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At least 1,369 records · Page 76

Four different dimensional Zn(II) coordination polymers as fluorescent sensor for detecting Hg{sup 2+}, Cr{sub 2}O{sub 7}{sup 2-} in aqueous solution

Highlights: • Four Zn-based coordination polymers were solvethermally synthesized. • Compound 1 and 2 could mutual conversion between different solvent ratios. • Both 1 and 2 exhibit high selectivity for Cr{sub 2}O{sub 7}{sup 2-} and Hg{sup 2+} ions in aqueous solution. • The mechanism of sensing properties were discussed in details. - Abstract: Four Zn(II) coordination polymers (CPs), [Zn(4-pzpt){sub 2}(H{sub 2}O)]{sub n} (1), {[Zn(4-pzpt)_2]·CH_3OH}{sub n} (2), [Zn{sub 2}(4-pzpt){sub 2}(suc)(H{sub 2}O)]{sub n} (3) and [Zn{sub 2}(4-pzpt){sub 2}(ndc)]{sub n} (4) were obtained from 3-(pyridin-4-yl)-5-(pyrazin-2-yl)-1H-1,2,4-triazole (4-Hpzpt), 1,4-Naphthalenedicarboxylic acid (H{sub 2}ndc) and succinic acid (H{sub 2}suc) ligands. Structural analysis reveals that 1 represents a five coordinated 0D structure. 2 possess a network featuring 2D 4{sup 4} grid-like layers structure. 3 displays a network featuring 2D (6{sup 3})-hcb layered structure. 4 shows a rare 3D (4,4)-connected topology with a Schläfli symbol of (4.6{sup 4.}7){sub 2}(6{sup 4.}7{sup 2}). Complexes 1 and 2 can mutual conversion between different solvent ratios. Luminescence properties reveal that 1 and 2 exhibit excellent selectivity for Hg{sup 2+} and Cr{sub 2}O{sub 7}{sup 2-} ions in aqueous solution, in which suggests that 1 and 2 is a promising multifunctional sensing materials. The possible sensing mechanism is also discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

SPRUCE NDVI Data from Selected SPRUCE Experimental Plots, 2016-2018

This dataset consists of observations of Normalized Difference Vegetation Index (NDVI) observations from the Spruce and Peatland Responses Under Changing Environments (SPRUCE) experimental site within the Marcell Experimental Forest in northern Minnesota, USA. Measurements were collected via stationary sensors positioned 1.5 meter above unobstructed areas of the ground layer. Sensors were installed above undisturbed community composition plots, that are not instrumented or destructively sampled in any way, in six of the ten chambered SPRUCE experimental study plots located in the S1-Bog. Spectral data (630 and 800 nanometers) were collected at 10-minute intervals over a field of view of ~53 cm in diameter beginning May 6, 2016. Data collection ended at a different time for each sensor as batteries discharged – ranging from January 1, 2018 to April 1, 2018. The spectral sensors were manufactured by Decagon Inc., (now METER) for observation of ecosystem canopies. Sensors were deployed at the beginning of the 2016 growing season in +0, +4.5, and +9.0 C temperature treatments, with one each in an ambient and elevated carbon dioxide (CO2) plot, for a total of six sensors. These data have been analyzed and reported on in McPartland et al (2018). This dataset contains one data file in comma-separate values (*.csv) format and PDF (*.pdf) file containing plot maps. Additional metadata are provided: a data dictionary and a file-level metadata file in comma-separate values (.csv) format and a user guide in PDF (*.pdf) format.

54 ENVIRONMENTAL SCIENCES↗

A wearable patch for continuous analysis of thermoregulatory sweat at rest

The body naturally and continuously secretes sweat for thermoregulation during sedentary and routine activities at rates that can reflect underlying health conditions, including nerve damage, autonomic and metabolic disorders, and chronic stress. However, low secretion rates and evaporation pose challenges for collecting resting thermoregulatory sweat for non-invasive analysis of body physiology. Here we present wearable patches for continuous sweat monitoring at rest, using microfluidics to combat evaporation and enable selective monitoring of secretion rate. We integrate hydrophilic fillers for rapid sweat uptake into the sensing channel, reducing required sweat accumulation time towards real-time measurement. Along with sweat rate sensors, we integrate electrochemical sensors for pH, Cl - , and levodopa monitoring. We demonstrate patch functionality for dynamic sweat analysis related to routine activities, stress events, hypoglycemia-induced sweating, and Parkinson’s disease. By enabling sweat analysis compatible with sedentary, routine, and daily activities, these patches enable continuous, autonomous monitoring of body physiology at rest.

47 OTHER INSTRUMENTATION↗

Comparative evaluation of analogue front-end designs for the CMS Inner Tracker at the High Luminosity LHC

The CMS Inner Tracker, made of silicon pixel modules, will be entirely replaced prior to the start of the High Luminosity LHC period. One of the crucial components of the new Inner Tracker system is the readout chip, being developed by the RD53 Collaboration, and in particular its analogue front-end, which receives the signal from the sensor and digitizes it. Three different analogue front-ends (Synchronous, Linear, and Differential) were designed and implemented in the RD53A demonstrator chip. A dedicated evaluation program was carried out to select the most suitable design to build a radiation tolerant pixel detector able to sustain high particle rates with high efficiency and a small fraction of spurious pixel hits. The test results showed that all three analogue front-ends presented strong points, but also limitations. The Differential front-end demonstrated very low noise, but the threshold tuning became problematic after irradiation. Moreover, a saturation in the preamplifier feedback loop affected the return of the signal to baseline and thus increased the dead time. The Synchronous front-end showed very good timing performance, but also higher noise. For the Linear front-end all of the parameters were within specification, although this design had the largest time walk. This limitation was addressed and mitigated in an improved design. The analysis of the advantages and disadvantages of the three front-ends in the context of the CMS Inner Tracker operation requirements led to the selection of the improved design Linear front-end for integration in the final CMS readout chip.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Determination of normal-shock position in a mixed compression supersonic inlet

Methods of determining inlet normal shock position from wall static pressure profiles were investigated. By using methods investigated in this report, it should be possible to control an inlet with less stability margin. Variation in inlet angle-of-attack caused drastic changes in pressure profile shape and wide variations in the angle of the shock plane with respect to the inlet axis. Thus, four sensors located around the circumference may be required to handle angle-of-attack and sideslip variations. One criterion would determine the shock position by comparing individual statics to a properly selected reference pressure.

Dustin, M. O.↗

Path selection system simulation and evaluation for a Martian roving vehicle

A comprehensive digital computer simulation program has been developed for evaluating the path-selection system performance of an autonomous roving vehicle being designed for the exploration of Mars. Vehicle performance over realistic three-dimensional terrains in the presence of random motion disturbances and sensor measurement noise is simulated and plotted on a terrain contour map. In addition, a numerical figure-of-merit is computed automatically for each run.

Frederick, D. K.↗

Advanced Photovoltaic Experiment, S0014: Preliminary Flight Results and Post-Flight Findings

The Advanced Photovoltaic Experiment (APEX) is an LDEF experiment designed to provide reference solar cell standards for laboratory measurements as well as to investigate the solar spectrum and the effects of long term exposure of solar cells to the LEO environment. Silicon and gallium arsenide solar cells were flown with the appropriate instrumentation to periodically measure cell performance and temperature. The experimental objectives, the design employed to realize these objectives and the solar cells and instrumentation selected for the flight are presented. A discussion of the flight data returned are included. Preliminary results from the post flight analysis of the absolute cavity radiometer, the digital solar angle sensor, and the Barr Associates narrow bandpass optical filters are also presented. The initial findings of work to determine the chemical nature of contamination layers on APEX are also presented.

Brinker, David J.↗

Aircraft scanner data availability via the version 0 Information Management System

As part of the Earth Observing System Data and Information System (EOSDIS) development, NASA and other government agencies have developed an operational prototype of the Information Management System (IMS). The IMS provides access to the data archived at the Distributed Active Archive Centers (DAAC's) that allows users to search through metadata describing the (image) data. Criteria based on sensor name or type, date and time, and geographic location are used to search the archive. Graphical representations of coverage and browse images are available to further refine a user's selection. previously, the EROS Data Center (EDC) DAAC had identified the Advanced SOlid-state Array Spectrometer (ASAS), Airborne Visible and infrared Imaging Spectrometer (AVIRIS), NS-001, and Thermal Infrared Multispectral Scanner (TIMS) as precursor data sets similar to those the DAAC will handle in the Earth Observing System era. Currently, the EDC DAAC staff, in cooperation with NASA, has transcribed TIMS, NS-001, and Thematic Mapper Simulation (TMS) data from Ames Research Center and also TIMS data from Stennis Space Center. During the transcription process, the IMS metadata and browse images were created to populate the inventory at the EDC DAAC. These data sets are now available in the IMS and may be requested from the any of the DAAC's via the IMS.

Mah, G. R.↗

Work on Planetary Atmospheres and Planetary Atmosphere Probes

A summary final report of work accomplished is presented. Work was performed in the following areas: (1) Galileo Probe science analysis, (2) Galileo probe Atmosphere Structure Instrument, (3) Mars Pathfinder Atmosphere Structure/Meteorology instrument, (4) Mars Pathfinder data analysis, (5) Science Definition for future Mars missions, (6) Viking Lander data analysis, (7) winds in Mars atmosphere Venus atmospheric dynamics, (8) Pioneer Venus Probe data analysis, (9) Pioneer Venus anomaly analysis, (10) Discovery Venus Probe Titan probe instrument design, and (11) laboratory studies of Titan probe impact phenomena. The work has resulted in more than 10 articles published in archive journals, 2 encyclopedia articles, and many working papers. This final report is organized around the four planets on which there was activity, Jupiter, Mars, Venus, and Titan, with a closing section on Miscellaneous Activities. A major objective was to complete the fabrication, test, and evaluation of the atmosphere structure experiment on the Galileo probe, and to receive, analyze and interpret data received from the spacecraft. The instrument was launched on April 14, 1989. Calibration data were taken for all experiment sensors. The data were analyzed, fitted with algorithms, and summarized in a calibration report for use in analyzing and interpreting data returned from Jupiter's atmosphere. The sensors included were the primary science pressure, temperature and acceleration sensors, and the supporting engineering temperature sensors. Computer programs were written to decode the Experiment Data Record and convert the digital numbers to physical quantities, i.e., temperatures, pressures, and accelerations. The project office agreed to obtain telemetry of checkout data from the probe. Work to extend programs written for use on the Pioneer Venus project included: (1) massive heat shield ablation leading to important mass loss during entry; and (2) rapid planet rotation, which introduced terms of motion not needed on Venus. When the Galileo Probe encountered Jupiter, analysis and interpretation of data commenced. The early contributions of the experiment were to define (1) the basic structure of the deep atmosphere, (2) the stability of the atmosphere, (3) the upper atmospheric profiles of density, pressure, and temperature. The next major task in the Galileo Probe project was to refine, verify and extend the analysis of the data. It was the verified, and corrected data, which indicated a dry abiabatic atmosphere within measurement accuracy. Temperature in the thermosphere was measured at 900 K. Participation in the Mars atmospheric research included: (1) work as a team member of the Mars Atmosphere Working Group, (2) contribution to the Mars Exobiology Instrument workshop, (3) asssistance in planning the Mars global network and (4) assitance in planning the Soviet-French Mars mission in 1994. This included a return to the Viking Lander parachute data to refine and improve the definition of winds between 1.5 and 4 kilometer altitude at the two entry sites. The variability of the structure of Mars atmosphere was addressed, which is known to vary with season, latitude, hemisphere and dust loading of the atmosphere. This led to work on the Pathfinder project. The probe had a deployable meteorology mast that had three temperature sensors, and a wind sensor at the tip of the mast. Work on the Titan atmospheric probe was also accomplished. This included developing an experiment proposal to the European Space Agency (ESA), which was not selected. However, as an advisor in the design and preparation of the selected experiment the researcher interacted with scientist on the Huygens Probe Atmosphere Structure Experiment. The researcher also participated in the planning for the Venus Chemical Probe. The science objectives of the probe were to resolve unanswered questions concerning the minor species chemistry of Venus' atmosphere that control cloud formation, greenhouse effectiveness, and the thermal structure. The researcher also reviewed problems with the Pioneer Venus Probe, that caused anomalies which occurred on the Probes at and below 12.5 km level of the Venus' atmosphere. He convened and participated in a workshop that concluded the most likely hardware cause was insulation failure in the electrical harness outside the Probes' pressure vessels. It was discovered that the shrink tubing material failed at 600K. This failure could explain the anomalies experienced by the probes. The descent data of the Pioneer probes, and the Soviet Vega Lander was analyzed to evaluate the presence of small scale gravity waves in and below the Venus cloud layer.

Lester, Peter↗

Quasi-Steady Acceleration Direction Indicator in Three Dimensions

Many materials processing and fluids physics experiments conducted in a microgravity environment require knowledge of the orientation of the low-frequency acceleration vector. This need becomes especially acute for space experiments such as directional solidification of a molten semiconductor, which is extremely sensitive to orientation and may involve tens of hours of operations of a materials furnace. These low-frequency acceleration data have been measured for many Shuttle missions with the Orbital Acceleration Research Experiment. Previous attempts at using fluid chambers for acceleration measurements have met with limited success due to pointing and vehicle attitude complications. An acceleration direction indicator is described, which is comprised of two orthogonal short cylinders of fluid, each with a small bubble. The motion and the position of the bubble within the chamber will indicate the direction of the acceleration experienced at the sensor location. The direction of the acceleration vector may then be calculated from these data. The frequency response of such an instrument may be tailored for particular experiments with the proper selection of fluid and gas parameters, surface type, and geometry. A three-dimensional system for sensing and displaying the low-frequency acceleration direction via an innovative technique described in this paper has advantages in terms of size, mass, and power compared with electronic instrumentation systems.

DeLombard, Richard↗

The human power amplifier technology at the University of California, Berkeley

A human's ability to perform physical tasks is limited by physical strength, not by intelligence. We define "extenders" as a class of robot manipulators worn by humans to augment human mechanical strength, while the wearer's intellect remains the central control system for manipulating the extender. Our research objective is to determine the ground rules for the design and control of robotic systems worn by humans through the design, construction, and control of several prototype experimental direct-drive/non-direct-drive multi-degree-of-freedom hydraulic/electric extenders. The design of extenders is different from the design of conventional robots because the extender interfaces with the human on a physical level. Two sets of force sensors measure the forces imposed on the extender by the human and by the environment (i.e., the load). The extender's compliances in response to such contact forces were designed by selecting appropriate force compensators. This paper gives a summary of some of the selected research efforts related to Extender Technology, carried out during 1980s. The references, at the end of this article, give detailed description of the research efforts.

NASA Discipline Space Human Factors↗

Method and system for detecting a failure or performance degradation in a dynamic system such as a flight vehicle

A method and system for detecting a failure or performance degradation in a dynamic system having sensors for measuring state variables and providing corresponding output signals in response to one or more system input signals are provided. The method includes calculating estimated gains of a filter and selecting an appropriate linear model for processing the output signals based on the input signals. The step of calculating utilizes one or more models of the dynamic system to obtain estimated signals. The method further includes calculating output error residuals based on the output signals and the estimated signals. The method also includes detecting one or more hypothesized failures or performance degradations of a component or subsystem of the dynamic system based on the error residuals. The step of calculating the estimated values is performed optimally with respect to one or more of: noise, uncertainty of parameters of the models and un-modeled dynamics of the dynamic system which may be a flight vehicle or financial market or modeled financial system.

Miller, Robert H.↗

Sensor System Performance Evaluation and Benefits from the NPOESS Airborne Sounder Testbed-Interferometer (NAST-I)

Advanced satellite sensors are tasked with improving global-scale measurements of the Earth's atmosphere, clouds, and surface to enable enhancements in weather prediction, climate monitoring, and environmental change detection. Validation of the entire measurement system is crucial to achieving this goal and thus maximizing research and operational utility of resultant data. Field campaigns employing satellite under-flights with well-calibrated FTS sensors aboard high-altitude aircraft are an essential part of this validation task. The National Polar-orbiting Operational Environmental Satellite System (NPOESS) Airborne Sounder Testbed-Interferometer (NAST-I) has been a fundamental contributor in this area by providing coincident high spectral/spatial resolution observations of infrared spectral radiances along with independently-retrieved geophysical products for comparison with like products from satellite sensors being validated. This paper focuses on some of the challenges associated with validating advanced atmospheric sounders and the benefits obtained from employing airborne interferometers such as the NAST-I. Select results from underflights of the Aqua Atmospheric InfraRed Sounder (AIRS) and the Infrared Atmospheric Sounding Interferometer (IASI) obtained during recent field campaigns will be presented.

Larar, A.↗

Early Transition and Use of VIIRS and GOES-R Products by NWS Forecast Offices

The Visible Infrared Imaging Radiometer Suite (VIIRS) on the NPOESS Preparatory Project (NPP) satellite, part of the Joint Polar Satellite System (JPSS), and the ABI and GLM sensors scheduled for the GOES-R geostationary satellite will bring advanced observing capabilities to the operational weather community. The NASA Short-term Prediction Research and Transition (SPoRT) project at Marshall Space Flight Center has been facilitating the use of real-time experimental and research satellite data by NWS Weather Forecast Offices (WFOs) for a number of years to demonstrate the planned capabilities of future sensors to address particular forecast challenges through improve situational awareness and short-term weather forecasts. For the NOAA GOES-R Proving Ground (PG) activity, SPoRT is developing and disseminating selected GOES-R proxy products to collaborating WFOs and National Centers. SPoRT developed the a pseudo-Geostationary Lightning Mapper product and helped in the transition of the Algorithm Working Group (AWG) Convective Initiation (CI) proxy product for the Hazardous Weather Testbed (HWT) Spring Experiment,. Along with its partner WFOs, SPoRT is evaluating MODIS/GOES Hybrid products, which brings ABI-like data sets from existing NASA instrumentation in front of the forecaster for everyday use. The Hybrid uses near real-time MODIS imagery to demonstrate future ABI capabilities, while utilizing standard GOES imagery to provide the temporal frequency of geostationary imagery expected by operational forecasters. In addition, SPoRT is collaborating with the GOES-R hydrology AWG to transition a baseline proxy product for rainfall rate / quantitative precipitation estimate (QPE) to the OCONUS regions. For VIIRS, SPoRT is demonstrating multispectral observing capabilities and the utility of low-light channels not previously available on operational weather satellites to address a variety of weather forecast challenges. This presentation will discuss the results of transitioning these products to collaborating WFOs throughout the country.

Fuell, Kevin K.↗

Processing Near-Infrared Imagery of the Orion Heatshield During EFT-1 Hypersonic Reentry

The Scientifically Calibrated In-Flight Imagery (SCIFLI) team captured high-resolution, calibrated, near-infrared imagery of the Orion capsule during atmospheric reentry of the EFT-1 mission. A US Navy NP-3D aircraft equipped with a multi-band optical sensor package, referred to as Cast Glance, acquired imagery of the Orion capsule's heatshield during a period when Orion was slowing from approximately Mach 10 to Mach 7. The line-of-sight distance ranged from approximately 65 to 40 nmi. Global surface temperatures of the capsule's thermal heatshield derived from the near-infrared intensity measurements complemented the in-depth (embedded) thermocouple measurements. Moreover, these derived surface temperatures are essential to the assessment of the thermocouples' reliance on inverse heat transfer methods and material response codes to infer the surface temperature from the in-depth measurements. The paper describes the image processing challenges associated with a manually-tracked, high-angular rate air-to-air observation. Issues included management of significant frame-to-frame motions due to both tracking jerk and jitter as well as distortions due to atmospheric effects. Corrections for changing sky backgrounds (including some cirrus clouds), atmospheric attenuation, and target orientations and ranges also had to be made. The image processing goal is to reduce the detrimental effects due to motion (both sensor and capsule), vibration (jitter), and atmospherics for image quality improvement, without compromising the quantitative integrity of the data, especially local intensity (temperature) variations. The paper will detail the approach of selecting and utilizing only the highest quality images, registering several co-temporal image frames to a single image frame to the extent frame-to-frame distortions would allow, and then co-adding the registered frames to improve image quality and reduce noise. Using preflight calibration data, the registered and averaged infrared intensity images were converted to surface temperatures on the Orion capsule's heatshield. Temperature uncertainties will be discussed relative to uncertainties of surface emissivity and atmospheric transmission loss. Comparison of limited onboard surface thermocouple data to the image derived surface temperature will be presented.

Spisz, Thomas S.↗

Functional Data Analysis in Wearable Body Sensor Networks

Improving response time of indirect room-size calorimeters is still an outstanding problem in metabolic research. Accurate estimates of instantaneous rates of gaseous exchange require numerical differentiation of measured gaseousgas concentrations. We propose a new method to estimate the instantaneous gaseousgas exchange rates in indirect calorimetry. In contrast to the previously developed techniques, the method addresses the problem of differentiation of gaseous concentrations as an ill-posed problem. By applying the method of regularization, the problem of differentiation is converted into a well-posed problem resulting in smooth and consistent gaseous exchange rates. The validity of the method is tested on a large dataset of calorimeter experiments which included 313 human experiments along with 231 alcohol combustion experiments. It is demonstrated that the method is able to reliably differentiate between the “unphysiological” process of alcohol combustion and physiological variations produced by human metabolism. The method also allowed unraveling the previously unreported relative kinetics of O2 consumption and Respiratory Quotient (RQ) in humans. It was found that the kinetics of oxidative fuel selection lags behind the energy expenditure in humans exhibiting some sort of oxidative inertia. The time lag varies from 2-3 min up to 30 min, depending on particular individual. No such lag was found in alcohol combustion experiments. In addition to the relative kinetics of substrate oxidation, two statistical indexes reflecting variability of minute-by-minute RQ were estimated. The indexes were the RQ’s standard deviation and RQ’s first-order derivative. Both indexes showed statistically significant difference between human experiments and alcohol combustion experiments. We conclude that the proposed method can consistently extract physiologically-relevant information from noisy calorimetry data and the aforesaid information can provide additional insights into the mechanism of metabolic fuel selection in humans.

54 ENVIRONMENTAL SCIENCES↗

Assessing the Expansion of Ground-Motion Sensing Capability in Smart Cities via Internet Fiber-Optic Infrastructure

Monitoring ground motion in smart cities can improve the public safety by providing critical insights on natural and anthropogenic hazards, for example, earthquakes, landslides, explosions, infrastructure failures, and so forth. Although seismic activity is typically measured using dedicated point sensors (e.g., geophones and accelerometers), techniques such as distributed acoustic sensing have demonstrated the utility of using fiber-optic cable to detect seismic activity over comparable distances. In this article, we present the results of a study that quantifies the expansion in an area monitored for low-amplitude ground-motion events by augmenting existing point sensors with the internet fiber-optic cable infrastructure. Here we begin by describing our methodology, which utilizes geospatial data on point sensors and internet optical fiber deployed in metropolitan statistical areas (MSAs) in the United States. We extend these data to identify the area that can be monitored by (1) considering the observed seismic noise data in target locations, (2) applying the model from Wilson et al. (2021) to understand the potential coverage area gains using optical fiber sensing, and (3) optimizing the selection of fiber segments to maximize coverage and minimize deployment costs. We implement our methodology in ArcGIS to assess the additional area that can be monitored for low-amplitude ground-motion events (i.e., magnitude >0.5) by utilizing internet fiber-optic cables in the 100 most populous MSAs in the United States. We find that the addition of internet fiber-based sensors in MSAs would increase the area monitored on average by over an order of magnitude from 1% to 12%, if the subset of fiber cable segments that maximize coverage and minimize deployment costs is chosen even if only 20% of all fibers are used.

58 GEOSCIENCES↗