Loading across the Periodic Table: Introducing 14 Different Metal Ions To Enhance Metal–Organic Framework Performance
Loading metal guests within metal–organic frameworks (MOFs) via secondary functional groups is a promising route for introducing or enhancing MOF performance in various applications. In this work, 14 metal ions (Li + , Na + , K + , Mg 2+ , Ca 2+ , Ba 2+ , Zn 2+ , Co 2+ , Mn 2+ , Ag + , Cd 2+ , La 3+ , In 3+ , and Pb 2+ ) have been successfully introduced within the MIL-121 MOF using a cost-efficient route involving free carboxylic groups on the linker. The local and long-range structure of the metal-loaded MOFs is characterized using multinuclear solid-state NMR and X-ray diffraction methods. We note Li/Mg/Ca-loaded MIL-121 and Ag nanoparticle-loaded MIL-121 exhibit enhanced H 2 and CO 2 adsorption; Ag nanoparticle-loaded MIL-121 also demonstrates remarkable catalytic activity in the reduction of 4-nitrophenol.