SEARCH · Engineering Papers

Results for “Particle characterization”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,405 records · Page 78

All sources NASA NTRS DOE OSTI

DOE OSTI2025

Probing Plasmonic Near-Fields in Oxide-Modified Aluminum Nanocubes Using Photon-Induced Near-Field Electron Microscopy

Plasmonic nanoparticles generate strong electric fields near their surface upon photoexcitation, enabling applications in sensing, spectroscopy, and photocatalysis. Electron microscopy techniques – such as cathodoluminescence and electron energy loss spectroscopy – have been leveraged to produce nanoscale maps of localized surface plasmon (LSP) modes. More recently, photon-induced near-field electron microscopy (PINEM) has emerged as a powerful technique for imaging evanescent near-fields generated by ultrafast laser excitation. In this work, we employ PINEM within an ultrafast electron microscope, complemented by numerical calculations to investigate how optical polarization, surface modification, and light intensity affect the evanescent fields associated with LSPs on oxide-modified aluminum nanocubes. Polarization control of the incident light field enables spatial mapping of the nanocube’s LSPs at the single particle level. Systematic variation of the oxide layer thickness reveals that increased coating thickness correlates with a stronger PINEM signal and a greater energy gain of probing electrons. Additionally, higher light intensities at fixed polarization and oxide coating further amplify the PINEM signal. These findings demonstrate the utility of PINEM as a high-resolution technique for optical near-field imaging and spectroscopy of single plasmonic nanoparticles. The ability to probe single particle behavior offers new opportunities for advancing the design and characterization of nanophotonic and plasmonic materials.

PINEM↗

DOE OSTI2022

Octahedral oxide glass network in ambient pressure neodymium titanate

Abstract Rare-earth titanates form very fragile liquids that can be made into glasses with useful optical properties. We investigate the atomic structure of 83TiO 2 -17Nd 2 O 3 glass using pair distribution function (PDF) analysis of X-ray and neutron diffraction with double isotope substitutions for both Ti and Nd. Six total structure factors are analyzed (5 neutron + 1 X-ray) to obtain complementary sensitivities to O and Ti/Nd scattering, and an empirical potential structure refinement (EPSR) provides a structural model consistent with the experimental measurements. Glass density is estimated as 4.72(13) g cm −3 , consistent with direct measurements. The EPSR model indicates nearest neighbor interactions for Ti-O at $$\overline{r}_{TiO}$$ r ¯ TiO = 1.984(11) Å with coordination of $$n_{TiO}$$ n TiO = 5.72(6) and for Nd-O at $$\overline{r}_{NdO}$$ r ¯ NdO = 2.598(22) Å with coordination of $$n_{NdO}$$ n NdO = 7.70(26), in reasonable agreement with neutron first order difference functions for Ti and Nd. The titanate glass network comprises a mixture of distorted Ti-O 5 and Ti-O 6 polyhedra connected via 71% corner-sharing and 23% edge-sharing. The O-Ti coordination environments include 15% nonbridging O-Ti 1 , 51% bridging O-Ti 2 , and 32% tricluster O-Ti 3 . This structure is highly unusual for oxide glasses melt-quenched at ambient pressure, as it consists of Ti-O x predominantly in octahedral (with nearly no tetrahedral) coordination.

36 MATERIALS SCIENCE↗

DOE OSTI2023

SEEMS: A Single Event Effects and Muon Spectroscopy facility at the Spallation Neutron Source

This study outlines a concept that would leverage the existing proton accelerator at the Spallation Neutron Source (SNS) of Oak Ridge National Laboratory to enable transformative science via one world-class facility serving two missions: Single Event Effects (SEE) and Muon Spectroscopy (μSR). The μSR portion would deliver the world’s highest flux and highest resolution pulsed muon beams for material characterization purposes, with precision and capabilities well beyond comparable facilities. The SEE capabilities deliver neutron, proton, and muon beams for aerospace industries that are facing an impending challenge to certify equipment for safe and reliable behavior under bombardment from atmospheric radiation originating from cosmic and solar rays. With negligible impact on the primary neutron scattering mission of the SNS, the proposed facility will have enormous benefits for both science and industry. Herein, we have designated this facility “SEEMS.”

47 OTHER INSTRUMENTATION↗

DOE OSTI2025

Resilient stellarator divertor characteristics in the Helically Symmetric eXperiment

Resilient divertor features connected to open chaotic edge structures in the Helically Symmetric eXperiment are investigated. For the first time, an expanded vessel wall was considered that would give space for implementation of a physical divertor target structure. The analysis was done for four different magnetic configurations with very different chaotic plasma edges. A resilient plasma wall interaction pattern was identified across all configurations. This manifests as qualitatively very similar footprint behavior across the different plasma equilibria. Overall, the resilient field lines of interest with high connection length L C lie within a helical band along the wall for all configurations. This resiliency can be used to identify the best location of a divertor. The details of the magnetic footprint’s resilient helical band is subject to specific field line structures which are linked to the penetration depth of field lines into the plasma and directly influence the heat and particle flux patterns. The differences arising from these details are characterized by introducing a new metric, the minimum radial connection min $(\delta_N)$ of a field line from the last closed flux surface. The relationship, namely the deviation from a scaling law, between min $(\delta_N)$ and L C of the field lines in the plasma edge field line behavior suggests that the field lines are associated with structures such as resonant islands, cantori, and turnstiles. This helps determine the relevant magnetic flux channels based on the radial location of these chaotic edge structures and the divertor target footprint. These details will need to be taken into account for resilient divertor design.

divertor↗

DOE OSTI2023

Secular outflows from 3D MHD hypermassive neutron star accretion disc systems

Magnetized hypermassive neutron stars (HMNSs) have been proposed as a way for neutron star mergers to produce high electron fraction, high-velocity ejecta, as required by kilonova models to explain the observed light curve of GW170817. The HMNS drives outflows through neutrino energy deposition and mechanical oscillations, and raises the electron fraction of outflows through neutrino interactions before collapsing to a black hole (BH). Here, in this study, we perform 3D numerical simulations of HMNS–torus systems in ideal magnetohydrodynamics, using a leakage/absorption scheme for neutrino transport, the nuclear APR equation of state, and Newtonian self-gravity, with a pseudo-Newtonian potential added after BH formation. Due to the uncertainty in the HMNS collapse time, we choose two different parametrized times to induce collapse. We also explore two initial magnetic field geometries in the torus, and evolve the systems until the outflows diminish significantly ($\sim\!\! 1\!\! - \!\!2\ \mathrm{s}$). We find bluer, faster outflows as compared to equivalent BH–torus systems, producing M ∼ 10 −3 M ⊙ of ejecta with Y e ≥ 0.25 and v ≥ 0.25c by the simulation end. Approximately half the outflows are launched in disc winds at times $t\lesssim 500 \ \mathrm{ms}$, with a broad distribution of electron fractions and velocities, depending on the initial condition. The remaining outflows are thermally driven, characterized by lower velocities and electron fractions. Nucleosynthesis with tracer particles shows patterns resembling solar abundances in all models. Although outflows from our simulations do not match those inferred from two-component modelling of the GW170817 kilonova, self-consistent multidimensional detailed kilonova models are required to determine whether our outflows can power the blue kilonova.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2025

Quantifying dispersity in size and shape of nanoparticles from small-angle scattering data using machine learning based CREASE

Here, we use machine learning (ML) enhanced computational reverse engineering analysis of scattering experiments (CREASE) to interpret small-angle X-ray scattering (SAXS) data obtained from a system of nanoparticles without a priori knowledge of their exact shapes (e.g. spheres or ellipsoids), sizes (0.5–50 nm) and distributions. The SAXS measurements yielded three categories of scattering profiles exhibiting 'strong', 'weak' and 'no' features. Diminishing features (e.g. broadening or disappearing peaks) in scattering profiles have always been attributed to the presence of significant dispersity in the system. Such featureless SAXS data are not suitable for traditional analysis using analytical models. If one were to fit a relevant analytical model (e.g. the lmfit analytical model for polydisperse spheres) to these 'weak' and 'no' SAXS profiles from our nanoparticle systems, one would obtain non-unique interpretations of the data. Relying on electron microscopy to identify the distributions of nanoparticle shapes and sizes is also unfeasible, especially in high-throughput synthesis and characterization loops. In such situations, to identify the distributions of particle sizes and shapes that could be present in the sample, one must rely on methods like ML-CREASE to interpret the data quickly and output all relevant interpretations about the structure present in the system. The ML-CREASE optimization loop takes the experimental scattering profile as input and outputs multiple candidate solutions whose computed scattering profiles match the SAXS profile input. The ML-CREASE method outputs distributions of relevant structural features, such as the volume fraction of the nanoparticles in the system and the mean and standard deviation of the particle size and aspect ratio, assuming a type of distribution (e.g. normal, log-normal) for size and aspect ratio. We find that, for the SAXS profiles analyzed here, accounting for the shape dispersity along with size dispersity of the nanoparticles using ML-CREASE improved the match between the computed scattering profiles and input experimental profiles.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2017

Overview of NSTX Upgrade Initial Results and Modelling Highlights

The National Spherical Torus Experiment (NSTX) has undergone a major upgrade, and the NSTX Upgrade (NSTX-U) Project was completed in the summer of 2015. NSTX-U first plasma was subsequently achieved, diagnostic and control systems have been commissioned, H-Mode accessed, magnetic error fields identified and mitigated, and the first physics research campaign carried out. During 10 run weeks of operation, NSTX-U surpassed NSTX-record pulse-durations and toroidal fields, and high-performance ~1MA H-mode plasmas comparable to the best of NSTX have been sustained near and slightly above the n=1 no-wall stability limit and with H-mode confinement multiplier H98y2 above 1. Transport and turbulence studies in L-mode plasmas have identified the coexistence of at least two ion-gyro-scale turbulent micro-instabilities near the same radial location but propagating in opposite (i.e. ion and electron diamagnetic) directions. These modes have the characteristics of ion-temperature gradient and micro-tearing modes, respectively, and the role of these modes in contributing to thermal transport is under active investigation. The new second more tangential neutral beam injection was observed to significantly modify the stability of two types of Alfven Eigenmodes. Improvements in offline disruption forecasting were made in the areas of identification of rotating MHD modes and other macroscopic instabilities using the Disruption Event Characterization and Forecasting (DECAF) code. Lastly, the Materials Analysis and Particle Probe (MAPP) was utilized on NSTX-U for the first time and enabled assessments of the correlation between boronized wall conditions and plasma performance. These and other highlights from the first run campaign of NSTX-U are described.

Alfven Eigenmodes↗

DOE OSTI2020

Micropulse Lidar (MPL) Handbook

The micropulse lidar (MPL) is a ground-based optical remote sensing system designed primarily to determine the altitude of clouds overhead. The physical principle is the same as for radar. Pulses of energy are transmitted into the atmosphere; the energy scattered back to the transceiver is collected and measured as a time-resolved signal. From the time delay between each outgoing transmitted pulse and the backscattered signal, the distance to the scatterer is infered. Besides real-time detection of clouds, post-processing of the lidar return can also characterize the extent and properties of aerosol or other particle-laden regions.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2016

Scanning Electron Microscopy (SEM) Procedure for HE Powders on a LEO 438VP System

This method describes the characterization of HE powders by Scanning Electron Microscopy (SEM). HE particles are dispersed onto an aluminum standard SEM specimen mount. Electron micrographs are collected at various magnifications (150 to 10,000 X) depending on HE particle size.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2016

Scanning Electron Microscopy (SEM) Procedure for HE Powders on a LEO 438VP System

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2018

Measurement of Average Burnup in TRISO-Coated Particles from AGR-2 UCO Compacts 2-2-2 and 6-4-2

Burnup analysis was performed on tristructural-isotropic (TRISO)-coated particles deconsolidated from compacts irradiated by the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program in the second irradiation experiment (AGR-2) [Collin 2014]. The AGR-2 irradiation experiment included TRISO fuel particles with kernels containing both uranium oxide and uranium carbide, called UCO, where uranium carbide is included with the commonly-used uranium oxide in the kernel to provide a getter for oxygen liberated during fission and limit CO production. This allows the UCO-TRISO particles to be taken to higher burnup without failure from excessive internal CO pressure or CO-corrosion of the SiC layer. The UCO kernels were fabricated and coated at BWX Technologies Nuclear Operations Group (BWXT-NOG) with a 150-mm-diameter engineering-scale coater. The UCO-TRISO batch used in the AGR-2 irradiation experiment was Batch 93073, which had kernels with an average diameter of 426.7 μm and average coating thicknesses moving out from the kernel of 98.9 μm (buffer), 40.4 μm (IPyC), 35.2 μm (SiC), 43.4 μm (OPyC) [Barnes and Marshall 2009]. The TRISO particle were shipped to ORNL to be formed into compacts for irradiation testing. The compact lot qualified for the AGR-2 irradiation test was lot LEU09-OP2-Z and had an average of 3176 UCO-TRISO particles in each compact [Hunn, Montgomery, and Pappano 2010]. Compilations of the properties data for the particles and compacts are available in a pre-irradiation characterization summary report for the AGR-2 fuel composites [Hunn, Savage, and Silva 2010].

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

DOE OSTI2018

High Performance Reduction/Oxidation Metal Oxides for Thermochemical Energy Storage (PROMOTES) /CSP

Thermochemical energy storage (TCES) offers the potential for greatly increased storage density relative to sensible-only energy storage. Moreover, heat may be stored indefinitely in the form of chemical bonds via TCES, accessed upon demand, and converted to heat at temperatures significantly higher than current solar thermal electricity production technology and is therefore well-suited to more efficient high-temperature power cycles. However, this potential has yet to be realized as no current TCES system satisfies all requirements. This project involves the design, development, and demonstration of a robust and innovative storage cycle based on redox-active metal oxides that are Mixed Ionic-Electronic Conductors (MIECs). We will develop, characterize, and demonstrate a first of its kind 100kWth particle-based TCES system for direct integration with combined-cycle Air Brayton based on the endothermic reduction and exothermic reoxidation of MIECs. Air Brayton cycles require temperatures in the range of 1000-1230 °C for smaller axial flow turbines and are therefore inaccessible to all but the most robust storage solutions such as metal oxides. The choice of MIECs, with exceptional tunability and stability over the specified operating conditions allows us to optimally target this high impact cycle and to introduce the innovation of directly driving the turbine with the reacting/heat recovery fluid. The potential for high temperature thermal storage has direct bearing on next-gen CSP, and an appropriate investment for SETO.

25 ENERGY STORAGE↗

DOE OSTI2017

Examination of HIP for production of high density UN kernels

Depleted uranium nitride (UN) kernels with diameters ranging from 420 to 858 microns and theoretical densities between 87 and 91 percent were post-processed using hot isostatic pressing (HIP) in argon gas. This treatment was shown to increase the TD up to 96%. Uranium nitride is highly reactive with oxygen. Therefore, a novel crucible design was implemented to remove impurities in the argon gas via in situ gettering to avoid oxidation of the UN kernels. Established characterization techniques for determining average weight, volume, and ellipticity of particle fuel was used for calculating the density before and after HIPing. Micrographs confirm the nearly full densification of the particles using the gettering approach and processing parameters investigated in this work.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE OSTI2023

Co-Extrusion of Dissimilar Aluminum Alloys via Shear-Assisted Processing and Extrusion

Bimetallic tubes are used when a component requires more than one performance requirement, for instance, strength/creep resistance and oxidation/corrosion resistance. Shear-assisted processing and extrusion (ShAPE) can be used to fabricate extrudates that are comparable or superior in performance relative to conventionally manufactured extrudates. For the first time, ShAPE has been successfully employed in producing bimetallic Al tubing consisting of 6061 and 7075 Al alloys. Both light and electron microscopy techniques were used to investigate the integrity of the tubes, especially the interface between the core and cladding of the bimetallic tubes. Void-free bimetallic tubes were produced using ShAPE. Quantification of tube integrity was carried out with tensile testing under as-extruded and post-aged conditions. All the bimetallic tubes in the as-extruded samples exhibited uniform elongation above 5% with good tensile strength. Key insights such as material flow during bimetallic tube extrusion were obtained from the characterization of remnant billet and simulation results from a smoothed particle hydrodynamics model.

36 MATERIALS SCIENCE↗

DOE OSTI2021

Cometary Activity Begins at Kuiper Belt Distances: Evidence from C/2017 K2

We study the development of activity in the incoming long-period comet C/2017 K2 over the heliocentric distance range 9 ≲ r {sub H} ≲ 16 au. The comet continues to be characterized by a coma of submillimeter-sized and larger particles ejected at low velocity. In a fixed co-moving volume around the nucleus we find that the scattering cross section of the coma, C, is related to the heliocentric distance by a power law, C∝r{sub H}{sup -s}, with heliocentric index s = 1.14 ± 0.05. This dependence is significantly weaker than the r {sub H} {sup -2} variation of the insolation as a result of two effects. These are, first, the heliocentric dependence of the dust velocity and, second, a lag effect due to very slow-moving particles ejected long before the observations were taken. A Monte Carlo model of the photometry shows that dust production beginning at r {sub H} ~ 35 au is needed to match the measured heliocentric index, with only a slight dependence on the particle size distribution. Mass-loss rates in dust at 10 au are of order 10{sup 3} kg s{sup -1}, while loss rates in gas may be much smaller, depending on the unknown dust to gas ratio. Consequently, the ratio of the nongravitational acceleration to the local solar gravity, α', may, depending on the nucleus size, attain values of ~10{sup -7} ≲ α' ≲ 10{sup -5}, comparable to values found in short-period comets at much smaller distances. Nongravitational acceleration in C/2017 K2 and similarly distant comets, while presently unmeasured, may limit the accuracy with which we can infer the properties of the Oort cloud from the orbits of long-period comets.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

NASA NTRS1981

Characterization of aerosols from eruptions of Mount St. Helens

Measurements of mass concentration and size distribution of aerosols from eruptions of Mount St. Helens as well as morphological and elemental analyses were obtained between 7 April and 7 August 1980. In situ measurements were made in early phreatic and later, minor phreatomagmatic eruption clouds near the vent of the volcano and in plumes injected into the stratosphere from the major eruptions of 18 and 25 May. The phreatic aerosol was characterized by an essentially monomodal size distribution dominated by silicate particles larger than 10 micrometers in diameter. The phreatomagmatic eruption cloud was multimodal; the large size mode consisted of silicate particles and the small size modes were made up of mixtures of sulfuric acid and silicate particles. The stratospheric aerosol from the main eruption exhibited a characteristic narrow single mode with particles less than 1 micrometer in diameter and nearly all of the mass made up of sulfuric acid droplets.

Chuan, R. L.↗

NASA NTRS1981

The elemental and isotopic composition of cosmic rays - Silicon to nickel

The reported observations were made with the aid of the Cosmic Ray Isotope Instrument System (CRISIS) which had been designed to detect and resolve the isotopes of cosmic ray nuclei with atomic numbers equal to or greater than 10. The CRISIS detector was flown on a balloon launched from Aberdeen, South Dakota on 1977 May 20. The period 1977 May 19-22 has been classified by Mason et al. (1979) as one of 'superquiet' solar activity, characterized by the lowest fluxes of low-energy solar particles ever observed. The obtained results are presented in a number of graphs and tables. It was found that the elemental and isotopic abundances of Si are solar-like. Elemental S is underabundant in the cosmic rays by a factor of approximately 3 relative to the solar system, but its isotopic composition resembles the solar composition with S-32 being the dominant isotope. Elemental Ar is virtually absent in the source, and the observed isotopic composition is consistent with a secondary origin. Elemental Ni has a solar-like abundance.

Young, J. S.↗

NASA NTRS1983

Measurements of spectral attenuation coefficients in the lower Chesapeake Bay

The spectral transmission was measured for water samples taken in the lower Chesapeake Bay to allow characterization of several optical properties. The coefficients of total attenuation, particle attenuation, and absorption by dissolved organic matter were determined over a wavelength range from 3500 A to 8000 A. The data were taken over a 3 year period and at a number of sites so that an indication of spatial and temporal variations could be obtained. The attenuations determined in this work are, on the average, 10 times greater than those obtained by Hulburt in 1944, which are commonly accepted in the literature for Chesapeake Bay attenuation.

Houghton, W. M.↗