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At least 1,387 records · Page 77

Selection and Characterization of Surrogate Material for Developing Zr Barrier Coatings for Uranium Nitride Particles

In support of UC 1-x N x fuel kernels (~ 800 micrometer diameter) development work ongoing at Oak Ridge national laboratory (ORNL), where the fuel kernels will be embedded inside a possible zirconium based matrix, Argonne National Laboratory (ANL) is contributing to help develop a robust metal diffusion barrier coating. Zirconium nitride (ZrN) and Zirconium oxide (ZrO2) were selected as possible diffusion barrier candidates, and the atomic layer deposition (ALD) has been chosen as a candidate technology to deposit the film. Development of such a barrier coating with the ALD process entails significant number of trials to study relevant parameters. Therefore, to prevent needless wastage, instead of coating directly over fuel kernels, a surrogate candidate with similar dimensions and physical properties were been selected and coated to develop the diffusion barrier coating.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Particulate Fuel Modeling of MC 2 -3 using Iterative Local Spatial Self-shielding Method

We report a new spatial self-shielding method for particulate fuels has been developed based on disadvantage factors and implemented in the MC 2 -3 code. This method named the iterative local spatial self-shielding (ILSS) method considers the shadowing effect of randomly distributed particles on spatial self-shielding in particles through a homogenized composition region added outside the particle of interest at the center. The self-shielded cross sections of the central particle are determined iteratively since they are used in determining the cross sections of the homogenized composition region. The ILSS method was verified for infinite stochastic medium problems of single and multiple types of particles, VHTR unit cell problems, and HTTR assembly problems. The verification test results show that the ILSS method accurately predicts the stochastic particle shadowing effect and reaction rates in particles, whereas the regular array model and the stochastic collision probability method underpredict the particle shadowing effect and overestimate reaction rates in particles.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Fuel conservative guidance for shipboard landing of powered-lift STOL aircraft

A computer-simulation study was undertaken to investigate the application of Fuel Conservative Guidance (FCG) techniques, developed at NASA Ames Research Center, to improve the fuel efficiency and minimize recovery time of powered-lift short-takeoff-and-landing (STOL) airplanes operating from aircraft carriers at sea. The FCG system consists of a set of algorithms whose coefficients and parameters limits match those of the Quiet Short-Haul Research Aircraft. When a flightpath is specified by a set of initial conditions for the aircraft and a set of positional waypoints with associated airspeeds, the FCG synthesizes the necessary guidance commands to capture the specified path at any specified waypoint and to optimize fuel consumption and time fo fly along the path. Closed-form expressions are developed for calculating the altitude profile synthesized by the algorithm. Results of this simulation study show that when restrictions on the approach flightpath imposed for manual operation are removed completely, fuel consumption during the approach was reduced by as much as 38 percent (434 lb of fuel) and the time required to fly the flightpath was reduced by as much as 28 percent (209 sec). Savings because of FCG were produced by: (1) shortening the total flight time and distance, and (2) keeping the airspeed high as long as possible to minimize time spent flying in a powered-lift mode.

Warner, D. N., Jr.↗

FY24 Advancements in PFLOTRAN Development for GDSA Framework

The Spent Fuel & Waste Science and Technology (SFWST) Campaign of the Office of Spent Fuel & Waste Disposition of U.S. Department of Energy Office of Nuclear Energy (DOE-NE) is conducting research and development on geologic disposal of spent nuclear fuel (SNF) and high-level nuclear waste (HLW). This report describes fiscal year 2024 accomplishments in the Geologic Disposal Safety Assessment (GDSA) PFLOTRAN Development work package, which is charged with developing subsurface simulation software for postclosure performance assessment of deep geologic disposal of SNF and HLW.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Progress in High Power Density SOFC Material Development for Aerospace Applications

Solid oxide fuel cell (SOFC) systems for aircraft applications require order of magnitude increase in specific power density and long life under aircraft operating conditions. Advanced SOFC materials and fabrication processes are being developed at NASA GRC to increase specific power density and durability of SOFC cell and stack. Initial research efforts for increasing specific power density are directed toward increasing the operating temperature for the SOFC system and reducing the weight of the stack. While significant research is underway to develop anode supported SOFC system operating at temperatures in the range of 650 - 850 C for ground power generation applications, such temperatures may not yield the power densities required for aircraft applications. For electrode-supported cells, SOFC stacks with power densities greater than 1.0 W/sq cm are favorable at temperatures in excess of 900 C. The performance of various commercial and developmental anode supported cells is currently being evaluated in the temperature range of 900 to 1000 C to assess the performance gains and materials reliability. The results from these studies will be presented. Since metal interconnects developed for lower temperature operation are not practical at these high temperatures, advanced perovskite based ceramic interconnects with high electronic conductivity and lower sintering temperatures are being developed. Another option for increasing specific power density of SOFC stacks is to decrease the stack weight. Since the interconnect contributes to a significant portion of the stack weight, considerable weight benefits can be derived by decreasing its thickness. Eliminating the gas channels in the interconnect by engineering the pore structure in both anode and cathode can offer significant reduction in thickness of the ceramic interconnect material. New solid oxide fuel cells are being developed with porous engineered electrode supported structures with a 10 - 20 micron thin electrolyte. The performance data for advanced SOFC cells with engineered porosity in both electrodes will be presented.

Cable, Thomas L.↗

A high solids field-to-fuel research pipeline to identify interactions between feedstocks and biofuel production

Abstract Background Environmental factors, such as weather extremes, have the potential to cause adverse effects on plant biomass quality and quantity. Beyond adversely affecting feedstock yield and composition, which have been extensively studied, environmental factors can have detrimental effects on saccharification and fermentation processes in biofuel production. Only a few studies have evaluated the effect of these factors on biomass deconstruction into biofuel and resulting fuel yields. This field-to-fuel evaluation of various feedstocks requires rigorous coordination of pretreatment, enzymatic hydrolysis, and fermentation experiments. A large number of biomass samples, often in limited quantity, are needed to thoroughly understand the effect of environmental conditions on biofuel production. This requires greater processing and analytical throughput of industrially relevant, high solids loading hydrolysates for fermentation, and led to the need for a laboratory-scale high solids experimentation platform. Results A field-to-fuel platform was developed to provide sufficient volumes of high solids loading enzymatic hydrolysate for fermentation. AFEX pretreatment was conducted in custom pretreatment reactors, followed by high solids enzymatic hydrolysis. To accommodate enzymatic hydrolysis of multiple samples, roller bottles were used to overcome the bottlenecks of mixing and reduced sugar yields at high solids loading, while allowing greater sample throughput than possible in bioreactors. The roller bottle method provided 42–47% greater liquefaction compared to the batch shake flask method for the same solids loading. In fermentation experiments, hydrolysates from roller bottles were fermented more rapidly, with greater xylose consumption, but lower final ethanol yields and CO 2 production than hydrolysates generated with shake flasks. The entire platform was tested and was able to replicate patterns of fermentation inhibition previously observed for experiments conducted in larger-scale reactors and bioreactors, showing divergent fermentation patterns for drought and normal year switchgrass hydrolysates. Conclusion A pipeline of small-scale AFEX pretreatment and roller bottle enzymatic hydrolysis was able to provide adequate quantities of hydrolysate for respirometer fermentation experiments and was able to overcome hydrolysis bottlenecks at high solids loading by obtaining greater liquefaction compared to batch shake flask hydrolysis. Thus, the roller bottle method can be effectively utilized to compare divergent feedstocks and diverse process conditions.

09 BIOMASS FUELS↗

Low NOx Heavy Fuel Combustor Concept Program

The development of the technology required to operate an industrial gas turbine combustion system on minimally processed, heavy petroleum or residual fuels having high levels of fuel-bound nitrogen (FBN) while producing acceptable levels of exhaust emissions is discussed. Three combustor concepts were designed and fabricated. Three fuels were supplied for the combustor test demonstrations: a typical middle distillate fuel, a heavy residual fuel, and a synthetic coal-derived fuel. The primary concept was an air staged, variable-geometry combustor designed to produce low emissions from fuels having high levels of FBN. This combustor used a long residence time, fuel-rich primary combustion zone followed by a quick-quench air mixer to rapidly dilute the fuel rich products for the fuel-lean final burnout of the fuel. This combustor, called the rich quench lean (RQL) combustor, was extensively tested using each fuel over the entire power range of the model 570 K engine. Also, a series of parameteric tests was conducted to determine the combustor's sensitivity to rich-zone equivalence ratio, lean-zone equivalence ratio, rich-zone residence time, and overall system pressure drop. Minimum nitrogen oxide emissions were measured at 50 to 55 ppmv at maximum continuous power for all three fuels. Smoke was less than a 10 SAE smoke number.

Novick, A. S.↗

Triso Analysis Tool For Predictive Source Terms

Source term modeling for TRi-structural ISOtropic (TRISO) fuel has been performed for previous reactor designs, but few are available in the open literature. Thus, there is a need to develop a simple, versatile, and mechanistic model of fission product release and transport in gas reactor cores that can be applied to a variety of reactors through user inputs and reactor-specific radionuclide inventories. To meet this need, the TRISO Analysis Tool for Predictive Source terms (TRISO-ATOPS) was developed. This model calculates the release of the key safety-important fission products by diffusion through the kernel, silicon carbide and graphite based on fuel and graphite temperatures in the reactor under normal operation. These releases from the fuel enter the coolant where they can plate-out on cooler surfaces. A clean-up model is included for designs with a coolant purification system for removing fission gases. This initial distribution of fission products in the reactor serves as an initial condition for potential releases under postulated accident conditions. From this initial condition, the model calculates the fission product release for any transient temperature profile, and the fission product releases can then be used to assess radiological dose to the workers and the public using conventional radiological dose tools. Data on the diffusion of fission products is based on historic German TRISO experiments and the more current Department of Energy Advanced Gas Reactor TRISO fuel development program. The example cases in this work demonstrate the flexibility of the model

Stoyer, Benjamin [Idaho National Laboratory (INL),↗

Hydrogen Stations for Urban Sites

Additional fueling stations need to be constructed in the U.S. to enable the wide-spread adoption of fuel cell electric vehicles. A wide variety of private and public stakeholders are involved in the development of this hydrogen fueling infrastructure. Each stakeholder has particular needs in the station planning, development, and operation process that may include evaluation of potential sites and requirements, understanding the components in a typical system, and/or improving public acceptance of this technology. Publicly available templates of representative station designs can be used to meet many of these stakeholder needs. These 'Reference Stations' help reduce the cost and speed the deployment of hydrogen stations by providing a common baseline with which to start a design, enabling quick assessment of the suitability of a particular site for a hydrogen station, and identifying contributors to poor economics and research and development areas for certain station designs.

08 HYDROGEN↗

Functional Gene Discovery and Characterization of Genes and Alleles Affecting Wood Biomass Yield and Quality in Populus

Adoption of biofuels as economically and environmentally viable alternative to fossil fuels would require development of specialized bioenergy varieties. A major goal in the breeding of such varieties is the improvement of lignocellulosic biomass yield and quality. These are complex traits and understanding the underpinning molecular mechanism can assist and accelerate their improvement. This is particularly important for tree bioenergy crops like poplars (species and hybrids from the genus Populus), for which breeding progress is extremely slow due to long generation cycles. A variety of approaches have been already undertaken to better understand the molecular bases of biomass yield and quality in poplar. An obvious void in these undertakings has been the application of mutagenesis. Mutagenesis has been instrumental in the discovery and characterization of many plant traits including such that affect biomass yield and quality. In this proposal we use activation tagging to discover genes that can significantly affect biomass associated traits directly in poplar, a premier bioenergy crop. We screened a population of 5,000 independent poplar activation tagging lines under greenhouse conditions for a battery of biomass yield traits. These same plants were then analyzed for changes in wood chemistry using pyMBMS. As a result of these screens we have identified nearly 800 mutants, which are significantly (P<0.05) different when compared to wild type. Of these majority (~700) are affected in one of ten different biomass yield traits and 100 in biomass quality traits (e.g., lignin, S/G ration and C6/C5 sugars). We successfully recovered the position of the tag in approximately 130 lines, showed activation in nearly half of them and performed recapitulation experiments with 20 genes prioritized by the significance of the phenotype. Recapitulation experiments are still ongoing for many of the genes but the results are encouraging. For example, we have shown successful recapitulation for a fascilin-like gene that when overexpressed increase many biomass-yield associated traits. Genes discovered through activation tagging showed polymorphisms in P. trichocarpa association mapping population linked to the traits modified by the activation tagging. This suggests that putative alleles that are associated with improvement of the trait o interest can be discovered and used in marker associated selection. This will significantly simplify and accelerate the breeding efforts.

09 BIOMASS FUELS↗

"COMBUSTION DEVELOPMENT OF A HIGH EFFICIENCY DIESEL MICRO PILOT NATURAL GAS ENGINE."

Dual fuel engine operation with premixed natural gas as the main fuel and diesel pilot ignition has been gaining interest among research and industry as natural gas is among the most promising existing alternative fuels. The dual fuel engine performance has been shown to equal and sometimes, depending on operating conditions, better the performance and efficiency of the diesel engine. Along with its advantages on the combustion high efficiency, diesel-like performance, and emissions of NOx and particulate matter reduction, some disadvantages are brought by the application of such operation. At light load conditions, there is an increase in CO and HC emissions, low fuel efficiency and combustion stability. While operating at higher loads, the dual fuel engine performance showed to be limited by combustion knock. This effectively reduces the maximum break mean effective pressure (BMEP) the engine can output when compared to a diesel engine. Although combustion knock is well defined in SI and diesel engines, dual fuel knock characterization still needs more investigation. This project centers on developing a fuel system for a diesel engine conversion to dual fuel to deliver high load and high efficiency. The selected engine has been converted to the dual fuel operation and dual fuel combustion has been demonstrated. After achieving the project goal of a high load and high efficiency dual fuel engine, the combustion knock in dual fuel operation will be characterized and a method for detection and intensity calculation will be modeled. The characterization will also be compared to spark ignition (SI) and reactivity-controlled compression ignition (RCCI) operating engines.

03 NATURAL GAS↗

Thermodynamic Properties of Rare Earth Chlorides in Molten Salts: A Novel Approach to Experimental Electrochemistry of Molten Salts

The thermodynamic and electrochemical properties of rare earth chlorides in molten salt solutions are of interest from the standpoint of both pyrochemical processing of spent nuclear fuel and for the development of Generation IV nuclear reactors. Knowledge of key properties like activity coefficients and phase diagrams will accelerate the development of safe reliable carbon free energy. In this work, three conduits of research have been pursued and reported within the larger theme of minimization of waste in spent fuel reprocessing and associated technology development. The activity coefficient of rare earth chlorides has been investigated using ground breaking theory and experimental approach. Furthermore, an ionic size dependent activity coefficient model is presented. This book also contains research into quaternary phase diagrams for LiCl-KCl-CsCl-RECl3 molten salt systems. This book should prove an excellent introduction to anyone pursuing a career in experimental high temperature electrochemistry and molten salt chemistry.

Bagri, Prashant↗

Fuel Qualification for Molten Salt Reactors

This report supports the development and review of an efficient methodology or process for liquid salt fuel system qualification. The report describes the technical issues encountered when developing an adequate understanding of the fuel salt’s chemical and physical behavior under both normal and accident conditions. The concepts presented in this report align with the fundamental safety functions (FSFs) approach of the more general non-light water reactor (nonLWR) fuel qualification guidance provided in NUREG-2246. However, because liquid salt fuel has substantial technical differences from solid fuels, this report describes tailored approaches for achieving the common safety intents when using liquid salt. The purpose of this report is to illustrate how variations in fuel salt properties impact achievement of FSFs at liquid-salt fueled molten salt reactors (MSRs). The focus on FSFs supports methodology compatibility with both current and developing licensing processes. Customized fuel qualification guidance for liquid salt–fueled Nuclear Power Plants (NPPs) are also provided in this report to supplement the generic non-LWR guidance recently developed by the NRC. As with the broader non-LWR fuel qualification, this report focuses on identification and understanding of fuel life-limiting failure and fuel salt property degradation mechanisms that occur as a result of irradiation during reactor operation.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Fuel Cell Buses in U.S. Transit Fleets: Current Status 2018

This report, published annually, summarizes the progress of fuel cell electric bus (FCEB) development in the United States and discusses the achievements and challenges of introducing fuel cell propulsion in transit. The report provides a summary of results from evaluations performed by the U.S. Department of Energy's (DOE's) National Renewable Energy Laboratory. This annual status report combines results from all FCEB demonstrations, tracks the progress of the FCEB industry toward meeting technical targets, documents the lessons learned, and discusses the path forward for commercial viability of fuel cell technology for transit buses. The data from these early FCEB deployments funded by the U.S. Department of Transportation, state agencies, and the private sector help to guide future early-stage research and development supported by DOE's Fuel Cell Technologies Office. The 2018 summary results primarily focus on the most recent year for each demonstration, from August 2017 through July 2018. NREL has included an up-to-date analysis of operational costs including scheduled and unscheduled cost and cost per mile by system. The primary results presented in the report are from five demonstrations of two different fuel-cell-dominant bus designs.

30 DIRECT ENERGY CONVERSION↗

Anhydrous Proton-Conducting Membranes for Fuel Cells

Polymeric electrolyte membranes that do not depend on water for conduction of protons are undergoing development for use in fuel cells. Prior polymeric electrolyte fuel-cell membranes (e.g., those that contain perfluorosulfonic acid) depend on water and must be limited to operation below a temperature of 125 C because they retain water poorly at higher temperatures. In contrast, the present developmental anhydrous membranes are expected to function well at temperatures up to 200 C. The developmental membranes exploit a hopping-and-reorganization proton- conduction process that can occur in the solid state in organic amine salts and is similar to a proton-conduction process in a liquid. This process was studied during the 1970s, but until now, there has been no report of exploiting organic amine salts for proton conduction in fuel cells.

Narayanan, Sekharipuram↗

Report on waterproofing of UN studies

Fuels with high uranium densities have been considered in the Nuclear Technology Research and Development program’s Advanced Fuels Campaign as potential replacements for uranium(IV) oxide in commercial light water reactors. One such candidate fuel is uranium mononitride, UN, which has been observed to readily oxidize in steam and simulated pressurized water reactor conditions. Thus, it is important to examine methods for waterproofing UN, especially for potential cladding breach scenarios. This can be achieved by controlling the microstructure so as to prevent contact between the UN fuel and coolant. Research highlighted in this L2 milestone has focused on screening potential candidate additive materials to control UN microstructure using steam oxidation TGA. From these candidates, silicon (Si), chromium (Cr), and silicon carbide (SiC) were selected based on corrosion resistance, which led to attempts to develop a method for compositing these materials with UN. Powders of these materials were mixed with UN, pressed, and sintered. UN-metal composite sintering was attempted through liquid-phase sintering at temperatures above the melting point of the respective metals, while the UN-SiC composite sintering was attempted using two-step sintering at 2100 and 2050 °C. Results of silicon and silicon carbide appeared to show chemical interaction with UN to form uranium silicides, while chromium was found to significantly volatilize near the melting point of chromium. No indication of densification was observed. These observations, along with those of the preceding, related L3 milestone (NTRD-M3FT-19LA020201024) were used to develop a better understanding of microstructure control to advance efforts for UN waterproofing.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Systems Analysis Initiated for All-Electric Aircraft Propulsion

A multidisciplinary effort is underway at the NASA Glenn Research Center to develop concepts for revolutionary, nontraditional fuel cell power and propulsion systems for aircraft applications. There is a growing interest in the use of fuel cells as a power source for electric propulsion as well as an auxiliary power unit to substantially reduce or eliminate environmentally harmful emissions. A systems analysis effort was initiated to assess potential concepts in an effort to identify those configurations with the highest payoff potential. Among the technologies under consideration are advanced proton exchange membrane (PEM) and solid oxide fuel cells, alternative fuels and fuel processing, and fuel storage. Prior to this effort, the majority of fuel cell analysis done at Glenn was done for space applications. Because of this, a new suite of models was developed. These models include the hydrogen-air PEM fuel cell; internal reforming solid oxide fuel cell; balance-of-plant components (compressor, humidifier, separator, and heat exchangers); compressed gas, cryogenic, and liquid fuel storage tanks; and gas turbine/generator models for hybrid system applications. Initial mass, volume, and performance estimates of a variety of PEM systems operating on hydrogen and reformate have been completed for a baseline general aviation aircraft. Solid oxide/turbine hybrid systems are being analyzed. In conjunction with the analysis efforts, a joint effort has been initiated with Glenn s Computer Services Division to integrate fuel cell stack and component models with the visualization environment that supports the GRUVE lab, Glenn s virtual reality facility. The objective of this work is to provide an environment to assist engineers in the integration of fuel cell propulsion systems into aircraft and provide a better understanding of the interaction between system components and the resulting effect on the overall design and performance of the aircraft. Initially, three-dimensional computer-aided design (CAD) models of representative PEM fuel cell stack and components were developed and integrated into the virtual reality environment along with an Excel-based model used to calculate fuel cell electrical performance on the basis of cell dimensions (see the figure). CAD models of a representative general aviation aircraft were also developed and added to the environment. With the use of special headgear, users will be able to virtually manipulate the fuel cell s physical characteristics and its placement within the aircraft while receiving information on the resultant fuel cell output power and performance. As the systems analysis effort progresses, we will add more component models to the GRUVE environment to help us more fully understand the effect of various system configurations on the aircraft.

Kohout, Lisa L.↗

Status Report on Photothermal Radiometry Development

Thermal transport properties such as thermal conductivity and diffusivity, are critical parameters in the development of improved nuclear fuels and components. It is well known that thermal transport properties change temporally and spatially due to dynamic microstructural evolution as a result of neutron irradiation. Laser based photothermal techniques are an ideal candidate for thermal properties measurement of irradiated materials because they are non contact, non destructive and can be performed remotely. In this report, we present the progress in the development of a photothermal radiometry (PTR) system to measure the thermal diffusivity of solid samples. The PTR technique measures the local temperature response from a modulated heat source by detecting the sample radiation heat flux. Initially, a well developed thermal wave analytical model was fit to the data to obtain the thermal diffusivity. However, systematic errors from the diffraction effect and non linearity issues resulted in thermal diffusivity measurements higher than literature values. These effects have been studied, an improved analytical model has been developed, and the physics behind the phenomena are still under investigation. A procedure for optimizing measurements from the benchtop system has been provided.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗