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At least 1,369 records · Page 76

Refined Telluric Absorption Correction for Low-resolution Ground-based Spectroscopy: Resolution and Radial Velocity Effects in the O{sub 2}A-band for Exoplanets and K i Emission Lines

Telluric correction of spectroscopic observations is either performed via standard stars that are observed close in time and airmass along with the science target, or recently growing in importance, by theoretical telluric absorption modeling. Both approaches work fine when the telluric lines are resolved, i.e., at a spectral resolving power larger than about 10,000, and it is sufficient to facilitate the detection of spectral features at lower resolution. However, a meaningful quantitative analysis also requires the reliable recovery of line strengths. Here, we show for the Fraunhofer A-band of molecular O{sub 2} that the standard telluric correction approach fails in this at lower spectral resolutions, as an example for the general problem. Doppler-shift-dependent errors of the restored flux may arise, which can amount to more than 50% in extreme cases, depending on the line shapes of the target spectral features. Two applications are discussed: the recovery of the O{sub 2} band in the reflected light of an Earth analog atmosphere, as facilitated potentially in the future using an orbiting starshade and a ground-based extremely large telescope; and the recovery of the intrinsic ratio of the K i lines in the post-nova V4332 Sgr tracing the optical depth of the emitting region, to exemplify the relevance using present-day instrumentation. We show how one should derive correction functions for the compensation of the error in dependence of radial velocity shift, spectral resolution, and target line-profile function by use of high-resolution atmospheric transmission modeling, which has to be solved for the individual case.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Results of convective heating tests of a longitudinal gap on the Rockwell flat plate model (15-0, insert 7) in the NASA/Ames Research Center

Results are presented which were obtained from tests in a hypersonic wind tunnel to determine aerodynamic heating rates in a gap running parallel or slightly askew to the flow direction. The model used was a flat plate instrumented in thin-skin sections with chromelconstantan thermocouples. Heating rate profiles lengthwise along and down into the gap were obtained, and additional data were obtained from a total temperature probe and rake fabricated during the test to investigate an apparent aerodynamic cooling trend in the gap. Model variables were width, depth, length, and orientation of the gap relative to the flow direction. The tests were conducted at Mach 5.1 and Reynolds numbers per foot of 500,000, 1,000,000, and 2,000,000.

Quan, M.↗

Skylab program earth resources experiment package: Ground truth data for test sites (SL-2)

Field measurements were performed at selected ground sites in order to provide comparative calibration measurements of sensors for the Earth Resources Experiment Package. Specifically, the solar radiation (400 to 1300 namometers) and thermal radiation (8-14 micrometers) were measured. Sites employed for the thermal measurements consisted of warm and cold water lakes. The thermal brightness temperature of the lake water, the temperature and humidity profile above the lake, and near surface meteorology (wind speed, pressure, etc.) were measured near the time of overpass. Sites employed for the solar radiation measurements were two desert type sites. Ground measurements consisted of: (1) direct solar radiation - optical depth; (2) diffuse solar radiation; (3) total solar radiation, (4) target directional (normal) reflectance; (5) target hemispherical reflectance; and (6) near surface meteorology.

Source record↗

Vertical distribution of scattering hazes in Titan's upper atmosphere

Radial intensity scans of a Voyager 2 high phase angle image of Titan have been inverted to yield vertical extinction profiles at 1 deg intervals around the limb. A detached haze layer with peak particle number densities of about 0.2 cu/cm exists at all latitudes south of about 45 N, and at an altitude of 300-350 km. The optical depth 0.01 level lies at a radius of 2932 + or - 5 km at the equator and at a radius of 2915 + or - 10 km over the poles (altitudes of 357 + or - 5 and 340 + or - 10 km, respectively). In addition to the haze layer at 300-350 km, there is a small enhancement in the extinction at about 450 km which exists at all latitudes between 75 deg S and about 60 deg N.

Rages, K.↗

Iron K lines from low-mass X-ray binaries

Models are presented for the 6-7 keV iron line emission from low-mass X-ray binaries. A simplified model for an accretion disk corona is used to examine the dependence of the observable line properties, line width and mean energy, on the radial distance of the emission region from the X-ray source, and on the fraction of the X-rays from the source which reach the disk surface. The effects of blending of multiple line components and of Comptonization of the line profile are included in numerical calculations of the emitted profile shape. The results of these calculations, when compared with the line properties observed from several low-mass X-ray binaries, suggest that the broadening is dominated either by rotation or by Compton scattering through a greater optical depth than is expected from an accretion disk corona.

Kallman, T.↗

Initial Results from the Micro-pulse Lidar Network (MPL-Net)

The micro-pulse lidar system (MPL) was developed in the early 1990s and was the first small, eye-safe, and autonomous lidar built for full time monitoring of cloud and aerosol vertical distributions. In 2000, a new project using MPL systems was started at NASA Goddard Space Flight Center. This new project, the Micro-pulse Lidar Network or MPL-Net, was created to provide long-term observations of aerosol and cloud vertical profiles at key sites around the world. This is accomplished using both NASA operated sites and partnerships with other organizations owning MPL systems. The MPL-Net sites are co-located with NASA AERONET sunphotometers to provide aerosol optical depth data needed for calibration of the MPL. In addition to the long-term sites, MPL-Net provides lidar support for a limited number of field experiments and ocean cruises each year. We will present an overview of the MPL-Net project and show initial results from the first two MPL-Net sites at the South Pole and at Goddard Space Flight Center. Observations of dust layers transported from the Gobi desert, across the Pacific Ocean, to the east coast of the United States will also be shown. MPL-Net affiliated instruments were in place at the desert source region in China, on a research vessel in the Sea of Japan, at ARM sites in Alaska and Oklahoma, and finally at our home site in Maryland (GSFC) during the massive dust storms that occurred in April 2001. The MPL observations of dust layers at each location are shown in comparison to dust layers predicted using the Georgia Tech/Goddard Global Ozone Chemistry Aerosol Radiation and Transport model (GOCART). Finally, the MPL-Net project is the primary ground-validation program for the Geo-Science Laser Altimeter System (GLAS) satellite lidar project (launch date 2002). We will present an overview demonstrating how MPL-Net results are used to help prepare the GLAS data processing algorithms and assist in the calibration/validation of the GLAS data products.

Welton, Ellsworth J.↗

Thermal transport across nanoscale damage profile in sapphire irradiated by swift heavy ions

In this work, we studied the degradation of thermal conductivity in single crystal sapphire (α-Al 2 O 3 ) irradiated by 167 MeV Xe swift heavy ions (SHIs) over the multiple fluences in the range of 10 12 –10 14 ions/cm 2 . Thermal conductivity was measured primarily in the cross-plane direction using a noncontact ultrafast optical pump-probe technique called picosecond time domain thermoreflectance (TDTR). Multiple samples with variable ion fluences allowed us to probe distinct regions resulting from different regimes of microstructure evolution caused by electronic energy loss. By tuning the penetration depth of the thermal waves using different modulation frequencies, two regions with distinct conductivities were identified and the values of which were found to be consistent with phonon-mediated thermal transport models while the microstructure was confirmed by electron microscopy characterization. These damaged regions were determined to be a several micrometer thick ion track region and several tens of nanometer-thick amorphous layer present only above 5.0 × 10 13 ions/cm 2 . These results demonstrate the applicability of TDTR to resolve thermal transport behavior in SHI irradiated oxides having nonhomogeneous damage profile on a nanometer scale. The presented approach facilitates future studies aiming at resolving the impact of distinct damage resulting from electronic and nuclear stopping regimes under irradiation.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Planetary Boundary-Layer Height (PBLHT) Value-Added Product: Remote-Sensing Retrievals

The planetary boundary layer (PBL) is fundamental to numerous atmospheric processes, including aerosol mixing and transport, cloud evolution, and precipitation formation. A critical parameter in these studies is the PBL height (PBLHT). This vertical depth is essential for characterizing PBL structures in numerical simulations and serves as a primary metric for estimating flux exchanges between the Earth’s surface and the atmosphere. Radiosonde (SONDE) observations provide high-vertical-resolution measurements of temperature and moisture profiles and are widely used to estimate PBLHT (Liu and Liang 2010, Seidel et al. 2010). The U.S. Department of Energy Atmospheric Radiation Measurement (ARM) User Facility’s PBLHT value-added product (VAP) for radiosonde measurements, known as PBLHTSONDE, applies three commonly used methods—the Heffter (1980) method, the Liu and Liang (2010) method, and the bulk Richardson number approach (Seibert et al. 2000)—to derive PBLHT. The PBLHTSONDE VAP operates routinely at ARM observatories and mobile facilities, with data available from the ARM Data Center shortly after sounding observations are collected (Sivaraman et al. 2013). However, radiosonde observations are limited by their low temporal resolution. Most stations launch soundings only twice daily, which constrains the ability to investigate and characterize the temporal evolution of the PBL using radiosonde data alone. The use of continuous remote-sensing observations provides high temporal resolution of PBLHT estimates. These observations include aerosol lidars (Dang et al. 2019, Su et al. 2020), Doppler lidar (DL; Tucker et al. 2009, Krishnamurthy et al. 2021), and water vapor and/or temperature lidars and radiometers (Turner et al. 2014). These observations provide valuable data on the PBL’s thermodynamic properties (e.g., water vapor and/or temperature lidars and radiometers), dynamic properties (e.g., DL), and distribution of tracer substances (e.g., aerosol lidars), all of which can be used to estimate PBLHT. ARM developed PBLHT estimates from the micropulse lidar (MPL; PBLHTMPL), Doppler lidar (PBLHTDL), and combined Raman lidar (RL)/atmospheric emitted radiance interferometer (AERI) thermodynamic profiles (PBLHTTHERMO). Each estimate captures different physical characteristics of the boundary layer—aerosol tracers, vertical velocity turbulence, and thermodynamic structure—and exhibits distinct strengths and limitations depending on the PBL regime and time of day. In addition, the ARM ceilometer (CEIL) provides three potential PBLHT candidates derived from the vendor's built-in algorithm. Building on these individual retrievals, ARM developed the PBLHTBEML VAP, which combines the four remote-sensing-based estimates with ancillary meteorological variables using the machine learning approach of Zhang et al. (2025) to produce a best-estimate PBLHT at 10-minute resolution.

54 ENVIRONMENTAL SCIENCES↗

Improving the estimate of higher-order moments from lidar observations near the top of the convective boundary layer

Abstract. Ground-based lidar data have proven extremely useful for profiling the convective boundary layer (CBL). Many groups have derived higher-order moments (e.g., variance, skewness, fluxes) from high-temporal-resolution lidar data using an autocovariance approach. However, these analyses are highly uncertain near the CBL top when the depth of the CBL (zi) is changing during the analysis period. This is because the autocovariance approach is usually applied to constant height levels and the character of the eddies is changing on either side of the changing CBL top. Here, a new approach is presented wherein the autocovariance analysis is performed on a normalized height grid, with a temporally smoothed zi. Output from a large eddy simulation model demonstrates that deriving higher-order moments from time series on a normalized height grid has better agreement with the slab-averaged quantities than the moments derived from the original height grid.

Rosenberger, Tessa E. (ORCID:0000000333205873)↗

A comparison of radiative transfer models for predicting the microwave emission from soils

Noncoherent and coherent numerical models for predicting emission from soils are compared. Coherent models use the boundary conditions on the electric fields across the layer boundaries to calculate the radiation intensity, and noncoherent models consider radiation intensities directly. Interference may cause different results in the two approaches when coupling between soil layers in coherent models causes greater soil moisture sampling depths. Calculations performed at frequencies of 1.4 and 19.4 GHz show little difference between the models at 19.4 GHz, although differences are apparent at the lower frequency. A definition for an effective emissivity is also given for when a nonuniform temperature profile is present, and measurements made from a tower show good agreement with calculations from the coherent model.

Schmugge, T. J.↗

Lidar analysis techniques for use in the atmospheric boundary layer

There is a growing body of observational and theoretical evidence which suggests that local climate characteristics are associated with variations in the earth's surface. The link between surface variability and local-scale processes must be made if we are to improve our understanding of the feedback mechanisms involved in surface-atmosphere dynamics. However, to understand these interactions, the surface-atmosphere interface must be studied as a large-scale spatial system. Lidars are ideal tools to study the spatial properties of the atmosphere. The described techniques were developed for use with the Los Alamos Water Raman-Lidar, but are applicable to many other types of lidar. The methodology of the analysis of lidar data is summarized in order to determine meteorological parameters in the atmospheric boundary layer. The techniques are not exhaustive but are intended to show the depth and breadth of the information which can be obtained from lidars. Two methods for the computation of water-vapor fluxes were developed. The first uses the fact that the water vapor concentration in the vertical direction follows a logarithmic profile when corrected for atmospheric stability. The second method involves using inertial dissipation techniques in which lidar-derived spatial and temporal power spectra are used to determine the flux.

Eichinger, William E.↗

Over-Luminous Elliptical Galaxies

We have completed a first draft of a paper on the galaxy group ES03060170, the hottest known fossil group. We have submitted a first draft of the paper but the final completion is delayed due to several issues mentioned by the referee that we wish to revisit and discuss in more detail. The XMM data was combined with Chandra data which allowed a rich set of projects. The paper discusses the north-south elongation which is similar to that of the central dominant galaxy as well as the galaxy distribution. We detect an X-ray "finger" or small tail emanating from the central galaxy to the north, suggesting motion of the galaxy within the elongated gravitational potential. The overall agreement between XMM and Chandra data are excellent (although the XMM data extend to larger radii). Both data sets show a cool core centered on the dominant galaxy. Surprisingly, the temperature maps and detailed spectra indicate that the finger of gas is NOT cool, but has the same temperature as the ambient gas. We extracted surface brightness profiles, deprojected gas density profiles, cooling time profiles, and entropy profiles. There is a sharp discontinuity in gas temperature where the surface brightness profile starts to rise rapidly at 10 kpc. This produces a decrease in the cooling time and the gas entropy within 10 kpc. The central cooling time (within 10 kpc) is less than l0(exp 9) years and falls to almost half that value in the inner 5 kpc. Despite the very short cooling time, we find no evidence (even with the excellent statistics from XMM-Newton) for multi-phased gas, i.e., a cooling flow. We find two "edges" associated with the gas distribution (common in peaked X-ray groups and galaxies). On large scales, the temperature profile is flat and disagrees with the profile predicted by Loken et al. (2003) from detailed numerical simulations. We studied the galaxy distribution within one virial radius. The galaxy concentration associated with the group is detectable only within 0.3 of the virial radius (450 kpc) given the available depth of the optical galaxy catalogs at present. We have derived total mass and gas mass distributions (from the X- ray data) and find the gas fraction approaches a constant 8% (for Ho = 70).

Mushotzky, Richard↗

Over-Luminous Elliptical Galaxies

We have completed a first draft of a paper on the galaxy group ESO3060170, the hottest known fossil group. We have submitted a first draft of the paper but the final completion is delayed due to several issues mentioned by the referee that we wish to revisit and discuss in more detail. The XMM data was combined with Chandra data which allowed a rich set of projects. The paper discusses the north-south elongation which is similar to that of the central dominant galaxy as well as the galaxy distribution. We detect an X-ray 'finger' or small tail emanating from the central galaxy to the north, suggesting motion of the galaxy within the elongated gravitational potential. The overall agreement between XMM and Chandra data are excellent (although the XMM data extend to larger radii). Both data sets show a cool core centered on the dominant galaxy. Surprisingly, - the temperature maps and detailed spectra indicate that the finger of gas is NOT cool, but has the same temperature as the ambient gas. We extracted surface brightness profiles, deprojected gas density profiles, cooling time profiles, and entropy profiles. There is a sharp discontinuity in gas temperature where the surface brightness profile starts to rise rapidly at 10 kpc. This produces a decrease in the cooling time and the gas entropy within 10 kpc. The central cooling time (within 10 kpc) is less than 109 years and falls to almost half that value in the inner 5 kpc. Despite the very short cooling time, we find no evidence (even with the excellent statistics from XMM-Newton) for multi-phased gas, i.e., a cooling flow. We find two 'edges' associated with the gas distribution (common in peaked X-ray groups and galaxies). On large scales, the temperature profile is flat and disagrees with the profile predicted by Loken et al. (2003) from detailed numerical simulations. We studied the galaxy distribution within one virial radius. The galaxy concentration associated with the group is detectable only within 0.3 of the virial radius (450 kpc) given the available depth of the optical galaxy catalogs at present. We have derived total mass and gas mass distributions (from the X-ray data) and find the gas fraction approaches a constant 8% (for H0 = 70).

Mushotsky, Richard↗

Thermal Protection System P50 Cork Environments and Response due to Radiative Heating

Space Launch System (SLS) experienced deflagration of the acreage of the Core Stage base heat shield during the Green Run hot-fire test campaigns and Artemis I flight. The burning products from the base heat shield during Green Run hot-fire test operation led to concerns in aerothermal environments and thermal protection system (TPS) performance prior to Artemis I flight. This work documents a highly controlled ground test within the NASA Marshall Space Flight Center’s Nonmetallic Materials Branch thermal vacuum chamber (TVC) and investigates the P50 cork heat transfer environments and thermal protection system (TPS) response due to sensitivity changes in radiative heat rates, ambient pressure, air entrainment mass flow rates, test gas and TPS sample types. An SLS ascent ambient pressure profile was also simulated within the TVC facility. This test data enabled the efforts toward the Artemis I SLS post-flight reconstruction and initial assessment of flight TPS performance. A ground test program was developed to gain an in-depth understanding of the cork combustion dynamics and TPS response due to the SLS launch vehicle flight ascent environments.

thermal protection system↗

Surface Inspection Tool for Optical Detection of Surface Defects

The Space Shuttle Orbiter windows were damaged both by micrometeor impacts and by handling, and required careful inspection before they could be reused. The launch commit criteria required that no defect be deeper than a critical depth. The shuttle program used a refocus microscope to perform a quick pass/fail determination, and then followed up with mold impressions to better quantify any defect. However, the refocus microscope is slow and tedious to use due to its limited field of view, only focusing on one small area of glass at a time. Additionally, the unit is bulky and unable to be used in areas with tight access, such as defects near the window frame or on the glass inside the Orbiter due to interference with the dashboard. The surface inspection tool is a low-profile handheld instrument that provides two digital video images on a computer for monitoring surface defects. The first image is a wide-angle view to assist the user in locating defects. The second provides an enlarged view of a defect centered in the window of the first image. The focus is adjustable for each of the images. However, the enlarged view was designed to have a focal plane with a short depth. This allows the user to get a feel for the depth of different parts of the defect under inspection as the focus control is varied. A light source is also provided to illuminate the defect, precluding the need for separate lighting tools. The software provides many controls to adjust image quality, along with the ability to zoom digitally the images and to capture and store them for later processing.

Nurge, Mark↗

Ma'adim Vallis Estuarine Delta in Elysium Basin and Its Relevance as a Landing Site for Exobiology Exploration on Mars

The debouche of Ma'adim Vallis in the Elysium Basin generated a transitional transported sediment structure, which planimetric shape is controlled by the enclosing topography of a deep reentrant gulf of the Basin into the highland. We defined it as an estuarine delta. The location and the importance of this estuarine delta is supported by the theoretical model of graded profile constructed for Ma'adim Vallis, and by two approaches: (i) the reconstruction of Ma'adim Vallis downstream course from Gusev to Elysium Basin, and (ii) the survey of the sediment deposit in the alleged estuary. The longitudinal graded profile of Ma'adim Vallis finds its base-level in the Elysium Basin, at a about 1000 m elevation, which is in agreement with the observed Basin shoreline. This model is supported by observational evidence of flow between the northern rim of Gusev crater, and the Elysium Basin shoreline. This downstream course of Ma'adim Vallis can be divided into three hydrogeologic regions. into three hydrogeologic regions. (a) The first region is a flooded plain (Zephiria Mensae), consisting in chaotic terrain formed by highland rocks, and disintegrated lava of the western flank of Apollinaris. Morphologic indicators of the flood process are: (1) the sediment deposit over the Gusev crater northern rim that reflects the overspilling of the crater-lake water through a 40-km wide gap provided by an ancient impact crater, (2) the tear-drop shaped feature on the northeastern flank of Apollinaris Patera, and (3) the chaotic terrain that suggest the emergence of ground water generated by the seepage of the crater lake through high-permeable broken rampart material. This underground water circulation sustained by the hydrostatic pressure of the crater-lake has likely generated a hydrothermal system in the volcanic environment of Apollinaris Patera. The stratigraphy of the flooded area is identified as Hesperian age, with occurrences of Noachian hilly individual features, and as Amazonian flooded plain and chaotic material, (b) The second region is located on the western flank of Apollinaris Patera. It is surrounded by relics of deep valleys that suggest a former downstream course of Ma'adim Vallis. The geologic setting of this region (Lucus Planum) is interpreted to be an Amazonian formation composed by the middle and lower members of the Medusae Formation., c) The third region corresponds to the convergence of the west and east branches of Ma'adirn Vallis into a deep re-entrant wide gulf that penetrates about 100 km into the highland. This topographic depression is delineated by the 1000 in elevation contour. This gulf has formed an estuarine configuration centered at 3S/190W within the Elysium Basin. This configuration has favored the formation of a estuarine sedimentary delta, because of topographically controlled lateral migration. This estuarine structure is strongly dominated by the incoming supply of Ma'adim Vallis fluvial sediment extracted from Zephiria Mensae and Lucus Planum. The obtuse-angle geometry of the estuary increases the sedimentation rate, which is higher than in the course of the channel. The sediment deposition process is governed by the estuarine water circulation. The inflowing loaded fluvial water enters the estuary as a bottom current, and mixes with the relatively less-loaded water of the receiving basin. When they mixed. the inflowing fluvial material, and the landward basin circulating water generate an accumulation of highly-diversified estuarine deposit stratification. This accumulation of material is mostly centered in the transitional zone of the delta. The sediment trapping efficiency of the estuary is function of the energy balance between the inflowing fluvial water, and the ingoing basin current. The submergence of the delta by the rising of the water-level increases the estuary water-depth, and consequently the sediment entrapment is favored. The locus of sediment accumulation moves landward in the zone of inflowing fluvial water. This results in the rising of the channel base-level, thus in the increase of the length of the longitudinal graded-profile. The sediment deposit facies of the zone A shows a generally smooth surface. The longitudinal deposit is bordered by alluvial terraces that reflect the variations of the channel level. The waning of the Elysium Basin caused the erosion of the Basin estuarine zone by small channels, this episode being characterized by dissected tear-drop shaped mesa-like morphologies in the delta. Our estuarine delta model predicts a lithostratigraphic depositional sequence associated with the water submergence and the transgression of Elysium Basin. The thickness of the estuarine sediment corresponds to the Elysium Basin levels changes relatively to the bed floor of the estuary, The depositional sequence of Ma'adim Vallis are described: (1) a pro-current filled region (A), where fluvial are longitudinally accumulated by the inflowing water, (2) inverse current from Elysium Basin (B), where fluvial and lacustrine sediments are accumulated, and (3) zone of current equilibrium (C), where the sediments are distributed as a shoreline at the boundary of the estuarine delta. The estuary sedimentology dynamics collects and keeps the record of the geologic unit material crossed by Ma'adim Vallis, and those of the lakebed deposit of Elysium Basin. The predicted mixed stratigraphic sequence from fluvial and lacustrine sediment makes this site an exceptional environment to concentrate potential multi-origin biologic records. We envision four possible strategies to explore this sedimentologic record: (1) longitudinal surface and subsurface traverses in region A to investigate outcrop levees, (2) exploration of the mesa walls in region B, (3) deep drilling hole lodging of the sequential deposits in the zones A and B, and (4) surface and subsurface exploration of the shoreline delta. The expected results for each of these strategies are: (1) in the deepest layers of region A are predicted frequent and abundant coarse material, sandy lenses lamination grading downward from sand to cobbles. Volcanic debris from the Noachian crustal Plateau unit material, hydrothermal altered rocks, carbonates, Hesperian and possibly Amazonian volcanic material, from Apollinaris Patera, altered rocks and carbonates from Zephiria Mensae are expected. As a favorable environment for inception of life, possible biological records are expected in transported rock, (2) At the surface, and subsurface (<=100 m), large deposits sandy to silted material from Elysium paleolake basin mixed with fine-grained sediments from Ma'adim Vallis are expected mostly in the upstream part of region B, (3) on the shoreline of the estuarine delta, abundant fine material from Elysium paleolake basin (evaporites, carbonates), mostly Amazonian in age are expected. The Ma'adini estuary is a favorable landing site for all the above mentioned science aspects, and .for its location. The site lies near the equator, which is favorable for the rover solar power supply, and at 1000m elevation, which is a favorable configuration for the descent system braking. Another advantage is the extent of the area of high scientific interest (33,000 sq km), which provides a good ellipse, and potential long study traverses.

Grin, E. A.↗

Pinatubo and Pre-Pinatubo Optical-Depth Spectra: Mauna Loa Measurements, Comparisons, Inferred Particle Size Distributions, Radiative Effects, and Relationship to Lidar Data

The Ames airborne tracking sunphotometer was operated at the National Oceanic and Atmospheric Administration (NOAA) Mauna Loa Observatory (MLO) in 1991 and 1992 along with the NOAA Climate Monitoring and Diagnostics Laboratory (CMDL) automated tracking sunphotometer and lidar. June 1991 measurements provided calibrations, optical-depth spectra, and intercomparisons under relatively clean conditions; later measurements provided spectra and comparisons for the Pinatubo cloud plus calibration checks. June 1991 results are similar to previous MLO springtime measurements, with midvisible particle optical depth tau(sub p)(lambda = 0.526 microns) at the near-background level of 0.012 +/- 0.006 and no significant wavelength dependence in the measured range (lambda = 0.38 to 1.06 microns). The arrival of the Pinatubo cloud in July 1991 increased midvisible particle optical depth by more than an order of magnitude and changed the spectral shape of tau(sub p)(lambda) to an approximate power law with an exponent of about -1.4. By early September 1991, the spectrum was broadly peaked near 0.5 microns, and by July 1992, it was peaked near 0.8 microns. Our optical-depth spectra include corrections for diffuse light which increase postvolcanic midvisible tau(sub p) values by 1 to 3% (i.e., 0.0015 to 0.0023). NOAA- and Ames Research Center (ARC)-measured spectra are in good agreement. Columnar size distributions inverted from the spectra show that the initial (July 1991) post-Pinatubo cloud was relatively rich in small particles (r less than 0.25 microns), which were progressively depleted in the August-September 1991 and July 1992 periods. Conversely, both of the later periods had more of the optically efficient medium-sized particles (0.25 less than r less than 1 micron) than did the fresh July 1991 cloud. These changes are consistent with particle growth by condensation and coagulation. The effective, or area-weighted, radius increased from 0.22 +/- 0.06 micron in July 1991 to 0.56 +/- 0.12 micron in August-September 1991 and to 0.86 +/- 0.29 micron in July 1992. Corresponding column mass values were 4.8 +/- 0.7, 9.1 +/- 2.7, and 5.5 +/- 2 micro g/sq cm, and corresponding column surface areas were 4.4 +/- 0.5, 2.9 +/- 0.2, and 1.1 +/- 0.1 sq micron/sq cm,. Photometer-inferred column backscatter values agree with those measured by the CMDL lidar on nearby nights. Combining lidar-measured backscatter profiles with photometer-derived backscatter-to-area ratios gives peak particle areas that could cause rapid heterogeneous loss of ozone, given sufficiently low particle acidity and suitable solar zenith angles (achieved at mid- to high latitudes). Top-of-troposphere radiative forcings for the September 1991 and July 1992 optical depths and size distributions over MLO are about -5 and -3 W 1/sq m, respectively (hence comparable in magnitude but opposite in sign to the radiative forcing caused by the increase in manmade greenhouse gases since the industrial revolution). Heating rates in Pinatubo layer over MLO are 0.55 +/- 0.13 and 0.41 +/- 0.14 K/d for September 1991 and July 1992, respectively.

Russell, P. B.↗

Oxidation Behavior of Candidate NiCr Alloys for Engine Exhaust Valves: Part I—Effect of Minor Alloying Elements

Oxidation-induced degradation of structural materials employed as exhaust valves within internal combustion engines (ICEs) will be a relevant life-limiting mechanism, in addition to creep and mechanical fatigue, due to ever-increasing severity of operating temperatures and pressures. Ni–Cr-based alloys, which form external chromia-based scales at the relevant operating temperatures are being considered as suitable candidate materials. Thermal cycling of these alloys in water vapor-containing atmospheres, such as those present during hydrocarbon fuel combustion within ICEs, can considerably influence their oxidation behavior. Here, the role of typical alloying additions such as Mn, Si, Al and Ti on the cyclic oxidation behavior of model NiCr–X (X = Mn,Si,Al,Ti) alloys exposed in dry air and air + 10% H 2 O at 800°C and 950°C was investigated. Combined additions of Mn and Si reduced scaling rates compared to binary Ni–22Cr alloys. The presence of water vapor possibly suppressed formation of NiMnCr spinel and thereby the Cr depletion in the alloy. Combined Al and Ti additions mainly resulted in accelerated oxidation kinetics due to the Ti doping of chromia scales. More porous external scales were observed in water vapor leading to a much deeper depth of nitridation in the Ni–22Cr–Al–Ti alloys.

36 MATERIALS SCIENCE↗