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At least 1,387 records · Page 77

Recent Progress in the Engineering of Polymeric Membranes for CO2 Capture from Flue Gas

CO2 capture from coal- or natural gas-derived flue gas has been widely considered as the next opportunity for the large-scale deployment of gas separation membranes. Despite the tremendous progress made in the synthesis of polymeric membranes with high CO2/N2 separation performance, only a few membrane technologies were advanced to the bench-scale study or above from a highly idealized laboratory setting. Therefore, the recent progress in polymeric membranes is reviewed in the perspectives of capture system energetics, process synthesis, membrane scale-up, modular fabrication, and field tests. These engineering considerations can provide a holistic approach to better guide membrane research and accelerate the commercialization of gas separation membranes for post-combustion carbon capture.

20 FOSSIL-FUELED POWER PLANTS↗

Effects of Charged Solute-Solvent Interaction on Reservoir Temperature during Subsurface CO2 Injection

A short-term side-effect of CO2 injection is a developing low-pH front that forms ahead of the bulk water injectant, due to differences in solute diffusivity. Observations of downhole well temperature show a reduction in aqueous-phase temperature with the arrival of a low-pH front, followed by a gradual rise in temperature upon the arrival of a high concentration of bicarbonate ion. In this work, we model aqueous-phase transient heat advection and diffusion, with the volumetric energy generation rate computed from solute-solvent interaction using the Helgeson–Kirkham–Flowers (HKF) model, which is based on the Born Solvation model, for computing specific molar heat capacity and the enthalpy of charged electrolytes. A computed injectant water temperature profile is shown to agree with the actual bottom hole sampled temperature acquired from sensors. The modeling of aqueous-phase temperature during subsurface injection simulation is important for the accurate modeling of mineral dissolution and precipitation because forward dissolution rates are governed by a temperature-dependent Arrhenius model.

58 GEOSCIENCES↗

A Laboratory Corrosion Inhibition Study of Carbon Steel Using 2-Mercaptobenzothiazole (MBT) Under Post-Combustion CO2 Capture Conditions

Corrosion mitigation is an important aspect of amine-based post-combustion carbon dioxide (CO2) capture operations due to the desire to use less expensive but corrosion-vulnerable materials such as low carbon steels in the construction of a capture system. In this study, the corrosion behavior of A106 (grade B) carbon steel with an in-house proprietary amine-based solvent was investigated in a laboratory environment at 80°C using an organic corrosion inhibitor, 2-mercaptobenzothiazole (MBT). The corrosion inhibition mechanism was interpreted by electrochemical methods and surface analyses. The results revealed that the corrosion rates of carbon steel were significantly retarded using MBT. The critical inhibitor concentration was determined to be lie between 10 ppm and 50 ppm under the tested conditions.

Materials Science↗

NGEE Arctic Tram: Periodic Soil CO2 and CH4 Flux Chamber Measurements across Polygonal Tundra, Utqiagvik (Barrow), Alaska, 2014-2017

Soil chamber flux measurements made from a 2014-2017 adjacent to the TRAM system, with measurements referenced to TRAM stop numbers. Dataset includes measurements using transparent and opaque chambers (CO2 and CH4 fluxes in light and dark). The Tram location was selected to be in the footprint of the NGEE Arctic AmeriFlux tower (US-NGB). Measurement stop positions are at 0.5 m intervals (1-137) over the 68 m Tram track. Dataset includes one CSV data file and one user guide in PDF. The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Dynamic integration of GCAM-Demeter and CLUBS-Select: Datasets on urban extensification effects on land cover, crop yields, net primary production, and CO2 emissions

The datasets provide background data from McManamay et al. (2024) Nature Communications Earth and Environment. We integrate projected dynamic non-urban lands from GCAM-Demeter with projected dynamic urban lands from SELECT from 2015 to 2100 at 1-km resolution to examine stress to the land system, compromised crop production, and losses in Net Primary Production (NPP), that can arise from the competition over land resources. These datasets include changes to non-urban land use and land cover, estimated losses in crop yields, losses in NPP, and increases in CO2 emissions.

Earth Systems↗

Operation manual for the CO2 laser system

A detailed complete step by step procedure for the alignment and successful operation of the 10.6 m CO2 laser system used for the study of Mandelshtam-Brillouin scattering is outlined.

Daniels, A.↗

Life testing of metal-ceramic CO2 lasers

The main purpose of this program was to determine the life characteristics of nine space-qualified, metal-ceramic CO2 lasers. Lifetimes ranged between about 400 hours to over 2000 hours (the limit of testing) with a high degree of consistency in like groups. In all cases the tubes which had failed could be restored to near their original power by doubling the cathode current for 30 minutes. Periodic rejuvenation allowed operation for the full 2000 hours on all tubes. The failure mechanism appears to involve formation of NiO and C on the nickel cathode emission surface with subsequent absorption of tube gases.

Fahlen, T. S.↗

Computer program of data reduction procedures for facilities using CO2-N2-O2-Ar equilibrium real-gas mixtures

Data reduction procedures for determining free-stream and post-normal-shock flow conditions are presented. These procedures are applicable to flows of CO2, N2, O2, Ar, or mixtures of these gases and include the effects of dissociation and ionization. The assumption of thermochemical equilibrium free-stream and post-normal-shock flow is made. Although derived primarily to meet the immediate needs of an expansion tube of a hot gas radiation research facility, these procedures are applicable to any supersonic or hypersonic test facility using these gases or mixtures thereof. The data reduction procedures are based on combinations of three of the following flow parameters measured in the immediate vicinity of the test section: (1) stagnation pressure behind normal shock, (2) free-stream static pressure, (3) stagnation-point heat-transfer rate, (4) free-stream velocity, and (5) free-stream density. Thus, these procedures do not depend explicitly upon measured or calculated upstream flow parameters. The procedures are incorporated into a single computer program written in FORTRAN IV language. A listing of this computer program is presented, along with a description of the inputs required and a sample of the data printout.

Miller, C. G., III↗

One-man, self-contained CO2 concentrating system

A program to design, fabricate, and test a 1-man, self-contained, electrochemical CO2 concentrating system is described. The system was designed with electronic controls and instrumentation to regulate performance, to analyze and display performance trends, and to detect and isolate faults. Ground support accessories were included to provide power, fluids, and a Parametric Data Display allowing real time indication of operating status in engineering units.

Wynveen, R. A.↗

Infrared spectra of CO2 in the atmospheres of Earth and Venus

A theoretical calculation was made of the CO2 infrared spectra of Earth and Venus atmospheres. The calculations cover line intensity, line shape, and line position. Theoretical results were compared with those observed by Nimbus 3 satellite and were found to be in reasonable agreement.

Maguire, W. C.↗