Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “formate”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,369 records · Page 76

Formation of Oxides in the Interior of Friction Stir Welds

In friction stir welding (FSWing) the actual solid state joining takes place between the faying surfaces which form the weld seam. Thus the seam trace is often investigated for clues when the strength of the weld is reduced. Aluminum and its alloys are known to form a native, protective oxide on the surface. If these native surface oxides are not sufficiently broken up during the FSW process, they are reported to remain in the FSW interior and weaken the bond strength. This type of weld defect has been referred to as a lazy "S", lazy "Z", joint line defect, kissing bond, or residual oxide defect. Usually these defects are mitigated by modification of the process parameters, such as increased tool rotation rate, which causes a finer breakup of the native oxide particles. This study proposes that there may be an alternative mechanism for formation of oxides found within the weld nugget. As the oxidation rate increases at elevated temperatures above 400ºC, it may be possible for enhanced oxidation to occur on the interior surfaces during the FSW process from entrained air entering the seam gap. Normally, FSWs of aluminum alloys are made without a purge gas and it is unknown how process parameters and initial fit up could affect a potential air path into the interior during the processing. In addition, variations in FSW parameters, such as the tool rotation, are known to have a strong influence on the FSW temperature which may affect the oxidation rate if internal surfaces are exposed to entrained air. A series of FSWs were made in 3 different thickness panels of AA2219 (0.95, 1.27 and 1.56 cm) at 2 different weld pitches. As the thickness of the panels increased, there was an increased tendency for a gap to form in advance of the weld tool. If sufficient air is able to enter the workpiece gap prior to consolidation, the weld temperature can increase the oxidation rate on the interior surfaces. These oxidation rates would also be accelerated in areas of localized liquation. Metallographs from the weld panels showed indications of liquation at the grain boundaries. In FSWs of thicker panels, these regions of liquation were found to be heavily oxidized. The quality of the FSWs was evaluated from tensile testing at room temperature. As the panel thickness increased, a slight decrease in tensile strength was observed which was attributed to the presence of oxides. No oxide formation was observed in the thinner workpieces, although there were indications of localized liquation at the grain boundaries. Results from this study will assist in a better understand of the mechanisms of oxide formation in FSW interiors and provide methodology for minimizing their occurrence.

Schneider, Judy↗

Initial Satellite Formation Flight Results from the Magnetospheric Multiscale Mission

This paper describes the underlying dynamics of formation flying in a high-eccentricity orbit such as that of the Magnetospheric Multiscale mission. The GPS-based results used for MMS navigation is summarized, as well as the procedures that are used to design the maneuvers used to place the spacecraft into a tetrahedron formation and then maintain it. The details of how to carry out these maneuvers are then discussed. Finally, the numerical results that have been obtained concerning formation flying for the MMS mission to date (e.g. tetrahedron sizes flown, maneuver execution error, fuel usage, etc.) are presented in detail.

Conjunction↗

Mechanisms for the Formations of the Thymine Under Astrophysical Conditions and Implications for the Origin of Life

Nucleobases are the carriers of the genetic information in ribonucleic acid and deoxyribonucleic acid (DNA) for all life on Earth. Their presence in meteorites clearly indicates that compounds of biological importance can form via non-biological processes in extraterrestrial environments. Recent experimental studies have shown that the pyrimidine-based nucleobases uracil and cytosine can be easily formed from the ultraviolet irradiation of pyrimidine in H2O-rich ice mixtures that simulate astrophysical processes. In contrast, thymine, which is found only in DNA, is more difficult to form under the same experimental conditions, as its formation usually requires a higher photon dose. Earlier quantum chemical studies confirmed that the reaction pathways were favorable provided that several H2O molecules surrounded the reactants. However, the present quantum chemical study shows that the formation of thymine is limited because of the inefficiency of the methylation of pyrimidine and its oxidized derivatives in an H2O ice, as supported by the laboratory studies. Our results constrain the formation of thymine in astrophysical environments and thus the inventory of organic molecules delivered to the early Earth and have implications for the role of thymine and DNA in the origin of life.

Origin↗

Smectite Formation in Acid Sulfate Environments on Mars

Phyllosilicates of the smectite group detected in Noachian and early Hesperian terrains on Mars were hypothesized to form under aqueous conditions that were globally neutral to alkaline. These pH conditions and the presence of a CO2-rich atmosphere should have been favorable for the formation of large carbonate deposits. However, large-scale carbonate deposits have not been detected on Mars. We hypothesized that smectite deposits are consistent with perhaps widespread acidic aqueous conditions that prevented carbonate precipitation. The objective of our work was to investigate smectite formation under acid sulfate conditions in order to provide insight into the possible geochemical conditions required for smectite formation on Mars. Hydrothermal batch incubation experiments were performed with Mars-analogue, glass-rich, basalt simulant in the presence of sulfuric acid of variable concentration.

Peretyazhko, T. S.↗

Meteorological Support Interface Control Working Group (MSICWG) Instrumentation, Data Format, and Networks Document

The purpose of this document is to provide an overview of instrumentation discussed at the Meteorological Interface Control Working Group (MSICWG), a reference for data formats currently used by members of the group, a summary of proposed formats for future use by the group, an overview of the data networks of the group's members. This document will be updated as new systems are introduced, old systems are retired, and when the MSICWG community necessitates a change to the formats. The MSICWG consists of personnel from the National Aeronautics and Space Administration (NASA) Kennedy Space Center (KSC), NASA Marshall Space Flight Center (MSFC), NASA Johnson Space Center (JSC), National Oceanic and Atmospheric Administration National Weather Service Spaceflight Meteorology Group (SMG), and the United States Air Force (USAF) 45th Space Wing and Weather Squadron. The purpose of the group is to coordinate the distribution of weather related data to support NASA space launch related activities.

Brenton, James↗

Chandra Reveals Heavy Obscuration and Circumnuclear Star Formation in Seyfert 2 Galaxy NGC 4968

We present the Chandra imaging and spectral analysis of NGC 4968, a nearby (z = 0.00986) Seyfert 2 galaxy. We discover extended (approx. 1 kpc) X-ray emission in the soft band (0.5-2 keV) that is neither coincident with the narrow line region nor the extended radio emission. Based on spectral modeling, it is linked to on-going star formation [approx. 2.6-4 Mass compared to Earth yr(exp.− 1)]. The soft emission at circumnuclear scales (inner approx. 400 pc) originates from hot gas, with kT approx. 0.7 keV, while the most extended thermal emission is cooler (kT approx. 0.3 keV). We refine previous measurements of the extreme Fe K alpha equivalent width in this source (EW 2.5 + 2.6/-1.0 keV), which suggests the central engine is completely embedded within Compton-thick levels of obscuration. Using physically motivated models fit to the Chandra spectrum, we derive a Compton-thick column density [N(sub H) is greater than 1.25× 10(exp 24) cm(exp.− 2)] and an intrinsic hard (2-10 keV) X-ray luminosity of approx. 3-8× 10(exp. 42) erg s(exp. − 1) (depending on the presumed geometry of the obscurer), which is over two orders of magnitude larger than that observed. The large Fe K Alpha EW suggests a spherical covering geometry, which could be confirmed with X-ray measurements above 10 keV. NGC 4968 is similar to other active galaxies that exhibit extreme Fe K Alpha EWs (i.e., greater than 2 keV) in that they also contain on-going star formation. This work supports the idea that gas associated with nuclear star formation may increase the covering factor of the enshrouding gas and play a role in obscuring active galactic nuclei.

LaMassa, Stephanie M.↗

Major Pathways to Electron Distribution Function Formation in Regions of Diffuse Aurora

This paper discusses the major pathways of electron distribution function formation in the region of diffuse aurora. The diffuse aurora accounts for about of 75% of the auroral energy precipitating into the upper atmosphere, and its origin has been the subject of much discussion. We show that an earthward stream of precipitating electrons initially injected from the Earth's plasma sheet via wave-particle interactions degrades in the atmosphere toward lower energies and produces secondary electrons via impact ionization of the neutral atmosphere. These electrons of magnetospheric origin are then reflected back into the magnetosphere along closed dipolar magnetic field lines, leading to a series of reflections and consequent magnetospheric interactions that greatly augment the initially precipitating flux at the upper ionospheric boundary (700-800 km). To date this, systematic magnetosphere-ionosphere coupling element has not been included in auroral research models, and, as we demonstrate in this article, has a dramatic effect (200-300%) on the formation of the precipitating fluxes that result in the diffuse aurora. It is shown that wave-particle interaction processes that drive precipitating fluxes in the region of diffuse aurora from the magnetospheric altitudes are only the first step in the formation of electron precipitation at ionospheric altitudes, and they cannot be separated from the atmospheric collisional machine that redistributes and transfers their energy inside the magnetosphere-ionosphere-atmosphere coupling system.

magnetospheric↗

Formation Flight System Extremum-Seeking-Control Using Blended Performance Parameters

An extremum-seeking control system for formation flight that uses blended performance parameters in a conglomerate performance function that better approximates drag reduction than performance functions formed from individual measurements. Generally, a variety of different measurements are taken and fed to a control system, the measurements are weighted, and are then subjected to a peak-seeking control algorithm. As measurements are continually taken, the aircraft will be guided to a relative position which optimizes the drag reduction of the formation. Two embodiments are discussed. Two approaches are shown for determining relative weightings: "a priori" by which they are qualitatively determined (by minimizing the error between the conglomerate function and the drag reduction function), and by periodically updating the weightings as the formation evolves.

Ryan, John J.↗

A Prognostics Framework Development for Swarm Satellite Formations

Prognostics is the science of predicting the failure(s) of a component or a system and understanding how the performance will change in the event of a failure or degradation mechanism. With accurate predictions of possible failures, autonomous mitigative actions can be taken to correct/repair any issues or alert human operators of a failure threshold exceedance requiring condition-based maintenance. Although there is extensive research on failure predictions for a component or a system, there are significantly more opportunities to foray into failure predictions and prognostics for a system of systems such as an airspace consisting of multiple aircraft, a fleet of unmanned aerial vehicles, and a swarm of intelligent satellite systems. Failure prediction and mitigation are particularly important in autonomous systems such as satellite swarm systems that need effective resource management and minimal human interactions. Based on NASA's decadal survey, there is a clear need to prioritize the development of satellite swarm technology for studies of space physics and Earth science. The science community will propose future missions that return in-situ measurements from a 3-D (three-dimensional) volume of space, with relative spacecraft motion and inter-satellite baselines controlled according to the mission objectives. For such multi-spacecraft missions, it is required that ground operations resources do not scale with the number of satellites, thus compromising the swarm or leading to inefficiencies in resource allocation. Swarms of tens or hundreds of small satellites will require autonomy in attitude control, navigation and failure. Although significant research has been conducted in the areas of autonomous formation flying algorithms, less attention has been given to the development of resilient systems robust to failures.The focus of this research paper is the integration of model-based prognostics into the swarm dynamics control and decision-making algorithms. We simulate swarm management strategies for a subsystem failure to demonstrate the importance of failure predictions by comparing two cases: (i) no health information is provided to the system and utilized in the decision-making process and (2) system health information is obtained using prognostics and employed by the control system. One example scenario presented is for the GPS (Global Positioning System) system of an individual satellite to perform off-nominally due to increasing estimated error. In this scenario, the keep-out zone for that satellite would become more conservative, thereby decreasing the risk of collision. This is achieved via tuning the individual artificial repulsive functions assigned to each satellite.This paper is structured as follows. First we provide an overview of current swarm technology development, where we specifically use the term swarm to define multiple satellites flying in formation in similar orbits, with cross-link communication and station-keeping capabilities. Second, we give an introduction to the Swarm Orbital Dynamics Advisor (SODA), a tool that accepts high-level configuration commands and provides the orbital maneuvers required to achieve the prescribed formation configuration. Third, we provide the details of the model-based prognostics algorithm implementation in SODA. Finally, we present different case studies for potential component/subsystem failures and the swarm responses based with and without failure prediction information.

prognostics↗

Considerations When Building Thermal Models that Require Conversion Between Formats

At times, it is inevitable to require conversion of thermal models from one software format to another. This most often occurs for missions with international partners where not all parties utilize the same software packages for thermal analysis. Mandating a single tool for all parties is one possible solution, but this approach can introduce problems if significant effort is required to overcome inexperience with the designated tool and may result in difficulty meeting analysis schedule requirements. Alternatively, allowing all parties to use their own familiar tools minimizes the impact to analysis schedules but does introduce the need to convert the models later to a common format for analysis at a higher level of assembly. External conversion tools and formats have been developed through the years to aid in this process, but have had limited success in fully converting models seamlessly. Having a basic familiarity with tool capabilities on both sides of the conversion process allows for models to be built in a manner to better facilitate conversion by avoiding features and capabilities which are unsupported by the destination tool or for which no workarounds exist. Also, the effort to convert a model is often neglected when developing the schedules for analysis at the higher assembly levels; delivery of models preconditioned for convertibility minimizes the schedule risk. This paper seeks to provide some guidance on modeling techniques to avoid when developing Geometrical Math Models (GMM) and Thermal Math Models (TMM) when conversion is required. The recommendations are based on GMM conversion experiences between TSS/ThermalDesktop/ESARAD and TMM conversions between SINDA-FLUINT/ESATAN.

Modeling↗

Experimentation to Understand Planet and Proto-Planet Formation

Experimental petrology has placed constraints on a wide variety of nebular and planet formation processes such as chondrule formation, CAI (Calcium-Aluminum-rich Inclusions) crystallization, asteroid magmatism, mantle melting, core formation, element partitioning related to radiogenic isotopes and heat production. Although great progress has been made, there remain several key problems where more data are required to constrain modelling, both empirical and thermodynamics-based. Here I will focus on several areas with implications for meteoritics and planetary science, including systems of low fO2 (Oxygen fugacity), constructing models that include both metal and silicate for mantle melting and differentiation, high pressure phase equilibria relevant to full range of silicate mantles, and core-mantle equilibria where H and O are specified, and their effects are measured.

Righter, K.↗

Wide-Field Infrared Survey Telescope and Starshade Formation Flying Dynamics at Sun-Earth L2

The formation flying of an occulter with a telescope at the Sun-Earth L2 (SEL2) Libration Point can be a challenging problem. A good knowledge of the Restricted Three Body Problem dynamics is required to understand how these two spacecraft interact with each other in the SEL2 unstable environment, and how other perturbations such as Solar Radiation Pressure (SRP) affect their mutual trajectories. This paper focuses on the transfer trajectories to achieve specific relative positions between two spacecraft as they fly in formation at SEL2, andanalyzes the relevance of SRP in this formation, using the Wide-Field Infrared Survey Telescope (WFIRST) and the Starshade occulter as an example. Given that WFIRST and Starshade have very different area-to-mass ratios, SRP will affect their motion in different ways, and their relative position can be key to reduce the V cost. In this paper we intend on providing an explanation on how the relative position between both spacecrafts affects the transfer V from one observation to the other using dynamical system theory and Floquet modes.

Pressure↗

Chain Formation as a Mechanism for Mass-Independent Fractionation of Sulfur Isotopes in the Archean Atmosphere

The anomalous abundances of sulfur isotopes in ancient sediments provide the strongest evidence for an anoxic atmosphere prior to ∼2.45 Ga, but the mechanism for producing this 'mass-independent' fractionation pattern remains in question. The prevailing hypothesis has been that it is created by differences in the UV photolysis rates of different SO2 isotopologues. We investigate here a recently proposed additional source of fractionation during gas-phase formation of elemental sulfur (S4 and S8). Because two minor S isotopes rarely occur in the same chain, the longer S4 and S8 chains should be strongly, and roughly equally, depleted in all minor isotopes. This gives rise to negative ∆(sup 33) S values and positive ∆(sub 36) S values in elemental sulfur-just the opposite of (and much larger than) what is predicted from SO2 photolysis itself. Back-reactions during chain formation, specifically photolysis of S2 and S3, pass sulfur having the opposite fractionation back to atomic S, and thence to other sulfur species, causing H2S, SO2, sulfate, and short-chain elemental sulfur to have positive ∆(sup 33) S and negative ∆(sup 36) S. Positive ∆(sup 33) S values in elemental sulfur produced in laboratory SO2 photolysis experiments could be caused by the initial fractionation during photolysis, combined with rapid condensation of short-chain sulfur species on the walls of the reaction chamber, along with a scarcity of back-reactions. The simulated fractionations produced by the chain formation mechanism do not directly match fractionations from the rock record. The mismatch might be explained if the isotopic signals leaving the atmosphere were significantly modulated by life, by uncertainties in the rates of reactions of both major and minor isotopic sulfur species, or by the relatively large potential range of atmospheric parameters. Further work is needed to better constrain these uncertainties, but this novel mechanism suggests new avenues to explore in our search for a explanation for the S-MIF record.

Great Oxidation Event↗

Chain Formation as a Mechanism for Mass-Independent Fractionation of Sulfur Isotopes in the Archean Atmosphere

The anomalous abundances of sulfur isotopes in ancient sediments provide the strongest evidence for an anoxic atmosphere prior to ∼2.45 Ga, but the mechanism for producing this ‘mass-independent’ fractionation pattern remains in question. The prevailing hypothesis has been that it is created by differences in the UV photolysis rates of different SO2 isotopologues. We investigate here a recently proposed additional source of fractionation during gas-phase formation of elemental sulfur (S4 and S8). Because two minor S isotopes rarely occur in the same chain, the longer S4 and S8 chains should be strongly, and roughly equally, depleted in all minor isotopes. This gives rise to negative Δ(exp 33)S values and positive Δ(exp 33)S values in elemental sulfur—just the opposite of (and much larger than) what is predicted from SO2 photolysis itself. Back-reactions during chain formation, specifically photolysis of S2 and S3, pass sulfur having the opposite fractionation back to atomic S, and thence to other sulfur species, causing H2S, SO2, sulfate, and short-chain elemental sulfur to have positive Δ(exp 33)S and negative Δ(exp 33)S. Positive Δ(exp 33)S values in elemental sulfur produced in laboratory SO2 photolysis experiments could be caused by the initial fractionation during photolysis, combined with rapid condensation of short-chain sulfur species on the walls of the reaction chamber, along with a scarcity of back-reactions. The simulated fractionations produced by the chain formation mechanism do not directly match fractionations from the rock record. The mismatch might be explained if the isotopic signals leaving the atmosphere were significantly modulated by life, by uncertainties in the rates of reactions of both major and minor isotopic sulfur species, or by the relatively large potential range of atmospheric parameters. Further work is needed to better constrain these uncertainties, but this novel mechanism suggests new avenues to explore in our search for a explanation for the S-MIF record.

C. E. Harman↗

Simulation of Stochastic Mud-Crack Damage Formation in an Environmental Barrier Coating

The integrated Finite Element Analysis–Micromechanics Analysis Code/Ceramics Analysis and Reliability Evaluation of Structures (FEAMAC/CARES) program was used to simulate the formation of mudflat-cracks from thermomechanical loading on a multi-layered Environmental Barrier Coating (EBC) system deposited on a ceramic substrate. FEAMAC/CARES combines MAC/GMC multiscale composite micromechanics code with CARES/Life probabilistic multiaxial failure criteria code and Abaqusfinite element analysis. In this work, step function elastic modulus reduction of randomly damaged finite elements was used to represent discrete cracking events. The use of many small-sized low-aspect-ratio finite elements enabled the depiction of crack boundaries and formation of mudflat patterned damage. Demonstrated examples include finite element models of button–sized disk–shaped 3-D specimen, and a 2-D model of through-the-thickness cross-section. All models were subjected to a progressive cool down from 1300oC to room temperature. Mudflat crack damage in the coating system resulted from the buildup of residual tensile stresses between the individual material constituents from thermal expansion mismatch. A 2-parameter Weibull distribution characterized the coating layer stochastic strength response and the effect of the Weibull modulus on the formation of damage was studied here.

residual tensile stress↗

Physically Based and Stochastic Models for Greenland Moulin Formation, Longevity, and Spatial Distribution

Nearly all proglacial water discharge from the Greenland Ice Sheet is routed englacially, from the surface to the bed, via moulins. Identification of moulins in high-resolution imagery is a frequent topic of study, but the processes controlling how and where moulins form remain poorly understood. We seek to leverage information gained from the development of a physical model of moulin formation, remotely sensed ice-sheet data products, and an analytic model of ice-flow perturbations to develop a predictive stochastic model of moulin distribution across Greenland. Here we present initial results from the physical model of moulin formation and characterize the sensitivity of moulin geometry to a range of model parameters. This parameterization of moulin formation is the first step in developing a stochastic model that will be a predictive, computationally efficient representation of the englacial hydrologic system.

Andrews, Lauren C.↗

Using Chemcam Derived Geochemistry to Identify the Paleonet Sediment Transport Direction and Source Region Characteristics of the Stimson Formation in Gale Crater, Mars

The NASA Curiosity rover has encountered both ancient and modern dune deposits within Gale crater. The modern dunes are actively migrating across the surface within the Bagnold Dune field of which Curiosity conducted analysis campaigns at two different localities. Variations in mafic-felsic mineral abundances between these two sites have been related to the aeolian mineral sorting regime for basaltic environments identified on the Earth which become preferentially enriched in olivine relative to plagioclase feldspar with increasing distance from the source. This aeolian mineral sorting regime for basaltic minerals has also been inferred for Mars from orbital data. The aim of this study is to investigate whether this aeolian mafic-felsic mineral sorting trend has left a geochemical signature in the ancient dune deposits preserved within the Stimson formation. The Stimson formation unconformably overlies the Murray formation and consists of thickly laminated, cross-bedded sandstone. Stimson outcrops have a variable thickness up to 5 meters covering a total area of 17 square kilometers. A dry, aeolian origin was determined for this sandstone due to the high sphericity and roundness of the grains, uniform bimodal grain size distribution (250-710 microns), and 1-meter-thick cross-beds. Identifying the geochemical signature of mineral sorting can provide insights about the paleo-net sediment transport direction of the dunes and prevailing wind direction at the time of deposition.

Bedford, C. C.↗

Formation Mechanism of Iron-Rich Olivine: Experimental Constrains into Early Fluid-Assisted Hydration and Dehydration Processes on Asteroids

Iron-rich olivine is one of the major minerals in the matrices of unequilibrated ordinary (UOCs) and carbonaceous (CV, CK, CO) chondrites whose petrologic type is >3.1. There has been an extensive discussion in the literature as to the formation mechanism of these olivines; however, their origin is poorly understood. The formation of ferroan olivine during hydrothermal alteration has been demonstrated to be thermodynamically viable. The stability of ferroan olivine is highly dependent on several variables, including temperature, water/ rock (W/R) ratio, pressure, oxygen fugacity, and bulk rock composition. So far, hydrothermal alteration experiments have not been successful at forming FeO-rich olivines with the compositions and textures observed in the matrices of chondrites. Therefore, understanding the formation conditions of FeO-rich olivines remains a key problem to explain the effects of hydrothermal alteration on chondrite matrices.

Iron-rich olivine↗