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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,369 records · Page 76
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NASA NTRS2021

The 32-year Record-high Surface Melt in 2019/2020 on the Northern George VI Ice Shelf, Antarctic Peninsula

In the 2019/2020 austral summer, the surface melt duration and extent on the northern George VI Ice Shelf (GVIIS) was exceptional compared to the 31 previous summers of distinctly lower melt. This finding is based on analysis of near-continuous 41-year satellite microwave radiometer and scatterometer data, which are sensitive to meltwater on the ice shelf surface and in the near-surface snow. Using optical satellite imagery from Landsat 8 (2013 to 2020) and Sentinel-2 (2017 to 2020), record volumes of surface meltwater ponding were also observed on the northern GVIIS in 2019/2020, with 23 % of the surface area covered by 0.62 km3 of ponded meltwater on 19 January. These exceptional melt and surface ponding conditions in 2019/2020 were driven by sustained air temperatures ≥0 ∘C for anomalously long periods (55 to 90 h) from late November onwards, which limited meltwater refreezing. The sustained warm periods were likely driven by warm, low-speed (≤7.5 m s−1) northwesterly and northeasterly winds and not by foehn wind conditions, which were only present for 9 h total in the 2019/2020 melt season. Increased surface ponding on ice shelves may threaten their stability through increased potential for hydrofracture initiation; a risk that may increase due to firn air content depletion in response to near-surface melting.

Alison F. Banwell↗
NASA NTRSDate not supplied

Surface Systems and Interface Standardization

Space exploration on planetary surfaces will require the use of various surface systems which will likely need to interface with one another. These systems must communicate and share data, as well as distribute power and transfer fluids for sustainable surface operations. Such systems can range from landers, surface habitats, mobility systems, cargo, and In-Situ Resource Utilizations (ISRUs). Previous and current programs have developed space interoperability standards that help aid in reducing potential risks of interface integration. One example of this is the International Deep Space Interoperability Standards (IDSIS) which focuses on deep space exploration. A goal of the Artemis program is to develop a sustained human presence on the lunar surface that would be a training ground for future Mars exploration. Therefore, it will be beneficial to identify interface standards between the surface assets which will help mitigate risk and reduce complexity in the harsh environments of space exploration. A key contribution to sustainability is commonality between hardware and software interfaces. Generic interfaces for data, power, and fluids will reduce risk, promote interoperability, and define standard interfaces across surface exploration projects and programs. Standardized interfaces would be advantageous for improving efficiency and reducing overall complexity, which are critical considerations for future space exploration. Furthermore, it will provide cost reductions to the Artemis programs over their life cycle (in Operations & Maintenance (O&M) and Logistics). Unique proprietary interfaces if considered or allowed would not only increase complexity but also add cost to the programs. Of course, understanding what will work and not work effectively in these unique environments such as the lunar surface is important. These unique environments require much needed intelligent design, prototyping, comprehensive testing, and field experience, utilizing consensus on common interface solutions.

Jaime Gomez↗
NASA NTRS2022

Rock Abundance on the Lunar Mare on Surfaces of Different Age: Implications for Regolith Evolution and Thickness

The growth of lunar regolith over time affects surface rock abundance, because larger, less frequent impacts are needed to penetrate thicker regolith developed on older surfaces and excavate rocks. On younger surfaces with thinner regolith, smaller, more frequent impacts are sufficient to excavate rocks. We quantify the correlation between observed rock abundances and age on the lunar surface by comparing Diviner rock abundance data to the surface ages of inter-crater parts on the maria. Our observations show the expected negative correlation between age and rock abundance. The commonality of non-zero rock abundance values on ancient surfaces, combined with a simple Monte Carlo model of the rock excavation process, suggest that rocks re-excavated from the regolith volume contribute to the presently observed rock population on the lunar surface. The half-life of meter-scale surface rocks most consistent with our observations is 80±20 Myr.

Sashank Vanga↗
NASA NTRS2022

Coupling Carbon Oxidation and Surface Recession in Direct-Simulation Monte Carlo Code, SPARTA

Ablative thermal protection system (TPS) materials for spacecraft are composites that are often made out of carbon-based reinforcement and a polymeric matrix. They endure high-temperature oxidation and surface recession when re-entering Earth’s atmosphere. Ablation is the result of many coupled and competing thermal, mechanical, and chemical phenomena, and it is difficult to isolate the role of each on the overall degradation of the TPS. Here we develop an ablation model for material recession coupled explicitly to finite rate carbon oxidation in complex microstructures. In this work, Stochastic PArallel Rarified-gas Time-accurate Analyzer (SPARTA), a direct-simulation Monte Carlo (DSMC) code, is modified to allow oxidation-driven ablation of implicitly defined carbon surfaces. In SPARTA, implicit surfaces are generated from the grid corner point values via a marching cubes algorithm, therefore creating a new set of surface elements every time ablation is performed. The finite-rate oxidation model developed by Gopalan et. al, was adapted to tally surface reactions and other surface data on a per-grid cell basis. The ablation functionality was also adjusted so once the reactions have occurred, the number of reactions leading to CO formation can be converted to corner point reduction values; therefore, carbon removal is directly proportional to surface recession. We also develop robust algorithms which handle the evolution of the flow cells and solid material regions, including split cells (flow cell divided in two by a solid surface). Finally, we demonstrate our implicit chemistry model for 2D and 3D geometries by producing reaction statistics and detailed visualization of oxidation-induced material recession at the microscale.

V Arias↗
NASA NTRS2022

Crater Population on Asteroid (101955) Bennu Indicates Impact Armouring and a Young Surface

The impactor-to-crater size scaling relationships that enable estimates of planetary surface ages rely on an accurate formulation of impactor–target physics. An armouring regime, specific to rubble-pile surfaces, has been proposed to occur when an impactor is comparable in diameter to a target surface particle (for example, a boulder). Armouring is proposed to reduce crater diameter, or prevent crater formation in the asteroid surface, at small crater diameters. Here, using measurements of 1,560 craters on the rubble-pile asteroid (101955) Bennu, we show that the boulder population controls a transition from crater formation to armouring at crater diameters ~2–3 m, below which crater formation in the bulk surface is increasingly rare. By combining estimates of impactor flux with the armouring scaling relationship, we find that Bennu’s crater retention age (surface age derived from crater abundance) spans from 1.6–2.2 Myr for craters less than a few meters to ~10–65 Myr for craters >100 m in diameter, reducing the maximum surface age by a factor of >15 relative to previous estimates. The range of crater retention ages, together with latitudinal variations in large-crater spatial density, indicate that ongoing resurfacing processes render the surface many times younger than the bulk asteroid.

Asteroids↗
NASA NTRS2022

Crater population on asteroid (101955) Bennu indicates impact armouring and a young surface

The impactor-to-crater size scaling relationships that enable estimates of planetary surface ages rely on an accurate formulation of impactor–target physics. An armouring regime, specific to rubble-pile surfaces, has been proposed to occur when an impactor is comparable in diameter to a target surface particle (for example, a boulder). Armouring is proposed to reduce crater diameter, or prevent crater formation in the asteroid surface, at small crater diameters. Here, using measurements of 1,560 craters on the rubble-pile asteroid (101955) Bennu, we show that the boulder population controls a transition from crater formation to armouring at crater diameters ~2–3m, below which crater formation in the bulk surface is increasingly rare. By combining estimates of impactor flux with the armouring scaling relationship, we find that Bennu’s crater retention age (surface age derived from crater abundance) spans from 1.6–2.2Myr for craters less than a few meters to ~10–65Myr for craters >100m in diameter, reducing the maximum surface age by a factor of >15 relative to previous estimates. The range of crater retention ages, together with latitudinal variations in large-crater spatial density, indicate that ongoing resurfacing processes render the surface many times younger than the bulk asteroid.

E. B. Bierhaus↗
NASA NTRSDate not supplied

Assessing Uncertainties and Variability 34 Years of Surface Radiative Fluxes Using GEWEX SRB Release4-IP

The NASA/GEWEX Surface Radiation Budget (SRB) project produces 3-hrly shortwave and longwave surface and top of atmosphere radiative fluxes for the 1983-near present time period. The new Release 4 Integrated Product (IP) uses the newly recalibrated and processed ISCCP HXS product as its primary input for cloud and radiance data, replacing ISCCP DX with a ninefold increase in pixel count (10 km instead of 30 km). This first version retains a 1°x1° resolution enabling intercomparison against previous versions and other data sets such as CERES, but spans 34 years from July 1983 through June 2017 and was announced by Kummerow et al. 2019 (GEWEX News). This new IP product also uses an atmospheric temperature and moisture dataset known as nnHIRS and other parameters such as near surface and skin temperatures from SeaFlux and LandFlux data sets. In addition to the input data improvements, several important algorithm improvements have been made since Release 3. These include recalculated SW atmospheric transmissivities and reflectivities, updated ocean and snow/ice albedos, and variable total solar irradiance consistent with SORCE measurements. The LW code has been updated to improve the optical property treatment for clouds and aerosols are included in this version. Radiative treatment of ice clouds is also improved in the LW. The variable aerosol optical properties for the SW and LW are specified using a detailed aerosol history from the Max Planck Institute Aerosol Climatology (MAC). Here we present an assessment of the LW radiative fluxes and the uncertainty of those fluxes relative to the various inputs to surface SW/LW flux measurements from BSRN and PMEL buoys measurements. We review the validation of the SW and LW fluxes and then in terms of time series and then assess the products in terms of their long-term variability of the surface SW and LW net fluxes compared to multiple other data products including atmospheric reanalysis products. The comparisons of radiative estimates to observations are performed at various temporal scales and aimed at investigation of agreement at longer time averages but accessing potential change in diurnal magnitude and daily variability. Utilizing this uncertainty information, to access long-term variability of surface radiation components at selected region and global scales, considering satellite sampling/calibration “artifacts” as necessary. At the longer time scales, the net SW and net LW the TOA and surface have implications toward closure of the energy budgets at the surface, we assess these compared to other studies on energy budget closure for the same selected global and regional scales.

Paul W Stackhouse↗
NASA NTRSDate not supplied

Towards a more realistic representation of NASA CERES-derived surface radiative fluxes during polar night: a comparison with the MOSAiC field campaign

The Arctic is one of the most sensitive regions of Earth to climate change, and yet remains one of the more difficult regions to both observe and simulate. The high latitude of the Arctic gives it some unusual features compared with much of Earth, such as large and variable sea ice cover, extensive mixed phase cloud cover, and the polar day/night cycle. These features significantly influence the radiative environment of the Arctic as well as the ability to observe it. The remoteness of the Arctic from most of civilization makes large volumes of in situ observations difficult to collect, and so satellite observations are a critical tool for observing the region, such as those from Clouds and the Earth’s Radiant Energy System (CERES). But validating the satellite radiative flux estimates is difficult because of the lack of in situ measurements. A useful remedy is utilizing measurements from field campaigns, such as the year-long Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition during 2019-2020. The extensive high-quality surface radiative flux and meteorological measurements collected from MOSAiC provide a useful check on flux retrievals from CERES instruments. Previous work compared MOSAiC and CERES surface radiative fluxes during the 2020 melt season (April-September). Errors in CERES fluxes were related to errors in estimated atmospheric optical depth and surface albedo. We conduct a similar assessment of CERES surface flux retrievals using MOSAiC data, but for the months of October through March instead. As this time period is mostly during polar night and twilight, the focus of the study is on longwave surface fluxes. To better understand the reasons for errors in CERES fluxes, we use the large set of meteorological measurements also collected by MOSAiC, including surface temperature, thermodynamic vertical profiles, surface turbulent fluxes, and cloud properties. For example, one notable possible source of error in the CERES estimate of surface downwelling longwave flux is the estimate of cloud base height when compared with MOSAiC W-band radar measurements – an overestimate of cloud base height yields an underestimate of the downwelling flux on the order of tens of W m2.

J. Brant Dodson↗
NASA NTRSDate not supplied

Representing the Sub-Grid Heterogeneity of Surface Precipitation in A General Circulation Model

Precipitation variability on spatial scales smaller than a typical general circulation model (GCM) grid box is often neglected, with the grid-mean precipitation rate being applied uniformly to underlying surface tiles. This reduces the extrema seen by the surface, with corresponding reductions in surface runoff and altered land-atmosphere fluxes. Here we present a novel approach to stochastically distribute precipitation across sub-grid surface tiles within a GCM. Based on 4 km Stage IV precipitation data, the scheme parameterizes the dry area fraction as a function of grid mean precipitation rate, and defines the relative distribution of intensities across non-dry surface tiles. To incorporate memory and mimic the persistence of precipitating storms, the relative intensity assigned to each sub-grid tile is determined by an autoregressive process. Using single column experiments, the scheme is shown to reproduce observed precipitation statistics at the scale of model surface tiles. We also document impacts on surface hydrology and energy partitioning, with notable increases in precipitation runoff, surface temperature variance, and the Bowen ratio.

GCM↗
NASA NTRS2023

Radiative interaction of atmosphere and surface: write up with elements of code

In passive satellite remote sensing of the Earth, separation of the path radiance (atmosphere-only contribution) from the surface reflection remains a “significant challenge”. Recent literature names it among the gaps in radiative transfer (RT) topics that “require continued research in the near future”. The challenge comes from multiple reflections (bouncing) between the atmosphere and surface – radiative interaction. In this paper we use a known RT technique, the matrix-operator method (MOM), and a new modification of the monochromatic vector RT (vRT) code IPOL (Intensity and POLarization) to simulate the interaction of a plane-parallel atmosphere and a few widely used surface reflection models. Following the idea of the Green’s function method, IPOL no longer takes the surface model parameters on input. Instead, it provides the path radiance, and the atmospheric reflection and transmission matrices as output. Despite many RT codes use the MOM formalism, this output does not seem common. The surface reflection matrix is computed externally. Therefore, this paper extends the Green’s function atmospheric correction technique to the case of polarized light. Aiming clarity rather than performance, we explain in Python the structure of the surface matrices for the isotropic (Lambertian), directional unpolarized, and polarized ocean reflection models. We then combine these surface matrices and the precomputed IPOL output to get numerically accurate signal at the top of atmosphere (TOA) and test it vs. published benchmarks. Then, for each benchmark scenario we show how to get the surface from the TOA signal, i.e. perform the RT-based atmospheric correction.

radiative transfer↗
NASA NTRSDate not supplied

Towards a More Realistic Representation of NASA CERES-derived Surface Radiative Fluxes during Polar Night: A Comparison with the MOSAiC Field Campaign

The Arctic remains one of the more difficult regions observe, and so satellite observations are a critical tool for observing the region, such as those from Clouds and the Earth’s Radiant Energy System (CERES). But validating the satellite surface radiative flux estimates is difficult because of the lack of in situ measurements. The extensive high-quality surface radiative flux and meteorological measurements collected from MOSAiC provide a useful check on flux retrievals from CERES instruments. We compare MOSAiC and CERES surface radiative fluxes during October through March of 2019-2020 using the large set of meteorological measurements also collected by MOSAiC, specifically cloud properties. Previous work identified a significant source of error in the CERES estimate of surface downwelling longwave flux as the estimate of low level cloud amount when compared with MOSAiC W-band radar measurements. Continuing this work, we examine the effects of errors in cloud water path on surface radiative fluxes. When using all cloud conditions, errors in cloud water are also significantly correlated with surface radiative flux errors, though the size off the effect is only about half that of cloud amount. But when considering low cloud conditions only, the effects of cloud water and cloud amount are comparable. We compare MOSAiC and CERES surface radiative fluxes during October through March of 2019-2020 using the large set of meteorological measurements also collected by MOSAiC, specifically cloud properties. Previous work identified a significant source of error in the CERES estimate of surface downwelling longwave flux as the estimate of low level cloud amount when compared with MOSAiC W-band radar measurements. We further examine this source of error by examining selected case studies in which the disagreements in radiative fluxes and clouds are large.

J Brant Dodson↗
NASA NTRSDate not supplied

Extending the Duration of Crewed Stays on the Lunar Surface

NASA’s Artemis missions aim to return humans to the Moon for the first time since the Apollo Program. Unlike the Apollo missions, Artemis missions will take advantage of pre-emplaced assets on the lunar surface to support crewed exploration, science, and utilization. Although the initial Artemis surface missions are intended to keep crew on the lunar surface for durations ranging from several days to several weeks, crewed stays of longer periods may provide additional support toward NASA’s Moon to Mars Objectives, including long-term exploration and continuous human lunar presence. If mission durations are extended beyond the expected few weeks, the elements and concepts of operation for the lunar architecture will need to be capable of supporting that extension. This paper uses an integrated systems analysis perspective to examine the architectural considerations of extending the duration of human missions on the lunar surface. By identifying these key architectural considerations, this paper offers insight into how elements and operations might meet the demands of potential future mission concepts. This paper does not recommend changes to NASA’s lunar architecture, and it does not evaluate whether any mission concepts affect the relative satisfaction of the Moon to Mars Objectives. However, if crew do remain on the surface for progressively longer periods of time, the functions and capabilities provided by the assets supporting the crew may need to adjust to support the needs of those missions. The functions and capabilities identified as key to enable such extended duration missions include power generation and storage, logistics delivery, radiation mitigation, provision of medical and exercise capability, abort from the lunar surface, maintenance, and the provision of pressurized volume. For example, the medical capabilities available to the crew may become more extensive, and habitable elements may need to change to support longer crewed periods (and shorter quiescent periods). In some cases, these changes may be accomplished through alterations to use cases, operational changes, or the evolution of lunar surface elements, but in other cases, new elements may be preferable. By identifying key considerations for the functions and capabilities of notional lunar surface elements as the length of each crewed mission is extended from several days to continuous human presence on the Moon, this paper assesses how the elements of NASA’s lunar architecture might support the extension of mission durations. In addition, this analysis can help inform future evaluation of whether such extended duration missions improve NASA’s ability to address its Moon to Mars Objectives.

Garrett M. Carman↗
NASA NTRSDate not supplied

Improving Ocean Reanalyses and ENSO Forecasts By Assimilation of Rain-Corrected Satellite Sea Surface Salinity Using the GMOA S2s Forecast System

The ENSO phenomenon has a significant global socio-economic impact and has been the key focus for improving coupled ocean-atmosphere forecasts. Assimilation of satellite altimetry and subsurface temperature and salinity from (mostly) Argo help improve the initialization of the thermocline, while satellite SST aids in constraining surface heat-fluxes, leading to improved coupled system sub-seasonal to seasonal forecasts. However, few studies have focused on improving the near-surface density and mixing through satellite sea surface salinity (SSS) assimilation. The few ocean models that assimilate satellite SSS, bias correct to normalize towards the near-surface Argo data for expediency. This assumption is likely inadequate in rainy regions, where buoyant water forms a fresh surface lens. In previous work, we showed that adjusting SSS to bulk salinity (Sb) using the Rain Impact Model (RIM) of Santos-Garcia et al., 2014 improves the near-surface density and mixed layer depth, leading to deeper thermocline and improved NINO3.4 SST forecasts. We now utilize the Soil Moisture and Ocean Salinity rain-corrected (SMOS_RC) SSS, available in SMOS-CATDS products, to represent Sb more accurately at the first model layer (e.g., 5 m). Rather than a diffusivity model as RIM, SMOS_RC uses a statistical correction dependent on Integrated Multi-satellitE Retrievals for GPM (IMERG) rain rates, established on observed SMOS SSS decreases related to Sb in the presence of rain (Supply et al., 2020). For all experiments, all available along-track absolute dynamic topography and in situ observations are assimilated using the LETKF scheme (Penny et al., 2013). One reanalysis additionally assimilates SMOS SSS data as is, and a separate reanalysis assimilates SMOS_RC. We assess the impact on near-surface and subsurface dynamics by validating against observations and explore how SSS assimilation (SMOS vs SMOS_RC) impacts ENSO forecasts using the NASA GMAO Sub-seasonal to Seasonal coupled forecast system (S2S-v3, Molod et al. 2020). We show that improved estimates of density and near-surface mixing led to more accurate coupled air/sea interaction and better ENSO forecasts. The increased SSS, resulting from the removal of the instantaneous rain effect, modifies the ocean state by enhancing mixing and deepening the thermocline.

Veronica Ruiz Xomchuk↗
NASA NTRSDate not supplied

Enabling Universal Access to Power on the Lunar Surface

The National Aeronautics and Space Administration (NASA) Artemis Missions will return human astronauts to the lunar surface, demonstrate technologies that establish a sustained presence on the lunar surface and enable human missions to Mars, and help create a lunar commercial economy. Creating a sustained permanent presence on the lunar surface will require access to continuous and highly reliable power to support mission needs. During Artemis, lunar surface operations will evolve and grow over time (years), requiring an increase in the amount of power needed (100s of kW) and distance that the power must be transmitted (up to 10 km during early Artemis missions). A lunar commercial economy is likely to exceed this power demand to the MW level and distance in the 100s of km. This increased distance and demand for highly reliable power drives the need to create an electric power grid by connecting localized lunar power systems (e.g., habitats, in-situ resource utilization plants, etc.), each containing one or more loads and/or sources. Developing a lunar surface power grid will allow lunar surface operations to resemble electrical utility operations on Earth; it allows power to be generated where it is convenient and allows power to be consumed where it is convenient and required. A lunar surface electric power grid will facilitate the growth of a lunar commercial economy because it provides a means to connect new loads to an existing electrical power system. A common standardized interface to the grid and a set of standardized voltages is required to take full advantage of the benefits of an electric power grid, similar to the terrestrial power grid. NASA Glenn Research Center is leading an effort to create universal access to power through the development of the Universal Modular Interface Converter (UMIC). The UMIC is designed to have a common interface that connects sources and loads compliant with the International Space Power System Interoperability Standard (ISPSIS) to a higher voltage AC transmission system or power grid. This presentation will further discuss the evolution of power during the Artemis missions, challenges associated with creating a sustained presence on the lunar surface, progress made on the UMIC, and future opportunities for technology development and standards.

space power systems↗
NASA NTRSDate not supplied

Using Machine Learning to Estimate Surface-Level SO2 Concentrations from Satellite-Based Measurements

Sulfur dioxide (SO2) is a criteria air pollutant due to its contributions to aerosol formation, rainfall acidification, and harm to human health. The placement of air quality monitoring sites is typically biased towards urban areas, leaving large areas with very limited monitoring data. The Ozone Monitoring Instrument (OMI) has been used to provide estimates of SO2 vertical column densities (VCDs) globally at spatial resolution of 10s of kms once per day. OMI SO2 VCDs have been previously used to estimate surface SO2 concentrations using chemical transport model (CTM) simulations. The CTMs use estimated emissions and assimilated meteorological data, and simulate the chemical and physical processes that determine the vertical profile of SO2, which can be used to derive a ratio between the surface concentrations and VCDs. These models are complex, computationally expensive, and have large uncertainties in the simulated surface-to-VCD ratio due to biases in emissions and relatively coarse resolution. Machine learning techniques are comparatively easier to use, much less computationally expensive to use after training, and can produce more accurate estimations of surface concentrations than the CTM-based method. The interpretation of machine learning models often poses challenges, and in some cases, non-physical variables unrelated to SO2 are used as predictors. In this work, we create an artificial neural network (ANN) to relate OMI retrievals and archived GEOS-FP boundary layer heights to surface SO2 concentrations from the ChinaHighAirPollutants ChinaHighSO2 dataset (CHAP; Wei et al., 2023) on a seasonal average timescale from 2013-2018. Our model only utilizes five variables that are directly relevant to the satellite retrieval, lifetime, and spatial distribution of SO2. The model was trained on 16 seasons (four of each) with independent validation (one of each season) and testing datasets (one of each season) to avoid overfitting. Our ANN generates surface SO2 concentrations that are sensitive (slope = 0.51) and consistent (r = 0.74) with the CHAP data, but are underpredicted by an average of 1.2 ppbv with a mean absolute error of 2.2 ppbv. These results are better than recent studies utilizing the CTM method. To our knowledge, this is the best performing machine learning model that only uses physical variables to predict surface SO2. Our work demonstrates that a carefully constructed, simple ML model can accurately estimate surface-based SO2 concentrations from satellite VCD measurements, and this technique has future promise to expend to newer, higher resolution satellites and other air pollutants.

SO2, air quality, OMI, machine learning↗
DOE OSTI2022

Effect of Electropolishing on Nitrogen Doped and Undoped Niobium Surfaces

Cold electropolishing (EP) of a nitrogen-doped (N-doped) niobium (Nb) superconducting RF (SRF) cavity was found to improve its quality factor. In order to understand the effect of EP temperature on N-doped and undoped surfaces, a systematic EP study was conducted with 2/0 N-doped and heat-treated Nb samples in a beaker. The Nb samples were electropolished at different surface temperatures ranging from 0 to 42 C. The results showed that the doped surface was susceptible to the sample temperature during EP. EP resulted in the surface pitting on the doped samples where the number density of pits increased at a higher temperature. The surface results were compared with the surface of cutouts from a 9-cell cavity which was 2/0 N-doped and electropolished. This paper shows de-tailed surface features of the N-doped and undoped Nb surfaces electropolished at different temperatures.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2021

PREPARATION OF CLAY-COATED GLASS SURFACES FOR MICROFLUIDICS-BASED STUDY ON CLAY-FLUID INTERACTIONS

Unique characteristics of clay, even though make any clay abundant shales a good source of adsorbed gas, make them equally difficult to produce. The clay-water interaction can cause significant swelling and fines migration in the shale formation, both of which can significantly impair the overall hydrocarbon recovery from shale. Geomaterial micromodels, developed by functionalizing traditional glass or PDMS surface with geomaterials (e.g., calcite, quartz, clay) can represent the physico-chemical properties of the natural porous media and have been used during the last few years to understand and evaluate the solid-fluid physicochemical interactions. This study focuses on developing a clay-coated geomaterial surface and investigates the effect of base fluid's salinity on clay adsorption to the glass surface. Glass capillary tubes and straight channel borosilicate glass micromodels are coated with Illite clay minerals to represent the pore-scale clay chemistry of Caney Shale, a Mississippian unconventional play in Southern Oklahoma, USA. 10 wt.% of Illite clay slurries made with brines of four different salinities are used to coat the glass-capillary tubes to understand the effect of salinity in clay adsorption on the glass surface and overall coating quality. To achieve a stable coating and evaluate the impact of heat treatment on coating's stability, straight channel glass flow cells coated with Illite clay are heat-treated at low (25 °C) and high temperature (125 °C). Dynamic flooding tests were carried out with brines on the coated surface to evaluate the stability of the coating. The experiments' outcome indicated a strong relationship between the brine's salinity and the adsorption of clay particles on the glass surface. An increase in brine concentration resulted in improved adsorption of clay particles on the glass surface. Experiments involving heat treating the glass surface following the coating demonstrated significant improvement in the stability of the coating.

02 PETROLEUM↗
DOE OSTI2020

Adsorption of Non-Ionic Surfactant and Monoclonal Antibody on Siliconized Surface Studied by Neutron Reflectometry

The adsorption of monoclonal antibodies (mAbs) on hydrophobic surfaces is known to cause protein aggregation and degradation. Therefore, surfactants, such as Poloxamer 188, are widely used in therapeutic formulations to stabilize mAbs and protect mAbs from interacting with liquid-solid interfaces. Here, the adsorption of Poloxamer 188, one mAb and their competitive adsorption on a model hydrophobic siliconized surface is investigated with neutron scattering coupled with contrast variation to determine the molecular structure of adsorbed layers for each case. Small angle neutron scattering measurements of the affinity of Poloxamer 188 to this mAb indicate that there is negligible binding at these solution conditions. Neutron reflectometry measurements of the mAb show irreversible adsorption on the siliconized surface, which cannot be washed off with neat buffer. Poloxamer 188 can be adsorbed on the surface already occupied by mAb, which enables partial removal of some adsorbed mAb by washing with buffer. The adsorption of the surfactant introduces significant conformational changes for mAb molecules that remain on the surface. In contrast, if the siliconized surface is first saturated with the surfactant, no adsorption of mAb is observed. Competitive adsorption of mAb and Poloxamer 188 from solution leads to a surface dominantly occupied with surfactant molecules, whereas only a minor amount of mAb absorbs. These findings clearly indicate that Poloxamer 188 can protect against mAb adsorption as well as modify the adsorbed conformation of previously adsorbed mAb.

36 MATERIALS SCIENCE↗