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At least 1,369 records · Page 76

Intercomparison of Aerosol Volume Size Distributions Derived from AERONET Ground-Based Remote Sensing and LARGE in Situ Aircraft Profiles During the 2011–2014 DRAGON and DISCOVER-AQ Experiments

Aerosol volume size distribution (VSD) retrievals from the Aerosol Robotic Network (AERONET) aerosol monitoring network were obtained during multiple DRAGON (Distributed Regional Aerosol Gridded Observational Network) campaigns conducted in Maryland, California, Texas and Colorado from 2011 to 2014. These VSD retrievals from the field campaigns were used to make comparisons with near-simultaneous in situ samples from aircraft profiles carried out by the NASA Langley Aerosol Group Experiment (LARGE) team as part of four campaigns comprising the DISCOVER-AQ (Deriving Information on Surface conditions from Column and Vertically Resolved Observations Relevant to Air Quality) experiments. For coincident (1 h) measurements there were a total of 91 profile-averaged fine-mode size distributions acquired with the LARGE ultra-high sensitivity aerosol spectrometer (UHSAS) instrument matched to 153 AERONET size distributions retrieved from almucantars at 22 different ground sites. These volume size distributions were characterized by two fine-mode parameters, the radius of peak concentration (rpeak_conc) and the VSD fine-mode width (widthpeak_conc). The AERONET retrievals of these VSD fine-mode parameters, derived from ground-based almucantar sun photometer data, represent ambient humidity values while the LARGE aircraft spiral profile retrievals provide dried aerosol (relative humidity; RH< 20 %) values. For the combined multiple campaign dataset, the average difference in rpeak_conc was 0:0330:035 μm (ambient AERONET values were 15.8% larger than dried LARGE values), and the average difference in widthpeak_conc was 0:0420:039 μm (AERONET values were 25.7% larger). For a subset of aircraft data, the LARGE data were adjusted to account for ambient humidification. For these cases, the AERONET–LARGE average differences were smaller, with rpeak_conc differing by 0:0110:019 μm (AERONET values were 5.2% larger) and widthpeak_conc average differences equal to 0:0300:037 μm (AERONET values were 15.8% larger).

Schafer, Joel S.↗

Assessment of holographic microscopy for quantifying marine particle size and concentration

Holographic microscopy has emerged as a tool for in situ imaging of microscopic organisms and other particles in the marine environment: appealing because of the relatively larger sampling volume and simpler optical configuration compared to other imaging systems. However, its quantitative capabilities have so far remained uncertain, in part because hologram reconstruction and image recognition have required manual operation. Here, we assess the quantitative skill of our automated hologram processing pipeline (CCV Pipeline), to evaluate the size and concentration measurements of environmental and cultured assemblages of marine plankton particles, and microspheres. Over 1 million particles, ranging from 10 to 200 μm in equivalent spherical diameter, imaged by the 4‐Deep HoloSea digital inline holographic microscope (DIHM) are analyzed. These measurements were collected in parallel with a FlowCam (FC), Imaging FlowCytobot (IFCB), and manual microscope identification. Once corrections for particle location and nonuniform illumination were developed and applied, the DIHM showed an underestimate in ESD of about 3% to 10%, but successfully reproduced the size spectral slope from environmental samples, and the size distribution of cultures (Dunaliella tertiolecta, Heterosigma akashiwo, and Prorocentrum micans) and microspheres. DIHM concentrations (order 1 to 1000 particles ml(exp −1)) showed a linear agreement (r(exp 2) = 0.73) with the other instruments, but individual comparisons at times had large uncertainty. Overall, we found the DIHM and the CCV Pipeline required extensive manual correction, but once corrected, provided concentration and size estimates comparable to the other imaging systems assessed in this study. Holographic cameras are mechanically simple, autonomous, can operate at very high pressures, and provide a larger sampling volume than comparable lens‐based tools. Thus, we anticipate that these characterization efforts will be rewarded with novel discovery in new oceanic environments.

Noah L. Walcutt↗

Apparent dust size discrepancy in aerosol reanalysis in north African dust after long-range transport

North African dust reaches the southeastern United States every summer. Size-resolved dust mass measurements taken in Miami, Florida, indicate that more than one-half of the surface dust mass concentrations reside in particles with geometric diameters less than 2.1 µm, while vertical profiles of micropulse lidar depolarization ratios show dust reaching above 4 km during pronounced events. These observations are compared to the representation of dust in the Modern-Era Retrospective analysis for Research and Applications, version 2 (MERRA-2) aerosol reanalysis and closely related Goddard Earth Observing System model version 5 (GEOS-5) Forward Processing (FP) aerosol product, both of which assimilate satellite-derived aerosol optical depths using a similar protocol and inputs. These capture the day-to-day variability in aerosol optical depth well, in a comparison to an independent sun-photometer-derived aerosol optical depth dataset. Most of the modeled dust mass resides in diameters between 2 and 6 µm, in contrast to the measurements. Model-specified mass extinction efficiencies equate light extinction with approximately 3 times as much aerosol mass, in this size range, compared to the measured dust sizes. GEOS-5 FP surface-layer sea salt mass concentrations greatly exceed observed values, despite realistic winds and relative humidities. In combination, these observations help explain why, despite realistic total aerosol optical depths, (1) free-tropospheric model volume extinction coefficients are lower than those retrieved from the micro-pulse lidar, suggesting too-low model dust loadings in the free troposphere, and (2) model dust mass concentrations near the surface can be higher than those measured. The modeled vertical distribution of dust, when captured, is reasonable. Large, aspherical particles exceeding the modeled dust sizes are also occasionally present, but dust particles with diameters exceeding 10 µm contribute little to the measured total dust mass concentrations after such long-range transport. Remaining uncertainties warrant a further integrated assessment to confirm this study's interpretations.

MEERA-2 aerosols reanalysis↗

An Evaluation of Biomass Burning Aerosol Mass, Extinction, and Size Distribution in Geos Using Observations From Camp2EX

Biomass burning aerosol impacts aspects of the atmosphere and Earth system through radiative forcing, serving as cloud condensation nuclei, and air quality. Despite its importance, the representation of biomass burning aerosol is not always accurate in numerical weather prediction and climate models or reanalysis products. Using observations collected as part of the Cloud, Aerosol and Monsoon Processes Philippines Experiment (CAMP2Ex) in August through October of 2019, aerosol concentration and optical properties are evaluated within the Goddard Earth Observing System (GEOS) and its underlying aerosol module, GOCART. In the operational configuration, GEOS assimilates aerosol optical depth observations at 550 nm to constrain aerosol fields. Particularly for biomass burning aerosol, without the assimilation of aerosol optical depth, aerosol extinction is underestimated compared to observations collected in the Philippines region during the CAMP2Ex campaign. The assimilation process adds excessive amounts of carbon to account for the underestimated extinction, resulting in positive biases in the mass of black and organic carbon, especially within the boundary layer, relative to in situ observations from the Langley Aerosol Research Group Experiment. Counteracting this, GEOS is deficient in sulphate and nitrate aerosol just above the boundary layer. Aside from aerosol mass, extinction within GEOS is a function of ambient relative humidity and an assumed particle size distribution. The relationship between dry and ambient extinction in GEOS reveals that hygroscopic growth is too aggressive within the model for biomass burning aerosol. An additional concern lies in the assumed particle size distribution for GEOS, which has a mode radius that is too small for organic carbon. Variability in the observed particle size distribution for biomass burning aerosol within a single flight also illuminates the fact that a single assumed particle size distribution is not sufficient and that for a proper representation, a more advanced aerosol module with GEOS may be necessary.

Aerosol Mass↗

Structural Sizing of a Composite Transonic Truss-Braced Wing

Accurate finite element modeling (FEM) is a vital part of the modern aircraft design process. As aircraft become increasingly complex, the time-consuming nature of detailed FEM approaches comes at a significant cost to program timeline and budget. In an effort produce modeling efforts that are sufficiently accurate and minimally costly, a proposed FEM approach and optimization scheme for a composite aircraft is explored, including a discussion of the manufacturing constraints of a highly tailored composite panel design. A high-fidelity structural model of a transonic truss-braced wing (TTBW) is generated, and the components are sized by structural optimization to satisfy buckling and strength constraints while subjected to critical maneuver loads. The structural modeling approaches and sizing of a TTBW are discussed, including details for FEM approaches, verification of an approximated FEM approach, a sizing optimization using the optimization software LS-OPT, and a manufacturing trial of integrally stiffened composite panels conducted to explore the validity of highly tailored composites as a design consideration. The results of study discussed herein indicate that the proposed FEM approach is suitable for modeling composite-construction aircraft and for use in sizing optimization. Further efforts regarding integrally stiffened composite panels will indicate the suitability of this method for the integration of highly tailored composite panels into the design and optimization process, given the manufacturability of such panels as shown here.

Finite Element↗

Structural Sizing of a Transonic Truss-Braced Wing

Accurate finite element modeling (FEM) is a vital part of the modern aircraft design process. As aircraft become increasingly complex, the time-consuming nature of detailed FEM approaches comes at a significant cost to program timeline and budget. In an effort produce modeling efforts that are sufficiently accurate and minimally costly, a proposed FEM approach and optimization scheme for a composite aircraft is explored, including a discussion of the manufacturing constraints of a highly tailored composite panel design. A high-fidelity structural model of a transonic truss-braced wing (TTBW) is generated, and the components are sized by structural optimization to satisfy buckling and strength constraints while subjected to critical maneuver loads. The structural modeling approaches and sizing of a TTBW are discussed, including details for FEM approaches, verification of an approximated FEM approach, a sizing optimization using the optimization software LS-OPT, and a manufacturing trial of integrally stiffened composite panels conducted to explore the validity of highly tailored composites as a design consideration. The results of study discussed herein indicate that the proposed FEM approach is suitable for modeling composite-construction aircraft and for use in sizing optimization. Further efforts regarding integrally stiffened composite panels will indicate the suitability of this method for the integration of highly tailored composite panels into the design and optimization process, given the manufacturability of such panels as shown here.

Finite Element↗

Modeling the Stochastic Response of Fiber Reinforced Composites with Varied Representative Volume Element Sizes

Fiber reinforced composites are desirable in applications where low weight and high strength are needed, but are susceptible to variability and flaws during manufacturing, making failure predictions difficult. These flaws may occur at the microscale where mechanical properties vary locally due to regions of fiber clusters and matrix pockets. In this study, a multiscale approach was taken to model 3-point bend, 4-point bend, and tensile experiments of a unidirectional composite from only having microstructure scans of these samples and constituent properties from literature. These scans were sampled with different sized windows, and statistically equivalent microstructures were generated, then simulated for stiffness, strength, and fracture toughness using a reduced order micromechanical model and NASA’s Multiscale Analysis Tool (NASMAT). Mesoscale models were created with equivalent element sizes to microstructures and properties sampled from microscale simulation results. Results showed how microscale size affects certain mechanical properties. Also shown is how well mesoscale models agree to experiments when using stochastic element properties and varying element size.

microstructure↗

Subnanometer and nanometer catalysts, method for preparing size-selected catalysts

Highly uniform cluster based nanocatalysts supported on technologically relevant supports were synthesized for reactions of top industrial relevance. The Pt-cluster based catalysts outperformed the very best reported ODHP catalyst in both activity (by up to two orders of magnitude higher turn-over frequencies) and in selectivity. The results clearly demonstrate that highly dispersed ultra-small Pt clusters precisely localized on high-surface area supports can lead to affordable new catalysts for highly efficient and economic propene production, including considerably simplified separation of the final product. The combined GISAXS-mass spectrometry provides an excellent tool to monitor the evolution of size and shape of nanocatalyst at action under realistic conditions. Also provided are sub-nanometer gold and sub-nanometer to few nm size-selected silver catalysts which possess size dependent tunable catalytic properties in the epoxidation of alkenes. Invented size-selected cluster deposition provides a unique tool to tune material properties by atom-by-atom fashion, which can be stabilized by protective overcoats.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Subnanometer and nanometer catalysts, method for preparing size-selected catalysts

Highly uniform cluster based nanocatalysts supported on technologically relevant supports were synthesized for reactions of top industrial relevance. The Pt-cluster based catalysts outperformed the very best reported ODHP catalyst in both activity (by up to two orders of magnitude higher turn-over frequencies) and in selectivity. The results clearly demonstrate that highly dispersed ultra-small Pt clusters precisely localized on high-surface area supports can lead to affordable new catalysts for highly efficient and economic propene production, including considerably simplified separation of the final product. The combined GISAXS-mass spectrometry provides an excellent tool to monitor the evolution of size and shape of nanocatalyst at action under realistic conditions. Also provided are sub-nanometer gold and sub-nanometer to few nm size-selected silver catalysts which possess size dependent tunable catalytic properties in the epoxidation of alkenes. Invented size-selected cluster deposition provides a unique tool to tune material properties by atom-by-atom fashion, which can be stabilized by protective overcoats.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Primary Water Stress Corrosion Cracks in Nickel Alloy Dissimilar Metal Welds: Detection and Sizing Using Established and Emerging Nondestructive Examination Techniques

The U.S. Nuclear Regulatory Commission has established the Program to Assess the Reliability of Emerging Nondestructive Techniques (PARENT) as a follow-on to the international cooperative Program for the Inspection of Nickel Alloy Components (PINC). The goal of PINC was to evaluate the capabilities of various nondestructive evaluation (NDE) techniques to detect and characterize surface-breaking primary water stress corrosion cracks in dissimilar-metal welds (DMW) in bottom-mounted instrumentation (BMI) penetrations and small-bore (≈400-mm diameter) piping components. A series of international blind round-robin tests were conducted by commercial and university inspection teams. Results from these tests showed that a combination of conventional and phased-array ultrasound techniques provided the highest performance for flaw detection and depth sizing in dissimilar metal piping welds. The effective detection of flaws in BMIs by eddy current and ultrasound shows that it may be possible to reliably inspect these components in the field. The goal of PARENT is to continue the work begun in PINC and apply the lessons learned to a series of open and blind international round-robin tests that will be conducted on a new set of piping components including large-bore (≈900-mm diameter) DMWs, small-bore DMWs, and BMIs. Open round-robin testing will engage universities and industry worldwide to investigate the reliability of emerging NDE techniques to detect and accurately size flaws having a wide range of lengths, depths, orientations, and locations. Blind round-robin testing will invite testing organizations worldwide, whose inspectors and procedures are certified by the standards for the nuclear industry in their respective countries, to investigate the ability of established NDE techniques to detect and size flaws whose characteristics range from easy to very difficult to detect and size. This paper presents highlights of PINC and reports on the plans and progress for PARENT round-robin tests.

cracks↗

Field Study of Performance, Comfort, and Sizing of Two Variable-Speed Heat Pumps Installed in a Single 2-Story Residence

With the recent advancements in the application of variable-speed (VS) compressors to residential HVAC systems, opportunities are now available to size heat pumps (HPs) to more effectively meet heating and cooling loads in many of the climate zones in the US with limited use of inefficient resistance heat. This is in contrast to sizing guidance for traditional single-speed HPs that limits the ability to oversize with regard to cooling loads, because of risks of poor dehumidification during the cooling season and increased cycling losses. VS-drive HPs can often run at 30-40% of their rated cooling capacity to reduce cycling losses, and can adjust fan speed to provide better indoor humidity control. Detailed air-side performance data was collected on two VS-drive heat pumps installed in a single unoccupied research house in Knoxville, TN, a mixed-humid climate. One system provided space conditioning for the upstairs, while the other unit provided space conditioning for the downstairs. Occupancy was simulated by operating the lights, shower, appliances, other plug loads, etc. to simulate the sensible and latent loads imposed on the building space by internal electric loads and human occupants according to the Building America Research Benchmark (2008). The seasonal efficiency and energy use of the units are calculated. Annual energy use is compared to that of the single speed minimum efficiency HPs tested in the same house previously. Sizing of the units relative to the measured building load and manual J design load calculations is examined. The impact of the unit sizing with regards to indoor comfort is also evaluated.

Munk, Jeffrey D↗

Round-Robin Verification and Final Development of the IEC 62788-1-5 Encapsulation Size Change Test; NREL (National Renewable Energy Laboratory)

Polymeric encapsulation materials may a change size when processed at typical module lamination temperatures. The relief of residual strain, trapped during the manufacture of encapsulation sheet, can affect module performance and reliability. For example, displaced cells and interconnects threaten: cell fracture; broken interconnects (open circuits and ground faults); delamination at interfaces; and void formation. A standardized test for the characterization of change in linear dimensions of encapsulation sheet has been developed and verified. The IEC 62788-1-5 standard quantifies the maximum change in linear dimensions that may occur to allow for process control of size change. Developments incorporated into the Committee Draft (CD) of the standard as well as the assessment of the repeatability and reproducibility of the test method are described here. No pass/fail criteria are given in the standard, rather a repeatable protocol to quantify the change in dimension is provided to aid those working with encapsulation. The round-robin experiment described here identified that the repeatability and reproducibility of measurements is on the order of 1%. Recent refinements to the test procedure to improve repeatability and reproducibility include: the use of a convection oven to improve the thermal equilibration time constant and its uniformity; well-defined measurement locations reduce the effects of sampling size -and location- relative to the specimen edges; a standardized sand substrate may be readily obtained to reduce friction that would otherwise complicate the results; specimen sampling is defined, so that material is examined at known sites across the width and length of rolls; and encapsulation should be examined at the manufacturer’s recommended processing temperature, except when a cross-linking reaction may limit the size change. EVA, for example, should be examined 100 °C, between its melt transition (occurring up to 80 °C) and the onset of cross-linking (often at 100 °C).

14 SOLAR ENERGY↗

Pore size distribution and methane equilibrium conditions at Walker Ridge Block 313, northern Gulf of Mexico

Coexistence of three methane phases (liquid (L), gas (G), hydrate (H)) in marine gas hydrate systems may occur according to in-situ pressure, temperature, salinity and pore size. In sediments with salinity close to seawater, a discrete zone of three-phase (3P) equilibrium may occur near the base of the regional hydrate stability zone (RHSZ) due to capillary effects. The existence of a 3P zone influences the location of the bottom-simulating reflection (BSR) and has implications for methane fluxes at the base of the RHSZ. We studied hydrate stability conditions in two wells, WR313-G and WR313-H, at Walker Ridge Block 313 in the northern Gulf of Mexico. We determined pore size distributions (PSD) by constructing a synthetic nuclear magnetic resonance (NMR) relaxation time distribution. Correlations were obtained by non-linear regression on NMR, gamma ray, and bulk density logs from well KC-151 at Keathley Canyon. The correlations enabled construction of relaxation time distributions for WR313-G and WR313-H, which were used to predict PSD through comparison with mercury injection capillary pressure measurements. With the computed PSD, L+H and L+G methane solubility was determined from in-situ pressure and temperature. The intersection of the L+G and L+H curves for various pore sizes allowed calculation of the depth range of the 3P equilibrium zone. As in previous studies at Blake Ridge and Hydrate Ridge, the top of the 3P zone moves upwards with increasing water depth and overlies the bulk 3P equilibrium depth. In clays at Walker Ridge, the predicted thickness of the 3P zone is approximately 35 m, but in coarse sands it is only a few meters due to the difference in absolute pore sizes and the width of the PSD. The thick 3P zone in the clays may explain in part why the BSR is only observed in the sand layers at Walker Ridge, although other factors may influence the presence or absence of a BSR.

Bihani, Abhishek↗

Cooperative storage of shared files in a parallel computing system with dynamic block size

Improved techniques are provided for parallel writing of data to a shared object in a parallel computing system. A method is provided for storing data generated by a plurality of parallel processes to a shared object in a parallel computing system. The method is performed by at least one of the processes and comprises: dynamically determining a block size for storing the data; exchanging a determined amount of the data with at least one additional process to achieve a block of the data having the dynamically determined block size; and writing the block of the data having the dynamically determined block size to a file system. The determined block size comprises, e.g., a total amount of the data to be stored divided by the number of parallel processes. The file system comprises, for example, a log structured virtual parallel file system, such as a Parallel Log-Structured File System (PLFS).

97 MATHEMATICS AND COMPUTING↗

Method for producing size selected particles

The invention provides a system for preparing specific sized particles, the system comprising a continuous stir tank reactor adapted to receive reactants; a centrifugal dispenser positioned downstream from the reactor and in fluid communication with the reactor; a particle separator positioned downstream of the dispenser; and a solution stream return conduit positioned between the separator and the reactor. Also provided is a method for preparing specific sized particles, the method comprising introducing reagent into a continuous stir reaction tank and allowing the reagents to react to produce product liquor containing particles; contacting the liquor particles with a centrifugal force for a time sufficient to generate particles of a predetermined size and morphology; and returning unused reagents and particles of a non-predetermined size to the tank.

36 MATERIALS SCIENCE↗

HIGH-ENERGY X-RAY PINHOLE CAMERA FOR HIGH-RESOLUTION ELECTRON BEAM SIZE MEASUREMENTS

The Advanced Photon Source (APS) is developing a multi-bend achromat (MBA) lattice based storage ring as the next major upgrade, featuring a 20-fold reduction in emittance. Combining the reduction of beta functions, the electron beam sizes at bend magnet sources may be reduced to reach 5 – 10 µm for 10% vertical coupling. The x-ray pinhole camera currently used for beam size monitoring will not be adequate for the new task. By increasing the operating photon energy to 120 – 200 keV, the pinhole camera’s resolution is expected to reach below 4 µm. The peak height of the pinhole image will be used to monitor relative changes of the beam sizes and enable the feedback control of the emittance. We present the simulation and the design of a beam size monitor for the APS storage ring.

Yang, B.↗

Synthetic methods for crystallite size control of bimetallic polyanionic battery compositions

Bimetallic polyanionic materials, such as silver vanadium phosphorus oxide (Ag 2 VO 2 PO 4 , SVOP), are promising cathode materials for Li batteries due in part to their large capacity and high current capability. A new synthesis of Ag 2 VO 2 PO 4 based on microwave heating is disclosed, where the reaction time is reduced by approximately 100 times relative to other reported methods, and the crystallite size is controlled via synthesis temperature, showing a linear positive correlation of crystallite size with temperature. Reaction times of an hour or less are sufficient to render phase-pure material after reaction at 50° C. to 180° C., significantly lower than the temperatures reported for other methods. Crystallite sizes between 42 nm and 60 nm are achieved by the novel method, smaller than by other methods. Silver/vanadium atomic ratios of 1.96 to 2.04 in the as-synthesized SVOP result and appear temperature-dependent. Notably, under galvanostatic reduction, the Ag 2 VO 2 PO 4 sample with the smallest crystallite size delivers the highest capacity and shows the highest loaded voltage.

Takeuchi, Kenneth J.↗

The Effect of Grain Size and Phosphorous-doping of Polycrystalline 3C-SiC on Infrared Reflectance Spectra

The effect of P-doping and grain size of polycrystalline 3C-SiC on the infrared reflectance spectra is reported. The relationship between grain size and full width at half maximum (FWHM) suggest that the behaviour of the 3C-SiC with the highest phosphorous doping level (of 1.2 x 10{sup 19} at. cm{sup -3}) is different from those with lower doping levels (< 6.6 x 10{sup 18} at. cm{sup -3}). It is also further demonstrated that the plasma resonance frequency (w{sub p}) is not influenced by the grain size.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗