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At least 1,387 records · Page 77

Imaging Phase Segregation in Nanoscale Li x CoO 2 Single Particles

Li x CoO 2 (LCO) is a common battery cathode material that has recently emerged as a promising material for other applications including electrocatalysis and as electrochemical random access memory (ECRAM). During charge– discharge cycling LCO exhibits phase transformations that are significantly complicated by electron correlation. While the bulk phase diagram for an ensemble of battery particles has been studied extensively, it remains unclear how these phases scale to nanometer dimensions and the effects of strain and diffusional anisotropy at the single-particle scale. Understanding these effects is critical to modeling battery performance and for predicting the scalability and performance of electrocatalysts and ECRAM. Here we investigate isolated, epitaxial LiCoO 2 islands grown by pulsed laser deposition. After electrochemical cycling of the islands, conductive atomic force microscopy (c-AFM) is used to image the spatial distribution of conductive and insulating phases. Above 20 nm island thicknesses, we observe a kinetically arrested state in which the phase boundary is perpendicular to the Li-planes; we propose a model and present image analysis results that show smaller LCO islands have a higher conductive fraction than larger area islands, and the overall conductive fraction is consistent with the lithiation state. Thinner islands (14 nm), with a larger surface to volume ratio, are found to exhibit a striping pattern, which suggests surface energy can dominate below a critical dimension. When increasing force is applied through the AFM tip to strain the LCO islands, significant shifts in current flow are observed, and underlying mechanisms for this behavior are discussed. The c-AFM images are compared with photoemission electron microscopy images, which are used to acquire statistics across hundreds of particles. Finally, the results indicate that strain and morphology become more critical to electrochemical performance as particles approach nanometer dimensions.

25 ENERGY STORAGE↗

Excitability in the H{sub 2}+O{sub 2} reaction on a Rh(110) surface induced by high coverages of coadsorbed potassium

By means of photoemission electron microscopy as spatially resolving method, the effect of high coverages of coadsorbed potassium (0.16 ≤ θ{sub K} ≤ 0.21) on the dynamical behavior of the H{sub 2} + O{sub 2} reaction over a Rh(110) surface was investigated. We observe that the originally bistable system is transformed into an excitable system as evidenced by the formation of target patterns and spiral waves. At K coverages close to saturation (θ{sub K} ≈ 0.21) mass transport of potassium with pulses is seen.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Influence of dislocations on indium diffusion in semi-polar InGaN/GaN heterostructures

The spatial distribution of indium composition in InGaN/GaN heterostructure is a critical topic for modulating the wavelength of light emitting diodes. In this letter, semi-polar InGaN/GaN heterostructure stripes were fabricated on patterned GaN/Sapphire substrates by epitaxial lateral overgrowth (ELO), and the spatial distribution of indium composition in the InGaN layer was characterized by using cathodoluminescence. It is found that the indium composition is mainly controlled by the diffusion behaviors of metal atoms (In and Ga) on the surface. The diffusivity of metal atoms decreases sharply as migrating to the region with a high density of dislocations and other defects, which influences the distribution of indium composition evidently. Our work is beneficial for the understanding of ELO process and the further development of InGaN/GaN heterostructure based devices.

36 MATERIALS SCIENCE↗

Experimental and ab initio studies on sub-lattice ordering and magnetism in Co{sub 2}Fe(Ge{sub 1−x}Si{sub x}) alloys

Crystallographic and magnetic properties of bulk Co{sub 2}Fe(Ge{sub 1−x}Si{sub x}) alloys with 0 ≤ x ≤ 1, synthesized by arc melting method, have been studied. Co{sub 2}FeSi alloy has been found to crystallize with L2{sub 1} structure, but the super-lattice peaks are absent in the X-ray diffraction patterns of alloys containing high Ge concentration. Unit cell volume of this series of alloys decreased from 185.2 to 178.5 Å{sup 3} as Si content was increased from 0 to 1.00. All alloy compositions exhibit ferromagnetic behavior with a high Curie temperature (T{sub C}). T{sub C} showed a systematic variation with x. A comparison between the values of saturation magnetization (M{sub s}) and effective moment per magnetic atom p{sub c} estimated from the temperature dependent susceptibility data above T{sub C}, shows that the alloys have half-metallic character. The alloy with x = 0 follows Slater-Pauling (S-P) rule with M{sub s} of 5.99μ{sub B}. However, M{sub s} for the alloy with x = 1.00 was found to be 5.42μ{sub B}, which is lower than the value of 6.0μ{sub B} predicted by S-P rule. Since atomic disorder is known to affect the M{sub s} and electronic structure of these alloys, ab initio calculations were carried out to explain the deviation in observed M{sub s} from S-P rule prediction and the half-metallic character of the alloys. Ab initio calculations reveal that alloys with L2{sub 1} structure have M{sub s} value as predicted by S-P rule. However, introduction of 12.5% DO{sub 3} disorder, which occurs due to swapping of Co and Fe atoms in the unit cell, decreases M{sub s} of alloys with x > 0 from the S-P prediction to values obtained experimentally. The results analyzed from the view point of electronic structure of the alloys in different ordered states bring out the influence of disorder on the observed magnetic properties of these technologically important alloys.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Design and simulation of MEMS vector hydrophone with reduced cross section based meander beams

MEMS based vector hydrophone is being one of the key device in the underwater communications. In this paper, we presented a bio-inspired MEMS vector hydrophone. The hydrophone structure consists of a proof mass suspended by four meander type beams with reduced cross-section. Modal patterns of the structure were studied. First three modal frequencies of the hydrophone structure were found to be 420 Hz, 420 Hz and 1646 Hz respectively. The deflection and stress of the hydrophone is found have linear behavior in the 1 µPa – 1Pa pressure range.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Understanding the Drivers of Mobility during the COVID-19 Pandemic in Florida, USA Using a Machine Learning Approach

As of March 2021, the State of Florida, U.S.A. had accounted for approximately 6.67% of total COVID-19 (SARS-CoV-2 coronavirus disease) cases in the U.S. The main objective of this research is to analyze mobility patterns during a three month period in summer 2020, when COVID-19 case numbers were very high for three Florida counties, Miami-Dade, Broward, and Palm Beach counties. To investigate patterns, as well as drivers, related to changes in mobility across the tri-county region, a random forest regression model was built using sociodemographic, travel, and built environment factors, as well as COVID-19 positive case data. Mobility patterns declined in each county when new COVID-19 infections began to rise, beginning in mid-June 2020. While the mean number of bar and restaurant visits was lower overall due to closures, analysis showed that these visits remained a top factor that impacted mobility for all three counties, even with a rise in cases. Our modeling results suggest that there were mobility pattern differences between counties with respect to factors relating, for example, to race and ethnicity (different population groups factored differently in each county), as well as social distancing or travel-related factors (e.g., staying at home behaviors) over the two time periods prior to and after the spike of COVID-19 cases.

60 APPLIED LIFE SCIENCES↗

VTOL in-ground effect flows for closely spaced jets

The interaction of two vertically impinging incompressible jets is studied through the invention of physical flow models that approximate the behavior of colliding wall jets as the incident jets are brought closer together. The mechanism for upwash formation is studied and momentum models for the upwash sheet are postulated. An approximate method for computing the ground isobar pattern of jet and upwash deflection zones is presented and compared with test data. A method for computing the upwash impingement force in the absence of secondary induced flow effects is also presented and reasonably good agreement is achieved with experimental data for cylindrical fuselage shapes of circular and rectangular cross section.

Siclari, M. J.↗

LANDSAT and radar mapping of intrusive rocks in SE-Brazil

The feasibility of intrusive rock mapping was investigated and criteria for regional geological mapping established at the scale of 1:500,00 in polycyclic and polymetamorphic areas using the logic method of photointerpretation of LANDSAT imagery and radar from the RADAMBRASIL project. The spectral behavior of intrusive rocks, was evaluated using the interactive multispectral image analysis system (Image-100). The region of Campos (city) in northern Rio de Janeiro State was selected as the study area and digital imagery processing and pattern recognition techniques were applied. Various maps at the 2:250,000 scale were obtained to evaluate the results of automatic data processing.

Parada, N. D. J.↗

Use of satellite soundings and imagery for nowcasting and very-short-range forecasting

Examples of GOES-East satellite imagery and sounding channel information are used to show how atmospheric behavior in the vicinity of intense mesoscale weather events can be analyzed. Mesoscale spatial and temporal information on atmospheric thermal structure and moisture distribution can be determined using satellite sounding and multispectral image data. Clouds and cloud patterns in a satellite image or animated series of images represent the integrated effect of ongoing dynamic and thermodynamic processes in the atmosphere. When information from satellite data is combined with radar, surface and upper air observations, important processes in storm development can be better understood.

Purdom, J. F. W.↗

Compressive creep strain measurements using moire interferometry

Uniaxial compressive creep loads were applied to quasi-isotropic composite laminates at room temperature. The x and y displacement fields were measured using moire interferometry. Moire fringe patterns were recorded photographically; these photographic records were subsequently digitized and reduced to in-plane strain levels numerically. Strain contours were plotted, providing a whole-field representation of in-plane strain distribution. Slight viscoelastic behavior was observed over the time period considered, except in one test in which time-dependent delamination failures were observed.

Tuttle, M. E.↗

Heterogeneity and scaling land-atmospheric water and energy fluxes in climate systems

The effects of small-scale heterogeneity in land surface characteristics on the large-scale fluxes of water and energy in land-atmosphere system has become a central focus of many of the climatology research experiments. The acquisition of high resolution land surface data through remote sensing and intensive land-climatology field experiments (like HAPEX and FIFE) has provided data to investigate the interactions between microscale land-atmosphere interactions and macroscale models. One essential research question is how to account for the small scale heterogeneities and whether 'effective' parameters can be used in the macroscale models. To address this question of scaling, three modeling experiments were performed and are reviewed in the paper. The first is concerned with the aggregation of parameters and inputs for a terrestrial water and energy balance model. The second experiment analyzed the scaling behavior of hydrologic responses during rain events and between rain events. The third experiment compared the hydrologic responses from distributed models with a lumped model that uses spatially constant inputs and parameters. The results show that the patterns of small scale variations can be represented statistically if the scale is larger than a representative elementary area scale, which appears to be about 2 - 3 times the correlation length of the process. For natural catchments this appears to be about 1 - 2 sq km. The results concerning distributed versus lumped representations are more complicated. For conditions when the processes are nonlinear, then lumping results in biases; otherwise a one-dimensional model based on 'equivalent' parameters provides quite good results. Further research is needed to fully understand these conditions.

Wood, Eric F.↗

Auxin-activated NADH oxidase activity of soybean plasma membranes is distinct from the constitutive plasma membrane NADH oxidase and exhibits prion-like properties

The hormone-stimulated and growth-related cell surface hydroquinone (NADH) oxidase activity of etiolated hypocotyls of soybeans oscillates with a period of about 24 min or 60 times per 24-h day. Plasma membranes of soybean hypocotyls contain two such NADH oxidase activities that have been resolved by purification on concanavalin A columns. One in the apparent molecular weight range of 14-17 kDa is stimulated by the auxin herbicide 2,4-dichlorophenoxyacetic acid (2,4-D). The other is larger and unaffected by 2,4-D. The 2,4-D-stimulated activity absolutely requires 2,4-D for activity and exhibits a period length of about 24 min. Also exhibiting 24-min oscillations is the rate of cell enlargement induced by the addition of 2,4-D or the natural auxin indole-3-acetic acid (IAA). Immediately following 2,4-D or IAA addition, a very complex pattern of oscillations is frequently observed. However, after several hours a dominant 24-min period emerges at the expense of the constitutive activity. A recruitment process analogous to that exhibited by prions is postulated to explain this behavior.

Non-NASA Center↗

Quantum-Assisted Variational Segmentation for Image-to-Image Wildfire Detection Using Satellite Data

The quantum computing community has been searching for suitable applications to demonstrate the potential of near-term quantum devices. Quantum machine learning is a potential candidate, particularly using models that cannot be efficiently simulated with classical computers [1, 2]. This work focuses on a transition phase of quantum computers where the quantum machine learning model is still simulable classically but projected not to be simulable as the size of the model grows. Ultimately quantum computers may have advantages for high-dimensional real-world problems. Due to the limited number of qubits in current noisy intermediate-scale quantum (NISQ) devices, the direct application of quantum computers in high dimensional data is not feasible. To remedy this problem, an encoder-decoder architecture can be utilized. The encoder model would transform the high-dimensional data into a compact representation, to a level that small quantum computers can be used today (or in the near future), and the decoder would take the quantum processed outputs back to the high-dimensional space. Addressing the two challenges of quantum machine learning, this work investigates a hybrid supervised generative model with a quantum Ising Born machine embedded as the latent distribution. The model contains four main parts (Figure 1.a.): (1) a U-NET architecture responsible for learning segmentation flow, (2) a Prior network responsible for learning an encoded latent distribution of the input data, (3) a Born machine which represents the latent distribution, and (4) a Posterior network in charge of learning the joint encoded latent distribution of inputs and target data. The initial model, proposed by [3], is optimized by (1) maximizing the overlap of the prior and posterior latent distributions, and (2) minimizing the segmentation loss. The proposed model is designed to be investigated in a simulation environment applied to the real-world application of wildfire segmentation. Specifically, the model is designed to solve the patchy wildfire segmentations of Moderate Resolution Imaging Spectroradiometer (MODIS) by taking the MODIS observations and using Visible Infrared Imaging Radiometer Suite’s (VIIRS) consistent wildfire product as the target. The model solves patchy wildfire segmentations and provides insight into the epistemic errors sourced from model variation. The model utilizes the Born machine as a QUBO solver to represent the latent space as a Bernoulli distribution. The proposed configuration allows the variational segmentation model to leverage the true quantum probabilistic nature and derive a more expressive latent configuration, increasing the model performance in describing wildfire segmentations. The quantum probabilistic information of the Born machine is directly incorporated in the Kullback-Leibler divergence loss in the prior and posterior distributions, forcing the Bernoulli latent distribution to maximize the overlap of input and joint input-target distributions. The proposed model is then trained and compared with a baseline only consisting of direct Bernoulli latent distribution with no Born machine representing the latent space. The models are evaluated based on the segmentation metrics, such as precision, recall, intersect of union, with uncertainty boundaries accounting for the stochastic nature of the model. Our findings show that even in low latent-dimensional space (due to the limit in computational power of the classical quantum simulator), we are able to effectively capture the latent representation and hence the model performs better than the baseline. The findings are a projection for scaling the model into higher dimensional latent space with the Born machine surpassing the baseline performance. Figure 1. Sub-figure (a) demonstrates the architecture for the training phase. The model consists of a Prior and Posterior network that encode inputs and joint input-target data into compact representations, respectively. The Born machine represents the latent distribution, and the U-NET branch learns the segmentation patterns of the data. The stochasticity is introduced to the U-NET through its last layer to create meaningful but stochastic segmentations. Sub-figure (b) represents the inference phase where the model takes the stochastic behavior from the prior network and injects that into the U-NET. Each attempt of inference will generate different but similar segmentations from the same distribution of the wildfire event. REFERENCES [1] Coyle, B., Mills, D., Danos, V., & Kashefi, E. (2020). The Born supremacy: quantum advantage and training of an Ising Born machine. npj Quantum Information, 6(1), 1-11. [2] Liu, J. G., & Wang, L. (2018). Differentiable learning of quantum circuit born machines. Physical Review A, 98(6), 062324. [3] Kohl, S., Romera-Paredes, B., Meyer, C., De Fauw, J., Ledsam, J. R., Maier-Hein, K., ... & Ronneberger, O. (2018). A probabilistic u-net for segmentation of ambiguous images. Advances in neural information processing systems, 31.

quantum machine learning↗

The Diurnal Variation of Dust and Water Ice Aerosol Optical Depth at Jezero Crater Observed By MEDA/TIRS Over A Full Martian Year

The Thermal InfraRed Sensor (TIRS) on the Perseverance rover has provided nearly two full Mars years of systematic monitoring of the total aerosol optical depth above Jezero Crater. These observations span a wide range of timescales, capturing seasonal patterns, diurnal variations, and minute-to-minute fluctuations in aerosol loading. By combining TIRS retrievals with orbital observations, the relative contributions of dust and water ice aerosols can be estimated, revealing their different seasonal and diurnal behaviors. The TIRS record shows distinct periods of dust storm activity, including strong regional storms during the perihelion season as well as short lived but intense dust events outside the typical dust storm season. Water ice clouds exhibit pronounced seasonal and diurnal variability, with peak activity occurring during the aphelion season but with a presence throughout the year. The diurnal variation of clouds differs significantly between the aphelion and perihelion seasons, with clouds persisting throughout the night during the aphelion season, while largely absent outside of specific periods after sunrise and sunset during the perihelion season. These results provide new insights into the complex behavior of aerosols at Jezero Crater and their connections to atmospheric dynamics and the Martian dust and water cycles.

Michael D Smith↗

Analysis of Electric Vehicle Charging Impact on the Electric Power Grid

In order to evaluate the impact of electric vehicles (EVs) on the distribution grid and assess their potential benefits to the future smart grid, it is crucial to study the EV charging patterns and the usage charging station. Though EVs are not yet widely adopted nationwide, a valuable methodology to conduct such studies is the statistical analysis of real-world charging data. This paper presents actual EV charging behavior of 64 EVs (5 brands, 8 models) from EV users and charging stations at Los Angeles Department of Water and Power for more than one year. Twenty-four-hour EV charging load curves have been generated and studied for various load periods: daily, monthly, seasonally and yearly. Finally, the effect and impact of EV load on the California distribution network are evaluated at different EV penetration rates.

33 ADVANCED PROPULSION SYSTEMS↗

Structural transitions in Pb(In 1/2 Nb 1/2 )O 3 under pressure

Here, Raman scattering, x-ray diffraction, and first-principles calculations were employed to investigate the behavior of disordered Pb(In 1/2 Nb 1/2 )O 3 (PIN) under pressure up to 50 GPa. The experiments were performed at room temperature while ab-initio calculations were carried out at 0 K. Raman spectra for disordered PIN show broad bands but a peak near the 380 cm -1 increases its intensity with pressure. The linewidth of the band at 550 cm -1 also increases with pressure, while two of the Raman peaks merge above 6 GPa. Above 16 GPa, we observe additional splitting of the band at 50 cm -1 . The pressure evolution of the diffraction patterns for PIN shows obvious splitting for Bragg peaks above 16 GPa; the results indicate a possible lowering symmetry transition. We identified that the transition at 0.5 GPa is from pseudo-cubic to orthorhombic (Pbam), the transitions at 16 GPa are isostructure transitions due to changes in linear compressibility and octahedral titling, and the transition at 30 GPa is from orthorhombic to monoclinic. First-principles calculations results indicated that ground state is Pbam with antiferrodisdortion consistent with experiment.

36 MATERIALS SCIENCE↗

High-resolution observations of the shock wave behavior for sunspot oscillations with the interface region imaging spectrograph

We present the first results of sunspot oscillations from observations by the Interface Region Imaging Spectrograph. The strongly nonlinear oscillation is identified in both the slit-jaw images and the spectra of several emission lines formed in the transition region and chromosphere. We first apply a single Gaussian fit to the profiles of the Mg II 2796.35 Å, C II 1335.71 Å, and Si IV 1393.76 Å lines in the sunspot. The intensity change is ∼30%. The Doppler shift oscillation reveals a sawtooth pattern with an amplitude of ∼10 km s{sup –1} in Si IV. The Si IV oscillation lags those of C II and Mg II by ∼6 and ∼25 s, respectively. The line width suddenly increases as the Doppler shift changes from redshift to blueshift. However, we demonstrate that this increase is caused by the superposition of two emission components. We then perform detailed analysis of the line profiles at a few selected locations on the slit. The temporal evolution of the line core is dominated by the following behavior: a rapid excursion to the blue side, accompanied by an intensity increase, followed by a linear decrease of the velocity to the red side. The maximum intensity slightly lags the maximum blueshift in Si IV, whereas the intensity enhancement slightly precedes the maximum blueshift in Mg II. We find a positive correlation between the maximum velocity and deceleration, a result that is consistent with numerical simulations of upward propagating magnetoacoustic shock waves.

79 ASTRONOMY AND ASTROPHYSICS↗

Zonal Flows and Turbulence in Fluids and Plasmas

In geophysical and plasma contexts, zonal flows are well known to arise out of turbulence. We elucidate the transition from statistically homogeneous turbulence without zonal flows to statistically inhomogeneous turbulence with steady zonal flows. Starting from the Hasegawa--Mima equation, we employ both the quasilinear approximation and a statistical average, which retains a great deal of the qualitative behavior of the full system. Within the resulting framework known as CE2, we extend recent understanding of the symmetry-breaking `zonostrophic instability'. Zonostrophic instability can be understood in a very general way as the instability of some turbulent background spectrum to a zonally symmetric coherent mode. As a special case, the background spectrum can consist of only a single mode. We find that in this case the dispersion relation of zonostrophic instability from the CE2 formalism reduces exactly to that of the 4-mode truncation of generalized modulational instability. We then show that zonal flows constitute pattern formation amid a turbulent bath. Zonostrophic instability is an example of a Type Is instability of pattern-forming systems. The broken symmetry is statistical homogeneity. Near the bifurcation point, the slow dynamics of CE2 are governed by a well-known amplitude equation, the real Ginzburg-Landau equation. The important features of this amplitude equation, and therefore of the CE2 system, are multiple. First, the zonal flow wavelength is not unique. In an idealized, infinite system, there is a continuous band of zonal flow wavelengths that allow a nonlinear equilibrium. Second, of these wavelengths, only those within a smaller subband are stable. Unstable wavelengths must evolve to reach a stable wavelength; this process manifests as merging jets. These behaviors are shown numerically to hold in the CE2 system, and we calculate a stability diagram. The stability diagram is in agreement with direct numerical simulations of the quasilinear system. The use of statistically-averaged equations and the pattern formation methodology provide a path forward for further systematic investigations of zonal flows and their interactions with turbulence.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗