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At least 1,369 records · Page 76

Self-Limitations of Heat Release in Coupled Core-Shell Spinel Ferrite Nanoparticles: Frequency, Time, and Temperature Dependencies

We explored a series of highly uniform magnetic nanoparticles (MNPs) with a core-shell nanoarchitecture prepared by an efficient solvothermal approach. In our study, we focused on the water dispersion of MNPs based on two different CoFe 2 O 4 core sizes and the chemical nature of the shell (MnFe 2 O 4 and spinel iron oxide). We performed an uncommon systematic investigation of the time and temperature evolution of the adiabatic heat release at different frequencies of the alternating magnetic field (AMF). Our systematic study elucidates the nontrivial variations in the heating efficiency of core-shell MNPs concerning their structural, magnetic, and morphological properties. In addition, we identified anomalies in the temperature and frequency dependencies of the specific power absorption (SPA). We conclude that after the initial heating phase, the heat release is governed by the competition of the Brown and Néel mechanism. In addition, we demonstrated that a rational parameter sufficiently mirroring the heating ability is the mean magnetic moment per MNP. Our study, thus, paves the road to fine control of the AMF-induced heating by MNPs with fine-tuned structural, chemical, and magnetic parameters. Importantly, we claim that the nontrivial variations of the SPA with the temperature must be considered, e.g., in the emerging concept of MF-assisted catalysis, where the temperature profile influences the undergoing chemical reactions.

36 MATERIALS SCIENCE↗

Coaxial radiative and convective heat transfer in gray and nongray gases

Coupled radiative and convective heat transfer is investigated for an absorbing gas flowing in a finite length channel and heated by blackbody radiation directed along the flow axis. The problem is formulated in one dimension and numerical solutions are obtained for the temperature profile of the gas and for the radiation escaping the channel entrance, assuming both gray and nongray absorption spectra. Due to radiation trapping, the flowing gas is found to have substantially smaller radiation losses for a given peak gas temperature than a solid surface that is radiatively heated to this temperature. A greenhouse effect is also evident whereby radiation losses are minimized for a gas having stronger absorption at long wavelengths.

Mattick, A. T.↗

Spaceborne lidar system for measurements of atmospheric water vapor and aerosols

The inclusion of a differential absorption lidar (DIAL) system as part of the NASA Earth Observing System (EOS) is proposed. Functioning at 720 nm, the DIAL could provide atmospheric water vapor profiles in the troposphere and stratosphere, and provide data for characterizing the physical properties of clouds. The use of frequency doubling of the laser could also open a window on the 355 nm region, and thereby molecular density and temperature profiles. The date would be of use in studies of the global hydrological cycle, the global radiation balance, climate, meteorology, and atmospheric structure and transport phenomena.

Browell, E. V.↗

A spectral approach to the unification of satellite and conventional temperature data

A method for combining temperature soundings derived from VISSR Atmospheric Sounder (VAS) radiance observations with conventional data is presented. Using data from the Atmospheric Variability Experiment/VAS Ground Truth Field Experiment, temperature profiles from rawinsonde and VAS observations were represented by Fourier cosine series, with harmonic-by-harmonic comparisons performed for collocated pairs as well as the spatial variations of harmonic coefficients. The zeroth and first harmonics in the VAS temperature soundings were combined with higher harmonics determined from conventional data to form a unified dataset. The quality of the unified data was examined by comparing the vertical motion fields derived from a linear balance model with satellite observations of cloud systems. Case studies at 1200 UTC on August 22, 23, and 24, 1983 over the western Atlantic gave good results.

Shin, Kyung-Sup↗

Stratospheric Benzene and Hydrocarbon Aerosols Detected in Saturn's Auroral Regions

Context. Saturn's polar upper atmosphere exhibits significant auroral activity; however, its impact on stratospheric chemistry (i.e. the production of benzene and heavier hydrocarbons) and thermal structure remains poorly documented. Aims. We aim to bring new constraints on the benzene distribution in Saturn's stratosphere, to characterize polar aerosols (their vertical distribution, composition, thermal infrared optical properties), and to quantify the aerosols' radiative impact on the thermal structure. Methods. Infrared spectra acquired by the Composite Infrared Spectrometer (CIRS) on board Cassini in limb viewing geometry are analysed to derive benzene column abundances and aerosol opacity profiles over the 3 to 0.1 mbar pressure range. The spectral dependency of the haze opacity is assessed in the ranges 680-900 and 1360-1440 cm(exp −1). Then, a radiative climate model is used to compute equilibrium temperature profiles, with and without haze, given the haze properties derived from CIRS measurements. Results. On Saturn's auroral region (80 deg S), benzene is found to be slightly enhanced compared to its equatorial and mid-latitude values. This contrasts with the Moses & Greathouse (2005, J. Geophys. Res., 110, 9007) photochemical model, which predicts a benzene abundance 50 times lower at 80◦S than at the equator. This advocates for the inclusion of ion-related reactions in Saturn's chemical models. The polar stratosphere is also enriched in aerosols, with spectral signatures consistent with vibration modes assigned to aromatic and aliphatic hydrocarbons, and presenting similarities with the signatures observed in Titan's stratosphere. The aerosol mass loading at 80 deg S is estimated to be 1−4 × 10(exp −5) g cm(exp −2), an order of magnitude less than on Jupiter, which is consistent with the order of magnitude weaker auroral power at Saturn.We estimate that this polar haze warms the middle stratosphere by 6 K in summer and cools the upper stratosphere by 5 K in winter. Hence, aerosols linked with auroral activity can partly account for the warm polar hood observed in Saturn's summer stratosphere.

satellites↗

Global Daily Atmospheric State Profiles from the Atmospheric Infrared Sounder

The Atmospheric Infrared Sounder (AIRS) is a hyperspectral infrared instrument on the EOS Aqua Spacecraft, launched on May 4, 2002. AIRS has 2378 infrared channels ranging from 3.7 (micro)m to 15.4 (micro)m and a 13.5 km footprint. AIRS, in conjunction with the Advanced Microwave Sounding Unit (AMSU), produces temperature profiles with 1K/km accuracy on a global scale, as well as water vapor profiles, clouds, dust and trace gas amounts for CO2, CO, SO2, O3 and CH4.[1] AIRS data are used for weather forecasting and studies of global climate change. The AIRS is a 'facility' instrument developed by NASA as an experimental demonstration of advanced technology for remote sensing and the benefits of high resolution infrared spectra to science investigations.

sounder↗

Experimental study and demonstration of pilot-scale oxy-coal combustion at elevated temperatures and pressures

High pressure oxy-fuel firing is a promising next-generation combustion technology for electricity generation, allowing net efficiency improvement compared to traditional oxy-fuel firing systems. Oxy-coal combustion has been extensively investigated at ambient pressure, but limited experimental data is available regarding this combustion method at elevated pressures at pilot or full scale. The study presented here investigates the operational performance of a high pressure, high temperature pilot-scale oxy-fuel combustor. Pulverized Utah bituminous coal in form of coal-water slurry was combusted at pressures up to 14 bar, temperatures up to 1600 °C and firing rates up to 300 kW. Eight different runs were selected for presentation and the measurements include flue gas composition (CO, CO 2 , CH 4 , SO 2 , O 2 ), carbon and sulfur content of fly ash, combustor temperature profile and flame radiation profile. The flame radiation measurements were carried out with a novel narrow beam radiometer which measures local radiant heat flux at a specific location in the combustor. The radiation ranged from 108 to 279 kW/m 2 depending mainly on combustor temperature. Additionally, the temperature significantly impacted the carbon content of fly ash: 2.66% was measured near 1600 °C, while the concentration increased to 36.7% when the temperature was decreased to 1300°C. Furthermore, the successful experimental demonstrations showed that increasing pressure is a viable combustion method and a step towards enhancing the efficiency in oxy-fuel firing based power plants.

01 COAL, LIGNITE, AND PEAT↗

The influence of temperature history and flow mixing on the vapor-phase speciation of uranium oxide nanoparticles

The transport of radioactive material following a nuclear event depends heavily on fallout characteristics (e.g., composition, shape, and size), which in turn are controlled by the conditions under which the fallout forms. To this end, we use a novel plasma flow reactor (PFR) to explore how conditions including temperature history and gas mixing influence the chemical speciation and physical characteristics of uranium oxide nanoparticles. The PFR consists of a glass tube attached to an inductively coupled plasma (ICP) torch via an adaptor piece (ring flow injector) located downstream of the plasma-generating RF coil. We increase the gas flow rates from normal ICP operating conditions to higher values both upstream at the RF coil and downstream at the ring flow injector to create four distinct temperature profiles and two distinct gas flow mixing conditions (normal and higher Ar atomic ratios). Ex situ transmission electron microscopy (TEM) analysis is used to determine the crystal structure, morphology, and size distribution of the synthesized particles as a function of temperature and mixing. The particles display a striking dependence on these conditions in terms of the resulting speciation of uranium oxide: lower temperature (higher upstream) and slower cooling (normal downstream with normal Ar atomic ratio mixing) favor the formation of α-UO 3 particles, while faster cooling (higher downstream with higher Ar atomic ratio mixing) and higher temperature (normal upstream) favor the formation of UO 2 particles. The extent of gas mixing dictates particle aggregation: better mixing encourages the particles to aggregate more extensively. Here these results demonstrate the sensitivity of uranium to initial local conditions and can be used to improve our understanding of the kinetics that drive uranium speciation and ultimately inform fallout transport models.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Autonomous Controls For Reactor Technologies (acorn)

ACORN (Autonomous Controls fOr Reactor techNologies) software utilizes data, obtained from an experimental test bed and/or simulation, to implement a control command for microreactor operation. Command examples include a change to the temperature profile, power profiles, heat fluxes, etc. The control command recommended by the code is derived based on future predicted states of a microreactor, allowing proactive optimal and autonomous microreactor operation. The software is written in Python languages. The current software supports autonomous temperature controls of heat pipe simulator and autonomous heat flux controls of a 37 heat pipe non-nuclear testbed simulator (or its surrogate models).

Lin, Linyu [Idaho National Laboratory (INL), Idaho↗

Testing Fast Reactor Fuels in a Thermal Reactor: A Comparison Report

The testing of fast reactor fuels in the thermal-spectrum of the Advanced Test Reactor using cadmium-filtering has been underway since 2003. The objective of this experimental approach to create a temperature profile inside of test fuel rodlets that is nearly prototypic of corresponding fast reactor conditions. This requires, necessarily, that the power generation profile inside of test fuel rodlets also be nearly prototypic of corresponding fast reactor conditions. By doing so, this experimental approach should allow for the study of fast reactor fuel performance phenomena that are primarily dependent upon the conditions of temperature and/or temperature gradient inside the fuel to be possible using a thermal test reactor. Validation of this assertion has been undertaken by both supporting analyses and by comparing fuel performance phenomena observed in fuels irradiated in cadmium-filtered positions in ATR to similar or identical fuels irradiated under similar conditions in genuine fast reactors. This report documents a preliminary comparison of fuel performance data available from the testing of metallic, oxide, and nitride fuels in cadmium-filtered positions in the ATR to the performance of identical or similar fuels irradiated in genuine fast reactors. Although a variety of fuel performance metrics are presented, particular attention is paid to those phenomena that are primarily, or significantly, dependent on conditions of temperature and temperature gradient with the fuel. Although the comparisons presented in this report are at this time limited in scope and preliminary in nature, they do support the assertion that the objectives of the cadmium-filtered testing approach in ATR are both feasible and appear sound. The analyses and comparisons presented in this report show that ATR irradiations performed using cadmium shrouding are sufficiently prototypic that they can be used with confidence in the development and testing of fast reactor fuels.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A thermal control approach for a solar electric propulsion thrust subsystem

A thrust subsystem thermal control design is defined for a Solar Electric Propulsion System (SEPS) proposed for the comet Halley Flyby/comet Tempel 2 rendezvous mission. A 114 node analytic model, developed and coded on the systems improved numerical differencing analyzer program, was employed. A description of the resulting thrust subsystem thermal design is presented as well as a description of the analytic model and comparisons of the predicted temperature profiles for various SEPS thermal configurations that were generated using this model. It was concluded that: (1) a BIMOD engine system thermal design can be autonomous; (2) an independent thrust subsystem thermal design is feasible; (3) the interface module electronics temperatures can be controlled by a passive radiator and supplementary heaters; (4) maintaining heat pipes above the freezing point would require an additional 322 watts of supplementary heating power for the situation where no thrusters are operating; (5) insulation is required around the power processors, and between the interface module and the avionics module, as well as in those areas which may be subjected to solar heating; and (6) insulation behind the heat pipe radiators is not necessary.

Maloy, J. E.↗

Turbulence effects on flame speed and flame structure

Turbulence effects on methane-air flames stabilized in grid turbulence were investigated through measurements of flame speed and mean and fluctuating flame temperature profiles. Published turbulent flame speed correlations were able to correlate the experimental flame speed data but were contradictory in indicating flame structure and combustion mechanisms. A simple, one-dimensional, wrinkled laminar flame model was used to predict characteristic flame temperature fluctuation levels. Comparison of these predictions with measured temperature fluctuations indicated that the majority of the flames studied were wrinkled laminar flames. However, a wrinkled laminar flame structure was inappropriate for the most intensely turbulent flames examined.

Smith, K. O.↗

CARS temperature measurements in the fuel preburner of the Space Shuttle main engine: A feasibility study

This report discusses the feasibility of making temperature profile measurements in the fuel preburner of the main engine of the space shuttle (SSME) using coherent anti-Stokes Raman spectroscopy (CARS). The principal thrust of the work is to identify problems associated with making CARS measurements in high temperature gas phase hydrogen at very high pressures (approx 400 atmospheres). To this end a theoretical study was made of the characteristics of the CAR spectra of H2 as a function of temperature and pressure and the accuracy with which temperatures can be extracted from this spectra. In addition the experimental problems associated with carrying out these measurements on a SSME at NSTL were identified. A conceptual design of a CARS system suitable for this work is included. Many of the results of the calculations made in this report are plotted as a function of temperature. In the course of presenting these results, it was necessary to decide whether the number of density or the pressure should be treated as a fixed parameter.

Beiting, E. J.↗

Amalthea - Implications of the temperature observed by Voyager

The temperature profile of Amalthea's surface layer is modeled as a function of location and time of day, assuming a triaxial ellipsoid shape and thermal properties similar to those of the lunar soil. Although the major heat source is direct insolation, temperatures are slightly increased by thermal radiation from Jupiter, sunlight reflected from the planet, and charged particle bombardment. Possible sources of error in the model are discussed in detail, including satellite shape effects, unusually low emissivity, uncommonly rough surface, abnormal thermal inertia, charged particle flux variability, and Joule heating. Voyager 1 IRIS observations suggest that the Amalthean surface has an emissivity near unity, but cannot put any useful limits on the thermal inertia of the Amalthean surface layer.

Simonelli, D. P.↗

On the specta of X-ray bursters: Expansion and contraction stages

The theory of spectral formation during the explosion and contraction stages of X-ray bursters, which include the effects of Computonization and free-free absorption and emission, is described. Analytical expressions are provided for color ratios, and the spectral shape is given as a function of input parameters, elemental abundance, neutron star mass and radius, and Eddington ratio. An Eulerian calculation is used to determine the photospheric evolution accurately during the Eddington luminosity phase. The developed analytical theory for hydrodynamics of the expansion takes into account the dependence of Compton scattering opacity on electron temperature. An analytical expression is derived from the sonic point position and the value of the sonic velcoity. Using this value as a boundary condition at the sonic point, the velocity, density, and temperature profile are calculated throughout the whole photosphere. It is shown that the atmopsphere radiates spectra having a low-energy power-law shape and blackbody-like hard tail. In the expansion stage the spectra depend strongly on the temperature of the helium-burning zone at the neutron star surface. The X-ray photosheric radius increases to approximately 100 km or more, depending on the condition of the nuclear burning on the surface of the neutron star in the course of the expansion.

Titarchuk, Lev↗

Geophysica MTP observations during the EUPLEX campaign

The Jet Propulsion Laboratory (JPL) Microwave Temperature Profiler (MTP) was the first United States instrument to fly on the Russian Geophysica high-altitude research aircraft. Careful comparison of MTP measurements with radiosondes launched near the Geophysica flight track has allowed us to establish the flight level temperature to an accuracy of 0.2K.

MTP↗

Secondary electron emission and the bifurcation of the heat flux to the targets in fusion plasmas

The presence of secondary electron emission (SEE) from plasma facing components in fusion devices can result in a strong localization of the heat flux from plasma to the wall and subsequent wall erosion. Usually, the impact of the SEE is considered assuming the Maxwellian distribution of the electrons coming to the surface. As a result, the SEE coefficient only depends on the temperature of primary electrons. However, the tail of primary electron distribution function in the scrape off layer (SOL) of fusion devices can be far from Maxwellian due to preferential loss of fast electrons. Consequently, it is shown that the SEE coefficient will depend on the wall potential and multiple solutions can be possible corresponding to different regimes of plasma flow to the wall: with and without SEE effects. This effect can cause two-slope electron temperature profiles in the SOL, which are often seen in experiments.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗