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At least 1,387 records · Page 77

Utilization of the Differential Die-Away Self-Interrogation Technique for Characterization and Verification of Spent Nuclear Fuel

New nondestructive assay techniques are sought to better characterize spent nuclear fuel. One of the NDA instruments selected for possible deployment is differential die-away self-interrogation (DDSI). The proposed DDSI approach for spent fuel assembly assay utilizes primarily the spontaneous fission and (α, n) neutrons in the assemblies as an internal interrogating radiation source. The neutrons released in spontaneous fission or (α,n) reactions are thermalized in the surrounding water and induce fission in fissile isotopes, thereby creating a measurable signal from isotopes of interest that would be otherwise difficult to measure. The DDSI instrument employs neutron coincidence counting with 3He tubes and list-mode-based data acquisition to allow for production of Rossi-alpha distributions (RADs) in post-processing. The list-mode approach to data collection and subsequent construction of RADs has expanded the analytical possibilities, as will be demonstrated throughout this thesis. One of the primary advantages is that the measured signal in the form of a RAD can be analyzed in its entirety including determination of die-away times in different time domains. This capability led to the development of the early die-away method, a novel leakage multiplication determination method which is tested throughout the thesis on different sources in simulation space and fresh fuel experiments. The early die-away method is a robust, accurate, improved method of determining multiplication without the need for knowledge of the (α,n) source term. The DDSI technique and instrument are presented along with the many novel capabilities enabled by and discovered through RAD analysis. Among the new capabilities presented are the early die-away method, total plutonium content determination, and highly sensitive missing pin detection. Simulation of hundreds of different spent and fresh fuel assemblies were used to develop the analysis algorithms and the techniques were tested on a variety of spontaneous fission-driven fresh fuel assemblies at Los Alamos National Laboratory and the BeRP ball at the Nevada National Security Site. The development of the new, improved analysis and characterization methods with the DDSI instrument makes it a viable technique for implementation in a facility to meet material control and safeguards needs.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Hardware-in-the-Loop Testing of Utility-Scale Wind Turbine Generators

Historically, wind turbine prototypes were tested in the field, which was--and continues to be--a slow and expensive process. As a result, wind turbine dynamometer facilities were developed to provide a more cost-effective alternative to field testing. New turbine designs were tested and the design models were validated using dynamometers to drive the turbines in a controlled environment. Over the years, both wind turbine dynamometer testing and computer technology have matured and improved, and the two are now being joined to provide hardware-in-the-loop (HIL) testing. This type of testing uses a computer to simulate the items that are missing from a dynamometer test, such as grid stiffness, voltage, frequency, rotor, and hub. Furthermore, wind input and changing electric grid conditions can now be simulated in real time. This recent advance has greatly increased the utility of dynamometer testing for the development of wind turbine systems.

17 WIND ENERGY↗

Advanced Burner Reactor with Breed-and-Burn Thorium Blankets for Improved Economics and Resource Utilization

This study assesses the feasibility of designing Seed and Blanket (S&B) Sodium-cooled Fast Reactor (SFR) to generate a significant fraction of the core power from radial thorium fueled blankets that operate on the Breed-and-Burn (B&B) mode without exceeding the radiation damage constraint of presently verified cladding materials. The S&B core is designed to maximize the fraction of neutrons that radially leak from the seed (or “driver”) into the subcritical blanket and reduce neutron loss via axial leakage. The blanket in the S&B core makes beneficial use of the leaking neutrons for improved economics and resource utilization. A specific objective of this study is to maximize the fraction of core power that can be generated by the blanket without violating the thermal hydraulic and material constraints. Since the blanket fuel requires no reprocessing along with remote fuel fabrication, a larger fraction of power from the blanket will result in a smaller fuel recycling capacity and lower fuel cycle cost per unit of electricity generated. A unique synergism is found between a low conversion ratio (CR) seed and a B&B blanket fueled by thorium. Among several benefits, this synergism enables the very low leakage S&B cores to have small positive coolant voiding reactivity coefficient and large enough negative Doppler coefficient even when using inert matrix fuel for the seed. The benefits of this synergism are maximized when using an annular seed surrounded by an inner and outer thorium blankets. Among the high-performance S&B cores designed to benefit from this unique synergism are: (1) the ultra-long cycle core that features a cycle length of ~7 years; (2) the high-transmutation rate core where the seed fuel features a TRU CR of 0.0. Its TRU transmutation rate is comparable to that of the reference Advanced Burner Reactor (ABR) with CR of 0.5 and the thorium blanket can generate close to 60% of the core power; but requires only one sixth of the reprocessing and fabrication capacity per unit of core power. Nevertheless, these high-performance cores were designed to set upper bounds on the S&B core performance by using larger height and pressure drop than those of typical SFR design. A study was subsequently undertaken to quantify the tradeoff between S&B core design variables and the core performance. This study concludes that a viable S&B core can be designed without significant deviation from SFR core design practices. For example, the S&B core with 120cm active height will be comparable in volume, HM mass and specific power with the S-PRISM core and could fit within the S-PRISM reactor vessel. 43% of this core power will be generated by the once-through thorium blanket; the required capacity for reprocessing and remote fuel fabrication per unit of electricity generated will be approximately one fifth of that for a comparable ABR. The sodium void worth of this 120cm tall S&B core is significantly less positive than that of the reference ABR and the Doppler coefficient is only slightly smaller even though the seed uses a fertile-free fuel. The seed in the high transmutation core requires inert matrix fuel (TRU-40Zr) that has been successfully irradiated by the Fuel Cycle Research & Development program. An additional sensitivity analysis was later conducted to remove the bias introduced by the discrepancy between radiation damage constraints -- 200 DPA applied for S&B cores and fast fluence of 4x1023 n(>0.1MeV)/cm2 applied for ABR core design. Although the performance characteristics of the S&B cores are sensitive to the radiation damage constraint applied, the S&B cores offer very significant performance improvements relative to the conventional ABR core design when using identical constraint.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Enhancement of photoassimilate utilization by manipulation of starch regulatory enzymes

ADPglucose pyrophosphorylase (AGPase) and the plastidial starch phosphorylase1 (Pho1) are two regulatory enzymes whose catalytic activities are essential for starch granule synthesis. Conversion of the pre-starch granule to the mature form is dependent on AGPase, which produces ADPglucose, the substrate used by starch synthases. The catalytic activity of AGPase is controlled by small effector molecules and a prime goal of this project was to decipher the role of the two subunit types that comprise the heterotetrameric enzyme structure. Extensive genetic and biochemical studies showed that catalysis was contributed mainly by the small subunit although the large subunit was required for maximum activity. Both subunits were needed for allosteric regulatory properties. We had also demonstrated that the AGPase catalyzed reaction limits the amount of starch accumulation in developing rice seeds and that carbon flux into rice seed starch can be increased by expression of a cytoplasmic-localized, up-regulated bacterial AGPase enzyme form. Results of subsequent physiological and metabolite studies showed that the AGPase reaction is no longer limiting in the AGPase transgenic rice lines and that one or more downstream processes prevent further increases in starch biosynthesis. Further studies showed that over-production of ADPglucose dramatically alters the gene program during rice seed development. Although the expression of nearly all of the genes are down-regulated, levels of a starch binding domain containing protein (SBDCP) are elevated. This SBDCP was found to bind to and inhibit the catalytic activity of starch synthase III and, thereby preventing maximum starch synthesis from occurring. Surprisingly, repression of SBDCP elevated expression of starch synthase III resulting in increasing rice grain weight. A second phase of this project examined the structure-function of Pho1, the enzyme required during the initial phase of pre-starch granule formation and its maturation to a starch granule. Although Pho1 catalyzes a reversible reaction, our DoE supported studies clearly demonstrated that the kinetic properties of this enzyme strongly favor synthesis of starch and that these catalytic properties are independent of the L80 peptide, a structural domain that is absent in phosphorylases from other organisms. Interesting expression of a Pho1 lacking the L80 peptide enhanced plant growth and seed yields, suggesting that Pho1 has a second function in controlling growth. Overall, results from these biochemical and physiological studies have increased our fundamental understanding on how these important starch regulatory enzymes operate at the molecular level and in planta, which will collectively aid in efforts to increase the utilization of higher plants as a renewable source of energy.

59 BASIC BIOLOGICAL SCIENCES↗

Assessing Pinyon Juniper Feedstock Properties and Utilization Options

Pinyon-juniper woodlands are a major ecosystem type found in the Southwest and the Intermountain West regions of the United States. These ecosystems are characterized by the presence of several different species of pinyon pine and juniper as the dominant plant cover. Since the 1800s, pinyon-juniper woodlands have rapidly expanded their range at the expense of existing ecosystems. Additionally, existing woodlands have become more dense, potentially increasing fire hazards. Land managers responsible for these areas often desire to reduce pinyonjuniper coverage on their lands for a variety of reasons, including restoration to previous vegetative cover, mitigation of fire risk, and improvement in wildlife habitat. However, the cost of clearing or thinning pinyon-juniper stands can be prohibitive. One reason for this is the lack of utilization options for the resulting biomass that could help recover some of the cost of pinyonjuniper stand management. The goal of this project was to assess the feedstock characteristics of biomass from a pinyon-juniper harvest so that potential applications for the biomass may be evaluated.

59 BASIC BIOLOGICAL SCIENCES↗

Utilization of UV Curing Technology to Significantly Reduce the Manufacturing Cost of LIB Electrodes

Previously identified novel binders and associated UV curing technology have been shown to reduce the time required to apply and finish electrode coatings from tens of minutes to less than one second. This revolutionary approach can result in dramatic increases in process speeds, significantly reduced capital (a factor of 10 to 20) and operating costs, reduced energy requirements, and reduced environmental concerns and costs due to the virtual elimination of harmful volatile organic solvents and associated solvent dryers and recovery systems. The accumulated advantages of higher speed, lower capital and operating costs, reduced footprint, lack of VOC recovery, and reduced energy cost is a reduction of 90% in the manufacturing cost of cathodes. When commercialized, the resulting cost reduction in Lithium batteries will allow storage device manufacturers to expand their sales in the market and thereby accrue the energy savings of broader utilization of HEVs, PHEVs and EVs in the U.S., and a broad technology export market is also envisioned.

14 SOLAR ENERGY↗

Evaluating Proposed Investments in Power System Reliability and Resilience: Preliminary Results from Interviews with Public Utility Commission Staff

Policymakers and regulatory agencies are expressing renewed interest in the reliability and resilience of the U.S. electric power system in large part due to growing recognition of the challenges posed by climate change, extreme weather events, and other emerging threats. Unfortunately, there has been little or no consolidated information in the public domain describing how public utility/service commission (PUC) staff evaluate the economics of proposed investments in the resilience of the power system. Having more consolidated information would give policymakers a better understanding of how different state regulatory entities across the U.S. make economic decisions pertaining to reliability/resiliency. To help address this, Lawrence Berkeley National Laboratory (LBNL) was tasked by the U.S. Department of Energy Office of Energy Policy and Systems Analysis (EPSA) to conduct an initial set of interviews with PUC staff to learn more about how proposed utility investments in reliability/resilience are being evaluated from an economics perspective. LBNL conducted structured interviews in late May-early June 2016 with staff from the following PUCs: Washington D.C. (DCPSC), Florida (FPSC), and California (CPUC).

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

An Early Survey of Best Practices for the Use of Small Unmanned Aerial Systems by the Electric Utility Industry

This technical manual is about doing things safely. It isn’t so much a how-to guide as it is a collection of best practices from unmanned aerial system (UAS) operators from all over the world. The desired end state is to provide a touchstone for utility businesses, directors, managers, and operators that will inform them as they begin to strategize, plan, and incorporate this technology into day-to-day operations.

99 GENERAL AND MISCELLANEOUS↗

Production of hydrogen driven from biomass waste to power Remote areas away from the electric grid utilizing fuel cells and internal combustion engines vehicles

Recent concerns over the security and reliability of the world’s energy supply has caused a flux towards the research and development of renewable sources. A leading renewable source has been found in the biomass gasification of biological materials derived from organic matters such as wood chips, forest debris, and farm waste that are found in abundance in the USA. Accordingly, there is a very strong interest worldwide in the development of new technologies that provide an in-depth understanding of this economically viable energy source. This work aims to allow the coupling of biomass gasification and fuel cell systems as well as Internal Combustion Engines (ICE) to produce high-energy efficiency, clean environmental performance and near-zero greenhouse gas emissions. Biomass gasification is a process, which produces synthesis gas (syngas) that contains 19% hydrogen and 20% carbon monoxide from inexpensive organic matter waste. This project main goal is to provide cost effective energy to the public utilizing remote farms’ waste and landfill recycling area.

08 HYDROGEN↗

Modeling of Dust Levels Associated with Potential Utility-Scale Solar Development in the San Luis Valley-Taos Plateau Study Area

The San Luis Valley (SLV)–Taos Plateau study area in south-central Colorado and north-central New Mexico is a large alpine valley surrounded by mountains with an area of approximately 6,263,000 acres (25,345 km 2 ) (Figure ES.1-1). This area receives ample sunshine throughout the year, making it an ideal location for solar energy generation, and there are currently five photovoltaic facilities operating on private lands in the SLV, ranging in capacity from 1 to 30 megawatt (MW). In 2012 the Bureau of Land Management (BLM) launched its Solar Energy Program, which included the identification of four solar energy zones (SEZs) in the SLV totaling 16,308 acres (66 km 2 ), as well as over 50,000 (202 km 2 ) acres of other BLM-administered lands potentially available for application for solar development. The SEZ areas, named Antonito Southeast, De Tilla Gulch, Fourmile East, and Los Mogotes East, were defined by the BLM as areas well-suited for utility-scale (i.e., larger than 20 MW) production of solar energy where solar energy development would be prioritized (BLM 2012). Nonetheless, it was recognized that solar development in the SEZs would result in some unavoidable adverse impacts, and so the BLM initiated a solar regional mitigation strategy (SRMS) study for three of the SEZs (BLM and Argonne 2016). The SRMS is designed to identify residual impacts of solar development in the SEZs (that is, those that cannot be avoided or minimized onsite), identify those residual impacts that warrant compensatory mitigation when considering the regional status and trends of the resources, identify appropriate regional compensatory mitigation locations and actions to address those residual impacts, and recommend appropriate fees to implement those compensatory mitigation measures.

14 SOLAR ENERGY↗

Improved sample utilization in thermal ionization mass spectrometry isotope ratio measurements: refined development of porous ion emitters for nuclear forensic applications

The precise and accurate determination of isotopic composition in nuclear forensic samples is vital for assessing origin, intended use and process history. Thermal ionization mass spectrometry (TIMS) is widely accepted as the gold standard for high performance isotopic measurements and has long served as the workhorse in the isotopic ratio determination of nuclear materials. Nuclear forensic and safeguard specialists have relied heavily on such methods for both routine and atypical e orts. Despite widespread use, TIMS methods for the assay of actinide systems continue to be hindered by poor ionization e ciency, often less than tenths of a percent; the majority of a sample is not measured. This represents a growing challenge in addressing nextgeneration nuclear detection needs by limiting the ability to analyze ultratrace quantities of high priority elements that could potentially provide critical nuclear forensic signatures. Porous ion emitter (PIE) thermal ion sources were developed in response to the growing need for new TIMS ion source strategies for improved ionization e ciency, PIEs have proven to be simple to implement, straightforward approach to boosting ion yield. This work serves to expand the use of PIE techniques for the analysis of trace quantities of plutonium and americium. PIEs exhibited superior plutonium and americium ion yields when compared to direct lament loading and the resin bead technique, one of the most e cient methods for actinide analysis, at similar mass loading levels. Initial attempts at altering PIE composition for the analysis of plutonium proved to enhance sample utilization even further. Preliminary investigations of the instrumental fractionation behavior of plutonium and uranium analyzed via PIE methods were conducted. Data collected during these initial trial indicate that PIEs fractionate in a consistent, reproducible manner; a necessity for high precision isotope ratio measurements. Ultimately, PIEs methods were applied for the age determination of various uranium isotopic standards. PIEs did not exhibit signi cant advantages for the determination of model ages when compared to traditional laments; however, this trial was able to provide valuable insight for guiding future investigations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Utilization of SRNL-developed radiation-resistant polymer in high radiation environments

The radiation-resistant polymer developed by the Savannah River National Laboratory is adaptable for multiple applications to enhance polymer endurance and effectiveness in radiation environments. SRNL offers to collaborate with TEPCO in evaluation, testing, and utilization of SRNL’s radiation-resistant polymer in the D&D of the Fukushima Daiichi NPS. Refinement of the scope and associated costs will be conducted in consultation with TECPO.

36 MATERIALS SCIENCE↗

Algae Cultivation for Carbon Capture and Utilization Workshop Summary Report

The Algae Cultivation for Carbon Capture and Utilization Workshop Summary Report summarizes a workshop hosted by the U.S. Department of Energy's Bioenergy Technologies Office on May 23–24, 2017, in Orlando, Florida. The event gathered stakeholder input through facilitated discussions focused on innovative technologies and business strategies for growing algae on waste carbon dioxide resources.

59 BASIC BIOLOGICAL SCIENCES↗

Utilizing Weak Indicators to Detect Anomalous Behaviors in Networks

We consider the use of a novel weak in- dicator alongside more commonly used weak indicators to help detect anomalous behavior in a large computer network. The data of the network which we are studying in this research paper concerns remote log-in information (Virtual Private Network, or VPN sessions) from the internal network of Los Alamos National Laboratory (LANL). The novel indicator we are utilizing is some- thing which, while novel in its application to data science/cyber security research, is a concept borrowed from the business world. The Her ndahl-Hirschman Index (HHI) is a computationally trivial index which provides a useful heuristic for regulatory agencies to ascertain the relative competitiveness of a particular industry. Using this index as a lagging indicator in the monthly format we have studied could help to detect anomalous behavior by a particular or small set of users on the network.

97 MATHEMATICS AND COMPUTING↗

Carbon Dioxide Utilization (CO2U) ICEF Roadmap 2.0. Draft October 2017

Last year, experts from CO 2 Sciences, Columbia University and Valence Strategic came together to develop a roadmap. That document, Carbon Dioxide Utilization ICEF Roadmap 1.0, released at the UNFCCC Marrakesh Climate Change Conference in 2016, surveyed the commercial and technical landscape of CO 2 conversion and use. The document provided extensive background and analysis and has helped to provide a foundation for additional studies, including this one.This roadmap is meant to complement and expand upon the work of its predecessor. Based in part on a workshop at Columbia University’s Center on Global Energy Policy in July 2017, it explores three distinct categories of CO 2 -based products, the technologies that can be harnessed to convert CO2 to these products, and the associated research and development needs. It also explores the complicated topic of life cycle analysis—critically important when considering the climate impacts of CO 2 conversion and use—as well as policy tools that could be used to promote CO 2 -based products.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗