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NASA NTRS2024

Unveiling the Transferability of PLSR Models for Leaf Trait Estimation: Lessons from a Comprehensive Analysis with a Novel Global Dataset

Leaf traits are essential for understanding many physiological and ecological processes. Partial least-squares regression (PLSR) models with leaf spectroscopy are widely applied for trait estimation, but their transferability across space, time and plant functional types (PFTs) remains unclear. We compiled a novel dataset of paired leaf traits and spectra, with 47,393 records for >700 species and eight PFTs at 101 globally-distributed locations across multiple seasons. Using this dataset, we conducted an unprecedented comprehensive analysis to assess the transferability of PLSR models in estimating leaf traits. While PLSR models demonstrate commendable performance in predicting chlorophyll content, carotenoid, leaf water and leaf mass per area prediction within their training data space, their efficacy diminishes when extrapolating to new contexts. Specifically, extrapolating to locations, seasons, and PFTs beyond the training data leads to reduced R 2 (0.12-0.49, 0.15-0.42, and 0.25-0.56) and increased NRMSE (3.58-18.24%, 6.27-11.55% and 7.0-33.12%) compared to nonspatial random cross-validation (NRCV). The results underscore the importance of incorporating greater spectral diversity in model training to boost its transferability. These findings highlight potential errors in estimating leaf traits across large spatial domains, diverse PFTs and time due to biased validation schemes and provide guidance for future field sampling strategies and remote sensing applications.

Leaf traits↗
NASA NTRS1999

Apollo 17 Soil Characterization for Reflectance Spectroscopy

It is the fine fractions that dominate the observed spectral signatures of bulk lunar soil, and the next to the smallest size fractions are the most similar to the overall properties of the bulk soil. Thus, our Lunar Soil Characterization Consortium has concentrated on understanding the inter-relations of compositional, mineralogical, and optical properties of the <45-micron size fraction and its component sizes (20-44 micron, 10-20 micron, and <10 micron size fractions). To be able to generalize our results beyond the particular sample set studied, it is necessary to quantitatively identify the observed effects of space weathering and evaluate the processes involved. For this, it is necessary to know the chemistry of each size fraction, modal abundances of each phase, average compositions of the minerals and glasses, I(sub s)/FeO values, reflectance spectra, and the physical makeup of the individual particles and their patinas. This characterization includes the important dissection of the pyroxene minerals into four separate populations, with data on both modes and average chemical compositions. Armed with such data, it should be possible to effectively isolate spectral effects of space weathering from spectral properties related to mineral and glass chemistry. Four mare soils from the Apollo 17 site were selected for characterization based upon similarities in bulk composition and their contrasting maturities, ranging from immature to submature to mature. The methodology of our characterization has been discussed previously. Results of the Apollo 17 mare soils, outlined herein, are being prepared for publication in MAPS. As shown, with decreasing grain size, the agglutinitic (impact) glass content profoundly increases. This is the most impressive change for the mare soils. In several soils we have examined, there is an over two-fold increase in the agglutinitic glass contents between the 90-150- micron and the 10-20-micron size fractions. Accompanying this increase in agglutinitic glass is a definite decrease in pyroxenes and to lesser extents, the oxides (ilmenite), volcanic glass, and olivine. Unexpectedly, however, the absolute plagioclase abundances stay relatively constant throughout the different grain sizes, although the abundance of plagioclase relative to the mafic minerals increases with decreasing particle size. These soils were chosen for study based upon their similarities in FeO and Ti02 content, allowing for direct comparisons between evolutions of chemistry between size fractions and among different maturities of soils. The bulk chemistry of these fractions was determined by EMP analyses of fused glass beads. In contrast to the systematic variations in bulk chemistry discussed below, the relatively uniform composition of agglutinitic glass with grain size and soil maturity is illustrated. The composition of the bulk fraction of each size fraction becomes more feldspathic with increasing maturity, with the effect being most pronounced for the finest fractions. The composition of the agglutinitic glass, however, is relatively invariant and more feldspathic (i.e., rich in Al2O3) than even the <10-micron fraction. This relation not only strengthens the "fusion of the finest fraction" (F(sup 3)) hypothesis, but also highlights the important role of plagioclase in the formation of agglutinitic glass. With decreasing grain size, FeO, MgO, and TiO2 contents decrease, whereas CaO, Na2O, and Al2O3 (plag components) increase for all soils. These chemical variations would appear to be coupled with the significant increase in agglutinitic glass and decrease in oxide (ilmenite),pyroxene, and volcanic glass. These changes in chemistry do not appear to be due to distinct changes in the compositions of individual phases but to their abundances. Values of I(sub s)/FeO increase with decreasing grain size, even though the bulk FeO contents decrease. That is, the percentage of the total Fe that is present as nanophase Fe(sup O) has increased substantially in the smaller size fraction. Note that the increase in nanophase FeO in smaller size fractions is significantly greater than the increase in agglutinitic glass content, with its single-domain FeO component. This would seem to indicate that at least some of the FeO is surface correlated. To illustrate this effect, if it is assumed that the nanophase FeO is entirely surface correlated, then equal masses of 15-micron and 6-micron spheres should have about 3x as much FeO in the finer fraction. The recent findings of Kelleret al. of the major role of vapor-deposited, nanophase FeO-containing patinas on most soil particles is a major breakthrough in our understanding of the distribution of FeO within agglutinitic glass and upon grain surfaces. Bidirectional reflectance spectra for a representative Apollo 17 soil (70181) are shown. The size separates all have similar albedo in the blue and follow a regular sequence in which the continuum slope increases, ferrous bands weaken, and albedo, increases with decreasing particle size. The bulk <45-micron soil is typically close to the 10-20 micron spectrum. It is important to note that although the finest fraction (<10 micron) is close in composition to the abundant agglutinitic glass in each size fraction, this size fraction is relatively featureless and does not dominate the spectrum of the bulk <45-micron soil. It has long been suspected that agglutinitic glass, to a large extent, is the product of melting of the finest fraction of the soils, with a dominance of plagioclase. Given the low abundance of pyroxene in the finest fractions of each soil the source of the FeO in these Apollo 17 agglutinitic glasses is not fully identified. We suspect the abundant volcanic glass in these samples may be a significant contributor and this hypothesis will be tested with the suite under study from other Apollo sites.

Taylor, L. A.↗
NASA NTRS1982

Corn and soybean Landsat MSS classification performance as a function of scene characteristics

In order to fully utilize remote sensing to inventory crop production, it is important to identify the factors that affect the accuracy of Landsat classifications. The objective of this study was to investigate the effect of scene characteristics involving crop, soil, and weather variables on the accuracy of Landsat classifications of corn and soybeans. Segments sampling the U.S. Corn Belt were classified using a Gaussian maximum likelihood classifier on multitemporally registered data from two key acquisition periods. Field size had a strong effect on classification accuracy with small fields tending to have low accuracies even when the effect of mixed pixels was eliminated. Other scene characteristics accounting for variability in classification accuracy included proportions of corn and soybeans, crop diversity index, proportion of all field crops, soil drainage, slope, soil order, long-term average soybean yield, maximum yield, relative position of the segment in the Corn Belt, weather, and crop development stage.

Batista, G. T.↗
NASA NTRS1990

Dynamics of groups around interacting double ellipticals: Measuring dark matter haloes

Binary galaxies, as binary stars, are important to measure masses, as suggested by Page (1952). Because three orbit parameters are measurable for galaxies at one instant of time, severe uncertainties remain in the orbit and mass determinations. These uncertainties can partly be overcome by statistical studies of selected samples and/or n-body simulations. Close double galaxies (and isolated galaxies) could also be useful to estimate dynamical masses if we can find test particles around them. Interacting elliptical pairs or dumb-bell galaxies are found with a large range, between 0-1200 km s(exp -1), of relative radial velocities. Standard 2-body orbit calculations, highly uncertain due to projection factors, suggest for the largest velocity differences very large galaxy masses, if the systems are bound and stationary. However, recent n-body simulations model these binaries as galaxies captured from hyperbolic orbits, requiring masses of order a few times 10(exp 11) solar maximum (Borne et al. 1988), but producing systems that are short lived. A different picture appears when we study observationally the dynamical mass of interacting double ellipticals using faint satellite galaxies. These satellites contribute little luminosity and, presumably, little mass to the system. The authors present results of two such groups, basically forming systems of test particles, around the dumb-bells NGC 4782/3 and IC 5049. They also briefly discuss the satellite group around the central dumb-bell in the cluster Sersic 40/6. Apparently, they detect large quantities of dark matter in the vicinity of these dumb-bell galaxies, because the system masses of approx. 4.5 times 10(exp 13) solar mass and 8 times 10(exp 13) solar mass for NGC 4782/3 and IC 5049, respectively, are quite high. Likewise, the mass of the Sersic 40/6 inner core is 7 times 10(exp 13) solar mass. The possibility that a common massive dark matter halo increases the merging times of these types of galaxies is suggested. Here, the authors assume H sub o = 100 km s (exp -1) Mpc(exp -1).

Quintana, H.↗
NASA NTRS1996

From Stardust to Planetesimals: Contributed Papers

On June 24 through 26, 1996, a scientific conference entitled From Stardust to Planetesimals was held at the Westin Hotel, Santa Clara, California, as part of the 108th annual meeting of the Astronomical Society of the Pacific. Over the last decade, our understanding of the formation and early evolution of the solar system has advanced considerably due to progress that has been made simultaneously on many fronts. Stardust has been isolated in meteorites and interplanetary dust particles (IDP's), providing us with sample materials which predate the solar system and which offer clues to the processing that has occurred. At the same time, infrared studies have led to a better characterization of the composition of interstellar dust, which is now readily accepted as an important component of the interstellar medium infrared observations have also provided a much better view of the star-formation process and the role of dust therein. Recently, the presence of Kuiper Belt planetesimals has been confirmed and spectroscopy of these rather pristine objects may soon become available. Analysis of spacecraft data from the Comet Halley flybys has yielded a wealth of information on the composition of this comet. These observational advances have changed our understanding of planetesimal processing. The launch of the Infrared Space Observatory, the opening of 10-meter class telescopes, and, in the longer term, the Rosetta mission, promise to continue to broaden and deepen our understanding of the evolution from stardust to planetesimals. For these reasons we considered it timely to organize a meeting focused on the processes that connect stardust and planetesimals. The goal of this meeting was, therefore, to bring together astronomers interested in star- and planet-formation, planetary scientists studying early solar system relics, laboratory scientists studying the processing of analogs, and scientists analyzing meteorites and interplanetary dust particles, grain by grain. As a result of this endeavor, over 200 participants, including 153 scientists from 14 different countries, gathered to discuss the origin and evolution of stardust. We hope that this encounter in Santa Clara will foster an ongoing interchange of information and ideas within this diverse group of scientists. A major aim of this meeting was to produce conference proceedings which reflect the current situation regarding the evolution from stardust to planetesimals.

Kress, M. E.↗
NASA NTRS1999

Space Portable Spectroreflectometer (SPSR) Investigation on Mir Space Station

Degradation of thermal control surface properties results from the synergistic effects of the space environment's interaction with materials. This includes the natural space environment and the contamination environment produced by the spacecraft itself. Past flight experiments have utilized small witness samples which were recovered for post flight analysis on the ground. However, reintroduction into an oxygen atmosphere can, in itself, cause a change in the properties of the material being studied. Space based measurements using video cameras were not quantifiable. Very limited experiments have previously measured material properties in-situ on a spacecraft but only using small prepared witness samples with minimal exposure to space. The only way to really determine the properties of actual spacecraft surfaces after an extended exposure to the space environment is to measure them directly, in space. The SPSR provides this capability to measure the most important thermal property which can change in the space environment, the solar absorptivity. The Mir space station provides an excellent opportunity for such experiments due to the long exposure that some of the modules have experienced. Measurements from different modules would have provided an opportunity to determine the effect of various exposure time in orbit and under different contamination environments. Due to other pressing issues only one site was measured using the SPSR.

Carruth, M. Ralph, Jr.↗
NASA NTRS2006

The Dos and Don'ts of how to Build a Planet, Using the Moon as an Example

The bulk chemical compositions of planets may yield important clues concerning planetary origins. Failing that, bulk compositions are still important, in that they constrain calculation of planetary mineralogies and also constrain the petrogenesis of basaltic magmas. In the case of the Earth, there is little or no debate about the composition of the Earth's upper mantle. This is because our sample collections contain peridotitic xenoliths of that mantle. The most fertile of these are believed to have been little modified from their primary compositions. Using these samples and chondritic meteorites as a starting point, small perturbations on the compositions of existing samples allow useful reconstruction of the bulk silicate Earth (BSE). Elsewhere, I have argued that the next simplest case is the Eucrite Parent Body (EPB). Reconstructions based on Sc partitioning indicate that the EPB can be well approximated by a mixture of 20% eucrite and 80% equilibrium olivine. This leads to a parent body that is similar to CO (or devolatilized CM) chondrites. Partial melting experiments on CM chondrites confirm this model, because the residual solids in these experiments are dominated by olivine with minor pigonite [3]. The most difficult bodies to reconstruct are those that have undergone the most differentiation. Both the Moon and Mars may have passed through a magma ocean stage. In any event, lunar and martian basalts, unlike eucrites, were not derived from undifferentiated source regions. Reconstructions are primarily based on compositional trends within the basalts themselves with some critical assumptions: (i) Refractory lithophile elements (Ca, Al, REE, actinides) are presumed to be in chondritic relative abundances; and (ii) some major element ratio is believed to exist in a chondritic ratio (e.g., Mg/Si, Mg/Al). The most commonly used parameter is Mg/Si.

Jones, J. H.↗
NASA NTRS2011

A Bi-Modal Distribution of ALHA77307 Matrix Olivine: Evidence for Fine-Grained Mixing from Multiple Reservoirs in the CO Formation Zone

The CO 3.0 chondrite ALHA77307 is thought to be the least metamorphosed of all the CO chondrites [1]. As such, the fine-grained (<30 m) olivine found in its matrix is a valuable resource for investigating the CO formation environment since its compositions should be primary. In the CO matrix, we indeed find a wide range of major element compositions (Fa(0.5-71)). However, more importantly, we find that the olivines make up two compositionally distinct populations (Fa(0.5-5) and Fa(21-71)). Grains from both populations are found within an extremely close proximity and we see no obvious evidence of two distinct lithologies within our samples. Therefore, we conclude that the olivine grains found in the ALHA77307 matrix must have crystallized within two unique formation conditions and were later mixed at a very fine scale during the accretion epoch. Here, we propose a possible explanation based on Cr and Mn concentrations in the olivine.

Frank, D.↗
NASA NTRS2013

MISSE in the Materials and Processes Technical Information System (MAPTIS )

Materials International Space Station Experiment (MISSE) data is now being collected and distributed through the Materials and Processes Technical Information System (MAPTIS) at Marshall Space Flight Center in Huntsville, Alabama. MISSE data has been instrumental in many programs and continues to be an important source of data for the space community. To facilitate great access to the MISSE data the International Space Station (ISS) program office and MAPTIS are working to gather this data into a central location. The MISSE database contains information about materials, samples, and flights along with pictures, pdfs, excel files, word documents, and other files types. Major capabilities of the system are: access control, browsing, searching, reports, and record comparison. The search capabilities will search within any searchable files so even if the desired meta-data has not been associated data can still be retrieved. Other functionality will continue to be added to the MISSE database as the Athena Platform is expanded

Burns, DeWitt↗
NASA NTRS2015

3-D Printed Ultem 9085 Testing and Analysis

The purpose of this document is to analyze the mechanical properties of 3-D printed Ultem 9085. This document will focus on the capabilities, limitations, and complexities of 3D printing in general, and explain the methods by which this material is tested. Because 3-D printing is a relatively new process that offers an innovative means to produce hardware, it is important that the aerospace community understands its current advantages and limitations, so that future endeavors involving 3-D printing may be completely safe. This document encompasses three main sections: a Slosh damage assessment, a destructive test of 3-D printed Ultem 9085 samples, and a test to verify simulation for the 3-D printed SDP (SPHERES Docking Port). Described below, 'Slosh' and 'SDP' refer to two experiments that are built using Ultem 9085 for use with the SPHERES (Synchronized Position Hold, Engage, Reorient, Experimental Satellites) program onboard the International Space Station (ISS) [16]. The SPHERES Facility is managed out of the National Aeronautics and Space Administration (NASA) Ames Research Center in California.

Aguilar, Daniel↗
NASA NTRS2015

Measuring Skew in Average Surface Roughness as a Function of Surface Preparation

Characterizing surface roughness is important for predicting optical performance. Better measurement of surface roughness reduces grinding saving both time and money and allows the science requirements to be better defined. In this study various materials are polished from a fine grind to a fine polish. Each sample's RMS surface roughness is measured at 81 locations in a 9x9 square grid using a Zygo white light interferometer at regular intervals during the polishing process. Each data set is fit with various standard distributions and tested for goodness of fit. We show that the skew in the RMS data changes as a function of polishing time.

Stahl, Mark T.↗
NASA NTRS2016

The Biomolecule Sequencer Project: Nanopore Sequencing as a Dual-Use Tool for Crew Health and Astrobiology Investigations

Human missions to Mars will fundamentally transform how the planet is explored, enabling new scientific discoveries through more sophisticated sample acquisition and processing than can currently be implemented in robotic exploration. The presence of humans also poses new challenges, including ensuring astronaut safety and health and monitoring contamination. Because the capability to transfer materials to Earth will be extremely limited, there is a strong need for in situ diagnostic capabilities. Nucleotide sequencing is a particularly powerful tool because it can be used to: (1) mitigate microbial risks to crew by allowing identification of microbes in water, in air, and on surfaces; (2) identify optimal treatment strategies for infections that arise in crew members; and (3) track how crew members, microbes, and mission-relevant organisms (e.g., farmed plants) respond to conditions on Mars through transcriptomic and genomic changes. Sequencing would also offer benefits for science investigations occurring on the surface of Mars by permitting identification of Earth-derived contamination in samples. If Mars contains indigenous life, and that life is based on nucleic acids or other closely related molecules, sequencing would serve as a critical tool for the characterization of those molecules. Therefore, spaceflight-compatible nucleic acid sequencing would be an important capability for both crew health and astrobiology exploration. Advances in sequencing technology on Earth have been driven largely by needs for higher throughput and read accuracy. Although some reduction in size has been achieved, nearly all commercially available sequencers are not compatible with spaceflight due to size, power, and operational requirements. Exceptions are nanopore-based sequencers that measure changes in current caused by DNA passing through pores; these devices are inherently much smaller and require significantly less power than sequencers using other detection methods. Consequently, nanopore-based sequencers could be made flight-ready with only minimal modifications.

John, K. K.↗
NASA NTRS2018

Sustaining PICA for Future NASA Robotic Science Missions Including NF-4 and Discovery

Phenolic Impregnated Carbon Ablator (PICA), invented in the mid 1990's, is a low-density ablative thermal protection material proven capable of meeting sample return mission needs from the moon, asteroids, comets and other unrestricted class V destinations as well as for Mars. Its low density and efficient performance characteristics have proven effective for use from Discovery to Flag-ship class missions. It is important that NASA maintain this thermal protection material capability and ensure its availability for future NASA use. The rayon based carbon precursor raw material used in PICA preform manufacturing has experienced multiple supply chain issues and required replacement and requalification at least twice in the past 25 years and a third substitution is now needed. The carbon precursor replacement challenge is twofold - the first involves finding a long-term replacement for the current rayon and the second is to assess its future availability periodically to ensure it is sustainable and be alerted if additional replacement efforts need to be initiated. This paper reviews current PICA sustainability activities to identify a rayon replacement and to establish that the capability of the new PICA derived from an alternative precursor is in family with previous versions.

Stackpoole, Mairead↗
NASA NTRS2018

Sustaining PICA for Future NASA Robotic Science Missions Including NF-4 and Discovery

Phenolic Impregnated Carbon Ablator (PICA), invented in the mid 1990's, is a low-density ablative thermal protection material proven capable of meeting sample return mission needs from the moon, asteroids, comets and other unrestricted class V destinations as well as for Mars. Its low density and efficient performance characteristics have proven effective for use from Discovery to Flag-ship class missions. It is important that NASA maintain this thermal protection material capability and ensure its availability for future NASA use. The rayon based carbon precursor raw material used in PICA preform manufacturing has experienced multiple supply chain issues and required replacement and requalification at least twice in the past 25 years and a third substitution is now needed. The carbon precursor replacement challenge is twofold - the first involves finding a long-term replacement for the current rayon and the second is to assess its future availability periodically to ensure it is sustainable and be alerted if additional replacement efforts need to be initiated. This paper reviews current PICA sustainability activities to identify a rayon replacement and to establish that the capability of the new PICA derived from an alternative precursor is in family with previous versions.

Stackpoole, Mairead↗
NASA NTRS1999

TRMM and Its Connection to the Global Water Cycle

The importance of quantitative knowledge of tropical rainfall, its associated latent heating and variability is summarized in the context of the global hydrologic cycle. Much of the tropics is covered by oceans. What land exists, is covered largely by rainforests that are only thinly populated. The only way to adequately measure the global tropical rainfall for climate and general circulation models is from space. The TRMM orbit is inclined 35' leading to good sampling in the tropics and a rapid precession to study the diurnal cycle of precipitation. The precipitation instrument complement consists of the first rain radar to be flown in space (PR), a multi-channel passive microwave sensor (TMI) and a five-channel VIS/IR (VIRS) sensor. The precipitation radar operates at a frequency of 13.6 GHz. The swath width is 220 km, with a horizontal resolution of 4 km and the vertical resolution of 250 in. The minimum detectable signal from the precipitation radar has been measured at 17 dBZ. The TMI instrument is designed similar to the SSM/I with two important changes. The 22.235 GHz water vapor absorption channel of the SSM/I was moved to 21.3 GHz in order to avoid saturation in the tropics and 10.7 GHz V&H polarized channels were added to expand the dynamic range of rainfall estimates. The resolution of the TMI varies from 4.6 km at 85 GHz to 36 km at 10.7 GHz. The visible and infrared sensor (VIRS) measures radiation at 0.63, 1.6, 3.75, 10.8 and 12.0 microns. The spatial resolution of all five VIRS channels is 2 km at nadir. In addition to the three primary rainfall instruments, TRMM will also carry a Lightning Imaging Sensor (LIS) and a Clouds and the Earth's Radiant Energy System (CERES) instrument.

Kummerow, Christian↗
NASA NTRS1999

TRMM and Its Connection to the Global Water Cycle

The importance of quantitative knowledge of tropical rainfall, its associated latent heating and variability is summarized in the context of the global hydrologic cycle. Much of the tropics is covered by oceans. What land exists, is covered largely by rainforests that are only thinly populated. The only way to adequately measure the global tropical rainfall for climate and general circulation models is from space. The TRMM orbit is inclined 35 degrees leading to good sampling in the tropics and a rapid precession to study the diurnal cycle of precipitation. The precipitation instrument complement consists of the first rain radar to be flown in space (PR), a multi-channel passive microwave sensor (TMI) and a five-channel VIS/IR (VIRS) sensor. The precipitation radar operates at a frequency of 13.6 GHz. The swath width is 220 km, with a horizontal resolution of 4 km and the vertical resolution of 250 m. The minimum detectable signal from the precipitation radar has been measured at 17 dBZ. The TMI instrument is designed similar to the SSM/I with two important changes. The 22.235 GHz water vapor absorption channel of the SSM/I was moved to 21.3 GHz in order to avoid saturation in the tropics and 10.7 GHz V&H polarized channels were added to expand the dynamic range of rainfall estimates. The resolution of the TMI varies from 4.6 km at 85 GHz to 36 km at 10.7 GHz. The visible and infrared sensor (VIRS) measures radiation at 0.63, 1.6, 3.75, 10.8 and 12.0 microns. The spatial resolution of all five VIRS channels is 2 km at nadir. In addition to the three primary rainfall instruments, TRMM will also carry a Lightning Imaging Sensor (LIS) and a Clouds and the Earth's Radiant Energy System (CERES) instrument. This presentation will focus primarily on the advances in our understanding of tropical rain systems needed to interpret the TRMM data. Global averages, as well as case studies from TRMM radar (PR), the TRMM Microwave Imager (TMI) and Visible and Infrared Sensor (VIRS) will be presented. Comparisons and contrasts among the different sensors will be drawn. Results will also be compared to previous rainfall climatologies generated from the SSM/I instrument. In particular this paper will focus on the synergy between the TRMM radar and passive microwave radiometer and what we have learned from is synergy.

Kummerow, Chiristian↗
NASA NTRS1989

Vega-Giotto flyby missions and cometary cosmogony

The most important implication of the Vega/Giotto flyby missions to Halley's Comet for cometary cosmogony is the opportunity to absorb the results of the in-situ measurements as made onboard the spacecrafts. Unfortunately the exploration of ejecta form the nucleus was unable to provide an unambiguous definition of the chemical-mineralogical nature of the nucleus: it failed to provide information comparable to that which was expected from a sample return mission. However, the obtained results are significant enough to affect and redirect cosmogonical thinking. Accordingly, the understanding of the cometary-matter dichotomy is modified as deduced from the distiction of water-dominated volitiles and silicate-based non-volitiles. Organic carbon compounds emerge as a major constituent of cometary nuclei. Presently, it is likely that the revision of Whipple's classic concept of the icy conglomerate cannot be avoided. Affected by the Vega/Giotto flyby missions to Hally's Comet, cometary cosmogony seems to enter a new conceptual period. The results of the in-situ measurements (mass spectrometric, UV spectroscopic, and IR spectroscopic) appear to be of basic importance. A chemical explanation is employed to explain the occurrence inside the nuclei of the variety of species, as inferred from the mass spectrometric data, to predict the results of the processes possibly involved. A cosmochemical factor is postulated to operate behind the observed cometary phenomena. The chemistry of the interstellar medium, covering the circumstellar and interstellar dust, advances cometary cosmogony.

Lang, Bruno↗
NASA NTRS1990

Statistical and physical evolution of quasi-stellar objects

The relationship between the physical evolution of discrete extragalactic sources, the statistical evolution of the observed population of sources, and the cosmological model are discussed. Three simple forms of statistical evolution - pure luminosity evolution (PLE), pure density evolution (PDE), and generalized luminosity evolution (GLE) are considered in detail together with what these forms imply about the physical evolution of individual sources. Two methods are used to analyze the statistical evolution of the observed distribution of QSOs from combined flux-limited samples. It is shown that both PLE and PDE are inconsistent with the data over the redshift range between 0.2 and 2.2 and that a more complicated form of evolution such as GLE is required, independent of the cosmological model. This result is important for physical models of AGN, and in particular, for the accretion disk model which recent results show may be inconsistent with PLE.

Caditz, David↗