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At least 1,405 records · Page 78

Effect of component compression on the initial performance of an IPV nickel-hydrogen cell

An experimental method was developed for evaluating the effect of component compression on the charge and discharge voltage characteristics of a 3 1/2 in. diameter boiler plate cell. A standard boiler plate pressure vessel was modified by the addition of a mechanical feedthrough on the bottom of the vessel which permitted different compressions to be applied to the components without disturbing the integrity of the stack. Compression loadings from 0.94 to 27.4 psi were applied by suspending weights from the feedthrough rod. Cell voltages were measured for 0.96-C, 55-min charge and for 1.37-C, 35-min and 2-C, 24-min discharges. An initial change in voltage performance on both charge and discharge as the loading increased was attributed to seating of the components. Subsequent variation of the compression from 2.97 to 27.4 psi caused only minor changes in either the charge or the discharge voltages. Several one month open-circuit voltage stands and 1100 cycles under LEO conditions at the maximum loading have produced no change in performance.

Gahn, Randall F.↗

Effect of impregnation method on cycle life of the nickel electrode

The nickel electrode has been identified as the life limiting component for individual pressure vessel (IPV) nickel-hydrogen cells when cycled under a low earth orbit (LEO) cycle regime at deep depths of discharge. As a part of an overall program to develop a long life nickel electrode for nickel-hydrogen cells, the effect of two different methods of electrochemical impregnation on the cycle life of the nickel electrode was investigated. One method was the Pickett (aqueous/ethanolic) process. The other was the modified Bell (aqueous) process. The plaques for both impregnation methods were made by sintering dry carbonyl nickel powder in a reducing atmosphere. The plaques contain a nickel screen substrate. Electrodes made from both processes were cycle tested in Air Force design IPV nickel-hydrogen cells. The only factor different for this test was the method of plaque impregnation; all other factors were the same. The cells were cycled to failure under a 90 min LEO cycle regime at a deep depth of discharge (80 percent DOD). Failure for this test was defined to occur when the cell voltage degraded to 1.0 V prior to the completion of the 35 min discharge.

Smithrick, J. J.↗

Case histories involving fatigue and fracture mechanics; Proceedings of the Symposium, Charleston, SC, Mar. 21, 22, 1985

Papers are presented on cracking at nozzle corners in the nuclear pressure vessel industry, applied fracture mechanics for assessing defect significance in a crude oil pipeline, failure analysis of a large wind-tunnel compressor blade, analysis of a compressor-wheel failure, and preventing fracture by inspection and analysis. Consideration is also given to the fatigue crack growth predictions of welded aircraft structures containing flaws in the residual stress field, the fatigue and fracture mechanics analysis of a compression loaded aircraft structure, fracture of an aircraft horizontal stabilizer, fatigue life analysis of fuel tank skins under combined loads, and aircraft structural maintenance recommendations based on fracture mechanics analysis. Additional papers discuss an analysis of two metal-forming die failures, an analysis of a failed saw arbor, and the role of fracture mechanics in assessing the effect on fatigue life of design changes in welded fabrications.

Hudson, C. Michael↗

Stiffening Rings For Rocket-Case Joints

Loss of seal preventable. Rotation of components joint reversed from that caused by normal outward bulge at joint, or else eliminated. Elimination or reversal of rotation by suitable amount prevents opening of gap on O-ring, thus preserving seal. Applicable to segmented terrestrial pressure vessels.

Thompson, Bryce W.↗

Effect of NASA advanced designs on thermal behavior of Ni-H2 cells

As part of an overall effort to advance the technology of nickel-hydrogen batteries for low Earth orbit (LEO) applications, advanced designs for individual pressure vessel (IPV) nickel-hydrogen cells have been conceived. These designs incorporate alternative methods of oxygen recombination which affect the thermal behavior of the cells. The effect of these oxygen recombination methods on the cell temperature profiles is examined.

Gonzalez-Sanabria, Olga D.↗

Failure analysis of a 3.5 inch, 50 ampere-hour nickel-hydrogen cell

The 3.5 inch, 50 ampere-hour nickel-hydrogen cell was on a Low Earth Orbit (LEO) test regime and was being cycled at 10 C and 60 percent depth of discharge. At cycle number 511 the Automatic Control and Data Acquisition System (ACDAS) terminated the test when the end of discharge voltage dropped below the 1.00 volt cutoff. Upon removal of the stack assembly from the pressure vessel, portions of the zircar separator were found to be completely missing. Upon further examination portions of both the positive and negative plates were found to be missing from its substrate and several gas screens were damaged due to excessive heat which caused fusing. The postulated cause of failure is free electrolyte in the cell which caused oxygen channelization resulting in localized recombination which degraded the stack components.

Fuhr, Kenneth H.↗

Effect of LEO cycling at shallow depths of discharge on MANTECH IPV nickel-hydrogen cells

An individual pressure vessel nickel-hydrogen battery is being considered as an alternate for a nickel-cadmium battery on the Hubble Space Telescope. The space telescope battery will primarily be operating at a shallow depth of discharge (10 percent DOD) with an occasional 40 percent DOD. This shallow DOD raises several issues: (1) What is the cycle life. It is projected to be acceptable; however, there is no reported real time data base for validation. (2) The state of charge of the nickel electrode at the beginning of charge is 90 percent. Will this cause an acceleration of divergence in the battery individual cell voltages. (3) After prolonged cycling at 10 percent DOD, will there be enough capacity remaining to support the 40 percent DOD. (4) Is the state of charge really 90 percent during cycling. There is no reported real time data base at shallow depths of discharge. A data base to address the above issues was initiated.

Smithrick, John J.↗

Effect of component compression on the initial performance of an IPV nickel-hydrogen cell

An experimental method was developed for evaluating the effect of component compression on the charge and discharge voltage characteristics of a 3 1/2 in. diameter boiler plate cell. A standard boiler plate pressure vessel was modified by the addition of a mechanical feedthrough on the bottom of the vessel which permitted different compressions to be applied to the components without disturbing the integrity of the stack. Compression loadings from 0.94 to 27.4 psi were applied by suspending weights from the feedthrough rod. Cell voltages were measured for 0.96-C, 55-min charge and for 1.37-C, 35-min and 2-C, 24-min discharges. An initial change in voltage performance on both charge and discharge as the loading increased was attributed to seating of the components. Subsequent variation of the compression from 2.97 to 27.4 psi caused only minor changes in either the charge or the discharge voltages. Several one month open-circuit voltage stands and 1100 cycles under LEO conditions at the maximum loading have produced no change in performance.

Gahn, Randall F.↗

A telescope for high energy gamma-ray measurements in the Space Station era

This paper describes the concept of a large gamma-ray imaging telescope system (GRITS) which will provide sufficient sensitivity for the identification of faint objects to be catalogued by the Gamma-Ray Observatory. The technique used in this telescope for the detection of gamma rays is based on the conversion of the incident gamma ray into an electron-positron pair which subsequently produces Cherenkov radiation. The gamma ray is identified by a unique signature based on a sequence of time-delayed coincidence events. The GRITS telescope will use the extended Shuttle external tank, ET, as the pressure vessel necessary for the gas-Cherenkov process. Astronauts from the Shuttle or the Space Station performing EVA will convert ET to an autonomous spacecraft and install the telescope inside the ET.

Koch, David G.↗

Long-life assurance for Space Station - Is it an issue?

Various issues related to the long-life assurance (LLA) of the Space Station (SS) are discussed. The effects of exposure to atomic oxygen, radiation, thermal cycling, micrometeoroid and debris damage, and the physical aging of polymers on the SS materials are examined. The proper design of the SS truss system and pressure vessels, electronic systems, mechanical systems, and software for LLA is addressed.

Cruse, T. A.↗

Computing Viscoplastic Behavior Of A Material

Finite-element implementation developed for Robinson's unified model of viscoplasticity. Implemented via MARC general-purpose finite-element computer program by incorporating all of nonlinearity of material into initial load vector and treating vector as pseudo body force in finite-element equilibrium equations. In technique, each finite increment split into several equal subincrements, constitutive equations integrated by explicit Euler forward-difference method. HYPELA subroutine in MARC includes adaptive integration scheme selecting optimal sizes of subincrements. Spline function smooths discontinuous boundaries in Robinson's model to facilitate finite-element numerical calculations. Method used to calculate elastic, plastic, and creep deformations in solid materials at various temperatures; also used to study thermomechanical behavior of such things as hot pressure vessels and highly stressed components in engines.

Arya, V. K.↗

Applying Elastomeric Insulation Inside A Round Case

Elastomer wound onto inside surface in continuous strip. Technique being developed to apply elastomeric insulation to inner surfaces of axisymmetric cases. Requires modification of machine wrapping strip of elastomer on outside of rotating mandrel. Intended for coating insides of rocket-motor cases, technique also used to install elastomeric linings in pressure vessels, containers for chemical, and environmental chambers.

Russell, Peter G.↗

Computational and theoretical analysis of free surface flow in a thin liquid film under zero and normal gravity

The results of a numerical computation and theoretical analysis are presented for the flow of a thin liquid film in the presence and absence of a gravitational body force. Five different flow systems were used. Also presented are the governing equations and boundary conditions for the situation of a thin liquid emanating from a pressure vessel; traveling along a horizontal plate with a constant initial height and uniform initial velocity; and traveling radially along a horizontal disk with a constant initial height and uniform initial velocity.

Faghri, Amir↗

A new concept for high-cycle-life LEO: Rechargeable MnO2-hydrogen

The nickel-hydrogen secondary battery system is now the one of choice for use in GEO satellites. It offers superior energy density to that of nickel-cadmium, with a lifetime that is at least comparable in terms of both cycle life and overall operating life. While the number of deep cycles required for GEO use is small, LEO satellites with long lifetimes (5 to 10 years) will require secondary battery systems allowing 30,000 to 60,000 useful cycles which are characterized by an approximately 2C charge rate and C average discharge rate. Recent work has shown that birnessite MnO2 doped with bismuth oxide can be cycled at very high rates (6C) over a very large number of cycles (thousands) at depths-of-discharge in the 85 to 90 percent range, based on two electrons, which discharge at the same potential in a flat plateau. The potential is about 0.7 V vs. hydrogen, with a cut-off at 0.6 V. At first sight, this low voltage would seem to be a disadvantage, since the theoretical energy density will be low. However, it permits the use of lightweight materials that are immune from corrosion at the positive. The high utilization and low equivalent weight of the active material, together with the use of teflon-bonded graphite for current collection, result in very light positives, especially when these are compared with those in a derated nickel-hydrogen system. In addition, the weight of the pressure vessel falls somewhat, since the dead volume is lower. Calculations show that a total system will have 2.5 times the Ah capacity of a derated nickel-hydrogen LEO battery, so that the energy density, based on 1.2 V for nickel-hydrogen and 0.7 V for MnO2-hydrogen, will be 45 percent higher for comparable cycling performance.

Appleby, A. John↗

Cracking of a layered medium on an elastic foundation under thermal shock

The cladded pressure vessel under thermal shock conditions which is simulated by using two simpler models was studied. The first model (Model 1) assumes that, if the crack size is very small compared to the vessel thickness, the problem can be treated as a semi-infinite elastic medium bonded to a very thin layer of different material. However, if the crack size is of the same order as the vessel thickness, the curvature effects may not be negligible. In this case it is assumed that the relatively thin walled hollow cylinder with cladding can be treated as a composite beam on an elastic foundation (Model 2). In both models, the effect of surface cooling rate is studied by assuming the temperature boundary condition to be a ramp function. The calculated results include the transient temperature, thermal stresses in the uncracked medium and stress intensity factors which are presented as a function of time, and the duration of cooling ramp. The stress intensity factors are also presented as a function of the size and the location of the crack. The problem is solved for two bonded materials of different thermal and mechanical properties. The mathematical formulation results in two singular integral equations which are solved numerically. The results are given for two material pairs, namely an austenitic steel layer welded on a ferritic steel substrate, and a ceramic coating on ferritic steel. In the case of the yielded clad, the stress intensity factors for a crack under the clad are determined by using a plastic strip model and are compared with elastic clad results.

Rizk, Abd El-Fattah A.↗

Effect of LEO cycling at shallow depths of discharge on MANTECH IPV nickel-hydrogen cells

An individual pressure vessel nickel-hydrogen battery is being considered as an alternate for a nickel-cadmium battery on the Hubble Space Telescope. The space telescope battery will primarily be operating at a shallow depth of discharge (10 percent DOD) with an occasional 40 percent DOD. This shallow DOD raises several issues: (1) What is the cycle life. It is projected to be acceptable; however, there is no reported real time data base for validation. (2) The state of charge of the nickel electrode at the beginning of charge is 90 percent. Will this cause an acceleration of divergence in the battery individual cell voltages. (3) After prolonged cycling at 10 percent DOD, will there be enough capacity remaining to support the 40 percent DOD. (4) Is the state of charge really 90 percent during cycling. There is no reported real time data base at shallow depths of discharge. A data base to address the above issues was initiated.

Smithrick, John J.↗

Effect of NASA advanced designs on thermal behavior of Ni-H2 cells

As part of an overall effort to advance the technology of nickel-hydrogen batteries for low earth orbit (LEO) applications, advanced designs for individual pressure vessel (IPV) nickel-hydrogen cells have been conceived. These designs incorporate alternative methods of oxygen recombination which affect the thermal behavior of the cells. The effect of these oxygen recombination methods on the cell temperature profiles will be examined.

Gonzalez-Sanabria, Olga D.↗

Use of pure nickel and LiOH for thermal energy storage

The solid to liquid phase transformation of LiOH has been proposed as an ideal candidate thermal energy storage media for a Rankine Cycle powered electrical generation unit envisioned in Space Station based solar dynamic systems. Due to the corrosive nature of molten hydroxides, long term containment of LiOH is of concern. Pure nickel is thought to be a suitably resistant material, and a program has been instituted to measure the effects of prolonged exposure of liquid and gaseous LiOH on the mechanical properties of pure nickel alloys. Results to date indicate that negligible weight and thickness changes occurred in Ni alloys exposed to LiOH for as long as 2500 hr at 775 K, and essentially no difference in 77-900 K tensile properties could be detected between LiOH exposed and vacuum annealed Ni specimens. Although there was little sign of outward damage, microstructural examination revealed that all hydroxide contaminated tensile test specimens had surface connected intergranular cracks along the gage lengths. Two other potential problems, which have strong implications with respect to a LiOH/Ni energy storage system, were also noted during the corrosion experiments. In particular stress corrosion cracking of weld joints in pressurized vessel and permeation of hydrogen through nickel were observed.

Whittenberger, J. D.↗