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At least 1,387 records · Page 77

Multiscale Assessment of Caprock Integrity for Geologic Carbon Storage in the Pennsylvanian Farnsworth Unit, Texas, USA

Leakage pathways through caprock lithologies for underground storage of CO2 and/or enhanced oil recovery (EOR) include intrusion into nano-pore mudstones, flow within fractures and faults, and larger-scale sedimentary heterogeneity (e.g., stacked channel deposits). To assess multiscale sealing integrity of the caprock system that overlies the Morrow B sandstone reservoir, Farnsworth Unit (FWU), Texas, USA, we combine pore-to-core observations, laboratory testing, well logging results, and noble gas analysis. A cluster analysis combining gamma ray, compressional slowness, and other logs was combined with caliper responses and triaxial rock mechanics testing to define eleven lithologic classes across the upper Morrow shale and Thirteen Finger limestone caprock units, with estimations of dynamic elastic moduli and fracture breakdown pressures (minimum horizontal stress gradients) for each class. Mercury porosimetry determinations of CO2 column heights in sealing formations yield values exceeding reservoir height. Noble gas profiles provide a “geologic time-integrated” assessment of fluid flow across the reservoir-caprock system, with Morrow B reservoir measurements consistent with decades-long EOR water-flooding, and upper Morrow shale and lower Thirteen Finger limestone values being consistent with long-term geohydrologic isolation. Together, these data suggest an excellent sealing capacity for the FWU and provide limits for injection pressure increases accompanying carbon storage activities.

58 GEOSCIENCES↗

Stratigraphically Controlled Stress Variations at the Hydraulic Fracture Test Site-1 in the Midland Basin, TX

We investigated the relationship between stratigraphy, stress, and microseismicity at the Hydraulic Fracture Test Site-1. The site comprises two sets of horizontal wells in the Wolfcamp shale and a deviated well drilled after hydraulic fracturing. Regional stresses indicate normal/strike-slip faulting with E-W compression. Stress measurements in vertical and horizontal wells show that the minimum principal stress varies with depth. Strata with high clay and organic content show high values of the least compressive stress, consistent with the theory of viscous stress relaxation. By integrating data from core, logs, and the hydraulic fracturing stages, we constructed a stress profile for the Wolfcamp sequence, which predicts how much pressure is required for hydraulic fracture growth. We applied the results to fracture orientation data from image logs to determine the population of pre-existing faults that are expected to slip during stimulation. We also determined microseismic focal plane mechanisms and found slip on steeply dipping planes striking NW, consistent with the orientations of potentially active faults predicted by the stress model. This case study represents a general approach for integrating stress measurements and rock properties to predict hydraulic fracture growth and the characteristics of injection-induced microseismicity.

microseismicity↗

Tuscaloosa Marine Shale: Seal or Source? Petrophysical Comparative Study of Wells in SE Louisiana and SW Mississippi

The Tuscaloosa Marine Shale (TMS) is a versatile Late Cretaceous shale formation present in central and SE Louisiana and SW Mississippi, which drew attention because of the various roles played within the Tuscaloosa Group. In this paper, it is debated whether the Tuscaloosa Marine Shale can act as a source, reservoir, or seal all throughout the shale play or only in certain areas. Well log and core data from Adams County, Mississippi, are compared to data from East Feliciana Parish in Louisiana. Conclusions were drawn based on the results of well log analysis, X-ray Diffraction (XRD), porosity–permeability measurements, programmed pyrolysis, and fracture analysis. It was shown that the Tuscaloosa Marine Shale interval in SE Louisiana consists of important amounts of calcite, exhibits multiple natural fractures, has porosity values as high as 9.3%, and shows a TOC content of up to 2.8 wt%. On the other hand, samples from a well at the Cranfield field, MS, are characterized by considerably lower TOC values of around 0.88 wt%, porosities between 0.33% and 4%, and no serious fracturing. The formation demonstrates better reservoir and source potential in SE Louisiana and reliable CO2 sealing capacity in SW Mississippi. The analysis presented in this paper represents a holistic approach to the characterization of shale formations, is applicable to other plays around the world, and can be used as an integral part of CO2 sequestration or hydraulic fracturing programs.

04 OIL SHALES AND TAR SANDS↗

Cybersecurity Certification Requirements for Distributed Energy Resources: A Survey of SunSpec Alliance Standards

This survey paper explores the cybersecurity certification requirements defined by the SunSpec Alliance for Distributed Energy Resource (DER) devices, focusing on aspects such as software updates, device communications, authentication mechanisms, device security, logging, and test procedures. The SunSpec cybersecurity standards mandate support for remote and automated software updates, secure communication protocols, stringent authentication practices, and robust logging mechanisms to ensure operational integrity. Furthermore, the paper discusses the implementation of the SAE J3072 standard using the IEEE 2030.5 protocol, emphasizing the secure interactions between electric vehicle supply equipment (EVSE) and plug-in electric vehicles (PEVs) for functionalities like vehicle-to-grid (V2G) capabilities. This research also examines the SunSpec Modbus standard, which enhances the interoperability among DER system components, facilitating compliance with grid interconnection standards. This paper also analyzes the existing SunSpec Device Information Models, which standardize data exchange formats for DER systems across communication interfaces. Finally, this paper concludes with a detailed discussion of the energy storage cybersecurity specification and the blockchain cybersecurity requirements as proposed by SunSpec Alliance.

Tsikteris, Sean (ORCID:0009000524202250)↗

Silver Nanoparticles Functionalized Nanosilica Grown over Graphene Oxide for Enhancing Antibacterial Effect

The continuous growth of multidrug-resistant bacteria due to the overuse of antibiotics and antibacterial agents poses a threat to human health. Silver nanoparticles, silica-based materials, and graphene-based materials have become potential antibacterial candidates. In this study, we developed an effective method of enhancing the antibacterial property of graphene oxide (GO) by growing nanosilica (NS) of approximately 50 nm on the graphene oxide (GO) surface. The structures and compositions of the materials were characterized through powdered X-ray diffraction (P-XRD), transmission electron microscopy (TEM), scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM-EDS), ultraviolet–visible spectroscopy (UV–VIS), dynamic light scattering (DLS), Raman spectroscopy (RM), Fourier-transform infrared spectroscopy (FTIR), Brunauer–Emmet–Teller (BET) surface area, and pore size determination. The silver nanoparticles (AgNPs) with an average diameter of 26 nm were functionalized on the nanosilica (NS) surface. The composite contained approximately 3% of silver nanoparticles. The silver nanoparticles on nanosilica supported over graphene oxide (GO/NS/AgNPs) exhibited a 7-log reduction of Escherichia coli and a 5.2-log reduction of Bacillus subtilis within one hour of exposure. Both GO/NS and GO/NS/AgNPs exhibited substantial antimicrobial effects against E. coli and B. subtilis.

36 MATERIALS SCIENCE↗

13 TeV pp collisions, Exotics type, PYTHIA8 generator: tev13pp_qstar_pythia8_mbins

Excited Fermions in mass range pT=6-40 TeV. 5000 events per file, 100 files per mass. Compositeness scale (Lambda) is set to the mass of the fermion, so the width is expected to be small (see the log files for details) Cross sections are included in the log files (mass dependent). How to decode name: Name: tev100_pythia8_qstar_m[MASS]_[NUMBER] where [MASS] is generator-level mass as given below: Mass bins (in GeV) m[1]=2000 m[2]=4000 m[3]=6000 m[4]=8000 m[5]=10000 m[6]=12000 m[7]=14000. How to use: To get a sample with a given mass, use "glob" regular expressions. Slimmed as: Particle records are slimmed (all stable with pT>0.3 GeV) and (PID=5 || PID=6) or PID>22 && PID<38) or PID>10 && PID<17).

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

13 TeV pp collisions, Exotics type, PYTHIA8 generator: tev13pp_pythia8_zbbar

Zprime decaying to b-quarks (bbar) for different masses of Zprime. Cross sections depend on the mass (given in the log files). The Zprime mass is encoded in the file names as *_m[MASS]. For each mass, 10 files are generated with 5,000 events per file. Other details are in the log files attached to the files.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

13 TeV pp collisions, Exotics type, PYTHIA8 generator: tev13pp_pythia8_zbbar_nnpf

Zprime decaying to b-quarks (bbar) for different masses of Zprime. Cross sections depend on the mass (given in the log files). The Zprime mass is encoded in the file names as *_m[MASS]. For each mass, 10 files are generated with 5,000 events per file. Other details are in the log files attached to the files. The file was created using ATLAS A14 tune and NNPDF23.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

M STARS IN THE TW HYA ASSOCIATION: STELLAR X-RAYS AND DISK DISSIPATION

To investigate the potential connection between the intense X-ray emission from young low-mass stars and the lifetimes of their circumstellar planet-forming disks, we have compiled the X-ray luminosities (L {sub X}) of M stars in the ∼8 Myr old TW Hya Association (TWA) for which X-ray data are presently available. Our investigation includes analysis of archival Chandra data for the TWA binary systems TWA 8, 9, and 13. Although our study suffers from poor statistics for stars later than M3, we find a trend of decreasing L{sub X}/L{sub bol} with decreasing T {sub eff} for TWA M stars, wherein the earliest-type (M0–M2) stars cluster near log(L{sub X}/L{sub bol})≈−3.0 and then log(L{sub X}/L{sub bol}) decreases, and its distribution broadens, for types M4 and later. The fraction of TWA stars that display evidence for residual primordial disk material also sharply increases in this same (mid-M) spectral type regime. This apparent anticorrelation between the relative X-ray luminosities of low-mass TWA stars and the longevities of their circumstellar disks suggests that primordial disks orbiting early-type M stars in the TWA have dispersed rapidly as a consequence of their persistent large X-ray fluxes. Conversely, the disks orbiting the very lowest-mass pre-MS stars and pre-MS brown dwarfs in the Association may have survived because their X-ray luminosities and, hence, disk photoevaporation rates are very low to begin with, and then further decline relatively early in their pre-MS evolution.

79 ASTRONOMY AND ASTROPHYSICS↗

Young, star-forming galaxies and their local counterparts: The evolving relationship of mass–SFR–metallicity since z ∼ 2.1

We explore the evolution of the Stellar Mass–Star Formation Rate (SFR)–Metallicity relation using a set of 256 COSMOS and GOODS galaxies in the redshift range 1.90 < z < 2.35. We present the galaxies’ rest-frame optical emission-line fluxes derived from IR-grism spectroscopy with the Hubble Space Telescope and combine these data with SFRs and stellar masses obtained from deep, multi-wavelength (rest-frame UV to IR) photometry. We then compare these measurements to those for a local sample of galaxies carefully matched in stellar mass (7.5≲log(M{sub ∗}/M{sub ⊙})≲10.5) and SFR (−0.5≲log(SFR)≲2.5 in M{sub ⊙} yr{sup −1}). We find that the distribution of z ∼ 2.1 galaxies in stellar mass–SFR–metallicity space is clearly different from that derived for our sample of similarly bright (L{sub Hβ}>3×10{sup 40} erg s{sup −1}) local galaxies, and this offset cannot be explained by simple systematic offsets in the derived quantities. At stellar masses above ∼10{sup 9} M{sub ⊙} and SFRs above ∼10 M{sub ⊙} yr{sup −1}, the z ∼ 2.1 galaxies have higher oxygen abundances than their local counterparts, while the opposite is true for lower-mass, lower-SFR systems.

79 ASTRONOMY AND ASTROPHYSICS↗

NUSTAR OBSERVATIONS OF THE YOUNG, ENERGETIC RADIO PULSAR PSR B1509–58

We report on Nuclear Spectroscopic Telescope Array (NuSTAR) hard X-ray observations of the young rotation-powered radio pulsar PSR B1509−59 in the supernova remnant MSH 15−52. We confirm the previously reported curvature in the hard X-ray spectrum, showing that a log parabolic model provides a statistically superior fit to the spectrum compared with the standard power law. The log parabolic model describes the NuSTAR data, as well as previously published γ-ray data obtained with COMPTEL and AGILE, all together spanning 3 keV through 500 MeV. Our spectral modeling allows us to constrain the peak of the broadband high energy spectrum to be at 2.6 ± 0.8 MeV, an improvement of nearly an order of magnitude in precision over previous measurements. In addition, we calculate NuSTAR spectra in 26 pulse phase bins and confirm previously reported variations of photon indices with phase. Finally, we measure the pulsed fraction of PSR B1509−58 in the hard X-ray energy band for the first time. Using the energy resolved pulsed fraction results, we estimate that the pulsar’s off-pulse emission has a photon index value between 1.26 and 1.96. Our results support a model in which the pulsar’s lack of GeV emission is due to viewing geometry, with the X-rays originating from synchrotron emission from secondary pairs in the magnetosphere.

79 ASTRONOMY AND ASTROPHYSICS↗

Inferences from the distributions of fast radio burst pulse widths, dispersion measures, and fluences

The widths, dispersion measures (DMs), dispersion indices, and fluences of Fast Radio Bursts (FRBs) impose coupled constraints that all models must satisfy. The non-monotonic dependence of burst widths (after deconvolution of instrumental effects) on DMs excludes the intergalactic medium as the location of scattering that broadens the FRBs in time. Temporal broadening far greater than that of pulsars at similar high Galactic latitudes implies that scattering occurs close to the sources where high densities and strong turbulence or heterogeneity are plausible. FRB energetics are consistent with supergiant pulses from young, fast, high-field pulsars at cosmological distances. The distribution of FRB DMs is: (1) inconsistent with that of expanding clouds (such as SNRs); (2) inconsistent with space-limited source populations (such as the local Supercluster); and (3) consistent with intergalactic dispersion of a homogeneous source population at cosmological distances. Finally, the FRB log N–log S relation also indicates a cosmological distribution aside from the anomalously bright Lorimer burst.

79 ASTRONOMY AND ASTROPHYSICS↗

Globular cluster populations: Results including S{sup 4}G late-type galaxies

Using 3.6 and 4.5 μm images of 73 late-type, edge-on galaxies from the S{sup 4}G survey, we compare the richness of the globular cluster populations of these galaxies to those of early-type galaxies that we measured previously. In general, the galaxies presented here fill in the distribution for galaxies with lower stellar mass, M{sub *}, specifically log(M{sub ∗}/M{sub ⊙})<10, overlap the results for early-type galaxies of similar masses, and, by doing so, strengthen the case for a dependence of the number of globular clusters per 10{sup 9}M{sub ⊙} of galaxy stellar mass, T{sub N}, on M{sub *}. For 8.5<log(M{sub ∗}/M{sub ⊙})<10.5 we find the relationship can be satisfactorily described as T{sub N}=(M{sub ∗}/10{sup 6.7}){sup −0.56} when M{sub *} is expressed in solar masses. The functional form of the relationship is only weakly constrained, and extrapolation outside this range is not advised. Our late-type galaxies, in contrast to our early types, do not show the tendency for low-mass galaxies to split into two T{sub N} families. Using these results and a galaxy stellar mass function from the literature, we calculate that, in a volume-limited, local universe sample, clusters are most likely to be found around fairly massive galaxies (M{sub *} ∼ 10{sup 10.8}M{sub ⊙}) and present a fitting function for the volume number density of clusters as a function of parent-galaxy stellar mass. We find no correlation between T{sub N} and large-scale environment, but we do find a tendency for galaxies of fixed M{sub *} to have larger T{sub N} if they have converted a larger proportion of their baryons into stars.

79 ASTRONOMY AND ASTROPHYSICS↗

Star formation black hole growth and dusty tori in the most luminous AGNS at Z = 2–3.5

We report Herschel/SPIRE observations of 100 very luminous, optically selected active galactic nuclei (AGNs) at z=2--3.5 with log L{sub 1350} (erg s{sup −1}) ≥ 46.5 , where L{sub 1350} is λL{sub λ} at 1350 Å. The distribution in L{sub 1350} is similar to the general distribution of Sloan Digital Sky Survey AGNs in this redshift and luminosity interval. We measured star-formation (SF) luminosity, L{sub SF}, and SF rate (SFR) in 34 detected sources by fitting combined SF and torus templates, where the torus emission is based on Wide Field Infrared Survey Explorer observations. We also obtained statistically significant stacks for the undetected sources in two luminosity groups. The sample properties are compared with those of very luminous AGNs at z>4.5. The main findings are: (1) The mean and the median SFRs of the detected sources are 1176{sub −339}{sup +476} and 1010{sub −503}{sup +706} M{sub ⊙} yr{sup −1}, respectively. The mean SFR of the undetected sources is 148 M{sub ⊙} yr{sup −1}. The ratio of SFR to the black hole accretion rate is ≈80 for the detected sources and less than 10 for the undetected sources. Unlike a sample of sources at z ≃ 4.8 that we studied recently, there is no difference in L{sub AGN} and only a very small difference in L{sub torus} between the detected and undetected sources. (2) The redshift distribution of L{sub SF} and L{sub AGN} for the most luminous, redshift 2–7 AGNs are different. Similar to previous studies, the highest L{sub AGN} are found at z ≈ 3. However, the L{sub SF} of such sources peaks at z ≈ 5. Assuming the objects in our sample are hosted by the most massive galaxies at those redshifts, we find that approximately 2/3 of the hosts are already below the main sequence of SF galaxies at z = 2−3.5. (3) The spectral energy distributions (SEDs) of dusty tori at high redshift are similar to the shapes found in low redshift, low luminosity AGNs. Herschel upper limits put strong constraints on the long wavelength shape of the SED, ruling out several earlier suggested torus templates as applicable for this sample. (4) We find no evidence for a luminosity dependence of the torus covering factor in sources with log L{sub AGN} (erg s{sup −1}) = 44−47.5. This conclusion is based on the recognition that the estimated L{sub AGN} in several earlier studies is highly uncertain and non-uniformally treated. The median covering factors over this range are 0.68 for isotropic dust emission and 0.4 for anisotropic emission.

79 ASTRONOMY AND ASTROPHYSICS↗

HIERARCHICAL FORMATION IN ACTION: CHARACTERIZING ACCELERATED GALAXY EVOLUTION IN COMPACT GROUPS USING WHOLE-SKY WISE DATA

Compact groups provide an environment to study the growth of galaxies amid multiple prolonged interactions. With their dense galaxy concentrations and relatively low velocity dispersions, compact groups mimic the conditions of hierarchical galaxy assembly. Compact group galaxies are known to show a bimodality in Spitzer IRAC infrared color space: galaxies are preferentially either quiescent with low specific star formation rates (SSFRs) or prolifically forming stars—galaxies with moderate levels of specific star formation are rare. Previous Spitzer IRAC studies identifying this “canyon” have been limited by small number statistics. We utilize whole-sky Wide-field Infrared Survey Explorer (WISE) data to study 163 compact groups, thereby tripling our previous sample and including more galaxies with intermediate mid-IR colors indicative of moderate SSFRs. We define a distinct WISE mid-IR color space (log[((f{sub 12})/(f{sub 4.6}))]) versus (log[((f{sub 22})/(f{sub 3.4}))]) that we use to identify canyon galaxies from the larger sample. We confirm that compact group galaxies show a bimodal distribution in the mid-infrared and identify 37 canyon galaxies with reliable photometry and intermediate mid-IR colors. Morphologically, we find that the canyon harbors a large population of both Sa–Sbc and E/S0 type galaxies, and that they fall on the optical red sequence rather than the green valley. Finally, we provide a catalog of WISE photometry for 567 of 652 galaxies selected from the sample of 163 compact groups.

79 ASTRONOMY AND ASTROPHYSICS↗

STELLAR MASS–GAS-PHASE METALLICITY RELATION AT 0.5 ≤ z ≤ 0.7: A POWER LAW WITH INCREASING SCATTER TOWARD THE LOW-MASS REGIME

We present the stellar mass (M{sub ∗})–gas-phase metallicity relation (MZR) and its scatter at intermediate redshifts (0.5⩽z⩽0.7) for 1381 field galaxies collected from deep spectroscopic surveys. The star formation rate (SFR) and color at a given M{sub ∗} of this magnitude-limited (R≲24 AB) sample are representative of normal star-forming galaxies. For masses below 10{sup 9} M{sub ⊙}, our sample of 237 galaxies is ∼10 times larger than those in previous studies beyond the local universe. This huge gain in sample size enables superior constraints on the MZR and its scatter in the low-mass regime. We find a power-law MZR at 10{sup 8} M{sub ⊙} < M{sub ∗} < 10{sup 11} M{sub ⊙}: 12+log(O/H)=(5.83±0.19) +(0.30±0.02)log(M{sub ∗}/M{sub ⊙}). At 10{sup 9} M{sub ⊙} < M{sub ∗} < 10{sup 10.5} M{sub ⊙}, our MZR shows agreement with others measured at similar redshifts in the literature. Our power-law slope is, however, shallower than the extrapolation of the MZRs of others to masses below 10{sup 9} M{sub ⊙}. The SFR dependence of the MZR in our sample is weaker than that found for local galaxies (known as the fundamental metallicity relation). Compared to a variety of theoretical models, the slope of our MZR for low-mass galaxies agrees well with predictions incorporating supernova energy-driven winds. Being robust against currently uncertain metallicity calibrations, the scatter of the MZR serves as a powerful diagnostic of the stochastic history of gas accretion, gas recycling, and star formation of low-mass galaxies. Our major result is that the scatter of our MZR increases as M{sub ∗} decreases. Our result implies that either the scatter of the baryonic accretion rate (σ{sub M-dot }) or the scatter of the M{sub ∗}–M{sub halo} relation (σ{sub SHMR}) increases as M{sub ∗} decreases. Moreover, our measure of scatter at z=0.7 appears consistent with that found for local galaxies. This lack of redshift evolution constrains models of galaxy evolution to have both σ{sub M-dot }and σ{sub SHMR} remain unchanged from z=0.7 to z = 0.

79 ASTRONOMY AND ASTROPHYSICS↗

PROPERTIES OF CARBON–OXYGEN WHITE DWARFS FROM MONTE CARLO STELLAR MODELS

We investigate properties of carbon–oxygen white dwarfs with respect to the composite uncertainties in the reaction rates using the stellar evolution toolkit, Modules for Experiments in Stellar Astrophysics (MESA) and the probability density functions in the reaction rate library STARLIB. These are the first Monte Carlo stellar evolution studies that use complete stellar models. Focusing on 3 M{sub ⊙} models evolved from the pre main-sequence to the first thermal pulse, we survey the remnant core mass, composition, and structure properties as a function of 26 STARLIB reaction rates covering hydrogen and helium burning using a Principal Component Analysis and Spearman Rank-Order Correlation. Relative to the arithmetic mean value, we find the width of the 95% confidence interval to be ΔM{sub 1TP} ≈ 0.019 M{sub ⊙} for the core mass at the first thermal pulse, Δt{sub 1TP} ≈ 12.50 Myr for the age, Δlog(T{sub c}/K) ≈ 0.013 for the central temperature, Δlog(ρ{sub c}/g cm{sup −3}) ≈ 0.060 for the central density, ΔY{sub e,c} ≈ 2.6 × 10{sup −5} for the central electron fraction, ΔX{sub c}({sup 22}Ne) ≈ 5.8 × 10{sup −4}, ΔX{sub c}({sup 12}C) ≈ 0.392, and ΔX{sub c}({sup 16}O) ≈ 0.392. Uncertainties in the experimental {sup 12}C(α,γ){sup 16}O, triple-α, and {sup 14}N(p,γ){sup 15}O reaction rates dominate these variations. We also consider a grid of 1–6 M{sub ⊙} models evolved from the pre main-sequence to the final white dwarf to probe the sensitivity of the initial–final mass relation to experimental uncertainties in the hydrogen and helium reaction rates.

79 ASTRONOMY AND ASTROPHYSICS↗