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At least 1,387 records · Page 77

Managing Sn-Supply to Tune Surface Characteristics of Vapor-Diffusion Coating of Nb₃Sn

Nb₃Sn promises better RF performance (Q and E_{acc}) than niobium at any given temperature because of superior superconducting properties. Nb₃Sn-coated SRF cavities are now produced routinely by growing a few microns thick Nb₃Sn films inside Nb cavities via the tin vapor diffusion technique. Sn evaporation and consumption during the growth process notably affect the quality of the coating. Aiming at favorable surface characteristics that could enhance the RF performance, many coatings were produced by varying Sn sources and temperature profiles. Coupon samples were examined using different material characterization techniques, and a selected few sets of coating parameters were used to coat 1.3 GHz single-cell cavities for RF testing. The Sn supply’s careful tuning is essential to manage the microstructure, roughness, and overall surface characteristics of the coating. We summarize the material analysis of witness samples and discuss the performance of several Nb₃Sn-coated single-cell cavities linked to Sn-source characteristics and observed Sn consumption during the film growth process.

Pudasaini, U.↗

Managing Sn-supply to tune surface characteristics of vapor-diffusion coating of Nb3Sn

Nb₃Sn promises better RF performance (Q and E_{acc}) than niobium at any given temperature because of superior superconducting properties. Nb₃Sn-coated SRF cavities are now produced routinely by growing a few microns thick Nb₃Sn films inside Nb cavities via the tin vapor diffusion technique. Sn evaporation and consumption during the growth process notably affect the quality of the coating. Aiming at favorable surface characteristics that could enhance the RF performance, many coatings were produced by varying Sn sources and temperature profiles. Coupon samples were examined using different material characterization techniques, and a selected few sets of coating parameters were used to coat 1.3 GHz single-cell cavities for RF testing. The Sn supply’s careful tuning is essential to manage the microstructure, roughness, and overall surface characteristics of the coating. We summarize the material analysis of witness samples and discuss the performance of several Nb₃Sn-coated single-cell cavities linked to Sn-source characteristics and observed Sn consumption during the film growth process.

Pudasaini, U.↗

A radiation-hard, low-background multiplexer design for spacecraft imager applications

A possible multiplexer design for the focal plane for the Cassini Visible and Infrared Mapping Spectrometer (VIMS) is reviewed. The instrument's requirements for the multiplexed array are summarized. The VIMS instrument has a modest radiation-hardness requirement due to the trajectory and planetary environments in which the instrument will be required to operate. The total ionizing dose hardness requirement is a few tens of kilorads. A thin-gate oxide of a few hundred angstroms thickness is to be used. Field hardness is to be achieved by guard bands or hardened dielectric isolation. The design is argued to meet the low-noise and radiation-hardness required for imaging at Saturn. The design is versatile enough to provide double-correlated and double-uncorrelated sampling, which is accomplished in the signal processing electronics outside the focal plane.

Staller, Craig↗

Synchrotron Characterization of Hydrogen and Ferric Iron in Martian Meteorites

The hydrogen budget of the Martian interior is distributed among several phases: melts, hydrous minerals, and nominally anhydrous minerals like olivine, pyroxene, and garnet. All these phases are vulnerable to loss of hydrogen during shock, excavation and transport via the mechanism of dehydrogenation, in which the charge on the H protons is left behind as polarons on Fe atoms. Thus, both H and F(3x) must be analyzed in order to reconstruct hydrogen and oxygen fugacities on Mars. To date, SIMS data have elucidated D/H and H contents of hydrous phases in SNC meteorites, but anhydrous martian minerals have not been systematically examined for trace hydrogen. Ferric iron has been quantified using XANES in many marital phases, but integrated studies of both Fe(3x) and H on the same spots are really needed to address the H budget. Here, we measure and profile H and Fe(3x) abundances in and across individual grains of glass and silicates in Martian meteorites. We use the new technology of synchrotron microFI'lR spectroscopy to measure the hydrogen contents of hydrous and nominally anhydrous minerals in martian meteorites on 30-100 microns thick, doubly polished thin sections on spots down to 3 x 3 microns. Synchrotron microXANES was used to analyze Fe(3x) on the same scale, and complementary SIMS D/H data will be collected where possible, though at a slightly larger scale. Development of this combination of techniques is critical because future sample return missions will generate only microscopic samples for study. Results have been used to quantitatively assess the distribution of hydrogen and ferric iron among phases in the martian interior, which will better constrain the geodynamic processes of the interior, as well as the overall hydrogen and water budgets on Mars.

Dyar, Melinda D.↗

Optimization of Aluminum Anodization Conditions for the Fabrication of Nanowires by Electrodeposition

Anodized alumina nanotemplates have a variety of potential applications in the development of nanotechnology. Alumina nanotemplates are formed by oxidizing aluminum film in an electrolyte solution.During anodization, aluminum oxidizes, and, under the proper conditions, nanometer-sized pores develop. A series of experiments was conducted to determine the optimal conditions for anodization. Three-micrometer thick aluminum films on silicon and silicon oxide substrates were anodized using constant voltages of 13-25 V. 0.1-0.3M oxalic acid was used as the electrolyte. The anodization time was found to increase and the overshooting current decreased as both the voltage and the electrolyte concentrations were decreased. The samples were observed under a scanning electron microscope. Anodizing with 25V in 0.3M oxalic acid appears to be the best process conditions. The alumina nanotemplates are being used to fabricate nanowires by electrodeposition. The current-voltage characteristics of copper nanowires have also been studied.

Fucsko, Viola↗

Heat Transfer Modeling and Validation for Optically Thick Alumina Fibrous Insulation

Combined radiation/conduction heat transfer through unbonded alumina fibrous insulation was modeled using the diffusion approximation for modeling the radiation component of heat transfer in the optically thick insulation. The validity of the heat transfer model was investigated by comparison to previously reported experimental effective thermal conductivity data over the insulation density range of 24 to 96 kg/cu m, with a pressure range of 0.001 to 750 torr (0.1 to 101.3 x 10(exp 3) Pa), and test sample hot side temperature range of 530 to 1360 K. The model was further validated by comparison to thermal conductivity measurements using the transient step heating technique on an insulation sample at a density of 144 kg/cu m over a pressure range of 0.001 to 760 torr, and temperature range of 290 to 1090 K.

Daryabeigi, Kamran↗

Vertical Structure of Radiative Heating Rates of the MJO during DYNAMO

The vertical structure of radiative heating rates over the region of the tropi-cal Indian Ocean associated with the MJO during the DYNAMO/ARM MJO Investigation Experiment is presented. The mean and variability of heating rates during active, suppressed, and disturbed phases are determined from the Paci?c Northwest National Laboratory combined remote sensing retrieval (CombRet) from Gan Island, Maldives (0.69? S, 73.15? E). TOA and surface ?uxes from the CombRet product are compared with collocated three-hourly CERES SYN1deg Ed4A satellite retrievals. The ?uxes are correlated in time with correlation coef?cients around 0.9, yet CombRet time-mean OLR is 15 W m-2 larger. Previous work has suggested that CombRet under-samples high clouds, due to attenuation by low-level clouds and reduced instrument sensitivity with altitude. However, mean OLR differs between CombRet and CERES for all values of OLR, not just the lowest values corresponding to widespread high clouds. The discrepancy peaks for mid-range OLR, sugges-tive of precipitating, towering cumulus convective clouds, rather than strati-form cirrus clouds. Biases in the cloud-top height of thick clouds substantially contribute to the overestimate of OLR by CombRet. CombRet data is used to generate composite shortwave and longwave atmospheric heating rate pro-?les as a function of the local OLR. Though there is considerable variability in CombRet not directly related to OLR, the time-height structure of mean heating rate composites generated using OLR as the interpolant is broadly representative of tropical convective variability on intraseasonal time scales.

Shell, Karen M.↗

A simple method for floating graphene oxide films facilitates nanoscale investigations of ion and water adsorption

Graphene oxide (GO) is a promising material for separations. Nanoscale GO thin films at the air/water interface are excellent experimental models to understand molecular-scale interactions of ions and water with GO. However, the characteristics of GO, such as functional groups and flake size, also affect the thin film properties making it difficult to make systematic studies with GO thin films. This paper reports a simple, reliable, and quick method of preparing ultra-thin GO films, irrespective of their origin, and demonstrates the new opportunities possible with the utilization of this method. The total amount of GO used to form the thin film is significantly less compared to previous examples in the literature, minimizing the dissolved GO in the subphase. X-ray reflectivity (XR) studies show that the majority of the GO film has 1.5 nm thickness over a macroscopic area (~100 cm 2 ) with very small roughness. Sum frequency generation (SFG) spectroscopy measurements show that H 2 O and D 2 O interact differently with GO films, a property that was not observed before. SFG data show that functional groups vary significantly between different commercially available GO samples. The differences are also characterized with XR at high resolution. X-ray fluorescence near total reflection (XFNTR) measurements show that these differences strongly affect ion adsorption and interfacial water behavior near GO, which are vital properties in separation applications. The results pave the way for future studies to elucidate the complex separation mechanisms with GO.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Large-scale analysis of structural brain asymmetries in schizophrenia via the ENIGMA consortium

Left–right asymmetry is an important organizing feature of the healthy brain that may be altered in schizophrenia, but most studies have used relatively small samples and heterogeneous approaches, resulting in equivocal findings. We carried out the largest case–control study of structural brain asymmetries in schizophrenia, with MRI data from 5,080 affected individuals and 6,015 controls across 46 datasets, using a single image analysis protocol. Asymmetry indexes were calculated for global and regional cortical thickness, surface area, and subcortical volume measures. Differences of asymmetry were calculated between affected individuals and controls per dataset, and effect sizes were meta-analyzed across datasets. Small average case–control differences were observed for thickness asymmetries of the rostral anterior cingulate and the middle temporal gyrus, both driven by thinner left-hemispheric cortices in schizophrenia. Analyses of these asymmetries with respect to the use of antipsychotic medication and other clinical variables did not show any significant associations. Assessment of age- and sex-specific effects revealed a stronger average leftward asymmetry of pallidum volume between older cases and controls. Case–control differences in a multivariate context were assessed in a subset of the data (N = 2,029), which revealed that 7% of the variance across all structural asymmetries was explained by case–control status. Subtle case–control differences of brain macrostructural asymmetry may reflect differences at the molecular, cytoarchitectonic, or circuit levels that have functional relevance for the disorder. Reduced left middle temporal cortical thickness is consistent with altered left-hemisphere language network organization in schizophrenia.

60 APPLIED LIFE SCIENCES↗

Microfluidic cells for the 1–10 2 MPa pressure range

Thin membrane-delimited fluid cells supporting up to 1 at (0.1 MPa) of pressure are well known and commercially available for use in vacuum chambers of electron, photon, or various particle beam microscopies or spectroscopies. Hereby, we report on the development of fluid cells capable of working at 1–10 MPa, extending the analysis domain for investigating chemical, biochemical, or physical processes at pressures of interest in chemical synthesis, underwater biochemistry studies or underground geology. We explored ways to optimize cell membranes to better resist pressure beyond simply increasing the thickness or decreasing the size of the membranes, using finite element analysis and experimental validation via membrane bulging experiments and failure statistics. Fluid cell prototypes were fabricated using ∼75 nm-thick SiN x membranes, engineered to withstand 4.7 MPa (average value), compared to regular (un-engineered) membranes withstanding only 3.4 MPa (average value). The fluid cell prototypes include eight microchannels for feeding/evacuating the fluids and applying pressure into micro-reaction chambers, two electrodes for electrochemical or conduction measurements in the sample, and a possible pressure or temperature sensor, customizable for specific experiments.

hi-pressure↗

Chasing ghosts: characterization of artifact generation in coded aperture decoding due to experimental implementation

Coded aperture imaging is a form of lensless aperture imaging that projects multiple overlapping images of the source onto the detector, enhancing signal strength, which is advantageous for low-flux sources or high-resolution imaging. This technique requires decoding of the detector signal to reconstruct the original source, which involves convolving the detector data with the aperture pattern. When the signal is from a centered point source, the reconstructed source image is known as the point spread function (PSF). A clean PSF without artifacts is a Dirac delta function [Appl. Opt. 20, 1858 (1981)]. This paper examines the robustness of the decoding process against variations in experimental tolerances by analyzing artifact growth in the reconstructed PSF. We illustrate the effects of incorrect magnification, rotation, and detector size and find that aperture–detector rotational misalignment about the imaging axis is the most sensitive parameter, with significant artifact generation occurring with angular offsets of less than one degree. We discuss compensation methods for imperfect aperture placement, finding that small detector sizes produce uncompensatable artifact generation, and compare theoretical predictions with experimental PSF measurements of a rank , 6.8 mm thick (less than one mean free path) coded aperture with a 3.5 mm cell size, conducted at the MegaJOuLe Neutron Imaging Radiography dense plasma focus [IEEE Trans. Plasma Sci. 49, 3299 (2021)] using a 2.45 MeV neutron source. Based on our findings, we recommend using magnified coded apertures in the under-sampled regime, which allows for the inclusion of fiducial markers to characterize aperture–detector rotational offsets and the addition of mechanical coupling, where possible, to constrain rotational and magnification offsets.

Selwood, M. P. [Lawrence Livermore National Labora↗

Transport in Stochastic Media with Random Chord Length Distributions

Thermal radiation transport computations in binary Markovian random mixtures rely almost exclusively on the Levermore-Pomraning (LP) model which is obtained by applying a heuristic closure to the ensemble averaged random medium transport equation. The validity of this model has been extensively tested by comparing numerical results over a broad parameter range (material types and mixing parameters) against benchmark solutions in planar geometry. The conditions under which the LP-model provides useful results and when it breaks down are now well established, but work to date has been largely restricted to homogeneous mixing statistics, i.e., the mean chord lengths of both materials are taken to be spatially constant. In recent work, this limitation was relaxed by allowing the mean chord lengths and, in a consistent fashion, the volume fractions in the LP-model to vary spatially and in a follow-up investigation benchmark solutions were obtained by ensemble averaging results over material realizations sampled from a nonhomogeneous Poisson process (NHPP). Numerical experiments in rod geometry with specifically linear and quadratic spatial dependence of chord lengths showed that the material averaged radiation intensities vary nonmonotonically with depth into the medium, in stark contrast to solutions obtained assuming uniform chord lengths. Moreover, depending on the local optical thickness and strength of scattering, the LP-model results showed locally more nuanced deviations from the benchmark solutions than was the case with constant chord lengths. These limited numerical investigations highlight the nontrivial qualitative and quantitative consequences of nonhomogeneous mixing statistics, in particular that closure approximations may not be uniformly valid or invalid over the problem domain.

42 ENGINEERING↗

Beryllium heat shield technology in the area of thermal protection devices

For future space applications, it is important that thermal protection systems be reusable for space shuttle flights. Beryllium offers a unique combination of properties for use as a heat shield material (stiffness, lightweight, ability to absorb heat). In order to adequately test these properties, it was necessary to fabricate heat shields. The concept used was a two-section test panel 99.1 x 99.1 cm (39 x 39 inch) with each section made of two 0.051 cm (0.020 inch) thick beryllium corrugations brazed together as a mirror image, with titanium (Ti-6Al-4V) used as standoffs to support the panel structure. The work prior to fabrication included brazability of both beryllium and titanium, forming of beryllium and titanium, machining processes involving beryllium and chem-milling beryllium. Sub-scale samples were made of all details before actual fabrication of the large panel. The full scale test panel was hot-formed at 950 K, chem-milled to 0.041 + or - 0.005 cm (0.016 + or - 0.002 inches), trimmed, vacuum brazed, drilled and assembled.

Muhl, A. E.↗

Optical contamination evidence from Skylab and Gemini flights

Final results from a part of the T027 experiment performed on the first Skylab mission are presented. The sample array system containing 248 optical surfaces and exposed outside the orbital workshop did not collect any significant contaminants. Unfortunate performance compromises and the relative cleanliness of the assembly on the antisolar side placed the amount of available surface contaminants at or below the limiting sensitivity of the ground measuring instruments. Significant contamination was seen near the extravehicular hatch quadrant on the solar side of the orbiting assembly, and some results from returned samples are presented. Optical windows and mirrors exposed on the Gemini 12 mission showed degradation up to 35% in the UV wavelength region and solar absorptance increases up to 1.8 times the clean values. An expression for the attenuation coefficient vs wavelength is presented. The contaminant, a silicone base material, varied in thickness from 22 nm to 88 nm. The postflight scattered luminance of a contaminated Gemini 12 left-hand spacecraft hatch window was used to obtain threshold stellar visibility curves as a function of scattered and incident sunlight angles.

Muscari, J. A.↗

Design, development, and test of Shuttle/Centaur G-prime cryogenic tankage thermal protection systems

The thermal protection systems (TPS) for the Shuttle/Centaur were designed to provide fail-safe thermal protection during prelaunch, launch ascent, and on-orbit operations as well as during potential abort, where the Shuttle and Centaur would return to earth. The TPS selected used a helium-purged polyimide foam beneath three radiation shields for the liquid-hydrogen (LH2) tank and radiation shields only for the liquid-oxygen (LO2) tank. A double-walled vacuum bulkhead separated the two tanks. The LH2 tank had one 1.9 cm-thick layer of foam on the forward bulkhead and two layers on the larger-area sidewall. Full scale tests of the flight vehicle in a simulated Shuttle cargo bay gave total prelaunch heating rates of 29.5 and 12.9 kW for the LH2 and LO2 tanks, respectively. Calorimeter tests on a representative sample of the LH2 tank sidewall TPS indicated that the measured unit heating one would rapidly decrease from the prelaunch rate of about 300 W/sq m to a desired rate less than 4 W/sq m once on-orbit.

Macneil, Peter N.↗

Orientation of Planar Deformation Features (PDFs) in quartz

Differently oriented single crystal quartz was shocked experimentally at pressures of 20 to 32 GPa and pre-shock temperatures up to 630 C. Based on this systematic investigation, we can demonstrate that the orientation of planar deformation features in quartz is not only dependent on shock pressure but also on pre-shock temperature and shock direction. Moreover, the orientation of Planar Deformation Features (PDF's) is strongly influenced by the set-up in recovery experiments. PDF's in quartz are defined as optically recognizable, planar microstructures diagnostically produced by shock compression. PDF's differ from all kinds of microstructures found in volcanic environment and therefore, their presence is a primary criterion for recognizing impact craters and ejecta layers such as the K/T boundary. Because experiments have shown a pressure dependence of the orientation of PDF's, this property is used extensively for shock wave barometry in natural impact sites. However, the unreflected application of experimental results neglects that parameters such as pre-shock temperature, shock direction, or the experimental arrangement may influence the spatial distribution of PDF's. In order to test this assumption, shock experiments on single crystal quartz at pre-shock temperatures of 20, 275, 540, and 630 C, and with shock directions (1010) and (0001) were performed. Most of the recovery experiments were carried out by using a reverberation technique, whereas in only one experiment a single shock was produced (impedance method). In the former case 0.5 mm thin discs of single crystal quartz were used, in the latter a 15 mm thick cylinder. The orientation of PDF's was measured by means of a conventional universal stage and the results are given. Effects of the experimentation technique can be derived showing the orientation of PDF's in quartz shocked at 27.5 GPa. In comparison to the well defined peaks at (1012) found in samples from reverberation experiments, the impedance matching technique causes PDF's with a broad distribution pattern and indistinct maxima. Our results have serious implications for shock-wave barometry in nature: the existing classification scheme which relates PDF orientation exclusively to shock pressure is no longer applicable. In consequence more experimental data is needed.

Langenhorst, F.↗

Hydrocarbon-Fueled Rocket Plume Measurement Using Polarized UV Raman Spectroscopy

The influence of pressure upon the signal strength and polarization properties of UV Raman signals has been investigated experimentally up to pressures of 165 psia (11 atm). No significant influence of pressure upon the Raman scattering cross section or depolarization ratio of the N2 Raman signal was found. The Raman scattering signal varied linearly with pressure for the 300 K N2 samples examined, thus showing no enhancement of cross section with increasing pressure. However at the highest pressures associated with rocket engine combustion, there could be an increase in the Raman scattering cross section, based upon others' previous work at higher pressures than those examined in this work. The influence of pressure upon thick fused silica windows, used in the NASA Modular Combustion Test Article, was also investigated. No change in the transmission characteristics of the windows occurred as the pressure difference across the windows increased from 0 psig up to 150 psig. A calibration was performed on the UV Raman system at Vanderbilt University, which is similar to the one at the NASA-Marshall Test Stand 115. The results of this calibration are described in the form of temperature-dependent functions, f(T)'s, that account for the increase in Raman scattering cross section with an increase in temperature and also account for the reduction in collected Raman signal if wavelength integration does not occur across the entire wavelength range of the Raman signal. These functions generally vary only by approximately 10% across their respective temperature ranges, except for the case Of CO2, where there is a factor of three difference in its f(T) from 300 K to 2500 K. However this trend for CO2 is consistent with the experimental work of others, and is expected based on the low characteristic vibrational temperature Of CO2. A time-averaged temperature measurement technique has been developed, using the same equipment as for the work mentioned above, that is based upon high-spectral resolution UV Raman scattering. This technique can provide temperature measurements for flows where pressure cannot be measured.

Wehrmeyer, Joseph A.↗

The Galileo Probe: How it Has Changed Our Understanding of Jupiter

The Galileo Mission to Jupiter, which arrived in December of 1995, provided the first study by an orbiter, and the first in-situ sampling via an entry probe, of an outer planet atmosphere. The rationale for an entry probe is that, even from an orbiter, remote sensing of the jovian atmosphere could not adequately retrieve the information desired. This paper provides a current summary of the most significant aspects of the data returned from the Galileo entry probe. As a result of the probe measurements, there has been a reassessment of our understanding of outer planet formation and evolution of the solar system. The primary scientific objective of the Galileo probe was to determine the composition of the jovian atmosphere, which from remote sensing remained either very uncertain, or completely unknown, with respect to several key elements. The probe found that the global He mass fraction is. significantly above the value reported from the Voyager Jupiter flybys but is slightly below the protosolar value, implying that there has been some settling of He to the deep jovian interior. The probe He measurements have also led to a reevaluation of the Voyager He mass fraction for Saturn, which is now determined to be much closer to that of Jupiter. The elements C, N, S, Ar, Kr, Xe were all found to have global abundances approximately 3 times their respective solar abundances. This result has raised a number of fundamental issues with regard to properties of planetesimals and the solar nebula at the time of giant planet formation. Ne, on the other hand, was found to be highly depleted, probably as the result of it being carried along with helium as helium settles towards the deep interior. The global abundance of O was not obtained by the probe because of the influence of local processes at the probe entry site (PES), processes which depleted condensible species, in this case H2O, well below condensation levels. Other condensible species, namely NH3 and H2S, were similarly affected but attained their deep equilibrium mixing ratios before the maximum depth sampled by the probe. Processes that might be capable of producing such effects on the condensibles are still under investigation. Measured isotopic ratios of noble gases and other heavy elements are solar, and (D + (Sup 3)He)/H is the same to within measurement uncertainties as in the local interstellar medium. No thick clouds were detected, and in particular no significant water cloud, but the PES location clearly affected the probe measurements of clouds. In fact, the probe data must be understood in the context of the location of the PES, which was within what is termed a 5 micron hot spot, a local clearing in the clouds that is bright near the 5 microns spectral region. The thermal structure at the PES was determined from approximately 1000 km above the 1 bar pressure level (10(exp -9 bars)) to 132 km 1 bar (22bars). The probe showed the atmosphere to have a generally sub-adiabatic temperature gradient (static stability) of = 0.1 K/km to as deep as the probe made measurements. In the upper atmosphere the probe derived a maximum positive vertical temperature gradient of approximately 5 K/km, and maximum temperature of = 900 K. The energy sources producing the warm upper atmosphere have yet to be completely identified. At first glance, Doppler tracking of the probe indicates that the long observed cloud level zonal winds extend to levels at least as deep as the probe made measurements. Zonal wind increases from = 80 m/s at pressures less than a bar to about 180 m/s near 5 bars, and remains approximately constant with depth thereafter. However, there is a question as to whether the winds measured from probe tracking are representative of the general wind field, or are considerably influenced by localized winds associated with the PES.

Young, Richard E.↗