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At least 1,387 records · Page 77

Improving High Resolution Offshore Wind Resource Assessments and Forecasts using Observations in the MA/RI Lease Areas

The third Wind Forecast Improvement Project (WFIP3) sought to improve understanding of the physical phenomena in the atmosphere and ocean that dictate the structure and variability of wind and thermodynamic fields within the Marine Atmospheric Boundary Layer (MABL). WFIP3 conducted a comprehensive 18-month observational study over the Northeast U.S. outer continental shelf, a high use coastal zone, using a 3-D multiscale sensor array to highly resolve the temporal, vertical, and horizontal structure of the coupled atmospheric and oceanic boundary layers. Multiple land-based study sites adjacent to the coastal ocean observed surface meteorology and vertical profiles of atmospheric properties via passive infrared and microwave radiometers, active lidars and radars, and radiosondes. At sea, an array of surface flux buoys and two vertical profiling lidar buoys observed both atmospheric and oceanic properties, augmented by land-based oceanographic radar systems and routine ship-based surveys. Intensive observations of the MABL over the ocean was done from an air-sea interaction flux tower and extended deployments of a large barge platform. WFIP3 focused on mesoscale and sub-mesoscale flows -- including sea breezes, low-level jets, low-level clouds, and coastal storms -- and the ability of advanced numerical model parameterizations to represent them within fully coupled oceanic and atmospheric modeling systems and foundational weather forecast models. Numerous critical forecasting phenomena were observed, however the project was terminated prior to the completion of the field observational period and the analysis period.

54 ENVIRONMENTAL SCIENCES↗

Lightweight fuel cell powerplant for Tug

The design and characteristics of a lightweight powerplant based on advanced cell technology to meet the requirements of the Space Tug are described. The powerplant can be operated off low-pressure hydrogen and oxygen rocket propellant tanks and avoid the need for a dedicated reactant supply. Product water can be condensed or not, depending on vehicle or payload requirements. The heart of the unit, the fuel cell power section, consist of lightweight, series-connected, alkaline cells, while the power section contains accessory components for reactant conditioning, distribution, and venting, coolant circulation, passive product water removal and electric control. The proposed design offers at least a 50 per cent saving in powerplant weight, so that the total estimated powerplant dry weight including structure, tubing, wiring, interface connectors, and interface heat exchanger is 48 lb.

Handley, L. M.↗

Multitemperature Cryogenic Radiative Cooler

Multiple radiator stages separated by V-groove shields protect main cooler from parasitic heat radiation and offer usable cooling themselves. Proposed cryogenic radiative cooler achieves lower temperatures previously possible with passive radiators in space. Provides useful cooling power at several temperatures instead of one. Cold-radiator stage protected by multiple shield assemblies intercepting radiation heat leaks from warmer supporting structure and redirects it out to space. Each shield assembly has effective cooling capacity enabling it to cool optical filter.

Bard, Steven↗

Thermal Examination of an Orbiting Cryogenic Fuel Depot

For many years NASA has been interested in the storage and transfer of cryogenic fuels in space. Lunar, L2 and other chemical propulsive space vehicle missions now have staged refueling needs that a fuel depot would satisfy. The depot considered is located in lower earth orbit. Many considerations must go into designing and building such a station. Multi-layer insulation systems, thermal shielding and low conductive structural supports are the principal means of protecting the system from excessive heat loss due to boiloff. This study focuses on the thermal losses associated with storing LH2 in a passively cooled fuel depot in a lower earth equatorial orbit. The corresponding examination looks at several configurations of the fuel depot. An analytical model has been developed to determine the thermal advantages and disadvantages of three different fuel depot configurations. Each of the systems consists of three Boeing rocket bodies arranged in various configurations. The first two configurations are gravity gradient stabilized while the third one is a spin-stabilized concept. Each concept was chosen for self-righting capabilities as well as the fuel settling capabilities, however the purpose of this paper is to prove which of the three concepts is the most efficient passively cooled system. The specific areas to be discussed are the heating time from the fusion temperature to the vaporization temperature and the amount of boiloff for a specific number of orbits. Each of the previous points is compared using various sun exposed surface areas of the tanks.

Hull, Patrick V.↗

The Interstellar Conspiracy

If we were designing a human-carrying starship that could be launched in the not-too-distant future, it would almost certainly not use a warp drive to instantaneously bounce around the universe, as is done in Isaac Asimov's classic Foundation series or in episodes of Star Trek or Star Wars. Sadly, those starships that seem to be within technological reach could not even travel at high relativistic speeds, as does the interstellar ramjet in Poul Anderson's Tau Zero. Warp-speeds seem to be well outside the realm of currently understood physical law; proton-fusing ramjets may never be technologically feasible. Perhaps fortunately in our terrorist-plagued world, the economics of antimatter may never be attractive for large-scale starship propulsion. But interstellar travel will be possible within a few centuries, although it will certainly not be as fast as we might prefer. If humans learn how to hibernate, perhaps we will sleep our way to the stars, as do the crew in A. E. van Vogt's Far Centaurus. However, as discussed in a landmark paper in The Journal of the British Interplanetary Society, the most feasible approach to transporting a small human population to the planets (if any) of Alpha Centauri is the worldship. Such craft have often been featured in science fiction. See for example Arthur C. Clarke's Rendezvous with Rama, and Robert A. Heinlein's Orphans of the Sky. Worldships are essentially mobile versions of the O Neill free-space habitats. Constructed mostly from lunar and/or asteroidal materials, these solar-powered, multi-kilometer-dimension structures could house 10,000 to 100,000 humans in Earth-approximating environments. Artificial gravity would be provided by habitat rotation, and cosmic ray shielding would be provided by passive methods, such as habitat atmosphere and mass shielding, or magnetic fields. A late 21st century space-habitat venture might support itself economically by constructing large solar-powered satellites to beam energy back to Earth.

Johnson, Les↗

Rendezvous and Proximity Operations of the Space Shuttle

Space Shuttle rendezous missions presented unique challenges that were not fully recognized when the Shuttle was designed. Rendezvous targets could be passive (i.e., no lights or transponders), and not designed to facilitate Shuttle rendezvous, proximity operations and retrieval. Shuttle reaction control system jet plume impingement on target spacecraft presented induced dynamics, structural loading and contamination concerns. These issues, along with limited forward reaction control system propellant, drove a change from the Gemimi/Apollo coelliptic profile heritage to a stable orbit profile, and the development of new proximity operations techniques. Multiple scientific and on-orbit servicing missions and crew exchange, assembly and replinishment flights to Mir and to the International Space Station drove further profile and piloting technique changes, including new relative navigation sensors and new computer generated piloting cues.

Goodman, John L.↗

Rendezvous and Proximity Operations of the Space Shuttle

Space Shuttle rendezvous missions present unique challenges that were not fully recognized when the Shuttle was designed. Rendezvous targets could be passive (i.e., no lights or transponders), and not designed to facilitate Shuttle rendezvous, proximity operations, and retrieval. Shuttle reaction control system jet plume impingement on target spacecraft presented induced dynamics, structural loading, and contamination concerns. These issues, along with limited reaction control system propellant in the Shuttle nose, drove a change from the legacy Gemini/Apollo coelliptic profile to a stable orbit profile, and the development of new proximity operations techniques. Multiple scientific and on-orbit servicing missions, and crew exchange, assembly and replenishment flights to Mir and to the International Space Station drove further profile and piloting technique changes. These changes included new proximity operations, relative navigation sensors, and new computer generated piloting cues. However, the Shuttle's baseline rendezvous navigation system has not required modification to place the Shuttle at the proximity operations initiation point for all rendezvous missions flown.

Goodman, John L.↗

Programmable Thermostats for MPLM Shell Heater Control ULF1: Thermal Performances - 1

The Multi-Purpose Logistics Module (MPLM) is the primary carrier for "pressurized" logistics to and from the International Space Station (ISS). The MPLM is transported in the payload bay of the Space Shuttle and is docked to the ISS for unloading, and reloading, of contents within the ISS shirt sleeve environment. Foil heaters, controlled originally with bi-metallic thermostats, are distributed across the outside of the MPLM structure and are utilized to provide energy to the structure to avoid exposure to cold temperatures and prevent condensation. The existing bi-metallic, fixed temperature set point thermostats have been replaced with Programmable Thermostats Modules (PTMs) in the Passive Thermal Control Subsystem (PTCS) 28Vdc shell heater circuits. The goal of using the PTM thermostat is to improve operational efficiency of the MPLM on-orbit shell heaters by providing better shell temperature control via feedback control capability. Each heater circuit contains a programmable thermostat connected to an external temperature sensor, a Resistive Temperature Device (RTD), which is used to provide continuous temperature monitoring capability. Each thermostat has programmable temperature set points and control spans. The data acquisition system uses a standard RS-485 serial interface communications cable to provide digital control capability. The PTM system was designed by MSFC, relying upon ALTEC support for their integration within the MPLM system design, while KSC performed the installation and ground checkout testing of the thermostat and RS-485 communication cable on the MPLM FM1 flight module. The PTMs were used for the first time during the STS-121/ULF1.1 mission. This paper will describe the design, development and verification of the PTM system, as well as the PTM flight performance and comparisons with SINDA thermal model predictions.

Glasgow, Shaun↗

The Global Precipitation Measurement (GPM) Mission's Scientific Achievements and Societal Contributions: Reviewing Four Years of Advanced Rain and Snow Observations

Precipitation represents a life-critical energy and hydrologic exchange between the Earth’s atmosphere and its surface. As such, knowledge of where, when, and how much rain and snow falls is essential for scientific research and societal applications. Building on the 17-year success of the Tropical Rainfall Measurement Mission (TRMM), the Global Precipitation Measurement (GPM) Core Observatory (GPM-CO) is the first U.S. National Aeronautical and Space Administration (NASA) satellite mission specifically designed with sensors to observe the structure and intensities of both rain and falling snow. The GPM-CO has proved to be a worthy successor to TRMM, extending and improving high-quality active and passive microwave observations across all times of day. The GPM-CO launched in early 2014, is a joint mission between NASA and the Japanese Aerospace Exploration Agency (JAXA), with sensors that include the NASA-provided GPM Microwave Imager and the JAXA-provided Dual-frequency Precipitation Radar. These sensors were devised with high accuracy standards enabling them to be used as a reference for inter-calibrating a constellation of partner satellite data. These intercalibrated partner satellite retrievals are used with infrared data to produce merged precipitation estimates at temporal scales of 30 minutes and spatial scales of 0.1° x 0.1°. Precipitation estimates from the GPM-CO and partner constellation satellites, provided in near real time and later reprocessed with all ancillary data, are an indispensable source of precipitation data for operational and scientific users. Advances have been made using GPM data, primarily in improving sensor calibration, retrieval algorithms, and ground validation measurements, and used to further our understanding of the characteristics of liquid and frozen precipitation and the science of water and hydrological cycles for climate/weather forecasting. These advances have extended to societal benefits related to water resources, operational numerical weather prediction, hurricane monitoring, prediction, and disaster response, extremes, and disease.

Applications↗

High absorption photovoltaic material and methods of making the same

A high absorption photovoltaic material and method of making the material for use in a solar cell are disclosed. The photovoltaic material includes a surface modified with a layer of repeating photonic crystal structures. The photonic crystal structures are approximately inverse conically shaped and have a curved sidewall that has an approximately Gaussian shape. The photonic crystal structures generally have a high vertical depth and sidewall angle. The structures also have a gradient refractive index profile and exhibit the parallel-to-interface refraction light trapping effect. An anti-reflective coating is disposed over the photonic crystal structure layer. The photovoltaic material exhibits near unity light absorption over a broad range of visible and near infrared wavelengths and incidence angles, even at reduced thicknesses. The photovoltaic structures are formed via a combined photolithography and reactive-ion etching method at low power with a gas mixture having a high ratio of an etchant component to a passivation component.

Kuang, Ping↗

Purification of Lithium-Ion Battery Black Mass through Tailored Alkaline Corrosion

Obtaining high-purity material outputs is crucial to the viability of novel process aimed at direct recycling of lithium-ion batteries. Metallic impurities in recycled cathodes have been shown to inhibit performance, thereby threatening mainstream acceptance of recycled battery products. Thus, shredded black mass (BM) must be purified to remove metallic contaminants, and specifically Al and Cu originating from the electrode current collectors. We herein explore a process to ionize solid copper and aluminum to ionic form based on tailored alkaline chemistry, without incurring damage to the target cathode material (Li(NixMnyCo1-x-y)O2; NMC). Al and Cu corrosion may be enhanced through the addition of chloride salt, elevated temperatures, and the use of ultrasonication - all of which disrupt the formation of passivating films on the metallic surface, and thereby increase corrosion rate. We demonstrate optimized parameters for Al and Cu corrosion both from a kinetic and overall process cost perspective. Further, we analyze the impact of these conditions on the structural (XRD, SEM), chemical (EDS, ICP), and electrochemical (impedance, cycling, dQ/dV) properties of NMC, and suggest that the present purification method does not significantly disrupt NMC performance. Finally, we present preliminary results from a promising bench-scale demonstration of this purification process applied to a simulated black mass.

ADVANCED PROPULSION SYSTEMS,ENERGY STORAGE↗

Structured large-pore foams improve thermal performance of LiMIT-style liquid lithium PFC

As magnetically confined fusion devices improve, the conditions at the walls become increasingly intense. Plasma facing components (PFCs) must withstand these extreme heat and particle loads without damage or degradation. Liquid lithium PFCs are known to be quite resilient, and the presence of lithium also serves to improve plasma properties. The liquid metal infused trench (LiMIT) concept is an open surface liquid lithium PFC design that has been tested extensively at the University of Illinois and in fusion devices around the world. LiMIT utilizes thermoelectric magnetohydrodynamics (TEMHD) to passively drive liquid lithium flow. This work demonstrates an extension of the LiMIT trench geometry to three dimensions. Additively manufactured large pore metallic foams maintain TEMHD drive while drastically improving heat flux handling and resistance to lithium dryout, a phenomenon where locally high TEMHD forces depresses the lithium level and exposes underlying solid structure. COMSOL multiphysics modeling of the system yields insight into the forces at play in dryout development, and shows the 3D structures can eliminate dryout. Here, low heat proof-of-concept experimental testing of the system matches computational results, and high heat flux electron beam tests more than double the proven operational range of a LiMIT-style PFC, to 6.8 MW m –2 , with no indications of dryout or impending damage.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Corrosion of carbon steel and the passivating properties of corrosion films formed under high-PT geothermal conditions

Corrosion is a major obstacle to a safe implementation of geotechnical applications. Here, using a novel approach that includes vertical scanning interferometry (VSI) and electrochemical impedance spectroscopy (EIS) we discuss time-dependent carbon steel corrosion and film formation at geothermally relevant temperatures (80-160 °C) in CO 2 -saturated mildly acidic Na—Cl brine. Iron dissolution kinetics follows a logarithmic rate at 80 and 160 °C and a linear rate at 120 °C. At 80 °C, high initial corrosion rates (first 24 h) generate H 2 at a minimum rate of 12 μmol h -1 cm -2 and lead to the formation of a continuous ~100 μm thick porous corrosion film. It exhibits a duplex structure with a crystalline outer FeCO 3 layer and an inner layer composed of a skeletal network of Fe 3 C impregnated with FeCO 3 . Being an electrical conductor we hypothesize the Fe 3 C to strongly enhance corrosion rates by providing additional cathodic sites. Pseudo-passivity due to an anodic film-forming reaction (presumably Fe-oxide) was observed at 120 and 160 °C, soon followed by the initiation of pitting at 120 °C. Steady-state corrosion rates at 160 °C are at least one order of magnitude lower than for 120 °C. Lastly, our experimental approach demonstrated potential for general applicability in studying corrosion-related phenomena.

36 MATERIALS SCIENCE↗

Suspension systems for ground testing large space structures

A research program is documented for the development of improved suspension techniques for ground vibration testing of large, flexible space structures. The suspension system must support the weight of the structure and simultaneously allow simulation of the unconstrained rigid-body movement as in the space environment. Exploratory analytical and experimental studies were conducted for suspension systems designed to provide minimum vertical, horizontal, and rotational degrees of freedom. The effects of active feedback control added to the passive system were also investigated. An experimental suspension apparatus was designed, fabricated, and tested. This test apparatus included a zero spring rate mechanism (ZSRM) designed to support a range of weights from 50 to 300 lbs and provide vertical suspension mode frequencies less than 0.1 Hz. The lateral suspension consisted of a pendulum suspended from a moving cart (linear bearing) which served to increase the effective length of the pendulum. The torsion suspension concept involved dual pendulum cables attached from above to a pivoting support (bicycle wheel). A simple test structure having variable weight and stiffness characteristics was used to simulate the vibration characteristics of a large space structure. The suspension hardware for the individual degrees of freedom was analyzed and tested separately and then combined to achieve a 3 degree of freedom suspension system. Results from the exploratory studies should provide useful guidelines for the development of future suspension systems for ground vibration testing of large space structures.

Gold, Ronald R.↗

Amphilic Water-Lean Carbon Capture Solvent Wetting Behavior through Decomposition by Stainless-Steel Interfaces

In this work, we report on a combined experimental and theoretical study of the wetting and reactivity of water-lean carbon capture solvents on the surface of common column packing materials. Paradoxically, we find that these solvents are equally able to wet hydrophobic and hydrophilic surfaces. The solvents are amphiphilic and are able to adapt to any interfacial environment due to their inherent heterogeneous molecular structure. Ab initio molecular dynamics indicates that these structures enable the formation of a strong adlayer on the surface of hydrophilic surfaces like oxidized steel which promotes solvent decomposition akin to hydrolysis from surface oxides and hydroxides. This decomposition passivates the surface, making it effectively hydrophobic, and the decomposed solvent promotes leaching of the iron into the bulk fluid. This study links the wetting behavior to the observed corrosion of the steels via decomposition of solvent at steel interfaces. The overall affect is strongly dependent on the chemical composition of the solvent, in that amines are stable, whereas imines and alcohols are not. We also observed that plastic packing shows little to no solvent degradation, but an equal degree of wetting.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Characterization and Optimization of GaN Cap Layers and SiN Cap Layers on AlGaN/GaN HEMT Structures Grown on 200 mm GaN on Silicon

We have studied capping layers for AlGaN‐based high electron mobility transistor (HEMT) structures, looking at different thicknesses of GaN, SiN, and GaN + SiN caps. SiN capping has no effect on the sheet resistance of the layers, as expected from a high quality amorphous passivation layer. GaN cap layers increase the sheet resistance whether combined with a SiN cap or not, a consequence of the polarisation charge present at the GaN/AlGaN interface. For both GaN and SiN caps on their own, we get excellent morphology from only 2 nm thickness, with no degradation for layers up to 10 nm thick. For GaN + SiN caps, we have a speckled morphology with lots of small holes, which transmission electron microscopy (TEM) analysis showed to be linked to holes created in the GaN layers before the deposition of SiN layers. We attribute this to the roughening effect of silane on GaN layers, known in the literature. Upon processing SiN capped and GaN + SiN capped layers into HEMT based heterojunction diode devices, the two have equivalent forward current, but GaN + SiN capping has greatly increased reverse current. We conclude that GaN + SiN is not an appropriate capping layer for AlGaN HEMT based diodes, compared with high quality in situ SiN passivation directly grown on the AlGaN.

Charles, Matthew↗

Decimeter-scale mapping of carbonate-controlled trace element distribution in Neoarchean cuspate stromatolites

We present that ancient stromatolites can provide key insights into the early evolution of life on Earth. Neoarchean fenestrate stromatolites from the ~2520 Ma Upper Nauga Formation (Transvaal Supergroup, South Africa) preserve cuspate morphologies. They possess clearly delineated support and drape structures interpreted as dolomitized microbial mat material. Petrographic observations show that the biogenic structures are composed of planar-s to non-planar ferroan dolomite, encased in ferroan calcite, including herringbone calcite textures. The cuspate stromatolites were analyzed using Synchrotron Rapid Scanning X-Ray Fluorescence (SRS-XRF) and more conventional techniques to determine: (i) whether element distributions could be distinguished in ancient stromatolites at both cm to dm scales, (ii) whether element distributions show variation between biogenic and abiogenic textures, and (iii) the sample’s paragenesis. The distributions of Ca, Fe, Mn, Pb, Cu, As, Br, Al, Si, P, and S directly correspond to dolomitized stromatolitic structures and show trace element distributions are principally controlled by calcite and dolomite occurrence. Dolomite formation was mainly driven by seawater-derived fluids given the high concentrations of Fe and retention of marine shale-normalized rare earth element and yttrium (REY SN ) patterns, however the spatial association of dolomite to stromatolite structures may reflect microbially-influenced mineral nucleation. Lastly, given the complexity of this sample’s paragenetic evolution, trace metal distributions cannot be conclusively tied to specific metabolic pathways, bioaccumulation or passive binding, however, the results show SRS-XRF can be used for quantifiable, spatial, in-situ investigation of ancient microbialites.

58 GEOSCIENCES↗