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Measurements and Characterization

The Measurements and Characterization scientists at the National Renewable Energy Laboratory provide characterization support, conduct collaborative research, and develop new measurement capabilities and diagnostics to advance the photovoltaic (PV) generation of energy. We use state-of- the-art characterization tools to solve problems in all phases of material and device development. Results lead to an increased understanding that drives advances in the performance, reliability, cost, and manufacturability of PV materials, devices, and systems.

14 SOLAR ENERGY↗

Photovoltaic Reliability Workshop (PVRW) 2026 Oral Presentation Proceedings

Each year, the Photovoltaics Reliability Workshop (PVRW) brings together solar technology experts to discuss current and future issues in PV reliability. This document collects oral presentations that were part of PVRW 2026. Click the presentation titles in the following agenda to jump to each file. Not all talks listed in the agenda can be found in this document, as not all presentation files were provided to PVRW for inclusion in these proceedings.

14 SOLAR ENERGY↗

Affordable and Accessible Solar for All: Barriers, Solutions, and On-Site Adoption Potential

Solar energy technologies can be used as part of a suite of tools to reduce the energy burden of low-income customers, but to date, low- and moderate-income (LMI) customers have not adopted solar at the same rate as other income groups. This paper summarizes the barriers of LMI solar adoption related to finance and funding, community engagement, site suitability, policy and regulatory, and resilience and recovery and discusses existing and potential future solutions to address these barriers. In addition, we model future LMI on-site solar adoption, using the National Renewable Energy Laboratory's (NREL's) dGen model. We model future scenarios assuming no changes in the current LMI solar policy and program environment, and we add two incentives to low-income households for adopting solar: a $\$$3,000 incentive and a full incentive (i.e., the full cost of a PV system). While we model a financial incentive, this dollar reduction in cost could also come from other efforts, for example, reductions in solar soft costs. We find that by 2050, 48-49% of LMI households adopt solar, resulting in $\$$69- $\$$101 billion in first year utility bill savings to these consumers.

14 SOLAR ENERGY↗

Best Practices at the End of Photovoltaic System Performance Period

Responsible and cost-effective dissolution of photovoltaic (PV) system hardware at the end of the performance period has emerged as an important business and environmental consideration. Alternatives include extending the performance period and existing contracts for power purchase, lease, and utility interconnect; refurbishing the plant by correcting any deficiencies; repowering the plant with new PV modules and inverters; or decommissioning the plant and removing all the hardware from the site. Often key decisions are made very early in the project development and might require decommissioning by some certain date after the end of a power purchase agreement. To “abandon in place” is not an alternative acceptable to landowners and regulators, so any financial prospectus should include costs associated with decommissioning, even if those costs are deferred by extending operations, refurbishment, or repowering. Decommissioning costs are driven by regulations regarding the handling and disposal of waste, with reuse and recycling of PV modules and other components preferred as a way to reduce both costs and environmental impact. Each alternative is discussed with order-of-magnitude costs, and recommendations are provided considering site-specific details of that situation, such as estimated costs to refurbish or repower, projected revenue from continued operations, and tax considerations.

14 SOLAR ENERGY↗

2024 Photovoltaic Inverter Reliability Workshop Summary Report & Proceedings

The National Renewable Energy Laboratory (NREL) organized the 2024 Photovoltaic Inverter Reliability Workshop on April 11-12, 2024, hosted at NREL's South Table Mountain campus in Golden, Colorado. The workshop was organized around seven key topics, including the present state of inverter reliability; solutions for reliability challenges; life cycle cost and ownership issues; testing, standards, performance, and reliability metrics; data reporting, analytics, and sharing; and the future of PV inverter reliability research. Participants included inverter manufacturers, national laboratory researchers, academics, independent testing laboratories, and more. Over the course of the two-day workshop, attendees arrived at several key priorities and conclusions. This report summarizes these conclusions and then collects presentations from the workshop into a record of the workshop's proceedings.

14 SOLAR ENERGY↗

Four–Terminal Perovskite–CdSeTe Tandem Solar Cells: From 25% toward 30% Power Conversion Efficiency and Beyond

Thin-film tandem photovoltaic (PV) technology has emerged as a promising avenue to enhance power conversion efficiency beyond the radiative efficiency limit of single-junction devices. Combining a tunable wide-bandgap perovskite cell with a commercially established narrow-bandgap cadmium selenium telluride (CdSeTe) cell in a comparatively easy-to-fabricate four-terminal (4-T) arrangement is a great step in that direction. Herein, the impact of the transparent back contact and the perovskite absorber bandgap on the performance of 4-T perovskite–CdSeTe tandem solar cells is investigated. 4-T perovskite–CdSeTe tandem device architecture with ≈25% efficiency is demonstrated and a feasible pathway is shown to improve the tandem efficiency to more than 30%. Furthermore, the results show that the integration of CdSeTe with perovskite in 4-T tandem PV configurations represents a significant advancement toward achieving higher efficiency and low-cost tandem PVs.

14 SOLAR ENERGY↗

The promise of metal-halide-perovskite solar photovoltaics: A brief review

Solar photovoltaics (PVs) based on metal-halide perovskites (MHPs) have taken the renewable-energy world by storm. The excitement stems from the promise of a high-efficiency, low-cost, and low “carbon-footprint” new PV technology. Here, a brief overview of the important topics pertaining to MHPs, perovskite solar cells (PSCs) and perovskite solar modules (PSMs) is presented. The topics include: (1) PSC architectures, (2) MHPs, (3) synthesis and processing of MHP thin films, (4) MHP thin-film microstructures, (5) PSC functional layers, (6) interfacial engineering in PSCs, (7) PSC performance, (8) PSC stability, (9) PSMs, (10) lead toxicity, and (11) mechanical behavior and reliability. The significant challenges in the path toward commercialization of this burgeoning PV technology are also highlighted. Chief among them are scalability, stability, reliability, and safety, while achieving high efficiency, low cost, and low “carbon-footprint.” Furthermore, the promise of this new PV technology and the fascinating underlying science make it a worthwhile endeavor to address these challenges.

14 SOLAR ENERGY↗

PVAnalytics: A Python Package for Automated Processing of Solar Time Series Data

Multiple publicly available software packages exist that analyze solar time series data, including RdTools and Solar Data Tools, among others. Several of these packages contain their own unique quality assurance (QA) and feature recognition algorithms. The python PVAnalytics package was developed to offer an internally consistent source for these analysis tools, making it easier for the end user to deploy these routines on his or her solar data. The PVAnalytics package currently contains routines for outlier detection, inverter clipping detection, irradiance and temperature checks, orientation checks, and data shift detection, among other functions. These functions have been aggregated from various sources including Solar Forecast Arbiter, RdTools, and the QA process developed by NREL's PV Fleets Initiative. We are continuously adding new functionality to the package, including documentation, examples and algorithms. By bundling QA functionality into a single software package, we hope to make PVAnalytics a comprehensive software library to support analysis of solar metadata and time series data.

data cleaning↗

Selection of optimal wavelengths for optical soiling modelling and detection in photovoltaic modules

Soiling impacts the photovoltaic (PV) module performance by decreasing the amount of light reaching the photovoltaic cells and by changing their external spectral response. Currently, the soiling monitoring market is moving toward optical sensors that measure transmittance or reflectance, rather than directly measuring the impact of soiling on the performance of photovoltaic modules. These sensors, which use a single optical measurement, are not able to correct the soiling losses that depend on the solar irradiance spectra and on the spectral response of the monitored PV material. This work investigates methods that can improve the optical detection of soiling by extracting the full soiling spectrum profiles using only two or three monochromatic measurements. Spectral transmittance data, measured with a spectrophotometer and collected during a 46-week experimental soiling study carried out in Jaén, Spain, was analysed in this work. The use of a spectral profile for the hemispherical transmittance of soiled PV glass is found to significantly improve the soiling detection, returning the lowest errors independently of the PV materials and irradiance conditions. In addition, this work shows that it is also possible to select the measurement wavelengths to minimize the soiling loss detection error depending on the monitored PV semiconductor material (silicon, CdTe, a-Si, CIGS and a representative perovskite). The approaches discussed in this work are also found to be more robust to potential measurement errors compared to single wavelength measurement techniques.

14 SOLAR ENERGY↗

Seminar 13 - Advanced Methods for Grid Integration of High-Performance Residential Communities

High-performance residential communities such as net-zero energy (NZE) and NZE-ready communities are emerging across the United States as many cities and states have committed to achieve ambitious energy efficiency and renewable energy goals between now and 2050. The achievement of these goals will transform the nation's communities into the holistic paradigms consisting of pervasive solar photovoltaics (PVs) and other renewable distributed energy resources, energy storage and flexible loads. However, integrating residential communities with high PV penetration may bring many challenges to the grid. For example, during many hours of the year, electric power is flowing out of PV-enabled homes and back into the grid. When this happens simultaneously in many nearby homes, distribution feeder voltage can be raised significantly. Intermittent solar power can also cause voltage flickers, leading to potential damages on both distribution feeder and home appliances. Existing solutions, such as PV curtailment, battery storage, and direct load control, are not able to address all the challenges in a cost-effective way. Better understanding is needed on how to deploy rooftop PV, how to predict building loads, and how to coordinate the homes in a community to enhance grid reliability. This seminar consists of four integral presentations that cover different aspects of a solution to these challenges. First, we will present an automated method to identify the best surfaces to deploy PV and size PV according to the PV penetration goals in a community. Second, we will present a streamlined way to create gray-box building models that are suitable for large-scale building-grid co-simulation. Next, we will present a data-driven method to estimate the end-use energy consumption to better coordinate the behind-the-meter resources to reduce utility cost, provide grid services, and improve renewable energy integration. Lastly, we will present a hierarchical control system that integrates the building models and the estimated non-dispatchable loads into the decision-making process to enhance the reliability and resilience of the residential community. Simulation results from an NZE-ready community in Fort Collins, Colorado will be presented in all four presentations and the guidelines on better grid integration of residential communities will be provided.

14 SOLAR ENERGY↗

Performance Assessment of Photovoltaic Panels Using Impedance Spectroscopy

The goal of this project was to develop a technique for measuring internal characteristics of a PV module using light modulation under a fixed voltage bias while measuring the resulting alternating current. This technique, light-intensity modulated impedance spectroscopy (LIMIS), has the promise of detecting early signs of panel aging and degradation that could be used for example by solar farm operators to have early warnings to repair or replace panels to maintain reliability of the overall PV array. LIMIS would be complementary with the previously developed electrochemical impedance spectroscopy (EIS), which uses an alternating voltage applied electrically to a solar cell with a similar alternating current measurement. EIS has mostly been developed for individual PV cells rather than whole modules. The project was intended to assess what different information could be revealed by LIMIS, which may in some cases be more scalable to larger modules and potentially more practical to apply in field measurements without needing to electrically disconnect PV modules. We began with small 10 W PV modules and built a testbed capable of oscillating the light intensity with frequencies up to 50 kHz. In parallel, we built a large testbed for testing large 250 W PV modules. Meanwhile, we developed procedures for established measurement techniques: current–voltage (I–V), EIS, and electroluminescence (EL) imaging, where panels are subjected to forward bias while their infrared emission is recorded using a camera modified to be sensitive to IR wavelengths. In addition, we developed protocols for accelerated aging of PV modules in two ways. Thermal cycling from –40°C to +90°C simulates the diurnal temperature cycles on a rooftop. Mechanical stress by dropping a 227 g ball from a height of 1 m simulates damage such as that due to hail impacts.

14 SOLAR ENERGY↗

Enabling Interoperability on PV Inverters Using IEC 61850

Inverter based distributed energy resources are integrated into distribution system at a fast pace. Distribution management systems, microgrid controllers, and other distributed assets need to communicate with each other for sensing and control of the different assets. Interoperability is critical to the ease of data exchange between different assets. This presentation will provide a background on interoperability and a laboratory implementation using IEC 61850. Specifically, this presentation will discuss the use of IEC 61850 7-420 to enable interoperability in PV inverter.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Task 12 PV Sustainability - Mineral Resource Use Footprints of Residential PV Systems

Resource use intensity is often mentioned as one of the main characteristics of PV systems and PV electricity. Recently, the International Energy Agency published a report on the role of critical minerals in clean energy transitions. The Product Environmental Footprint pilot study on PV electricity quantified (among other environmental impacts) its abiotic depletion potential. So far, a comprehensive assessment of resource use impacts highlighting the different facets of its impacts is however lacking. For the first time, the resource use impacts of PV electricity are quantified simultaneously with four impact category indicators recommended or suggested by the Life Cycle Initiative hosted at UN Environment. The indicators cover distinctly different aspects of resource use, namely resource depletion with the Abiotic Depletion Potential, ultimate reserves (ADP UR ), economic resource scarcity with the Abiotic Depletion Potential, economic reserves (ADP ER ), resource quality with the Surplus Ore Potential, Ultimate Recoverable Resources (SOP URR ) and re-source criticality with the ESSENZ method. The resource use impacts caused from the generation of 1 kWh electricity with a residential scale photovoltaic (PV) system installed in Central Europe using mono- and multi-crystalline silicon panels and CdTe panels, respectively are quantified. The product system includes manufacture, use and end of life treatment (take back and recycling) of the PV panels, cabling, inverter and supporting structure, the supply chains of the raw materials and energy used in PV panel and inverter manufacture as well as transport logistics.

14 SOLAR ENERGY↗

Analysis of PV Fleet Performance in Western United States During August 2020 Extreme Heat Wave

Starting in June 2020 through the end of that year, the western and central United States experienced a widespread heat wave and drought, which resulted in US$5.44 billion (CPI-adjusted) worth of damages. The ongoing heat and drought produced record large wildfires across the region, responsible for an additional US$19.9 billion in damage. These natural disasters directly impacted the energy system in the western US, leading to power blackouts in August 2020. In this work, we analyze the NLR PV Fleets data set, focusing on the geographic area covered by the Western Coordinating Council (WECC). We find that over the 10-day period from August 14 through 24, the median PV system produced 12% lower energy than expected, with some locations experiencing total losses of around 30%. Analyzing the spatial-temporal structure of the data and supplementing with limited operational current and voltage data where available, we find that system underperformance was more strongly impacted by irradiance reduction from wildfire smoke rather than by the high heat itself.

14 SOLAR ENERGY↗

A 150-kW 99% Efficient All-Silicon-Carbide Triple-Active-Bridge Converter for Solar-Plus-Storage Systems

Solar-plus-storage systems could effectively mitigate the uncertainties of the photovoltaic (PV) generation and improve system reliability by adding an integrated battery energy storage system. As a three-port bidirectional isolated dc–dc converter with soft-switching capability, the triple-active-bridge (TAB) converter inherently matches the requirements of the solar-plus-storage system. However, challenges still remain in the TAB converter design to further improve system efficiency. In this article, the detailed design, implementation, and demonstration for a silicon carbide (SiC) 150-kW TAB converter are presented. Starting from a brief review of the TAB converter, the modulation scheme, power characteristics, and soft-switching region are analyzed. Then, the detailed design of the H-bridge converter building block is given. Here, to improve the system efficiency, a comprehensive characterization of the SiC gate driver with various external gate resistances is performed to address tradeoffs between switching loss and voltage overshoot during transients, as well as the thermal performance of the H-bridge building block. In addition, the design and characterization of the 20-kHz three-port transformer are also given. Comprehensive experimental studies are conducted on a full-power prototype to verify the proposed design. With a measured 99.1% peak efficiency, the proposed TAB converter can fulfill the requirements for solar-plus-storage applications.

14 SOLAR ENERGY↗

Predictive Coordinated and Cooperative Voltage Control for Systems With High Penetration of PV

In this paper, we propose a predictive coordinated and cooperative voltage control method in a power distribution system with high penetration of photovoltaic (PV) units. First, an integrated coordinated voltage control of voltage regulators (VRs) tap positions and cooperative distributed control of the reactive power output from PV inverters are used to maintain system voltages within an appropriate bandwidth. Next, solar power forecasting is applied to predict voltage changes, which are used to set the VR tap positions and capacitor switch status to prevent large voltage fluctuations. The fine tuning of voltage adjustment is then achieved by cooperative control of PV inverters to maintain a uniform voltage profile across the system. The proposed method is tested on a modified IEEE 123-node test feeder with high penetration of PVs using real measurement data and compared with the base case. Simulation results demonstrate the effectiveness of the integrated voltage control, as well as the enhancement from the predictive control through solar power forecasting-enabled voltage change estimates. Comparison to previous work in the literature shows significant improvement in terms of voltage deviation and reduction in excessive tap changes.

14 SOLAR ENERGY↗

Guanidinium-Assisted Surface Matrix Engineering for Highly Efficient Perovskite Quantum Dot Photovoltaics

Metal halide perovskite quantum dots (Pe-QDs) are of great interest in new-generation photovoltaics (PVs). However, it remains challenging in the construction of conductive and intact Pe-QD films to maximize their functionality. Herein, a ligand-assisted surface matrix strategy to engineer the surface and packing states of Pe-QD solids is demonstrated by a mild thermal annealing treatment after ligand exchange processing (referred to as “LE-TA”) triggered by guanidinium thiocyanate. The “LE-TA” method induces the formation of surface matrix on CsPbI 3 QDs, which is dominated by the cationic guanidinium (GA+) rather than the SCN-, maintaining the intact cubic structure and facilitating interparticle electrical interaction of QD solids. Consequently, the GA-matrix-confined CsPbI 3 QDs exhibit remarkably enhanced charge mobility and carrier diffusion length compared to control ones, leading to a champion power conversion efficiency of 15.21% when assembled in PVs, which is one of the highest among all Pe-QD solar cells. Additionally, the “LE-TA” method shows similar effects when applied to other Pe-QD PV systems like CsPbBr 3 and FAPbI 3 (FA = formamidinium), indicating its versatility in regulating the surfaces of various Pe-QDs. This work may afford new guidelines to construct electrically conductive and structurally intact Pe-QD solids for efficient optoelectronic devices.

36 MATERIALS SCIENCE↗