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At least 1,369 records · Page 76

Validation of EDGDE2D-EIRENE predicted 2D distributions of electron temperature and density against divertor Thomson scattering measurements in the low-field side divertor leg in DIII-D

Comparisons of profiles of the electron temperature (T e ), density (n e ) and pressure (p e ) measured with Divertor Thomson Scattering in DIII-D low-confinement mode discharges to predictions from the edge fluid code EDGE2D-EIRENE show that the models implemented in EDGE2D-EIRENE predict the measurements within their collective uncertainties if the T e at the separatrix (T e,sep ) is 10 eV, or higher. The simulations do not predict, however, the peaked T e and ne profiles measured adjacent to the target plate when T e,sep , is below 10 eV, i.e., for the plasma downstream from the region of ionization of deuterium atoms. Inclusion of cross-field drifts and a five-fold reduction of radial transport cannot reconcile the discrepancy between the measurements and predictions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Advances in ultrafast gas-phase x-ray scattering

Recent developments of x-ray free electron lasers and pulsed electron sources have enabled ultrafast scattering to become an increasingly powerful tool for exploring molecular dynamics. Here, this article describes our recent experimental and methodological advances in ultrafast gas-phase x-ray scattering experiments at the LCLS. A re-designed short-pathlength windowless diffractometer is coupled with careful optimization of sample density and independent normalization of x-ray intensity fluctuations to provide gas-phase scattering patterns with exceptionally high signal-to-noise ratios. These advances, coupled with careful geometry optimization and data treatment, provide both ground- and excited-state signals in excellent agreement with high level ab initio total scattering patterns.

74 ATOMIC AND MOLECULAR PHYSICS↗

Inhibition of Reaction Layer Formation on MgO(100) by Doping with Trace Amounts of Iron

Despite extensive research on MgO’s reactivity in the presence of CO 2 under various conditions, little is known about whether impurities incorporated into the solid, such as iron, enhance or impede hydroxylation and carbonation reactions. The purity of the MgO required for the successful implementation of MgO looping as a direct air capture technology affects the deployment costs. With this motivation, we tested how incorporated iron impacts MgO (100) reactivity and passivation layer formation under ambient conditions by using atomic force microscopy, electron microscopy, and synchrotron-based X-ray scattering. Based on electron microprobe analysis, our MgO samples were 0.5 wt % iron, and Mössbauer spectroscopy results indicated that 70% of the iron is present as Fe(II). We find that even these low levels of iron dopants impeded both the hydroxylation at various relative humidities (10%, 33%, 75%, and >95%) and carbonation in CO 2 (33%, 75%, and >95%) on the (100) surface. Crystalline reaction products were formed. Reaction layers on the sample were easily removed by exposing the sample to deionized water for 2 min. Overall, our findings demonstrate that the presence of iron dopants slows the reaction rate of MgO, indicating that MgO without incorporated iron is preferable for mineral looping applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Monte Carlo simulation of electron acceleration in modified relativistic shocks

We give a brief review of Monte Carlo simulations of nonlinear Fermi shock acceleration and then give new results on electron acceleration in SNRs and in relativistic parallel shocks. The acceleration of low energy electrons in shocks is poorly understood, but even when energetic electrons are considered, where electron and proton scattering should be qualitatively similar, dramatic differences result between electron and proton acceleration in relativistic shocks. If the shocked plasma is a mixture of electrons and protons, the electrons are accelerated much less efficiently than protons. We predict that only e(-)-e(+) pair dominated plasmas can produce significant radio emission in relativistic flows if the standard Fermi mechanism operates in parallel shocks.

Ellison, Donald C.↗

Effects of Cryogenic Temperature on Fracture Toughness of Core-Shell Rubber (CSR) Toughened Epoxy Nanocomposites

This study investigated the effects of core-shell rubber (CSR) nanoparticles on the mechanical properties and fracture toughness of an epoxy resin at ambient and liquid nitrogen (LN2) temperatures. Varying amounts of Kane Ace MX130 toughening agent were added to a commercially available EPON 862/Epikure W epoxy resin. Elastic modulus was calculated using quasi-static tensile data. Fracture toughness was evaluated by the resulting breaking energy measured in Charpy impact tests conducted on an instrumented drop tower. The size and distribution of the CSR nanoparticles were characterized using Transmission Electron Microscopy (TEM) and Small Angle X-ray Scattering (SAXS). Scanning Electron Microscopy (SEM) was used to study the fracture surface morphology. The addition of the CSR nanoparticles increased the breaking energy with negligible change in elastic modulus and ultimate tensile stress (UTS). At ambient temperature the breaking energy increased with increasing additions of the CSR nanoparticles, while at LN2 temperatures, it reached a maximum at 5 wt% CSR concentration. KEY WORDS: liquid nitrogen (LN2) properties, fracture toughness, core-shell rubber (CSR).

Wang, J.↗

Effects of Core-Shell Rubber (CSR) Nanoparticles on the Cryogenic Fracture Toughness of CSR Modified Epoxy

This study investigated the effects of core-shell rubber (CSR) nanoparticles on the mechanical properties and fracture toughness of an epoxy resin at ambient and liquid nitrogen (LN2) temperatures. Varying amounts of Kane Ace(Registered TradeMark) MX130 and Kane Ace(Registered TradeMark) MX960 toughening agent were added to a commercially available EPON 862/Epikure W epoxy resin. Elastic modulus was calculated using quasi-static tensile data. Fracture toughness was evaluated by the resulting breaking energy measured in Charpy impact tests conducted on an instrumented drop tower. The size and distribution of the CSR nanoparticles were characterized using Transmission Electron Microscopy (TEM) and Small Angle X-ray Scattering (SAXS). Scanning Electron Microscopy (SEM) was used to study the fracture surface morphology. The addition of the CSR nanoparticles increased the breaking energy with negligible change in elastic modulus and ultimate tensile stress (UTS). At ambient temperature the breaking energy increased with increasing additions of the CSR nanoparticles up to 13.8wt%, while at LN2 temperatures, it reached a plateau at much lower CSR concentration.

Wang, Jun↗

3C 279 Multiwavelength Monitoring: The Ground-Based Campaign - 2

The optically violently variable quasar 3C 279 was monitored simultaneously from radio to gamma-ray frequencies in 1992 December - 1993 January. We report a detailed study of the ground-based results from radio to optical wavelengths. These data show that 3C 279 has a typical blazar spectrum, slightly rising at radio frequency and then progressively steeper above a first turnover frequency between 37 and 90 GHz. In the millimeter wavelength region, a simple power law is not an adequate description of the spectrum. We suggest that the millimeter "shoulder" corresponds to an additional emission component, self-absorbed between 150 and 375 GHz, possibly associated with the detachment of a new Very Long Base Interferometry (VLBI) knot and with the start of radio flare. A flux increase of 20% over 20 days was observed at 37 and 90 GHz, while contemporaneously the R-band flux doubled in about two weeks. The lack of strong variability in contemporaneous X-ray light curves (possible X-ray variations are less than 30%) implies no direct (i.e., zero lag) correlation between the optical and X-ray fluxes. If X-rays are produced by inverse-Compton scattering of relativistic electrons on some seed photons, the above results exclude that the observed optical photons are the seeds and/or that the relativistic electrons radiating via synchrotron in the optical band are responsible for the scattering to X-ray energies. We suggest that the X-rays are instead produced through the inverse-Compton process by electrons of lower energy, which radiate via synchrotron in the radio to millimeter wave bands and which scatter either on the synchrotron photons themselves or on external photons.

Grandi, P.↗

Toward a theory of interstellar turbulence. 2: Strong alfvenic turbulence

We continue to investigate the possibility that interstellar turbulence is caused by nonlinear interactions among shear Alfven waves. Here, we restrict attention to the symmetric case where the oppositely directed waves carry equal energy fluxes. This precludes application to the solar wind in which the outward flux significantly exceeds the ingoing one. All our detailed calculations are carried out for an incompressible magnetized fluid. In incompressible magnetohydrodynamics (MHD), nonlinear interactions only occur between oppositely direct waves. We present a theory for the strong turbulence of shear Alfven waves. It has the following main characteristics. (1) The inertial-stage energy spectrum exhibits a critical balance between linear wave periods and nonlinear turnover timescales. (2) The 'eddies' are elongated in the direction of the field on small spatial scales; the parallel and perpendicular components of the wave vector, k(sub z) and k(perpendicular) are related by k(sub z) approximately equals k(sub perpendicular to)(exp 2/3) L(exp -1/3), where L is the outer scale of the turbulence. (3) The 'one-dimensional' energy spectrum is proportional to k(sub perpendicular)(exp -5/3)-an anisotropic Kolmogorov energy spectrum. Shear Alfvenic turbulence mixes specific entropy as a passive contaminant. This gives rise to an electron density power spectrum whose form mimics the energy spectrum of the turbulence. Radio wave scattering by these electron density fluctuations produces anisotropic scatter-broadened images. Damping by ion-neutral collisions restricts Alfvenic turbulence to highly ionized regions of the interstellar medium.

Goldreich, P.↗

Vibrational excitation in CO by electron impact in the energy range 10-90 eV.

The ratio of the scattering intensity for the v double prime = 1 excitation to the elastic scattering intensity at 40- and 80-deg scattering angles has been determined for 10- to 90-eV impact energies for electron scattering by CO. These ratio curves exhibit broad peaks near 20-eV impact energy which cannot be accounted for by plane-wave calculations based on potential scattering models. The peaks are indicative of a resonant excitation process (or processes) in the v double prime = 1 channel in the range from 15 to 25 eV.

Chutjian, A.↗

Predicted diurnal variations of electron density for three high-latitude incoherent scatter radars

A high-latitude ionospheric model is used to predict the diurnal variations of electron density which should be observed by the EISCAT, Chatanika, and Millstone Hill incorporated scatter facilities. The calculations take into account a strong convection model without substorms. The provided electron density predictions should be used to obtain an indication of the quantitative differences in measured electron density that are to be expected when the three radars probe the high-latitude ionosphere simultaneously. These differences vary with altitude, latitude, local time, and season, and are associated with the UT dependence of the high-latitude ionosphere which results from the offset between the geomagnetic and geographic poles. It was found that the three facilities should observe the greatest difference in electron density variations in winter.

Sojka, J. J.↗

Real-space inversion and super-resolution of ultrafast scattering

Ultrafast scattering using x-rays or electrons is an emerging method to obtain structure dynamics at the atomic lengthscales and timescales. However, directly resolving in real-space atomic motions is inherently limited by the finite detector range and the probe energy. So, as a result, the time-resolved signal interpretation is mostly done in reciprocal space and relies on modeling and simulations of specific structures and processes. Here, we introduce a model-free approach to directly resolve scattering signals in real space, surpassing the diffraction limit, using scattering kernels and signal priors that naturally arise from the measurement constraints. We demonstrate the approach on simulated and experimental data, recover multiple atomic motions at sub-angstrom resolutions, and discuss the recovery accuracy and resolution limits versus signal fidelity. The approach offers a robust path to obtain high-resolution real-space information of atomic-scale structure dynamics using current time-resolved x-ray or electron scattering sources.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Single-ion properties of the transverse-field Ising model material CoNb 2 O 6

We report CoNb 2 O 6 is one of the few materials that is known to approximate the one-dimensional transverse-field Ising model (1D-TFIM) near its quantum critical point. It has been inferred that Co 2+ acts as a pseudospin 1/2 with anisotropic exchange interactions that are largely Ising-like, enabling the realization of the TFIM. However, the behavior of CoNb 2 O 6 is known to diverge from the ideal TFIM under transverse magnetic fields that are far from the quantum critical point, requiring the consideration of additional anisotropic, bond-dependent (Kitaev-like) terms in the microscopic pseudospin-1/2 Hamiltonian. These terms are expected to be controlled in part by single-ion physics, namely the wave function for the pseudospin-1/2 angular momentum doublet. Here, we present the results of both inelastic neutron scattering measurements and electron paramagnetic resonance spectroscopy on CoNb 2 O 6 , which elucidate the single-ion physics of Co 2+ in CoNb 2 O 6 for the first time. We find that the system is well-described by an intermediate spin-orbit coupled Hamiltonian, and the ground state is a well-isolated Kramers doublet with an anisotropic g tensor. We provide the approximate wave functions for this doublet, which we expect will be useful in theoretical investigations of the anisotropic exchange interactions.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Bursts of gamma rays from Compton scattering at cosmological distances

Compton scattering of the microwave background photons by beams of ultrarelativistic electrons at large redshifts, z much greater than 1, is proposed as a source of some gamma-ray bursts. Such beams may be produced by cusps on superconducting cosmic strings. In the present model, a very narrow beam of ultrarelativistic electron-positron pairs scatters the microwave background photons into a very narrow beam of gamma rays. While the pairs lose energy, the beam of gamma rays opens up and sweeps the observer. The expected time variability and spectra of the resulting gamma-ray burst are calculated. The bursts have a rapid rise time, followed by a more gradual decline. The spectra are initially very hard and become softer during the decline.

Zdziarski, Andrzej A.↗

Obtaining Electron Temperatures and Flow Speeds from Thomson Scattered Coronal Emission Observed during the 29 March 2006 Total Solar Eclipse in Libya

An experiment to measure the electron temperature and flow speed in the solar corona by observing the visible K-coronal spectrum was conducted during the total solar eclipse on 29 March 2006 in Libya. New corona1 models accounting for the effect of electron temperature and flow on the resulting K-corona spectrum were used to interpret the observations. Results show electron temperatures of 1.10 +/- 0.05, 0.98 +/- 0.12, and 0.70 +/- 0.08 MK, at l.l{\it R)$-{\odot)$ in the solar north, east and west, respectively, and 0.93 +/- 0.12 MK, at 1.2 R(sub sun) in the solar east. The corresponding outflow speeds obtained from the spectral fit are 103 +/- 92, 0 + 10, 0 + 10, and 0 + 10 km/s. Since the observations are taken only at 1.1 and 1.2 R(sub sun) these velocities , consistent with zero outflow, are in agreement with expectations and provide additional confirmation that the spectral fitting method is working.

Davila, Joseph M.↗

Exchange Forces in Dispersion Relations Investigated Using Circuit Relations

We propose a novel method to compute in an exact manner the left-hand cut discontinuity of the electron-Atom partial wave scattering amplitude in the complex energy plane within the static stage approximation. Zero energy dispersion relations for electron-Hydrogen scattering are computed numerically for illustration.

Vrinceanu, D.↗