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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,405 records · Page 78
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

High freezing point fuels used for aviation turbine engines

Broadened-specification aviation fuels could be produced from a greater fraction of crude source material with improvements in fuel supply and price. These fuels, particularly those with increased final boiling temperatures, would have higher freezing temperatures than current aviation turbine fuels. For the small but significant fraction of commercial flights where low fuel temperatures make higher freezing-point fuel use unacceptable, adaptations to the fuel or fuel system may be made to accommodate this fuel. Several techniques are discussed. Fuel heating is the most promising concept. One simple design uses existing heat rejection from the fuel-lubricating oil cooler, another uses an engine-driven generator for electrical heating.

Friedman, R.↗
NASA NTRS1979

Evaluation of the application of some gas chromatographic methods for the determination of properties of synthetic fuels

The purpose of the investigation was to evaluate the applicability, to some synthetic fuels, of some gas chromatographic methods now under development for use with petroleum based fuels. Thirty-two jet and diesel fuel samples which were prepared from oil shale and coal syncrudes were examined. The boiling range distribution of each was determined by gas chromatography, and from that data distillation properties were calculated. The calculated results gave sufficient agreement with the measured values that the equations could be useable in their present form. Bulk fuel properties were calculated for the sixteen JP-5 and Diesel No. 2 type fuels. The results show that the equations would not give useable results. Capillary column gas chromatography was used to determine the n-alkane content of the eight JP-5 type samples and the results related to the observed freezing points. The results show that the concentrations of the long straight chain molecules in the fuels exert influence on the freezing point but are not the complete controlling factor.

Antoine, A. C.↗
NASA NTRS1978

High performance, high density hydrocarbon fuels

The fuels were selected from 77 original candidates on the basis of estimated merit index and cost effectiveness. The ten candidates consisted of 3 pure compounds, 4 chemical plant streams and 3 refinery streams. Critical physical and chemical properties of the candidate fuels were measured including heat of combustion, density, and viscosity as a function of temperature, freezing points, vapor pressure, boiling point, thermal stability. The best all around candidate was found to be a chemical plant olefin stream rich in dicyclopentadiene. This material has a high merit index and is available at low cost. Possible problem areas were identified as low temperature flow properties and thermal stability. An economic analysis was carried out to determine the production costs of top candidates. The chemical plant and refinery streams were all less than 44 cent/kg while the pure compounds were greater than 44 cent/kg. A literature survey was conducted on the state of the art of advanced hydrocarbon fuel technology as applied to high energy propellents. Several areas for additional research were identified.

Frankenfeld, J. W.↗
NASA NTRS1979

Condensation on a noncollapsing vapor bubble in a subcooled liquid

An experimental procedure is presented by which an estimate can be made of the condensation coefficient on a noncollapsing stationary vapor bubble in subcooled liquid nitrogen. Film boiling from a thin wire was used to generate vapor bubbles which remain fixed to the wire at their base. A balance was established between the evaporation in the thin annular region along the wire and the condensation in the vapor bubbles.

Baumeister, K. J.↗
NASA NTRS1979

Use of refinery computer model to predict fuel production

Several factors (crudes, refinery operation and specifications) that affect yields and properties of broad specification jet fuel were parameterized using the refinery simulation model which can simulate different types of refineries were used to make the calculations. Results obtained from the program are used to correlate yield as a function of final boiling point, hydrogen content and freezing point for jet fuels produced in two refinery configurations, each one processing a different crude mix. Refinery performances are also compared in terms of energy consumption.

Flores, F. J.↗
NASA NTRS1979

Comparison of the properties of some synthetic crudes with petroleum crudes

Physical properties and chemical compositions of six synthetic crudes were determined. The results were compared to those of typical petroleum crudes, with the interest being the feasibility of making jet fuels from oil shale and coal syncrudes. The specific gravity, viscosity, and pour point were measured, showing that these crudes would be described as heavier rather than lighter crudes. The boiling range distribution of the crudes was determined by distillation and by gas chromatography. In addition, gel permeation chromatograms were obtained, giving a unique molecular weight distribution profile for each crude. Analyses for carbon, hydrogen, nitrogen and sulfur concentrations were performed, as well as for hydrocarbon group type and trace element concentrations. It was found that the range in concentration of vanadium, an element whose presence in turbine fuels is of major concern, was lower than that of petroleum crudes. Sodium and potassium, other elements of concern, were present in comparatively high concentrations.

Antoine, A. C.↗
NASA NTRS1979

A study of the deposition of carbide coatings on graphite fibers

The chemical vapor deposition of boron carbide and silicon carbide on graphite fibers to increase their electrical resistance was studied. Silicon carbide coatings were applied without degradation of the mechanical properties of the filaments. These coatings typically added 1000 ohms to the resistance of a filament as measured between two mercury pools. When SiC-coated filaments were oxidized by refluxing in boiling phosphoric acid, average resistance increased by an additional 1000 ohms; in addition resistance increases as high as 150 K ohms and breakdown voltages as high as 17 volts were noted. Data on boron carbide coatings indicated that such coatings would not be effective in increasing resistance, and would degrade the mechanical properties.

Suplinskas, R. J.↗
NASA NTRS1978

Cooling radioisotope thermoelectric generators in the Shuttle

Radioisotope thermoelectric generators (RTG) to be used on future spacecraft and launched by the Shuttle must be cooled from the time they are installed and enclosed until the spacecraft is deployed from the Shuttle. A special Cooling Kit maintains their temperature well below critical by circulating water through the coils soldered to them and through a heat exchanger that boils water and externally discharges the resulting steam. The RTG Cooling Kit, including its support frame, if fully charged with about 64 kg of evaporation water, will increase the Shuttle launch mass by about 200 kg.

Norman, R. M.↗
NASA NTRS1978

Characteristics and combustion of future hydrocarbon fuels

Dwindling supply of high-quality crude is beginning to manifest itself in the form of crude oils containing higher percentages of aromatic compounds, sulfur, nitrogen, and trace constituents. In the present paper, problems which have arisen with regard to the hydrogen content in jet fuels derived from these crude oil sources are discussed, with particular reference to the effects of varying the fuel properties on the combustion and thermal stability characteristics of a fuel. The importance of knowing how severe the effects of variations in hydrogen content, fuel-bound-nitrogen content, and boiling range are on such combustion phenomena as soot and carbon formation, emissions, and ignition is pointed out.

Rudey, R. A.↗
NASA NTRS1977

Alternative aviation turbine fuels

The efficient utilization of fossil fuels by future jet aircraft may necessitate the broadening of current aviation turbine fuel specifications. The most significant changes in specifications would be an increased aromatics content and a higher final boiling point in order to minimize refinery energy consumption and costs. These changes would increase the freezing point and might lower the thermal stability of the fuel and could cause increased pollutant emissions, increased smoke and carbon formation, increased combustor liner temperatures, and poorer ignition characteristics. This paper discusses the effects that broadened specification fuels may have on present-day jet aircraft and engine components and the technology required to use fuels with broadened specifications.

Grobman, J.↗
NASA NTRS1978

Evaluation of the application of some gas chromatographic methods for the determination of properties of synthetic fuels

The purpose of the investigation was to evaluate the applicability, to some synthetic fuels, of some gas chromatographic methods now under development for use with petroleum based fuels. Thirty-two jet and diesel fuel samples which were prepared from oil shale and coal syncrudes were examined. The boiling range distribution of each was determined by gas chromatography, and from that data distillation properties were calculated. The calculated results gave sufficient agreement with the measured values that the equations could be useable in their present form. Bulk fuel properties were calculated for the 16 JP-5 and Diesel No. 2 type fuels. The results show that the equations would not give useable results. Capillary column gas chromatography was used to determine the n-alkane content of the eight JP-5 type samples and the results related to the observed freezing points. The results show that the concentrations of the long straight chain molecules in the fuels exert influence on the freezing point but are not the complete controlling factor.

Antoine, A. C.↗
NASA NTRS1979

Status review of PMR polyimides

In the NASA developed PMR (polymerization of monomer reactants) the reinforcing fibers are impregnated with a solution containing a mixture of monomers dissolved in a low boiling point alkyl alcohol solvent, with the monomers reacting in situ at elevated temperatures to form a thermo-oxidatively stable polyimide matrix. The current status of first and second generation PMR polyimides is reviewed, considering synthesis and properties, processing, and applications. It is concluded that the PMR approach offers various significant advantages, especially superior high temperature properties and processing versatility, to fabricators and users of polyimide/fiber composites.

Serafini, T. T.↗
NASA NTRS1979

High-freezing-point fuels used for aviation turbine engines

Broadened-specification aviation fuels could be produced from a greater fraction of crude source material with improvements in fuel supply and price. These fuels, particularly those with increased final boiling temperatures, would have higher freezing temperatures than current aviation turbine fuels. The higher-freezing-point fuels can be substituted in the majority of present commercial flights, since temperature data indicate that in-flight fuel temperatures are relatively mild. For the small but significant fraction of commercial flights where low fuel temperatures make higher freezing-point fuel use unacceptable, adaptations to the fuel or fuel system may be made to accommodate this fuel. Several techniques are discussed. Fuel heating is the most promising concept. One simple system design uses existing heat rejection from the fuel-lubricating oil cooler, another uses an engine-driven generator for electrical heating. Both systems offer advantages that outweigh the obvious penalties.

Friedman, R.↗
NASA NTRS1979

Preflight status of the External Tank portion of the Space Shuttle Main Propulsion System

The development progress of the External Tank (ET) of the Shuttle Main Propulsion System (MPS) is described. 87% of ET propulsion components have satisfactorily completed qualification tests in preparation for the first Shuttle flight and their performance has been verified in the Main Propulsion Test Article (MPTA) firings of up to 100 seconds duration. The design changes in the LH2 tank pressurant diffuser, the LO2 feed system, and the ground test LO2 tank are discussed. Propellant loading information from MPTA tests may be used to predict loading operations and performance at KSC and VAFB, while ullage pressure profiles and boil-off rates during loading, chilldown rates, and final bulk density data have been obtained with geyser suppression evaluated and loading procedures established and verified. The MPTA test experience provided data to evaluate pressurization system and ET to Orbiter interface propellant performance noting thus that the fluid interface requirements will be satisfied for the first Shuttle flight. The Intertank inerting system was found to be effective in minimizing hazardous gas mixtures and full scale separation tests of the ET to Ground Umbilical Carrier Plate system were successfully completed.

Norquist, L.↗
NASA NTRS1979

Condensation on a noncollapsing vapor bubble in a subcooled liquid

An experimental procedure is presented by which an estimate can be made of the condensation coefficient on a noncollapsing stationary vapor bubble in subcooled liquid nitrogen. The present experimental study utilizes film boiling from a thin wire to generate vapor bubbles which remain fixed to the wire at their base. A balance was established between the evaporation in the thin annular region along the wire and the condensation in the vapor bubbles.

Baumeister, K. J.↗
NASA NTRS1980

LVDT gage for fracture-toughness tests in liquid hydrogen

Linear-variable differential transformer replaces conventional resistance strain gages to measure crack-mouth-opening displacement. LVDT is superior in tests under liquid hydrogen, where boiling of hydrogen on resistive is suited to broad temperature range and hostile environments such as nuclear reactors.

Pierce, W. S.↗
NASA NTRS1980

Modified displacement gage for cryogenic testing

Modification of double-cantilever-beam resistance strain gage makes boiling of hydrogen on gage arms less of problem. Modified gages are encapsulated nickel/chromium alloy, and bridge-excitation voltage is reduced from 10 to 1.5 volts. Sensitivity is 1.0 millivolt per inch with 1.5 volt excitation.

Pierce, W. S.↗
NASA NTRS1979

Concerning a new classification of tricyanides

A new classification series of tricyanides is presented. Several tricyanides are synthesized by a simple method from aluminum chloride, benzonitrile, and a respective alkyl or phenyl chloride, purified by recrystallization and distillation, and then analyzed. Structural formulae are suggested, and molecular weights, melting points, and boiling points are determined for each.

Krafft, F.↗