercomparison Project phase 6 (CMIP6) models with the largest surface warming by the end of the 21st century under the high-emission SSP5-8.5 scenario. The global mean precipitation change is highly correlated with the global temperature change, while the spatial pattern of the change in runoff is consistent with the precipitation changes. The oceanic mixed layer generally shoals throughout the global ocean. The annual mean Atlantic meridional overturning circulation (AMOC) is overly weak with a slower change from ∼ 11 to ∼ 6 Sv (Sverdrup) relative to other CMIP6 models. The sea ice, especially in the Northern Hemisphere, decreases rapidly with large seasonal variability. We detect a significant polar amplification in E3SMv1.0 from the atmosphere, ocean, and sea ice. Comparing the SSP5-8.5 all-forcing experiment with the GHG-only experiment, we find that the unmasking of the aerosol effects due to the decline of the aerosol loading in the future projection period causes transient accelerated warming in the all-forcing experiment in the first half of the 21st century. While the oceanic climate response is mainly controlled by the GHG forcing, the land runoff response is impacted primarily by forcings other than GHG over certain regions, e.g., southern North America, southern Africa, central Africa, and eastern Asia. However, the importance of the GHG forcing on the land runoff changes grows in the future climate projection period compared to the historical period.

54 ENVIRONMENTAL SCIENCES↗

The effects of different types of mulch on soil properties and tea production and quality

Abstract BACKGROUND Tea is an important economic crop in China. Mulching, a modern agricultural practice, can modify the soil microenvironment and maintain the crop yield. RESULTS To investigate the effect of different mulching modes on tea plant growth, filed experiments were conducted in a Shizipu tea plantation located in Langxi Country (Xuanchen City, Anhui Province, China). Five treatments were carried out in a randomized complete block arrangement: (i) clean tillage (control); (ii) black plastic film; (iii) weed barrier fabric; (iv) rice straw mulch; and (v) intercropping with Vulpia myuros . The effects of different mulch modes on soil temperature, water moisture, soil compactness, root activity, soil enzyme activity and nutrition status on tea yield, quality and economic benefits were compared at the harvest stage. In the present study, compared with other mulch treatments, intercropping with V. myuros significantly reduced the topsoil temperature (to an optimum temperature) and soil compactness, and increased the water holding capacity in the deep soil layer, which contributed to increased tea root activity and respiration. Furthermore, intercropping with V. myuros significantly increased soil enzymes activity, soil organic matter, and the available nitrogen and phosphorus concentrations in the main root zone. Therefore, the stronger tea root activity accelerated nutrition uptake and increased the tea yield and quality‐related components of the tea, thus resulting in a larger average net income. CONCLUSION Intercropping with V. myuros could serve as a profitable agricultural method for tea production. © 2020 Society of Chemical Industry

Xianchen, Zhang↗

Spin injection by spin–charge coupling in proximity induced magnetic graphene

Abstract Within the field of spintronics major efforts are directed towards developing applications for spin-based transport devices made fully out of two-dimensional materials. In this work we present an experimental realization of a spin-valve device where the generation of the spin signal is exclusively attributed to the spin-dependent conductivity of the magnetic graphene resulting from the proximity of an interlayer antiferromagnet, chromium sulfide bromide (CrSBr). We clearly demonstrate that the usage of the conventional air-sensitive 3D magnetic contacts can be fully avoided when graphene/CrSBr heterostructures are employed. Moreover, apart from providing exceptionally long spin relaxation length, the usage of graphene for both generation and transport of the spin allows to automatically avoid the conductivity mismatch between the source and the channel circuits that has to be considered when using conventional low-resistive contacts. Our results address a necessary step in the engineering of spintronic circuitry out of layered materials and precede further developments in the area of complex spin-logic devices. Moreover, we introduce a fabrication procedure where we designed and implemented a recipe for the preparation of electrodes via a damage-free technique that offers an immediate advantage in the fields of air-sensitive and delicate organic materials.

36 MATERIALS SCIENCE↗

Direct Numerical Simulation of Transitional and Turbulent Flows Over Multi-Scale Surface Roughness—Part II: The Effect of Roughness on the Performance of a High-Pressure Turbine Blade

Abstract Turbine blades generally present surface roughness introduced in the manufacturing process or caused by in-service degradation, which can have a significant impact on aero-thermal performance. A better understanding of the fundamental physical mechanisms arising from the interaction between the roughness and the turbine flow at engine-relevant conditions can provide insights for the design of blades with improved efficiency and longer operational life. To this end, a high-fidelity numerical framework combining a well-validated solver for direct numerical simulation and a second-order accurate immersed boundary method is employed to predict roughness-induced aero-thermal effects on an LS89 high-pressure turbine (HPT) blade at engine-relevant conditions. Different amplitudes and distributions of surface roughness are investigated and a reference smooth-blade simulation under the same flow conditions is conducted for comparison. Roughness of increasing amplitude progressively shifts the blade suction side boundary layer transition upstream, producing larger values of the turbulent kinetic energy and higher total wake losses. The on-surface data-capturing capabilities of the numerical framework provide direct measurements of the heat flux and the skin friction coefficient, hence offering quantitative information between the surface topology and engineering-relevant performance parameters. This work may provide a benchmark for future numerical studies of turbomachinery flows with roughness.

Engineering↗

Misaligned Wind‐Waves Behind Atmospheric Cold Fronts

Abstract Atmospheric fronts embedded in extratropical cyclones are high‐impact weather phenomena, contributing significantly to mid‐latitude winter precipitation. The three vital characteristics of the atmospheric fronts, high wind speeds, abrupt change in wind direction, and rapid translation, force the induced surface waves to be misaligned with winds exclusively behind the cold fronts. The effects of the misaligned waves under atmospheric cold fronts on air‐sea fluxes remain undocumented. Using the multi‐year in situ near‐surface observations and direct covariance flux measurements from the Pioneer Array off the coast of New England, we find that the majority of the passing cold fronts generate misaligned waves behind the cold front. Once generated, the waves remain misaligned, on average, for about 8 hr. The parameterized effect of misaligned waves in a fully coupled model significantly increases the roughness length (185%), drag coefficient (19%), and air‐sea momentum flux (11%). The increased surface drag reduces the wind speeds in the surface layer. The upward turbulent heat flux is weakly decreased by the misaligned waves because of the decrease in temperature and humidity scaling parameters being greater than the increase in friction velocity. The misaligned wave effect is not accurately represented in a commonly used wave‐based bulk flux algorithm. Yet, considering this effect in the current formulation improves the overall accuracy of parameterized momentum flux estimates. The results imply that better representing a directional wind‐wave coupling in the bulk formula of the numerical models may help improve the air‐sea interaction simulations under the passing atmospheric fronts in the mid‐latitudes.

Oceanography↗

Direct measurement of ferroelectric polarization in a tunable semimetal

Abstract Ferroelectricity, the electrostatic counterpart to ferromagnetism, has long been thought to be incompatible with metallicity due to screening of electric dipoles and external electric fields by itinerant charges. Recent measurements, however, demonstrated signatures of ferroelectric switching in the electrical conductance of bilayers and trilayers of WTe 2 , a semimetallic transition metal dichalcogenide with broken inversion symmetry. An especially promising aspect of this system is that the density of electrons and holes can be continuously tuned by an external gate voltage. This degree of freedom enables measurement of the spontaneous polarization as free carriers are added to the system. Here we employ capacitive sensing in dual-gated mesoscopic devices of bilayer WTe 2 to directly measure the spontaneous polarization in the metallic state and quantify the effect of free carriers on the polarization in the conduction and valence bands, separately. We compare our results to a low-energy model for the electronic bands and identify the layer-polarized states that contribute to transport and polarization simultaneously. Bilayer WTe 2 is thus shown to be a fully tunable ferroelectric metal and an ideal platform for exploring polar ordering, ferroelectric transitions, and applications in the presence of free carriers.

36 MATERIALS SCIENCE↗

Advances in the Large Area Picosecond Photo-Detector (LAPPD TM ): 8" × 8" MCP-PMT with Capacitively Coupled Readout

Abstract We present advances made in the Large Area Picosecond Photodetector (LAPPD), an 8" × 8" microchannel plate photomultiplier tube (MCP-PMT), since pilot production was initiated at Incom, Inc. in 2018. The Gen-I LAPPD utilizes a stripline anode for direct charge readout. The novel Gen-II LAPPD employs an internal resistive thin-film which capacitively couples to a customizable external signal readout board, streamlining production and increasing customer flexibility. The Gen-II LAPPD, with an active area of 373 cm 2 , is capable of high single photoelectron (PE) gain of ∼10 7 , low dark rates (∼1 kHz/cm 2 ), single PE (SPE) timing resolution of ∼65 ps, and 𝒪(mm) position resolution. Coupled with a UV-grade fused silica window, the LAPPD features a high quantum efficiency (QE) bialkali photocathode of >30% at 365 nm with spectral response down to ∼165 nm. The LAPPD is an excellent candidate for electromagnetic calorimeter (ECAL) timing layers, photon-based neutrino detectors, high energy collider experiments, medical imaging systems, and nuclear non-proliferation applications.

Instruments & Instrumentation↗

Traces of electron-phonon coupling in one-dimensional cuprates

Abstract The appearance of certain spectral features in one-dimensional (1D) cuprate materials has been attributed to a strong, extended attractive coupling between electrons. Here, using time-dependent density matrix renormalization group methods on a Hubbard-extended Holstein model, we show that extended electron-phonon ( e–ph ) coupling presents an obvious choice to produce such an attractive interaction that reproduces the observed spectral features and doping dependence seen in angle-resolved photoemission experiments: diminished 3 k F spectral weight, prominent spectral intensity of a holon-folding branch, and the correct holon band width. While extended e–ph coupling does not qualitatively alter the ground state of the 1D system compared to the Hubbard model, it quantitatively enhances the long-range superconducting correlations and suppresses spin correlations. Such an extended e–ph interaction may be an important missing ingredient in describing the physics of the structurally similar two-dimensional high-temperature superconducting layered cuprates, which may tip the balance between intertwined orders in favor of uniform d -wave superconductivity.

36 MATERIALS SCIENCE↗

Towards developing robust solid lubricant operable in multifarious environments

Abstract Conventional solid lubricants such as MoS 2 , graphite, or diamond-like carbon films demonstrate excellent tribological performance but only in specific environments due to their inherent materials properties. This limitation prohibits using these solid lubricants in environments that change dynamically. This study presents the results of a novel solid lubricant that was developed using a combination of solution-processed 2D-molybdenum disulfide and graphene-oxide (GO) that can be deposited on to stainless steel substrates using a simple spray-coating technique and show exceptional performance in multifarious environments namely, ambient (humid) atmosphere, dry nitrogen, and vacuum. The tribological performance of the coatings was evaluated using a ball-on-disc sliding test and demonstrated an excellent wear/friction performance in all environments and coating survived even after 44 km of linear sliding. Transmission electron microscopy and Raman spectroscopy analysis of the tribolayers suggested in-operando friction-induced re-orientation of MoS 2 layers that were protected by GO layers and, an absence of MoO x peaks indicate a strong resistance to intercalation with moisture and oxygen. The simplicity and robustness of the hybrid MoS 2 –GO solid lubricant in mitigating wear-friction behavior of steel-on-steel tribopair in a multifarious environment is a game-changing and is promising for various applications.

36 MATERIALS SCIENCE↗

TOI-220 b : a warm sub-Neptune discovered by TESS

ABSTRACT In this paper, we report the discovery of TOI-220 b, a new sub-Neptune detected by the Transiting Exoplanet Survey Satellite (TESS) and confirmed by radial velocity follow-up observations with the HARPS spectrograph. Based on the combined analysis of TESS transit photometry and high precision radial velocity measurements, we estimate a planetary mass of 13.8 ± 1.0 M⊕ and radius of 3.03 ± 0.15 R⊕, implying a bulk density of 2.73 ± 0.47 $\rm {g\,cm}^{-3}$. TOI-220 b orbits a relative bright (V= 10.4) and old (10.1 ± 1.4 Gyr) K dwarf star with a period of ∼10.69 d. Thus, TOI-220 b is a new warm sub-Neptune with very precise mass and radius determinations. A Bayesian analysis of the TOI-220 b internal structure indicates that due to the strong irradiation it receives, the low density of this planet could be explained with a steam atmosphere in radiative–convective equilibrium and a supercritical water layer on top of a differentiated interior made of a silicate mantle and a small iron core.

Hoyer, S.↗

Effect of surface oxides on tritium entrance and permeation in FeCrAl alloys for nuclear fuel cladding: a review

Abstract Iron-chromium-aluminum (FeCrAl) alloys are being considered for the cladding of uranium dioxide fuel in light water reactors (LWRs). FeCrAl alloys have good mechanical properties at temperatures of 300 °C and higher, and have superlative resistance to attack by steam at temperatures of up to 1000 °C and higher. A concern has been raised that the use of FeCrAl for cladding would result in a higher content of tritium in the reactor coolant as compared with the current system where the cladding is a zirconium based alloy. This review shows that the flux of tritium from the fuel rod cavities to the coolant across the fuel cladding wall will be greatly reduced by the presence of oxides on the surface of the cladding. The review of current literature and permeation data show that (a) protective oxides are expected to be present on both sides of the FeCrAl cladding, and (b) depending on the characteristics of these oxide layers it is reasonable to expect about two–three orders of magnitude reduction in tritium permeation, relative to the permeation response in clean, unoxidized condition for FeCrAl steels of interest, around 277 °C–377 °C temperatures.

Electrochemistry↗

Freestanding BaTiO 3 ‐Au Vertically Aligned Nanocomposite toward Flexible Multi‐Sensing Platform

Abstract Flexible and wearable sensors show enormous potential for personalized healthcare devices by real‐time monitoring of an individual's health. Typically, a single functional material is selected for one sensor to sense a particular physical signal while multiple materials will be selected for multi‐mode sensing. Vertically aligned nanocomposites (VANs) have recently demonstrated various material combinations and novel coupled multifunctionalities that are hard to achieve in any single‐phase material alone, including multiphase multiferroics, magneto‐optic coupling, and strong magnetic and optical anisotropy. Integrating these novel VANs into wearable sensors shows enormous potential in multi‐mode sensing owing to their multifunctional nature. In this work, the transfer of VANs onto polydimethylsiloxane as a novel flexible chemical and pressure sensor is demonstrated. For this demonstration, the classical BaTiO 3 ‐Au VAN with combined plasmonic and piezoelectric properties is used to demonstrate a multi‐sensing mechanism. A thin water‐soluble buffer of Sr 3 Al 2 O 6 serves as a buffer layer for the epitaxial growth and transfer process. The electrical output based on the piezoelectric responses and identifying 4‐mercaptobenzoic acid by surface‐enhanced Raman spectroscopy reveal great potential for free‐standing VANs in a wearable multifunctional sensing platform.

Tsai, Benson Kunhung [School of Materials Engineer↗

Evaluating Shallow Convection Parameterization Assumptions With a q t – w Quadrant Analysis

Abstract Uncertainties associated with the response of shallow clouds to global warming remain a great challenge for climate projection. Due to the small size of these clouds, parameterizations are required to represent them in both current‐ and next‐generation climate models. We present a quantitative evaluation of several important assumptions used in both mass‐flux and Assumed‐PDF Higher‐Order Closure parameterizations of shallow convection. We use large‐eddy simulations (LESs) of four different shallow convection regimes as benchmarks and apply a q t (total moisture)– w (vertical velocity) quadrant analysis technique to identify the “coherent structures” of moist and dry up/down‐drafts. The statistics of these coherent structures and the environment are then used to evaluate commonly used assumptions in mass‐flux parameterizations related to (a) the convective downdrafts and (b) the subplume variability of convective updrafts. For quantitative evaluation of the PDF closure used in AP‐HOCs, we perform offline calculations with the PDF closure used in the Cloud Layers Unified By Bi‐normals and the Simplified Higher‐Order Closure schemes by supplying the closure with statistical quantities directly calculated from the LESs. Then, the impact of parameterization assumptions embedded in the PDF closure in the same two categories is analyzed and understood through comparisons of the output from the closure with the statistics of the moist and dry up/down‐drafts from the LESs.

54 ENVIRONMENTAL SCIENCES↗

Effect of metal/dielectric substrates on photopolymerization of BITh thin films

Abstract We have studied effects of metal–dielectric substrates on photopolymerization of [2,2ʹ-Bi-1H-indene]-1,1ʹ-dione-3,3ʹ-diyl diheptanoate (BITh) monomer. We synthetized BITh and spin-coated it onto a variety of dielectric, metallic, and metal–dielectric substrates. The films were exposed to radiation of a UV–Visible Xe lamp, causing photo-polymerization of monomer molecules. The magnitude and the rate of the photo-polymerization were monitored by measuring the strength of the ~ 480 nm absorption band, which existed in the monomer but not in the polymer. Expectedly, the rate of photo-polymerization changed nearly linearly with the change of the pumping intensity. In contrast with our early study of photo-degradation of semiconducting polymer P3HT, the rate of photo-polymerization of BITh is getting modestly higher if the monomer film is deposited on top of silver separated from the monomer by a thin insulating MgF 2 layer preventing a charge transfer. This effect is partly due to a constructive interference of the incident and reflected light waves, as well as known in the literature effects of metal/dielectric substrates on a variety of spectroscopic and energy transfer parameters. At the same time, the rate of photopolymerization is getting threefold larger if monomer is deposited on Ag film directly and charge transfer is allowed. Finally, Au substrates cause modest (~ 50%) enhancement of both monomer film absorption and the rate of photo-polymerization.

36 MATERIALS SCIENCE↗

Short-Term Energy and Meteorological Impacts on Thanksgiving CO2 in Salt Lake City

Abstract Long-term, high-frequency atmospheric CO2 measurements at multiple sites in the Salt Lake City (SLC), Utah, reveal that annual and monthly CO2 variability aligns with a priori estimates of emissions from anthropogenic and biological sources. In this study, we investigate whether short-term fluctuations in anthropogenic emissions, as captured in the Vulcan3 dataset for the United States, can be detected in atmospheric CO2 observations. Specifically, we focus on Thanksgiving holidays, when traffic and energy usage patterns differ from the rest of November. Onroad CO2 emissions exhibit a double peak during weekday morning and evening rush hours but remain relatively low on weekends and Thanksgiving. Interestingly, CO2 mole fractions during Thanksgiving were higher than the rest of November at all SLC monitoring sites, particularly from 2008 to 2013. This increase is partially attributed to elevated energy-related emissions — especially residential sources — and meteorological factors such as weak wind speeds, cold temperature, and a low planetary boundary layer height (PBLH).&#xD;&#xD; While CO₂ emissions and mole fraction patterns align over time, notable spatial differences exist. For instance, the near-highway site in Murray shows the highest CO₂ mole fractions despite low local emissions, suggesting pollution transport via highways and wind advection. Random Forest model-based SHapley Additive exPlanations (SHAP) analysis reveals that onroad emissions dominate CO2 contributions on weekdays and weekends, while energy-related emissions play a larger role during Thanksgiving, alongside meteorological drivers such as wind speed and PBLH. Across six urban cities, CO2 emissions display a consistent pattern: residential and commercial (onroad) emissions peak during Thanksgiving (weekday) with substantial (minimal) year-to-year variability. These findings highlight that urban CO₂ variability is driven by the combined influence of emissions and meteorology, underscoring the need for integrated mitigation strategies. Additionally, multi-site measurements are essential for accurate source attribution and the development of effective policy interventions. &#xD;

Ryoo, Ju-Mee (ORCID:0000000234256296)↗