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YHfRh2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two YHfRh2 ribbons oriented in the (1, 0, 0) direction. Y is bonded in a linear geometry to two equivalent Rh atoms. Both Y–Rh bond lengths are 2.57 Å. Hf is bonded in a linear geometry to two equivalent Rh atoms. Both Hf–Rh bond lengths are 2.30 Å. Rh is bonded in a linear geometry to one Y and one Hf atom.
ScRhGe crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Sc is bonded in a 11-coordinate geometry to six equivalent Rh and five equivalent Ge atoms. There are a spread of Sc–Rh bond distances ranging from 2.90–3.17 Å. There are four shorter (2.88 Å) and one longer (2.89 Å) Sc–Ge bond lengths. Rh is bonded in a 10-coordinate geometry to six equivalent Sc and four equivalent Ge atoms. There are a spread of Rh–Ge bond distances ranging from 2.50–2.55 Å. Ge is bonded in a 9-coordinate geometry to five equivalent Sc and four equivalent Rh atoms.
HfRh2Ge crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two HfRh2Ge ribbons oriented in the (1, 0, 0) direction. Hf is bonded in a linear geometry to two equivalent Rh atoms. Both Hf–Rh bond lengths are 2.21 Å. Rh is bonded in a linear geometry to one Hf and one Ge atom. The Rh–Ge bond length is 2.35 Å. Ge is bonded in a linear geometry to two equivalent Rh atoms.
CaRh2Sb crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two CaRh2Sb ribbons oriented in the (1, 0, 0) direction. Ca is bonded in a linear geometry to two equivalent Rh atoms. Both Ca–Rh bond lengths are 2.53 Å. Rh is bonded in a linear geometry to one Ca and one Sb atom. The Rh–Sb bond length is 2.40 Å. Sb is bonded in a linear geometry to two equivalent Rh atoms.
Yb3Rh4Ge13 crystallizes in the cubic Pm-3n space group. The structure is three-dimensional. Yb is bonded in a 8-coordinate geometry to four equivalent Rh and twelve equivalent Ge atoms. All Yb–Rh bond lengths are 3.19 Å. There are eight shorter (3.14 Å) and four longer (3.24 Å) Yb–Ge bond lengths. Rh is bonded in a 6-coordinate geometry to three equivalent Yb and six equivalent Ge atoms. All Rh–Ge bond lengths are 2.50 Å. There are two inequivalent Ge sites. In the first Ge site, Ge is bonded in a 2-coordinate geometry to three equivalent Yb, two equivalent Rh, and two Ge atoms. There are one shorter (2.64 Å) and one longer (3.07 Å) Ge–Ge bond lengths. In the second Ge site, Ge is bonded in a cuboctahedral geometry to twelve equivalent Ge atoms.
Sm2Rh2Cd crystallizes in the tetragonal P4/mbm space group. The structure is three-dimensional. Sm is bonded in a 6-coordinate geometry to six equivalent Rh and four equivalent Cd atoms. There are two shorter (2.88 Å) and four longer (3.00 Å) Sm–Rh bond lengths. All Sm–Cd bond lengths are 3.42 Å. Rh is bonded in a 9-coordinate geometry to six equivalent Sm and two equivalent Cd atoms. Both Rh–Cd bond lengths are 2.96 Å. Cd is bonded to eight equivalent Sm and four equivalent Rh atoms to form a mixture of distorted face and corner-sharing CdSm8Rh4 cuboctahedra.
Re3Rh is beta Cu3Ti-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. there are two inequivalent Re sites. In the first Re site, Re is bonded to eight Re and four equivalent Rh atoms to form distorted ReRe8Rh4 cuboctahedra that share corners with four equivalent RhRe12 cuboctahedra, corners with fourteen equivalent ReRe8Rh4 cuboctahedra, edges with six equivalent RhRe12 cuboctahedra, edges with twelve ReRe8Rh4 cuboctahedra, faces with four equivalent RhRe12 cuboctahedra, and faces with sixteen ReRe8Rh4 cuboctahedra. There are six shorter (2.69 Å) and two longer (2.89 Å) Re–Re bond lengths. There are two shorter (2.76 Å) and two longer (2.79 Å) Re–Rh bond lengths. In the second Re site, Re is bonded to eight equivalent Re and four equivalent Rh atoms to form distorted ReRe8Rh4 cuboctahedra that share corners with four equivalent RhRe12 cuboctahedra, corners with fourteen ReRe8Rh4 cuboctahedra, edges with six equivalent RhRe12 cuboctahedra, edges with twelve equivalent ReRe8Rh4 cuboctahedra, faces with four equivalent RhRe12 cuboctahedra, and faces with sixteen ReRe8Rh4 cuboctahedra. There are two shorter (2.76 Å) and two longer (2.79 Å) Re–Rh bond lengths. Rh is bonded to twelve Re atoms to form RhRe12 cuboctahedra that share corners with six equivalent RhRe12 cuboctahedra, corners with twelve ReRe8Rh4 cuboctahedra, edges with eighteen ReRe8Rh4 cuboctahedra, faces with eight equivalent RhRe12 cuboctahedra, and faces with twelve ReRe8Rh4 cuboctahedra.
RhO6PO4 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight phosphoric acid molecules and eight RhO6 clusters. In each RhO6 cluster, Rh is bonded in a distorted octahedral geometry to six O atoms. All Rh–O bond lengths are 1.93 Å. There are three inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Rh atom. In the second O site, O is bonded in a single-bond geometry to one Rh atom. In the third O site, O is bonded in a single-bond geometry to one Rh atom.
La2RhSi3 crystallizes in the hexagonal P6_3/mmc space group. The structure is three-dimensional. there are two inequivalent La sites. In the first La site, La is bonded to twelve equivalent Si atoms to form LaSi12 cuboctahedra that share edges with twelve equivalent LaSi8Rh4 cuboctahedra and faces with eight LaSi12 cuboctahedra. There are six shorter (3.21 Å) and six longer (3.23 Å) La–Si bond lengths. In the second La site, La is bonded to four equivalent Rh and eight equivalent Si atoms to form a mixture of face and edge-sharing LaSi8Rh4 cuboctahedra. There are two shorter (3.21 Å) and two longer (3.24 Å) La–Rh bond lengths. There are four shorter (3.22 Å) and four longer (3.25 Å) La–Si bond lengths. Rh is bonded in a 3-coordinate geometry to six equivalent La and three equivalent Si atoms. All Rh–Si bond lengths are 2.42 Å. Si is bonded in a 1-coordinate geometry to six La, one Rh, and two equivalent Si atoms. Both Si–Si bond lengths are 2.40 Å.
Sr(RhGa)2 is alpha Pu-derived structured and crystallizes in the orthorhombic Fddd space group. The structure is three-dimensional. Sr is bonded in a 6-coordinate geometry to eight equivalent Rh and ten equivalent Ga atoms. There are four shorter (3.31 Å) and four longer (3.53 Å) Sr–Rh bond lengths. There are a spread of Sr–Ga bond distances ranging from 3.38–3.77 Å. Rh is bonded in a 4-coordinate geometry to four equivalent Sr and four equivalent Ga atoms. There are two shorter (2.44 Å) and two longer (2.49 Å) Rh–Ga bond lengths. Ga is bonded in a 4-coordinate geometry to five equivalent Sr and four equivalent Rh atoms.
PrRhGe crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Pr is bonded in a 12-coordinate geometry to six equivalent Rh and six equivalent Ge atoms. There are a spread of Pr–Rh bond distances ranging from 3.02–3.37 Å. There are a spread of Pr–Ge bond distances ranging from 3.14–3.23 Å. Rh is bonded in a 10-coordinate geometry to six equivalent Pr and four equivalent Ge atoms. There are a spread of Rh–Ge bond distances ranging from 2.60–2.76 Å. Ge is bonded in a 10-coordinate geometry to six equivalent Pr and four equivalent Rh atoms.
NaCa2Rh is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Na is bonded in a 8-coordinate geometry to eight equivalent Ca and six equivalent Rh atoms. All Na–Ca bond lengths are 3.18 Å. All Na–Rh bond lengths are 3.67 Å. Ca is bonded in a distorted body-centered cubic geometry to four equivalent Na and four equivalent Rh atoms. All Ca–Rh bond lengths are 3.18 Å. Rh is bonded in a body-centered cubic geometry to six equivalent Na and eight equivalent Ca atoms.
RhGe4 crystallizes in the trigonal P3_121 space group. The structure is three-dimensional. Rh is bonded in a 8-coordinate geometry to eight Ge atoms. There are a spread of Rh–Ge bond distances ranging from 2.55–2.64 Å. There are three inequivalent Ge sites. In the first Ge site, Ge is bonded in a 2-coordinate geometry to two equivalent Rh atoms. In the second Ge site, Ge is bonded in a 4-coordinate geometry to two equivalent Rh and two equivalent Ge atoms. Both Ge–Ge bond lengths are 2.62 Å. In the third Ge site, Ge is bonded in a 2-coordinate geometry to two equivalent Rh and one Ge atom.
PuEuRh2 is Heusler structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Pu is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Pu–Rh bond lengths are 2.99 Å. Eu is bonded in a body-centered cubic geometry to eight equivalent Rh atoms. All Eu–Rh bond lengths are 2.99 Å. Rh is bonded in a body-centered cubic geometry to four equivalent Pu and four equivalent Eu atoms.
U3Rh3Bi4 crystallizes in the cubic I-43d space group. The structure is three-dimensional. U is bonded in a 12-coordinate geometry to four equivalent Rh and eight equivalent Bi atoms. All U–Rh bond lengths are 3.00 Å. There are four shorter (3.34 Å) and four longer (3.45 Å) U–Bi bond lengths. Rh is bonded in a 8-coordinate geometry to four equivalent U and four equivalent Bi atoms. All Rh–Bi bond lengths are 2.76 Å. Bi is bonded in a 3-coordinate geometry to six equivalent U and three equivalent Rh atoms.
W2Rh2C is H-Phase-like structured and crystallizes in the trigonal R-3m space group. The structure is three-dimensional. W is bonded to nine equivalent W and three equivalent Rh atoms to form WRh3W9 cuboctahedra that share corners with six equivalent WRh3W9 cuboctahedra, corners with six equivalent CRh6 octahedra, edges with twelve equivalent WRh3W9 cuboctahedra, faces with twelve equivalent WRh3W9 cuboctahedra, and a faceface with one CRh6 octahedra. The corner-sharing octahedral tilt angles are 43°. There are six shorter (2.85 Å) and three longer (2.94 Å) W–W bond lengths. All W–Rh bond lengths are 2.81 Å. Rh is bonded in a 3-coordinate geometry to three equivalent W and three equivalent C atoms. All Rh–C bond lengths are 2.09 Å. C is bonded to six equivalent Rh atoms to form CRh6 octahedra that share corners with twelve equivalent WRh3W9 cuboctahedra, edges with six equivalent CRh6 octahedra, and faces with two equivalent WRh3W9 cuboctahedra.
YbRhZn crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Yb is bonded in a 5-coordinate geometry to five equivalent Rh atoms. There are two shorter (2.90 Å) and three longer (2.94 Å) Yb–Rh bond lengths. Rh is bonded in a 9-coordinate geometry to five equivalent Yb and four equivalent Zn atoms. There are two shorter (2.59 Å) and two longer (2.60 Å) Rh–Zn bond lengths. Zn is bonded in a 4-coordinate geometry to four equivalent Rh atoms.
ScFeRh2 crystallizes in the orthorhombic Immm space group. The structure is one-dimensional and consists of two ScFeRh2 ribbons oriented in the (1, 0, 0) direction. Sc is bonded in a linear geometry to two equivalent Rh atoms. Both Sc–Rh bond lengths are 2.18 Å. Fe is bonded in a linear geometry to two equivalent Rh atoms. Both Fe–Rh bond lengths are 2.31 Å. Rh is bonded in a linear geometry to one Sc and one Fe atom.