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At least 1,369 records · Page 76

The 1991 November 9 flare at 03.2 UT: Observations from Yohkoh

We discuss X-ray spectra and soft X-ray images of an M1.9 flare that occurred on 1991 November 9 near 03.2 UT. These data were obtained with instrumentation on the Japanese Yohkoh spacecraft. They cover the entire rise phase and peak flare emission, and the beginning of the decay phase. We determine the dynamics, temperature, and emission measure of the flare as inferred from the X-ray line profiles of resonance lines of Fe XXV, Ca XIX, and S XV. We discuss the morphology of the flare as inferred from the soft X-ray images. The November 9 flare is atypical in that a stronger than usual blueshifted emission component (relative to the stationary component) is observed for the resonance lines at flare onset. We discuss several methods for deconvolving the blueshifted component from the stationary component. The X-ray line profiles are consistent with predictions of numerical simulations of chromospheric evaporation. The X-ray images reveal a flare with a complicated loop geometry that is not fully understood. Many of the features in the images are moving upwards at speeds ranging from a few km/s to about 800 km/s. The blueshifted emission begins near the onset of hard X-ray emission, implying that particle acceleration and upflowing plasma have a common energy source.

Doschek, G. A.↗

Enhancing and Archiving the APS Catalog of the POSS I

We have worked on two different projects: 1) Archiving the APS Catalog of the POSS I for distribution to NASA's NED at IPAC, SIMBAD in France, and individual astronomers and 2) The automated morphological classification of galaxies. We have completed archiving the Catalog into easily readable binary files. The database together with the software to read it has been distributed on DVD's to the national and international data centers and to individual astronomers. The archived Catalog contains more than 89 million objects in 632 fields in the first epoch Palomar Observatory Sky Survey. Additional image parameters not available in the original on-line version are also included in the archived version. The archived Catalog is also available and can be queried at the APS web site (URL: http://aps.umn.edu) which has been improved with a much faster and more efficient querying system. The Catalog can be downloaded as binary datafiles with the source code for reading it. It is also being integrated into the SkyQuery system which includes the Sloan Digital Sky Survey, 2MASS, and the FIRST radio sky survey. We experimented with different classification algorithms to automate the morphological classification of galaxies. This is an especially difficult problem because there are not only a large number of attributes or parameters and measurement uncertainties, but also the added complication of human disagreement about the adopted types. To solve this problem we used 837 galaxy images from nine POSS I fields at the North Galactic Pole classified by two independent astronomers for which they agree on the morphological types. The initial goal was to separate the galaxies into the three broad classes relevant to issues of large scale structure and galaxy formation and evolution: early (ellipticals and lenticulars), spirals, and late (irregulars) with an accuracy or success rate that rivals the best astronomer classifiers. We also needed to identify a set of parameters derived from the digitized images that separate the galaxies by type. The human eye can easily recognize complicated patterns in images such as spiral arms which can be spotty, blotchy affairs that are difficult for automated techniques. A galaxy image can potentially be described by hundreds of parameters, all of which may have some relation to the morphological type. In the set of initial experiments we used 624 such parameters, in two colors, blue and red. These parameters include the surface brightness and color measured at different radii, ratios of these parameters at different radii, concentration indices, Fourier transforms and wavelet decomposition coefficients. We experimented with three different classes of classification algorithms; decision trees, k-nearest neighbors, and support vector machines (SVM). A range of experiments were conducted and we eventually narrowed the parameters to 23 selected parameters. SVM consistently outperformed the other algorithms with both sets of features. By combining the results from the different algorithms in a weighted scheme we achieved an overall classification success of 86%.

Humphreys, Roberta M.↗

Topographic Rise in the Northern Smooth Plains of Mercury: Characteristics from Messenger Image and Altimetry Data and Candidate Modes of Origin

MESSENGER observations from orbit around Mercury have revealed that a large contiguous area of smooth plains occupies much of the high northern latitudes and covers an area in excess of approx.6% of the surface of the planet [1] (Fig. 1). Smooth surface morphology, embayment relationships, color data, candidate flow fronts, and a population of partly to wholly buried craters provide evidence for the volcanic origin of these plains and their emplacement in a flood lava mode to depths at least locally in excess of 1 km. The age of these plains is similar to that of plains associated with and postdating the Caloris impact basin, confirming that volcanism was a globally extensive process in the post-heavy bombardment history of Mercury [1]. No specific effusive vent structures, constructional volcanic edifices, or lava distributary features (leveed flow fronts or sinuous rilles) have been identified in the contiguous plains, although vent structures and evidence of high-effusion-rate flood eruptions are seen in adjacent areas [1]. Subsequent to the identification and mapping of the extensive north polar smooth plains, data from the Mercury Laser Altimeter (MLA) on MESSENGER revealed the presence of a broad topographic rise in the northern smooth plains that is ~1,000 km across and rises more than 1.5 km above the surrounding smooth plains [2] (Fig. 2). The purpose of this contribution is to characterize the northern plains rise and to outline a range of hypotheses for its origin.

Dickson, James L.↗

The Crystalline Behavior and Device Function of Nonfullerene Acceptors in Organic Solar Cells

The current research investigates the structure features and intermolecular interactions of nonfullerene acceptors (NFAs) in single crystal and thin films, as well as their solar cell applications. Guiding parameters and key intermolecular forces that lead to 2D brickwork or 3D web packing are identified. The atomic modification is shown as the key to induce hydrogen bonding or π–π stacking column, which results in different crystalline packing. The molecular assembly in thin film is initiated by hydrogen bonding and completed by π–π stacking reorganization. The packing energy is seen as a guiding parameter that dictates the NFA crystalline morphology in blended thin films. The crystalline packing motif is not directly related with device efficiency. However, the crystalline morphology is the key parameter to influence exciton/carrier dynamics and device performance. In conclusion, a broader picture on the scaling behavior of organic semiconductor crystals ranging from oligoacenes to NFAs is established.

14 SOLAR ENERGY↗

Site-Selective Doping and Oxidation State Control of Copper in Gold Nanorods

We report the synthesis of plasmonic gold–copper nanostructures with tunable copper spatial distribution and oxidation state. Au–Cu alloy shells were deposited in aqueous solution onto colloidal gold nanorods that functioned as seeds, and the resulting shell morphology was found to depend strongly on the nanorod aspect ratio. For relatively fat gold nanorods (16 x 31 nm), Au–Cu growth was preferentially localized near the rod midsections, forming belt-like structures, whereas for skinnier nanorods (9 x 32 nm), Au–Cu growth produced patchy surface coverage around the entire rod. The shell thickness was tuned from 1 to 4 nm; upon air exposure, thicker shells exhibited a higher Cu(I) fraction compared to the initial shell. Incorporation of the Au–Cu shell led to pronounced shifts in the plasmonic features of the gold nanorods. These tunable plasmonic Au–Cu nanorods provide a materials basis for Cu-based plasmonic materials in the context of electrochemical CO₂ reduction.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Understanding Solution State Conformation and Aggregate Structure of Conjugated Polymers via Small Angle X-ray Scattering

Donor-acceptor (D-A) conjugated polymers are high-performance organic electronic materials that exhibit complex aggregation behavior. Understanding the solution state conformation and aggregation of conjugated polymers is crucial for controlling morphology during thin-film deposition and the subsequent electronic performance. However, a precise multiscale structure of solution state aggregates is lacking. Here, we present an in-depth small-angle X-ray scattering (SAXS) analysis of the solution state structure of an isoindigo-bithiophene-based D-A polymer (PII-2T) in chlorobenzene and decane as our primary system. Modeling the system as a combination of hierarchical fibrillar aggregates mixed with dispersed polymers, we extract information about conformation and multiscale aggregation and also clarify the physical origin of features often observed but unaddressed or misinterpreted in small-angle scattering patterns of conjugated polymers. The persistence length of the D-A polymer extracted from SAXS agrees well with a theoretical model based on the dihedral potentials. Additionally, we show that the broad high q structure factor peak seen in scattering profiles can be attributed to lamellar stacking occurring within the fibril aggregates and that the low q aggregate scattering is strongly influenced by the polymer molecular weight. Overall, the SAXS profiles of D-A polymers in general exhibit a sensitive dependence on the co-existence of fibrillar aggregate and dispersed polymer chain populations. We corroborate our findings from SAXS with electron microscopy of freeze-dried samples for direct imaging of fibrillar aggregates. Finally, we demonstrate the generality of our approach by fitting the scattering profiles of a variety of D-A polymers based on thieno-isoindigo (PTII-2T), diketopyrrolopyrrole (DPP2T-TT, DPP-BTZ, PDPP2FT-C- 16 ), naphthalenediimide (P(NDI2OD-T2)), and a conjugated block copolymer P3HT-b-DPPT-T. The results presented here establish a picture of the D-A polymer solution state structure and provide a general method of interpreting and analyzing their scattering profiles.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Model-based quantification of margins and uncertainties in metal additive manufacturing for process design and qualification

Laser powder bed fusion (LPBF) Additive Manufacturing (AM) has the potential to enable the production of components with novel designs and material properties unachievable otherwise. However, process repeatability is a challenge, making qualification ill-defined and greatly reducing the utility of what could be an important manufacturing technology. In this work, a combination of modeling, uncertainty quantification (UQ), and experimentation are used in an effort to predict and bound the range of possible outcomes of the LPBF process. Quantities of interest predicted are melt pool dimensions, microstructure features, and mechanical distortions. A combination of high fidelity thermal-fluid models, microstructure growth models, and reduced fidelity, rapid thermal and mechanical models are used. Uncertainty propagation techniques are used to predict probability distributions of quantities of interest from estimates of process uncertainties. Repeated experiments are done to quantify observed probability distributions and compared to predicted distributions to determine if predictions are precise and accurate. Novel modeling methods are microstrucutre characterization techniques are also discussed. It is found that high fidelity models do a generally good job bounding experimentally observed melt pool morphologies for both bead-on-plate and powder bed cases. Microstructure models are able to bound a number of experimentally observed microstructure statistics, but with low precision due to challenges with calibrating the microstructure growth model parameters. A developed modified inherent strain distortion model does not accurately predict observed distortions. A lumped laser distortion model shows promise in being both accurately and precisely bounding observed outcomes from the deflection comb build, but requires further evaluation on more builds and geometries.

36 MATERIALS SCIENCE↗

The 27-28 October 1986 FIRE IFO Cirrus Case Study: Cloud Optical Properties Determined by High Spectral Resolution Lidar

During the First ISCCP Region Experiment (FIRE) cirrus intensive field observation (IFO) the High Spectral Resolution Lidar was operated from a roof top site on the University of Wisconsin-Madison campus. Because the HSRL technique separately measures the molecular and cloud particle backscatter components of the lidar return, the optical thickness is determined independent of particle backscatter. This is accomplished by comparing the known molecular density distribution to the observed decrease in molecular backscatter signal with altitude. The particle to molecular backscatter ratio yields calibrated measurements of backscatter cross sections that can be plotted ro reveal cloud morphology without distortion due to attenuation. Changes in cloud particle size, shape, and phase affect the backscatter to extinction ratio (backscatter-phase function). The HSRL independently measures cloud particle backscatter phase function. This paper presents a quantitative analysis of the HSRL cirrus cloud data acquired over an approximate 33 hour period of continuous near zenith observations. Correlations between small scale wind structure and cirrus cloud morphology have been observed. These correlations can bias the range averaging inherent in wind profiling lidars of modest vertical resolution, leading to increased measurement errors at cirrus altitudes. Extended periods of low intensity backscatter were noted between more strongly organized cirrus cloud activity. Optical thicknesses ranging from 0.01-1.4, backscatter phase functions between 0.02-0.065 sr (exp -1) and backscatter cross sections spanning 4 orders of magnitude were observed. the altitude relationship between cloud top and bottom boundaries and the cloud optical center altitude was dependent on the type of formation observed Cirrus features were observed with characteristic wind drift estimated horizontal sizes of 5-400 km. The clouds frequently exhibited cellular structure with vertical to horizontal dimension ratios of 1:5-1:1.

Grund, C. J.↗

Evolution of large shield volcanoes on Venus

We studied the geologic history, topographic expression, and gravity signature of 29 large Venusian shield volcanoes with similar morphologies in Magellan synthetic aperture radar imagery. While they appear similar in imagery, 16 have a domical topographic expression and 13 have a central depression. Typical dimensions for the central depression are 150 km wide and 500 m deep. The central depressions are probably not calderas resulting from collapse of a shallow magma chamber but instead are the result of a corona-like sagging of a previously domical volcano. The depressions all have some later volcanic filling. All but one of the central depression volcanoes have been post-dated by geologic features unrelated to the volcano, while most of the domical volcanoes are at the top of the stratigraphic column. Analysis of the gravity signatures in the spatial and spectral domains shows a strong correlation between the absence of post-dating features and the presence of dynamic support by an underlying plume. We infer that the formation of the central depressions occurred as a result of cessation of dynamic support. However, there are some domical volcanoes whose geologic histories and gravity signatures also indicate that they are extinct, so sagging of the central region apparently does not always occur when dynamic support is removed. We suggest that the thickness of the elastic lithosphere may be a factor in determining whether a central depression forms when dynamic support is removed, but the gravity data are of insufficient resolution to test this hypothesis with admittance methods.

Herrick, Robert R.↗

pH‐Mediated Strong Metal‐Support Interaction Construction Through Dynamic Fermi Level Tuning

The metal–support interface is central to governing catalytic transformations. While strong metal–support interaction (SMSI) is an established strategy to tailor the morphology and electronic properties of supported metal catalysts, the role of interfacial charge redistribution in SMSI formation remains poorly understood and rarely leveraged. Here, in this study, we report a dual-stimuli approach that combines pH modulation with ultrasonication to mediate SMSI construction in aqueous solution through dynamic Fermi level tuning. By leveraging in situ pH-driven charge redistribution at the metal–support interface, we achieve controllable SMSI encapsulation of metal nanoparticles, as verified by electrochemical analysis, work function measurements, and x-ray-based techniques. The resulting catalysts exhibit tunable SMSI features and deliver enhanced activity and selectivity in hydrogenation reactions. This work establishes a facile strategy to modulate catalyst structure and electronic properties by exploiting Fermi level variation as a driving force, thereby advancing rational SMSI design and catalytic performance across diverse environments.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Quiescent Host Galaxies of Extended Quasars Revealed by Spectrophotometric Decomposition

Previous works of low-redshift quasar host galaxies have focused on compact quasars and found that their host galaxies are mainly star-forming galaxies. Here, we present a study of host galaxies for quasars with extended morphologies in ground-based optical images. We select a sample of more than 1000 type 1 quasars at redshift 0.1 < z < 1 that are classified as extended objects by the Dark Energy Spectroscopic Instrument (DESI). Combining high-resolution spectra from DESI and high-quality images from Subaru Hyper Suprime-Cam, we develop a spectrophotometric decomposition technique to iteratively decompose each quasar into an active galactic nucleus (AGN) component and its host galaxy. The technique can effectively break the degeneracy between the AGN and host components and capture the host spectral features. Our results show that the host galaxies of most quasars have low star formation rates (SFRs) and low specific SFRs, indicating that they are quiescent galaxies. Many of them exhibit prominent post-starburst features with the existence of significant old stellar populations. These properties are quite different from the nature of compact quasars with star-forming host galaxies. In addition, the relation between the black hole mass and stellar mass for our sample is broadly consistent with the canonical local relations. This work is complementary to the previous studies and suggests that the host galaxies of low-redshift quasars are more diverse than was thought.

79 ASTRONOMY AND ASTROPHYSICS↗

Radar, visual and thermal characteristics of Mars - Rough planar surfaces

High-resolution Viking Orbiter images contain significant information on Martian surface roughness at 25- to 100-m lateral scales, while earth-based radar observations of Mars are sensitive to roughness at lateral scales of 1 to 30 m or more. High-rms slopes predicted for the Tharsis-Memnonia-Amazonis volcanic plains from extremely weak radar returns are qualitatively confirmed by the Viking image data. Large-scale, curvilinear ridges on lava flows in the Memnonia Fossae region are interpreted as innate flow morphology caused by compressional foldover of moving lava sheets of possible rhyolite-dacite composition. The presence or absence of a recent mantle of fine-grained eolian material on the volcanic surfaces studied was determined by the visibility of fresh impact craters with diameters less than 50 m. Lava flows with surfaces modified by eolian erosion and deposition occur west-northwest of Apollinaris Patera at the border of the cratered equatorial uplands and southern Elysium Planitia. Nearby yardangs, for which radar observations indicate very high-rms slopes, are similar to terrestrial features of similar origin.

Schaber, G. G.↗

Depth/diameter relationships of fresh craters within Hesperia Planum, Mars

Meteorite impact craters represent important geological features for revealing the near-surface layers of a planetary surface. In the case of Mars, this characteristic was proposed as a useful method to study spatial variations of such attributes as the distribution of sub-surface volatiles, and heat flow. Using the Planetary Image Cartography System (PICS) software, a quantitative analysis was completed of the geometry of fresh impact craters in the Hesperia Planum region of Mars, where an uniform target material and optimum viewing geometry make possible an analysis of target effects over a large geographic region. Because of the morphologic similarity to the lunar maria, it is likely that Hesperia Planum comprises a series of flood lavas that partially infilled topographic depressions within the Martian highlands. Measurements of partially buried crater rims suggest that the lava flows within Hesperia Planum are between 200-400 m thick.

Mouginis-Mark, P. J.↗

Investigating Space Weathering of Ryugu Grains Using Electron Microscopy and X-Ray Computed Tomography

The effects of micrometeorite bombardment and solar wind ion irradiation – collectively known as space weathering – alter the microstructural, chemical, and spectral properties of airless surfaces. Characteristics of space weathering include vesiculated textures, amorphous grain rims (upper ~100 nm), and the production of Fe-bearing nanoparticles (npFe). The resulting modifications in the optical properties of the surface regolith include changes in spectral slope and overall reflectance of the surfaces as well as the attenuation of their characteristic absorption bands across VIS-NIR wavelengths. As the surface is continuously exposed to interplanetary space over time, the accrual of these features complicates the interpretation of remote sensing spectral data and the characterization of returned samples. Laboratory experiments that simulate solar wind irradiation and micrometeoroid impacts using carbonaceous analogs have revealed novel and complex microstructural and chemical changes, including the decrease in organic species concentrations and the reduction of Fe 3+ . In 2020, the Japan Aerospace Exploration Agency (JAXA)’s Hayabusa2 mission returned over 5 g of regolith particles from near- Earth C-type asteroid (162173) Ryugu – a unique opportunity to study space weathering on carbonaceous materials. Initial studies have established that the surface morphology and chemical signatures of space weathering in returned samples share characteristics with laser irradiation experiments simulating micrometeoroid bombardment, indicating that impacts are a significant space weathering mechanism operating on Ryugu. Here, we seek to improve our understanding of space weathering of carbonaceous asteroidal regolith grains by characterizing its effects directly on returned samples to determine the nature of space weathering on Ryugu. To do so, we performed coordinated analyses using electron beam techniques and X-ray computed tomography (XCT) to examine the effects of space weathering on grains returned from the surface of Ryugu by the Hayabusa2 mission.

L. E. Melendez↗

Through a glass darkly: In-situ x-ray computed tomography imaging of feed melting in continuously fed laboratory-scale glass melter

his study describes the first direct in-situ 3-D observation of a steady-state melting process by imaging a laboratory-scale slurry-fed glass melter in operation by x-ray computed tomography. Features of the reacting glass-feed, the foam layer underneath, and cavities in the glass melt pool are reconstructed in three-dimensional images. A slurry pool formed in a deep central caldera of dense dried feed, which penetrated into the glass melt. Slurry overflow from the caldera led to fast-dried and highly porous feed structure. A thin layer of foam separated the caldera from the melt. Bubbles ?5-15 mm in diameter were seen to grow beneath the reacting feed and move through the melt to escape at the edge. Pore morphology is benchmarked against computed tomography scans of a pellet of reacting simulated waste glass feed, and evolved gas analysis describes the gases generated as a function of temperature. Cooling artifacts are imaged and compared to previous studies of quenched cold caps. Detailed understanding of processes occurring during the conversion process in and below the reacting feed layer is necessary for the development of representative models of the melting process.

36 MATERIALS SCIENCE↗

Two polymorphs of [Rh(μ-I)(COD)] 2

The solid-state structure of di-μ-iodido-bis{[(1,2,5,6-η)-cycloocta-1,4-diene]rhodium(I)}, [Rh 2 I 2 (C 8 H 12 ) 2 ] or [Rh(μ-I)(COD)] 2 , was determined from two crystals with different morphologies, which were found to correspond to two polymorphs containing Rh dimers with significantly different molecular structures. Both polymorphs are monoclinic and the [Rh(μ-I)(COD)] 2 molecules in each case possess C 2 v symmetry. However, the core geometry of the butterfly-shaped Rh 2 I 2 core differs substantially. In the C 2/ c polymorph, the core geometry of [Rh(μ-I)(COD)] 2 B is bent, with a hinge angle of 96.13 (8)° and a Rh...Rh distance of 2.9612 (11) Å. The P 2 1 / c polymorph features a more planar [Rh(μ-I)(COD)] 2 P core geometry, with a hinge angle of 145.69 (9)° and a Rh...Rh distance of 3.7646 (5) Å.

36 MATERIALS SCIENCE↗

Geophysical observations pertaining to solid-state convection in the terrestrial planets

Observational evidence for solid-state convection in the interiors of the terrestrial planets is reviewed. For the earth, the motion of the lithospheric plates constitutes clear evidence of large-scale convection in the mantle. Although Mars has been found to lack evidence of plate tectonics, the morphology of the Tharsis uplift and the elevation dichotomy between the northern and southern hemispheres may be evidence of mantle convection at one time. Measurements of lunar heat flow and seismic Q imply a convective mechanism limited to the lower mantle. Evidence for internal convection on Mercury consists of its dipole magnetic field and the 3/2 resonance between its rotational motion and its orbital motion, both of which can also be explained by other processes. The limited radar imagery of Venus has not yet provided conclusive evidence of either the presence or absence of convection features. It is concluded that although interior convection in terrestrial planets is implied by rheological, energy and momentum considerations, only on earth is the lithosphere thin enough to provide conclusive evidence of convection.

Phillips, R. J.↗

Venusian impact basins and cratered terrains

The consensus regarding interpretation of Magellan radar imagery assigns Venus a young volcanic surface subjected in many areas to moderate crustal shortening. I infer that, on the contrary, ancient densely cratered terrain and large impact basins may be preserved over more than half the planet and that crustal shortening has been much overestimated. I see wind erosion and deposition as far more effective in modifying old structures. Integration with lunar chronology suggests that most of the surface of Venus may be older than 3.0 Ga and much may be older than 3.8 Ga. Broad volcanos, hug volcanic domes, plains preserving lobate flow patterns, and numerous lesser volcanic features, pocked sparsely by impact craters, are indeed obvious on Magellan imagery. Some of these postvolcanic impact craters have been slightly extended, but only a small portion has been flooded by still younger lavas. Relative ages of the young craters are indicated by the varying eolian removal of their forms and ejecta blankets and flow lobes, and the oldest are much subdued. If these young impact craters, maximum diameter 275 km, include all preserved impact structures, then their quantity and distribution indicate that Venus was largely resurfaced by volcanism approx. 0.5 Ga, subsequent eruptions having been at a much reduced rate. Away from the approx. 0.5 Ga volcanic features, much of Venus is, however, dominated by circular and subcircular features, 50-2000 km in diameter, many of them multiring, that may be mostly older impact and impact-melt structures substantially modified by wind action. Eolian erosion scoured to bedrock old ridges and uplands, including those that may be cratered terrains and the rims and outer-ring depressions of large impact basins, and removed all surficial deposits to the limits of resolution of the imagery. The complementary eolian deposits form not only dunes, wind streaks, and small plains, but also broad radar-dark plains, commonly assumed to be volcanic although lacking flow morphology, whose materials appear to be thick because they are smoothly compacted into buried craters.

Hamilton, Warren B.↗