SEARCH · Engineering Papers

Results for “RIVERS”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,387 records · Page 77

All sources NASA NTRS DOE OSTI

DOE OSTI2021

Subseasonal-to-seasonal Prediction of Atmospheric Rivers in the Western United States

Atmospheric rivers (ARs) account for a large portion of winter total precipitation (especially heavy precipitation) in the coastal states of western US (Dettinger et al., 2011; Rutz et al., 2014), but accurate subseasonal-to-seasonal predictions of ARs remain challenging. The challenge stems from relatively short observational records, the interactions of different climate modes and their nonlinear impacts on ARs, and uncertainties in AR activity due to AR detection methods (Huang et al., 2021). Important sources of AR prediction skill include different climate modes, such as the El Niño/Southern Oscillation (ENSO), Madden–Julian oscillation (MJO), and quasi-biennial oscillation (QBO) (DeFlorio et al., 2018, 2019; Mundhenk et al., 2018). Nevertheless, a lack of consensus on climate mode–AR relationship limits the subseasonal-to-seasonal predictive skills on ARs.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2021

Calculated Roughness Changes due to Clear-Cutting At Savannah River Site

At the Savannah River Site (SRS), multiple facilities are routinely producing and working with radiological constituents which require safety basis modeling by the National Nuclear Safety Administration. The models used to determine the safety basis employ roughness length as an input parameter which describes the roughness of the ground surface which influences momentum exchange near the surface and the subsequent generation of mechanical turbulence. Because roughness length is dependent on surface characteristics, including vegetation, any changes to the surface would have a subsequent impact on the roughness length and require a new safety basis analysis to be performed. An analysis of measurements prior to and after the dear-cuts and thinning was performed and roughness lengths were calculated for each of sixteen wind sectors. Not all sectors contained dear-cuts, so this provides comparison of natural variations in roughness. Based on the results of the estimated changes, consideration will be given to how these changes may affect atmospheric dispersion modeling. It was found that clear-cutting activities generally led to a reduction in roughness. Reductions in roughness length also occurred in some of the wind sectors containing only undisturbed forest, but those in sectors with dear-cuts were found to be slightly greater in magnitude than natural variation. Only in one instance was the change in roughness length found to exceed a decrease of 10%, indicating that there is no significant safety basis to the site as a whole based on previous clear-cutting activities.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2021

Geochemical data package for performance assessment calculations related to the Savannah River Site

The Savannah River Site (SRS) disposes of low-level radioactive waste (LLW) and stabilizes high-level radioactive waste (HLW) tanks in the subsurface environment. Calculations used to establish the radiological limits of these facilities are referred to as Performance Assessments (PAs), Special Analyses (SAs), and Composite Analyses (CAs). The purpose of this document is to revise the existing geochemical data package used for these calculations (Kaplan, 2016). This work builds on earlier compilations of geochemical data, referred to a geochemical data packages (Kaplan, 2007; Kaplan, 2010; Kaplan, 2016; McDowell-Boyer et al., 2000). This work is being conducted as part of the on-going maintenance program of the SRS PA programs that periodically updates calculations and data packages when new information becomes available.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2021

FY2020 Savannah River Site Composite Analysis Annual Summary Review

This document provides the Department of Energy (DOE) Order 435.1 and its manual, Radioactive Waste Management (DOE 2021a, 2021b) required Annual Review for the Savannah River Site (SRS) Composite Analysis (CA). Progress made to-date toward addressing the secondary issue from the LFRG review of the 2010 SRS CA has focused primarily upon inventory estimate improvements. Inventory impacts dose in a linear fashion and reduces the uncertainty with the CA conclusions. Maintenance items are addressed, as funding allows, based on the relative risk associated with meeting the performance objectives. Currently, there is minimal risk in exceeding the DOE 100 mrem/yr CA primary dose limit or the DOE 30 mrem/yr dose constraint (administrative limit). Proposed activities, discoveries, new information and changes potentially affecting the 2010 SRS CA are documented in this and earlier Annual Summary reports, and a consolidated list of changes since the 2010 CA is documented in this report. The impact to the CA of changes arising from updated performance assessment (PA) baselines [i.e., Saltstone Disposal Facility (SDF), E-Area Low-Level Waste Facility (ELLWF), and F & H Tank Farm (FTF & HTF) closures] is expected to be minor for the following reasons: The primary contributors to the SRS CA dose impact at the Upper Three Runs (UTR) point of assessment (POA) are the H-Canyon and Mixed Waste Management Facility (MWMF), contributing 68% and 9%, respectively, to the dose impact at that POA. The combined contribution to the UTR dose impact from all PA’s (SDF, ELLWF, FTF and HTF) is ~2% of this total. The 2010 SRS CA model validation performed indicates that the CA projected dose, while generally conservative, provides a reasonable representation of the maximum annual doses. Doses evaluated are well below the SRS established 15 mrem/yr administrative limit (Crapse et al. 2011). Based on the assessment presented within this annual review and collective engineering judgement, the conclusions of the 2010 SRS CA remain valid and there is reasonable assurance that SRS will meet the performance objectives delineated in DOE Manual 435.1-1. The 2010 SRS CA should be updated to incorporate PA changes, proposed changes to inventories and sources and model improvements accumulated since the 2010 CA. The timing will be dependent on the completion of the ongoing E-Area PA revision.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2021

Vapor-Liquid Partitioning of Methylmercury Compounds: Fundamental Data to Support the Savannah River Site Liquid Waste System: Henry's Law, Solubility and Vapor Pressure Determination for Representative Methylmercury Compounds

The Savannah River Site (SRS) Liquid Waste System (LWS) contains approximately 66 tons of mercury within the liquids, salts, and sludges that are currently being processed into final wasteforms for disposal. Mercury concentrations within the system exceed those typically experienced in environmental or industrial systems; thus, management of mercury compounds continues to be a priority for SRS. In the LWS, waste is vitrified into a borosilicate glass wasteform that contains most of the radioactivity, while the lower activity solutions are dispositioned in a low-level grout wasteform, or “saltstone”. The alkaline, high ionic strength caustic wastes are pumped, evaporated, and otherwise managed throughout the LWS and Defense Waste Processing Facility (DWPF) as they are stored and prepared for conversion to the final wasteforms. Because of the complexity of this system, a key component of effective mercury management in the LWS requires analysis of mercury in various physical phases. The high concentration of mercury within the SRS LWS has the potential to generate vapor-phase contamination. Elemental mercury (Hg 0 ), dimethylmercury ((CH 3 ) 2 Hg), and methylmercury (CH 3 Hg + ) are among species known or suspected to contribute to the flux of mercury from liquid to vapor phase (Iverfeldt and Lindquist, 1982). Chemical speciation affects not only mercury behavior in LWS operations but may also affect the performance of mercury treatment and removal technologies in the LWS.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2021

Radiological Impact of 2020 Operations at the Savannah River Site

This report presents environmental dose assessment methods and the estimated potential doses to the public from 2020 Savannah River Site (SRS) atmospheric and liquid radioactive releases. It also documents potential doses from special-case exposure scenarios, such as the consumption of wildlife and/or goat milk. Unless noted, the generic term “dose,” as used in this report, includes both the committed effective dose (50-year committed dose) from internal deposition of radionuclides and the effective dose attributable to sources external to the body. Using the effective dose allows doses from different types of radiation and to different parts of the body to be expressed on the same basis. Humans, plants, and animals potentially receive radiation doses from natural and man-made occurrences. The average annual “background” dose for all people living in the United States is 625 mrem. This includes an average background dose of 311 mrem from naturally occurring radionuclides (found in our bodies and in the earth) and from cosmic radiation. Man-made sources include medical procedures (300 mrem), consumer products (13 mrem), and industrial and occupational exposures (less than 1 mrem).

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2014

Revision to Flood Hazard Evaluation for the Savannah River Site

Requirements for the Natural Phenomena Hazard (NPH) mitigation for new and existing Department of Energy (DOE) facilities are outlined in DOE Order 420.1. This report examines the hazards posed by potential flooding and represents an update to two previous reports. The facility-specific probabilistic flood hazard curve is defined as the water elevation for each annual probability of precipitation occurrence (or inversely, the return period in years). New design hyetographs for both 6-hr and 24-hr precipitation distributions were used in conjunction with hydrological models of various basins within the Savannah River Site (SRS). For numerous locations of interest, peak flow discharge and flood water elevation were determined. In all cases, the probability of flooding of these facilities for a 100,000 year precipitation event is negligible.

58 GEOSCIENCES↗

DOE OSTI2019

Three Years of Multilevel Monitoring Data at the Riverton, Wyoming, Processing Site That Show Contaminant Increases After River Flooding Events and a Large Recharge Event

The tailings pile at the Riverton, Wyoming, Processing Site has been removed, but contaminant concentrations in the shallow aquifer increase after large recharge events. The Riverton site experienced flooding near the Little Wind River in early May 2016, February 2017, and June 2017. The May 2016 flooding was from a large rain event. The February 2017 flooding was due to an ice jam, and the June 2017 flooding was due to mountain snowmelt runoff. In addition, the site experienced high water tables in April and May 2017, as this was the second wettest spring in Riverton since records began in 1918. Past reports indicated the accumulation of solid-phase uranium and molybdenum in evaporites above the respective contaminant groundwater plumes. Given these data, multilevel monitoring wells were installed in 2015 to monitor seasonal changes in groundwater quality. Data from three years of groundwater monitoring are summarized in this report and compared with the flooding and large recharge events. The results indicate that evaporite-related constituents (especially sodium, sulfate, and chloride) present across the site in a silt layer can be released to the shallow sand and gravel aquifer during flooding and large recharge events. The solid-phase and water-phase data confirm that these evaporites are mainly sodium sulfate and sodium chloride salts with some calcite and gypsum.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2022

Space and Time Dynamics of Transpiration in the East River Watershed: Biotic and Abiotic Controls

Alpine forests have important impacts on water resources by affecting how much of the precipitation that falls on a watershed is routed to streamflow or returned to the atmosphere as transpiration – so-called “green water”. In many of the high-altitude watersheds that supply critical water resources to the western US, it remains a challenge to predict how much water forests will utilize limiting the ability to predict both short and long term information on downstream water resources. The uncertainty emerges because transpiration varies between tree species, across landscapes and over time in ways that cannot readily be predicted from physically-based models for evaporation. In this project, we utilized a technique called sap flux to measure the rate of water use for three common species of fir, spruce and aspen distributed across a hillslope in the East River Watershed from 2019-2021. We also made ~weekly measurements of the concentration of stable isotopic tracers in transpiration to understand not only how much water was being used but whether it originated from summer rain or snowmelt. Firstly, our results show that the species tend to use similar amounts of total water but they achieve this similar cumulative water flux both by using water at different times of the year and by using different water sources. This shows the importance of including species-level information into models used to make seasonal streamflow predictions. Secondly, our results show that trees lower on the hillslope use older waters all through the summer whereas trees higher on the hillslope rely more heavily on recent summer rain. This means trees lower on the hillslope are less sensitive to year-to-year changes in summer climate. Lastly, we found that sites with dense forest stands displayed the largest amounts of year-to-year changes in transpiration and thus these high localized spots in the watershed are the primary drivers of changes in “green water” use. The results provide an unprecedented spatial and temporal picture of forest water use that confirms a number of fundamental hypotheses on hillslope ecohydrology that had not previously been tested against observations. Predictions of streamflow that will benefit from this work are highly valuable for agriculture management, flood control and ecological restoration efforts.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2022

Gap Flows Along the Columbia River Observed During the WFIP2 Field Campaign

Data collected in the Columbia River Gorge and Basin Area during the second Wind Forecasting Improvement Project (WFIP2) was used to study gap flow events in the region. In particular, the relationship between 200 m zonal wind speed and the zonal mesoscale pressure gradient at Troutdale (West of the gorge), Wasco (east of the gorge), and Boardman (farther east of the gorge) sites was examined. An objective criterion was used to identify 169 (Troutdale), 161 (Wasco), and 113 (Boardman) gap flow days that had weak synoptic forcing. The 200 m zonal wind speed exhibited a linear relationship with the zonal pressure gradient at Wasco during both easterly and westerly gap flow days at daily timescales. Such a relationship was only observed during easterly gap flow days at Troutdale and was not observed at Boardman. The zonal wind speed exhibited a diurnal cycle at Wasco and Boardman, with greater changes in the nighttime winds than the daytime winds due to changes in pressure gradient. The root mean square differences (RMSDs) between the observed pressure gradient at Wasco and that simulated by the High Resolution Rapid Refresh (HRRR) model in 3 km (HRRR-3km) and 750 m (HRRR-750m) horizontal resolution were 3.14 hPa and 0.57 hPa, respectively. However, the RMSDs for the 200 m zonal wind speed were 1.40 m s -1 for HRRR-3km and 1.20 m s -1 for HRRR- 750m. Improvement in simulating the zonal pressure gradient accompanied by negligible changes in simulating zonal wind speed due to higher horizontal resolution points to a complex interplay between different components of the model physics when simulating the meteorology. The HRRR-750m resolution model accurately mimicked the observed covariability (phase diagram) between the zonal pressure gradient and the 200 m zonal wind speed during the nighttime, but not during the daytime, suggesting model errors might be related to the representation of boundary layer processes.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2022

FY2021 Savannah River Site Composite Analysis Annual Summary Review

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2021

Physical, resource supply, and biological controls on nutrient processing along the river continuum

Nutrient impairment has led to damages to US surface and groundwater systems in excess of 100 billion dollars per year. Therefore, there is a strong need to develop methods to predict the transport, uptake, and export of nutrients along fluvial networks. We present results that are based on a data-driven mechanistic understanding of three factors that largely control nutrient uptake and export: 1) interactions between transport-related processes (mass transfer to metabolically active zones), 2) resource supply dynamics (nutrient concentration, stoichiometric constraints, etc.), and 3) biological controls (microbial community structure and function). Our results were generated from column experiments conducted along the Jemez River-Rio Grande continuum, which spans four orders of magnitude in mean annual discharge, more than 2000 m in altitude, and more than 500 km of stream longitude. Two resource supply injections were performed on each of the columns, i.e., a nitrate only addition, followed by a stoichiometrically ‘balanced’ 106Carbon:16Nitrogen:1Phosphorus addition. We quantified NO3-N uptake kinetics while constraining three variables: stream order, sediment type and type of injection (N vs stoichiometrically ‘balanced’ C:N:P). Following the laboratory nutrient uptake experiments, the columns were destructively sampled and the contents were homogenized to collect subsamples for DNA sequencing. Amplicon analysis was carried out as described by the Earth Microbiome Protocol for 16s and ITS sequencing.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2020

Opportunities to Update the Model of Tank Closure Grout Aging (SRNL-STI-2012-00404) Based on Experimental Results by the Savannah River Ecology Laboratory

The purpose of this report was to review the results of experiments on evolution of tank grout pore fluids performed by the Savannah River Ecology Laboratory (SREL) and reported in Seaman et al. (2020) and highlight opportunities for updating the model of tank grout degradation presented in Denham and Millings (2012). The SREL experimental results validate some assumptions used in the 2012 grout degradation model and provide information useful for updating the model. All experiments on tank grout degradation have limitations because of reaction rates and the enormous disparity between duration of the experiments and the duration of the degradation of the real tank grout system. Given these limitations, the experimental results form the basis for several recommendations for updating the grout degradation model described in this report.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2021

Recommended Updates to Solubility Controls for Modeling Leaching of Technetium, Uranium, Neptunium, Plutonium, and Iodine from the Residual Waste Layer of Closed Savannah River Site High Level Waste Tanks

The objective of this report is to relate waste leaching experiments by the Savannah River National Laboratory (SRNL) to performance assessment modeling of release of several radionuclides from residual waste in closed high-level waste tanks. SRNL leached residual waste from Tanks 18F and 12H with solutions simulating the modeled evolution of pore fluids in residual waste layers of closed tanks through various stages of grout degradation. Tc-99, uranium isotopes, Np-237, plutonium isotopes, and I-129 were analyzed in the leachate multiple times over 90 days.

07 ISOTOPE AND RADIATION SOURCES↗

DOE OSTI2022

Savannah River National Laboratory (FY2021 LDRD Annual Report)

Research efforts to build upon the unique knowledge base of the Savannah River National Laboratory (SRNL) are funded through the Laboratory Directed Research and Development (LDRD) Program. The program yields foundational scientific research and development (R&D) essential to SRNL’s core business areas, while aligning optimally and continuously with SRNL’s Strategic Plan to provide long-term benefits to the Department of Energy (DOE), the National Nuclear Security Administration (NNSA), and other customers and stakeholders.

99 GENERAL AND MISCELLANEOUS↗

DOE OSTI2022

Resource Recovery and Environmental Protection in Wyoming’s Greater Green River Basin Using Selective Nanostructured Membranes (Final Report)

Produced water (PW) represents a sizable waste stream that is co-generated with oil and natural gas production. In 2021 Wyoming ranked 8th and 9th, respectively in domestic oil and natural gas production. In 2017 Wyoming ranked as the 4th highest generator of PW in the U.S, accounting for 7% of the total volume generated. In the context of being the 3rd most arid state in the U.S., the value of water reuse becomes obvious. PW reuse, and resource recovery, in any form requires some level of treatment to remove particulates, residual (free, dispersed) hydrocarbons, organics, and salts. The level of treatment depends on the requirements of the reuse, or resource recovery, application. PW management systems in Wyoming employ in order of volume of PW managed the following management strategies: reinjection for enhanced oil recovery, surface discharge, deep well injection, evaporation ponds (impoundments), and commercial management/treatment. Complicating treatment efforts are the relatively high concentrations of organics (natural and synthetic), dispersed/free hydrocarbons, benzene-toluene-ethylbenzene, and xylenes (BTEX) compounds, biologicals, salts, and minerals. Hydrocarbons (dispersed/dissolved crude oils) and BTEX compounds, as well as synthetic organics, present economic and environmental concerns. The former represents lost revenue, while the latter results in negative environmental impacts like emissions from surface impoundments. The overall objective of this proposal was to synthesize superhydrophilic/oleophobic and superhydrophobic/oleophilic membranes for selectively concentrating and then separating BTEX compounds and oil and grease (O&G) from PW originating from the Greater Green River Basin (GGRB) in Wyoming. Three specific research aims were pursued to accomplish this overall objective. This final report details the development of the superhydrophobic and superhydrophilic membranes, as well as the design of the membrane module prototypes specifically. The technoeconomic assessment is separately reported in another document. 1. Aim #1 – Material optimization and performance evaluation of superhydrophilic/oleophobic and superhydrophobic/oleophilic membranes made by electrospinning/spraying. 2. Aim #2 – Design and construction of cross-flow membrane modules for selectively concentrating and then separating BTEX/oil from GGRB produced water. 3. Aim #3 – Techno-economic assessment of BTEX/oil recovery, and clean water production, using superhydrophilic/oleophobic and superhydrophobic/oleophilic membrane separation for GGRB PW. Superhydrophobic membranes were synthesized by electrospinning poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) nanofibers onto polyester (PET) substrates and electrospraying nano-carbon black/PVDF-HFP onto the nanofibrous layer. These membranes were characterized by high (>8000 liters per square meter per hour per bar (LMH/bar)) permeance values for pure hydrocarbon phases and a high hydrocarbon selectivity (>96%) when treating GGRB PW. All results were obtained when operating the membrane in a crossflow configuration representative of actual field operating conditions. Solvent/oil properties, specifically viscosity and total surface energy/tension, affected permeance across the membrane, which resulted in light mineral oil (394 LMH/bar) and o-xylene (1834 LMH/bar) being characterized by lower permeance values in the pure phase tests. Mixed phase fluxes between 40 to 80 LMH were obtained for the PW when operating the membrane at a feed pressure of 0.3 bar. Flux decreased as the mixed phase concentration in the feed decreased pointing to the importance of maximizing the collision efficiency between the emulsion and the membrane surface and maximizing the emulsion concentration in the feed and the turbulence within the feed channel. These tests demonstrated that the superhydrophobic membranes developed here are a viable hydrocarbon recovery method for GGRB PWs and should be pursued for testing in pilot-scale trials. Superhydrophilic membranes were successfully synthesized via electrospinning/spraying using polyacrylonitrile (PAN) nanofibers as a base nanofibrous matrix. Integration of polyaniline (PANI) into the nanofibrous matrix produced a superior membrane, for water filtration applications, relative to PAN alone and reduced graphene oxide (RGO) when integrated into the nanofibrous matrix. This conclusion was based on the PANI-PAN resistance to flux loss (fouling) when treating model solvent/oil solutions representative of GGRB PWs and field collected PW from the GGRB. The synthesized PAN membranes outperformed a commercially available PAN membrane designed for oil/water separation. This finding indicates that the surface chemical and physical characteristics of the electrospun membranes presents improved properties for filtration of challenging waters like GGRB PWs. The electrospun membranes therefore show promise overall as a substitute for conventionally polymerized membranes in PW treatment applications. The PANI-PAN membrane specifically presents superior performance characteristics for concentration O&G prior to treatment by the hydrocarbon recovery membrane and producing high-quality filtrate for reuse and/or additional treatment (desalination).

02 PETROLEUM↗

DOE OSTI2022

Radiological Impact of 2021 Operations at the Savannah River Site

This report presents the environmental dose assessment methods and the estimated potential doses to the public from 2021 Savannah River Site (SRS) air and liquid radioactive releases. Also documented are potential doses from special-case exposure scenarios, such as the consumption of wildlife or goat milk.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2022

Lightning strike prediction at the Savannah River Site

At the Savannah River Site, employees receive warnings about lightning only after three strikes have already occurred near the site. In order to increase employee safety, it is preferential to warn employees of a lightning threat much sooner. We used data from an on-site Electric Field Mill to measure values of the atmospheric electric charge. We also used lightning detection data from the National Lightning Detection Network and the Geostationary Lightning Mapper. By comparing the data of each, we can determine how long before or after a lightning strike did the Electric Field Mill first measure within our lightning detection threshold. If the detection threshold occurs before the strike does, this provides a lead time for knowing about lightning risks before they happen. Our findings conclude that 95% of lightning strikes have a lead time in the electric field where we can predict the lightning before it occurs and warn employees of the potential lightning threat. However, our lightning detection threshold can occur even without lightning or precipitation. Finding how these false lightning alarms affect our data is necessary to improving the lightning warning system.

54 ENVIRONMENTAL SCIENCES↗