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At least 1,369 records · Page 76

Hydrogen atom abstraction from aldehydes - OH + H2CO and O + H2CO

The essential features of the potential energy surfaces governing hydrogen abstraction from formaldehyde by oxygen atom and hydroxyl radical have been characterized with ab inito multiconfiguration Hartree-Fock (MCHF) and configuration interaction (CI) wave functions. The results are consistent with a very small activation energy for the OH + H2CO reaction, and an activation energy of a few kcal/mol for the O + H2CO reaction. In the transition state structure of both systems, the attacking oxygen atom is nearly collinear with the attacked CH bond.

Dupuis, M.↗

Oscillator strengths and collision strengths for S III

The present calculation, in a close-coupled approximation for the energy range up to 1,000,000 K, yields collision strengths for the electron impact excitation of S III from the ground 3p2 3P state to the excited states 3s3p3 3D0, 3P0, 3S0, 3d 3D0, 3P0, and 4s 3P0. Also obtained are those transitions' oscillator strengths, and strengths for others involving 3p2 1D and 1S. Configuration-interaction target wave functions yielding oscillator strengths that are accurate to 20 percent are used in collision strength calculations.

Ho, Y. K.↗

Observations of the magnetospheric boundary layers

Results on magnetospheric boundary layers are reviewed, emphasizing their dynamical importance based on hot plasma observations, energetic particle signatures, heavy ion contributions and the effects of wave-particle interactions. Satellite plasma observations show that 1% to 2% of the oncoming solar wind plasma enters the magnetosphere and is initially transported within the magnetospheric boundary layer. Some of this boundary layer plasma is entrained within the Earth's magnetotail where it can be accelerated. Tests are needed to determine the relative contributions of the primary acceleration processes whose effects are especially evident in the plasma sheet boundary layer.

Eastman, T. E.↗

Recoverable Plasma Diagnostics Package (RPDP)

The recoverable plasma diagnostics package (RPDP) is an ejectable and recoverable satellite with flight and ground support systems so that it can be utilized in three modes: attached to an remote manipulator system; tethered; or as a subsatellite. The satellite is well instrumented with particle and field diagnostic as well as optical sensors to: investigate the dynamics of the natural environment or ejected perturbations from particle beams; measure the characteristics and propagation of electrostatic and electromagnetic waves; study wave particle interactions; and study natural properties of the magnetosphere, ionosphere, and upper atmosphere.

Roberts, W. T.↗

The galaxy as a self-regulated star-forming system - The case of the OB associations

It is proposed that the energy and momentum injected from OB associations can act as the regulators of high-mass star formation throughout the disk of a spiral galaxy. The mechanism, interacting blast waves driven by supernovae and stellar winds, leads to a generalized Schmidt law for the star formation rate and could explain in a natural way the galactic gradients of metals and star formation rate. The formation of massive stars is determined by the average ambient density in the disk while low-mass star formation is regulated by the density in molecular clouds. That is, there are two modes of star formation, but the physical mechanism is the same in both cases.

Franco, J.↗

Voyager observations of ion phase space densities in the Jovian magnetosphere

Data from the Voyager low-energy charged particle experiment (LECP) were used to calculate ion phase space densities in Jupiter's magnetosphere. The calculation of F at constant mu and J(2) requires the determination of particle fluxes at specific pitch angles and energies. It is shown that the greatest uncertainties in the determination of F from LECP data arise from the fits to the measured pitch angle distributions and differential energy spectra. An estimate is provided of this uncertainty and of others arising from model radial diffusion coefficients and magnetic fields. The general nature of the curves is consistent with inward diffusion of these energetic ions from the outer magnetosphere combined with losses near but starting beyond the orbit of Io. These losses are not consistent with simple satellite sweeping by Io alone and are probably due to an Io-torus wave-particle interaction. The lifetime against loss deduced from the data is approximately 20,000 s near Io and is a value consistent with strong diffusion losses. The measured ion loss rate declines much more rapidly than the strong diffusion loss rate as L increases from 7 to 9, suggesting that the loss rate is well below the strong-diffusion rate beyond 7 Jupiter radii for ions observed by the LECP.

Paonessa, M.↗

Recombination-cascade X-ray spectra of highly charged helium-like ions

It is shown that the relative intensity distribution among the X-ray spectral lines of helium-like ions from the n = 2 states produced through recombination processes such as radiative and charge transfer recombination may be given by considering in detail the radiative cascades following recombination. Model calculations are presented with predicted line ratios for Ar XVII and Fe XXV in recombination-dominated noncoronal plasmas. In particular, compared to coronal intensities, the singlet resonance line (w) should be much weaker relative to the triplet intercombination (x, y) and forbidden (z) lines, yielding large values for the ratio G = (x + y + z)/w. Accurate configuration interaction type wave functions are employed to calculate the eigenenergies, transition probabilities, and cascade coefficients. Certain relevant tokamak and astrophysical observations are discussed.

Pradhan, A. K.↗

On the use of wall functions as boundary conditions for two-dimensional separated compressible flows

A new and improved wall function method for compressible turbulent flows has been developed and tested. This method is applicable to attached and separated flows, to both high- and low-Reynolds number flows, and to flows with adiabatic and nonadiabatic surfaces. This wall function method has been applied to the Launder-Spalding k-epsilon two-equation model of turbulence. The tests consist of comparisons of calculated and experimental results for: (1) an axisymmetrical transonic shock-wave/boundary-wave interaction flow at low Reynolds number in an adiabatic tube, (2) an axisymmetrical high-Reynolds number transonic flow over a nonadiabatic bump, and (3) a two-dimensional supersonic high-Reynolds number flow on a nonadiabatic deflected flap. Each of these experiments had significant regions of flow separation. The calculations are performed with an implicit algorithm that solves the Reynolds-averaged Navier-Stokes equations. It is shown that the results obtained agree very well with the data for the complex compressible flows tested.

Viegas, J. R.↗

Rocket measurements of mesospheric ionization irregularities

The Langmuir-probe technique for measurement of electron concentration in the mesosphere is capable of excellent altitude resolution, of order 1 m. Measurements from nine rocket flights frequently show small-scale ionization structures in the altitude region 60-90 km. These are believed to be identical with regions of strong coherent backscatter seen by VHF radars at Jicamarca, Peru and Urbana, Illinois. They are believed to represent intermittent turbulence attributable to nonlinear interaction of waves in the mesosphere. Parameters of the turbulent regions are estimated.

Stoltzfus, R. B.↗

DE 1 observations of Siple transmitter signals and associated sidebands

Initial results from an active wave injection experiment aimed at studying coherent VLF wave propagation and wave-particle interactions in the magnetosphere are presented. The VLF signals were injected from a transmitting facility at Siple Station, Antarctica, and were received on the high-altitude, polar-orbiting Dynamics Explorer 1 satellite. Data received by the satellite are described and measurements of the propagation delay, signal amplitude, and in situ electron densities are discussed. Ray propagation paths to the satellite for two days are discussed, and sidebands associated with Siple signals observed on one of the days are presented.

Rastani, K.↗

Simulation study of Type 2 counterstreaming electrons along auroral field lines

The production of counterstreaming electrons associated with parallel fields along auroral field lines is examined through the use of computer simulation. A 2 1/2-dimensional (two spatial and three velocity dimensions) electrostatic particle algorithm and auroral boundary conditions are used to set up a self-consistent V potential structure. The simulation produces signatures of counterstreaming electrons resembling those observed by the Dynamics Explorer 1 satellite. The main signatures are as follows: (1) the phase space contours of the electron distribution function are elongated along the V-parallel axis, and (2) the energy of electrons streaming in the upward direction is comparable to the energy of the accelerated electron beam. The simulation indicates that a portion of the accelerated electron beam is trapped by large amplitude electrostatic waves produced through the two-stream instability. Strong wave-particle interactions then thermalize the trapped electrons to produce suprathermal electrons streaming in the direction opposite to that of the accelerated electron beam. These results suggest a possible mechanism of producing counterstreaming electron fluxes through nonlinear processes of the two-stream instability.

Wagner, J. S.↗

A parabolized Navier-Stokes algorithm for separated supersonic internal flows

A stable global-iteration procedure is applied to a fully implicit noniterative parabolized Navier-Stokes algorithm to improve the solutions of the single-sweep method as well as to resolve small separation bubbles due to shock-wave/boundary-layer interactions. A modified form of the FLARE approximation is employed in the separated regions and some requirements for stable iterations are discussed. The results of the global-iteration scheme for two test cases of supersonic internal flows are compared against the results of the single-sweep method as well as the results of the full Navier-Stokes solver.

Chitsomboon, T.↗

Recoverable Plasma Diagnostics Package (RPDP)

The recoverable plasma diagnostics package (RPDP) is an ejectable and recoverable satellite with flight and ground support systems so that it can be utilized in three modes: attached to an remote manipulator system; tethered; or as a subsatellite. The satellite is well instrumented with particle and field diagnostic as well as optical sensors to: investigate the dynamics of the natural environment or ejected perturbations from particle beams; measure the characteristics and propagation of electrostatic and electromagnetic waves; study wave particle interactions; and study natural properties of the magnetosphere, ionosphere, and upper atmosphere.

Roberts, B.↗

Soliton turbulence

Theoretical and numerical works in atmospheric turbulence have used the Navier-Stokes fluid equations exclusively for describing large-scale motions. Controversy over the existence of an average temperature gradient for the very large eddies in the atmosphere suggested that a new theoretical basis for describing large-scale turbulence was necessary. A new soliton formalism as a fluid analogue that generalizes the Schrodinger equation and the Zakharov equations has been developed. This formalism, processing all the nonlinearities including those from modulation provided by the density fluctuations and from convection due to the emission of finite sound waves by velocity fluctuations, treats large-scale turbulence as coalescing and colliding solitons. The new soliton system describes large-scale instabilities more explicitly than the Navier-Stokes system because it has a nonlinearity of the gradient type, while the Navier-Stokes has a nonlinearity of the non-gradient type. The forced Schrodinger equation for strong fluctuations describes the micro-hydrodynamical state of soliton turbulence and is valid for large-scale turbulence in fluids and plasmas where internal waves can interact with velocity fluctuations.

Tchen, C. M.↗

Seasonal variation of the stratospheric circulation

An extensive analysis is made of the extratropical stratospheric circulation in terms of the seasonal variation of large-scale motion fields, with the aid of height and temperature data obtained from the TIROS satellite. Special attention is paid to a comparison of climatological aspects between the Northern Hemisphere (NH) and the Southern Hemisphere (SH). In order to see the general picture of the annual mach of the upper stratosphere, the zonal mean values of geopotential height of the 1 mb level at 70 deg N and 70 deg S were plotted on the daily basis throughout a year. It is observed that, during the winter, the zonal mean 1 mb height in the NH is much more variable than that in the SH. It is also notable that the SH height is rather oscillatory throughout the longer period from midwinter to early summer. Since the zonal mean height in the polar latitude is a rough measure of the mean zonal flow in extratropical latitudes, the difference of the seasonal variation between the two hemispheres mentioned above is considered to be due mainly to the planetary wave-mean flow interaction in the middle atmosphere. The wave activity in the middle atmosphere is represented more rigorously by the Eliassen-Palm flux associated with vertically propagating planetary waves forced from below. The day-to-day variation of the EP flux in the upper stratosphere shows that the wave activity varies intermittently with a characteristic time scale of about two weeks.

Hirota, I.↗

On the electron affinity of the oxygen atom

The electron affinity (EA) of oxygen is computed to be 1.287 eV, using 2p electron full configuration-interaction (CI) wave functions expanded in a 6s5p3d2f Slater-type orbital basis. The best complete active space self-consistent field - multireference CI (CASSCF-MRCI) result including only 2p correlation is 1.263 eV. However, inclusion of 2s intrashell and 2s2p intershell correlation increases the computed EA to 1.290 at the CASSCF-MRCI level. At the full CI basis set limit, the 2s contribution to the electron affinity is estimated to be as large as 0.1 eV. This study clearly establishes the synergistic effect between the higher excitations and basis set completeness on the electron affinity when the 2s electrons are correlated.

Bauschlicher, C. W., Jr.↗