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At least 1,369 records · Page 76
All sourcesNASA NTRSDOE OSTI
DOE OSTI2014

North American Board of Certified Energy Practitioners Final Report

The U.S. DOE’s Office of EERE National Solar Energy Technology Program (SETP) calls for a “National Accreditation and Certification Program for Installation and Acceptance of Photovoltaic Systems.” A near-term goal listed in the U.S. Photovoltaic Industry’s Roadmap, 2000 - 2020 is to work to establish standards, codes, and certifications which are essential for consumer protection and acceptance as part of the goal of building toward a viable future PV industry. This program paves the way for a voluntary national certification program for PV system practitioners and installers, initiation of the first steps toward certification of hardware, and reinforcement of all five of the technical objectives in the Systems category of SETPs Multi-Year technical Plan. Through this project, NABCEP will direct the continued initiation of and sustained implementation and administration of the NABCEP Solar PV Installer Certification Program (hereafter the “Program”). The NABCEP Program is a national, voluntary program designed to provide certification for those PV installers who demonstrate the requisite skills, abilities and knowledge typically required to install and maintain PV systems. The core document upon which the Program was developed and upon which the national exam is based, is referred to as the (Program) Task Analysis. It is a thorough descriptive document containing specific psychomotor and cognitive tasks for the purposes of identifying the types of training/assessment methods that apply. Psychomotor skills require measuring, assembling, fastening and related activities. Cognitive skills require knowledge processing, decision-making and computations. NABCEP effectively evaluates an applicant’s psychomotor skills through review of a candidate’s PV installations and hands-on training received. NABCEP evaluates the candidate’s cognitive skills through administration of its national Program exam. By first qualifying for and then obtaining the required passing score, NABCEP certificants receive an accreditation that upholds NABCEP’s standards of quality, compliance to applicable codes and safety in PV installation. The objectives of DOE’s National Solar Energy Technology Program (SETP) are intrinsic to NABCEP. As detailed in the PV Roadmap, the lifespan of a PV system is a function of reliability and value. PV system reliability is directly dependent upon the quality of components and, design, installation and maintenance of a system. The latter three are all core components of the NABCEP Task Analysis - accordingly NABCEP certified installers will be instrumental in improving reliability of systems through safe, code and manufacturer-compliant installation and necessary post-installation maintenance of PV systems. This will have the effect of ensuring and increasing the performance of installed systems and, as consumers realize the benefits of well-installed and maintained systems, increased demand will follow and manufacturers will respond - supporting further growth in the PV industry. Furthermore, as more NABCEP certified installers perform these installations and maintenance competently, additional installations (whole system re-installations) and unnecessary repairs can be avoided. This will drive down system costs. This combined with creation/enhancement of the DE-FG36-04GO14348/005 NABCEP Central Data Base of Installers – providing consumers with installation/maintenance service options will further reduce system costs and help meet the overall goal of reducing life cycle costs. As consumers receive more value from PV systems which are providing longer, trouble free, renewable energy, they will join the ranks of professionals and enthusiasts calling for reduced technological barriers to installation (particularly for grid-tied systems). States and utilities will react to pressure and begin easing onerous net-metering and other technological restrictions. The benefits of NABCEP’s Program will be evident to consumers, manufacturers, distributors, state energy officials and solar academic institutions. Consumers benefit through increased system performance and reduced costs. Manufacturers of PV and balance of system components as well as distributors support and benefit from NABCEP because of assurances that systems are installed in accordance to code (i.e., NEC) and their specifications, resulting in longer life. Collaborators including state energy officials (i.e., New York State Energy Research and Development Authority) benefit by knowing that rebate funds are spent on systems whose benefits will far exceed system costs. Program Objectives The improvements and advantages offered by a national voluntary certification program can only expand the horizons for photovoltaic applications.

14 SOLAR ENERGY↗
DOE OSTI2016

REPEATABILITY AND ACCURACY OF EXOPLANET ECLIPSE DEPTHS MEASURED WITH POST-CRYOGENIC SPITZER

We examine the repeatability, reliability, and accuracy of differential exoplanet eclipse depth measurements made using the InfraRed Array Camera (IRAC) on the Spitzer Space Telescope during the post-cryogenic mission. We have re-analyzed an existing 4.5 μ m data set, consisting of 10 observations of the XO-3b system during secondary eclipse, using seven different techniques for removing correlated noise. We find that, on average, for a given technique, the eclipse depth estimate is repeatable from epoch to epoch to within 156 parts per million (ppm). Most techniques derive eclipse depths that do not vary by more than a factor 3 of the photon noise limit. All methods but one accurately assess their own errors: for these methods, the individual measurement uncertainties are comparable to the scatter in eclipse depths over the 10 epoch sample. To assess the accuracy of the techniques as well as to clarify the difference between instrumental and other sources of measurement error, we have also analyzed a simulated data set of 10 visits to XO-3b, for which the eclipse depth is known. We find that three of the methods (BLISS mapping, Pixel Level Decorrelation, and Independent Component Analysis) obtain results that are within three times the photon limit of the true eclipse depth. When averaged over the 10 epoch ensemble, 5 out of 7 techniques come within 60 ppm of the true value. Spitzer exoplanet data, if obtained following current best practices and reduced using methods such as those described here, can measure repeatable and accurate single eclipse depths, with close to photon-limited results.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2026

Reliability Assessment of Cooling Fans for PV Inverters: Testing, Modeling, and Case Studies

The reliability of photovoltaic (PV) inverters is critical for long-term solar system performance, with cooling fan failures frequently leading to costly downtime. While much research exists on general cooling fan reliability, little attention has been given to fans operating within PV inverters and their unique environmental challenges. Here, this article proposes a comprehensive methodology to address this gap. First, a failure mode and effects analysis is performed on fans to identify the key failure mechanisms in PV applications, their corresponding stressors, and the models necessary for lifetime prediction. Second, an accelerated life test is designed and conducted to collect valuable experimental data for PV inverter fans in a reasonable amount of time. Third, a mathematical conversion of dynamic mission profiles into effective constant stress levels is derived. Fourth, case studies are given, showcasing lifetime estimates that account for geographic variations in mission profile data. The results demonstrate that this integrated approach leads to an accurate reliability assessment for PV inverter cooling fans.

accelerated life testing (ALT)↗
DOE OSTI2012

Comparison of Triton SODAR Data to Meteorological Tower Wind Measurement Data in Hebei Province, China

With the increased interest in remote sensing of wind information in recent years, it is important to determine the reliability and accuracy of new wind measurement technologies if they are to replace or supplement conventional tower-based measurements. In view of this, HydroChina Corporation and the United States National Renewable Energy Laboratory (NREL) conducted a comparative test near awind farm in Hebei Province, China. We present the results of an analysis characterizing the measurement performance of a state-of-the-art Sound Detection and Ranging (sodar) device when compared to a traditional tower measurement program. NREL performed the initial analysis of a three-month period and sent the results to HydroChina. When another month of data became available, HydroChina andtheir consultant Beijing Millenium Engineering Software (MLN) repeated NREL's analysis on the complete data set, also adding sensitivity analysis for temperature, humidity, and wind speed (Section 6). This report presents the results of HydroChina's final analysis of the four-month period.

17 WIND ENERGY↗
DOE OSTI2016

Degradation and corresponding failure mechanism for GaN-based LEDs

The degradation behaviors of high power GaN-based vertical blue LEDs on Si substrates were measured using in-situ accelerated life test. The results show that the dominant failure mechanism would be different during the operation. Besides that, the corresponding associated failure mechanisms were investigated systematically by using different analysis technologies, such as Scan Electron Microscopy, Reflectivity spectroscopy, Transient Thermal Analysis, Raman Spectra, etc. It is shown that initially, the failure modes were mainly originated from the semiconductor die and interconnect, while afterwards, the following serious deterioration of the radiant fluxes was attributed to the package. The interface material and quality, such as die attach and frame, play an important role in determining the thermal performance and reliability. In addition, the heating effect during the operation will also release the compressive strain in the chip. These findings will help to improve the reliability of GaN-based LEDs, especially for the LEDs with vertical structure.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2013

PLANETARY CANDIDATES OBSERVED BY KEPLER. III. ANALYSIS OF THE FIRST 16 MONTHS OF DATA

New transiting planet candidates are identified in 16 months (2009 May-2010 September) of data from the Kepler spacecraft. Nearly 5000 periodic transit-like signals are vetted against astrophysical and instrumental false positives yielding 1108 viable new planet candidates, bringing the total count up to over 2300. Improved vetting metrics are employed, contributing to higher catalog reliability. Most notable is the noise-weighted robust averaging of multi-quarter photo-center offsets derived from difference image analysis that identifies likely background eclipsing binaries. Twenty-two months of photometry are used for the purpose of characterizing each of the candidates. Ephemerides (transit epoch, T {sub 0}, and orbital period, P) are tabulated as well as the products of light curve modeling: reduced radius (R {sub P}/R {sub *}), reduced semimajor axis (d/R {sub *}), and impact parameter (b). The largest fractional increases are seen for the smallest planet candidates (201% for candidates smaller than 2 R {sub Circled-Plus} compared to 53% for candidates larger than 2 R {sub Circled-Plus }) and those at longer orbital periods (124% for candidates outside of 50 day orbits versus 86% for candidates inside of 50 day orbits). The gains are larger than expected from increasing the observing window from 13 months (Quarters 1-5) to 16 months (Quarters 1-6) even in regions of parameter space where one would have expected the previous catalogs to be complete. Analyses of planet frequencies based on previous catalogs will be affected by such incompleteness. The fraction of all planet candidate host stars with multiple candidates has grown from 17% to 20%, and the paucity of short-period giant planets in multiple systems is still evident. The progression toward smaller planets at longer orbital periods with each new catalog release suggests that Earth-size planets in the habitable zone are forthcoming if, indeed, such planets are abundant.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Techno-economic analysis of advanced small modular nuclear reactors

Here, small modular nuclear reactors (SMRs) represent a robust opportunity to develop low-carbon and reliable power with the potential to meet cost parity with conventional power systems. This study presents a detailed, bottom-up economic evaluation of a 12 × 77 MW e (924 MW e total) light-water SMR (LW-SMR) plant, a 4 × 262 MW e (1,048 MW e ) gas-cooled SMR (GC-SMR) plant, and a 5 × 200 MW e (1,000 MW e total) molten salt SMR (MS-SMR) plant. Cost estimates are derived from equipment costs, labor hours, material inputs, and process-engineering models. The advanced SMRs are compared to natural gas combined cycle plants with and without post-combustion carbon capture and a conventional large nuclear reactor. Overnight capital cost (OCC) and levelized cost of energy (LCOE) estimates are developed. The OCC of the LW-SMR, GC-SMR, and MS-SMR are found to be $\$4,844$/kW, $\$4,355$/kW, and $\$3,985$/kW respectively. The LCOE of the LW-SMR, GC-SMR, and MS-SMR are found to be $\$89.6$/MWh, $\$81.5$/MWh, and $\$80.6$/MWh respectively. A Monte Carlo analysis is performed, for which the OCC and construction time of the LW-SMR is found to have a lower mean and standard deviation than a conventional large reactor. The LW-SMR OCC is found to have a mean of $\$5,233$/kW with a standard deviation of $\$658$/kW and a 90 % probability of remaining between $\$4,254$/kW and $\$6,399$/kW, while the construction duration is found to have a mean of 4.5 years with a standard deviation of 0.8 years and a 90 % probability of remaining between 3.4 and 6.0 years. The economic impact of economies of scale, simplification, modularization, and construction time for SMRs are discussed. Additionally, policy implications for direct SMR capital subsidies and the impact of a carbon tax on natural gas emissions are explored.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2015

Optical coherence tomography for nondestructive evaluation of fuel rod degradation

Nuclear power plants regularly inspect fuel rods to ensure safe and reliable operation. Excessive corrosion can cause fuel failures which can have significant repercussions for the plant, including impacts on plant operation, worker exposure to radiation, and the plant's INPO rating. While plants typically inspect for fuel rod corrosion using eddy current techniques, these techniques have known issues with reliability in the presence of tenacious, ferromagnetic crud layers that can deposit during operation, and the nondestructive evaluation (NDE) inspection results can often be in error by a factor of 2 or 3. For this reason, alternative measurement techniques, such as Optical Coherence Tomography (OCT), have been evaluated that are not sensitive to the ferromagnetic nature of the crud. This paper demonstrates that OCT has significant potential to characterize the thickness of crud layers that can deposit on the surfaces of fuel rods during operation. Physical trials have been performed on simulated crud samples, and the resulting data show an apparent correlation between the crud layer thickness and the OCT signal.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2013

Quantitative description of microstructure defects in hexagonal boron nitrides using X-ray diffraction analysis

A routine for simultaneous quantification of turbostratic disorder, amount of puckering and the dislocation and stacking fault density in hexagonal materials was proposed and tested on boron nitride powder samples that were synthesised using different methods. The routine allows the individual microstructure defects to be recognised according to their effect on the anisotropy of the X-ray diffraction line broadening. For quantification of the microstructure defects, the total line broadening is regarded as a linear combination of the contributions from the particular defects. The total line broadening is obtained from the line profile fitting. As testing material, graphitic boron nitride (h-BN) was employed in the form of hot-isostatically pressed h-BN, pyrolytic h-BN or a h-BN, which was chemically vapour deposited at a low temperature. The kind of the dominant microstructure defects determined from the broadening of the X-ray diffraction lines was verified by high resolution transmission electron microscopy. Their amount was attempted to be verified by alternative methods. - Highlights: • Reliable method for quantification of microstructure defects in BN was suggested. • The method is based on the analysis of anisotropic XRD line broadening. • This XRD line broadening is unique and characteristic of the respective defect. • Thus, the quantification of coexistent microstructure defects is possible. • The method was tested on hexagonal BN, which was produced by different techniques.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Microstructure Characteristics and Comparative Analysis of Constitutive Models for Flow Stress Prediction of Inconel 718 Alloy

An accurate constitutive model is essential for analyzing deformation behavior of material and reliable numerical simulations in metal forming processes. In this study, hot tensile tests of Inconel 718 alloy have been conducted over a wide range of temperatures (300-973 K at an interval of 100 K), strains (0.01-0.3 at an interval of 0.01) and quasi-static strain rates (0.0001, 0.001, 0.01 s{sup −1}). Flow stress behavior is significantly affected by test temperatures and strain rates. Microstructure characteristics of deformed test specimens have been examined using scanning electron microscope and electron backscatter diffraction (EBSD). The fractography study revealed that fracture is mix-mode type, i.e., ductile and brittle. Subsequently, EBSD analysis shown that dynamic recrystallization mechanism is more pronounced at a higher temperature. Furthermore, four constitutive models, namely modified Cowper–Symonds, modified Johnson Cook, modified Zerillie-Armstrong and integrated Johnson Cook–Zerillie-Armstrong (JC-ZA) models have been investigated for flow stress prediction. Capability of models has been evaluated based on the correlation coefficient (R), average absolute error (Δ) and its standard deviation (δ). Accurate prediction of flow stress behavior is found by integrated JC-ZA model with R = 0.9873, Δ = 2.44 and δ = 4.08%.

36 MATERIALS SCIENCE↗
DOE OSTI2021

PV in the circular economy, a dynamic framework analyzing technology evolution and reliability impacts

Rapid, terawatt-scale deployment of photovoltaic (PV) modules is required to decarbonize the energy sector. Despite efficiency and manufacturing improvements, material demand will increase, eventually resulting in waste as deployed modules reach end of life. Circular choices for decommissioned modules could reduce waste and offset virgin materials. We present PV ICE, an open-source python framework using modern reliability data, which tracks module material flows throughout PV life cycles. We provide dynamic baselines capturing PV module and material evolution. PV ICE includes multimodal end of life, circular pathways, and manufacturing losses. We present a validation of the framework and a sensitivity analysis. Results show that manufacturing efficiencies strongly affect material demand, representing >20% of the 9 million tons of waste cumulatively expected by 2050. Reliability and circular pathways represent the best opportunities to reduce waste by 56% while maintaining installed capacity. Shorter-lived modules generate 81% more waste and reduce 2050 capacity by 6%.

14 SOLAR ENERGY↗
DOE OSTI2023

Scaling for Nuclear Reactor System: Overview

A scaling analysis is essential for predicting the behavior of a reactor system under various operating conditions, as well as for ensuring safe and reliable experimentation and adequate dataset generation for supporting the system code model development and assessment in accordance with USNRC guidelines 1.203. Testing and modeling can be carried out at various scales, from small test units to full-scale reactors, to validate the predictions produced by the analysis. However, due to the cost and challenges associated with full-scale testing, the nuclear industry uses scaled test facilities—integral effect test (IET) and separate effect test (SET)—to identify potential design issues and optimize the design to ensure regulatory compliance for safer operation and anticipated accident management. In general, IET facilities are non-nuclear thermal hydraulics test facilities. In contrast, SET facilities can be non-nuclear testing (e.g., steam generator, containment, pump system SETs) and nuclear testing (mostly fuel-material irradiation testing). IETs are used to study the system-level thermal-hydraulic behavior of the reactor coolant system (RCS) under different anticipated operational occurrences (AOOs) and design basis accidents (DBAs) such as loss-of-coolant-accident (LOCA) and loss-of-power (i.e., station blackout) and loss-of-flow (i.e., failure of RCS pump). Several LOCA scenarios could happen in reactor DBAs, such as main steam line break (MSLB), SG tube rapture (SGTR), break in direct vessel injection (DVI), and other small breaks LOCA. Scaling analysis determines the appropriate size and operating conditions for the test facility. This involves analyzing the system's thermal-hydraulic behavior at different scales and identifying the key parameters that affect the thermal-hydraulic behavior of the reactor. These key parameters can be identified so that the scaled facility can replicate the expected conditions in a prototypical setting. The scaled facility can simulate the same flow rates, pressure gradients, heat transfer coefficients, and fluid properties as the prototype. Scaling analysis is used to ensure that the results from these tests can be scaled up to predict the behavior of a full-scale prototype with an acceptable range of scaling distortions.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2024

Surrogate-assisted optimization under uncertainty for design for remanufacturing considering material price volatility

Remanufacturing is a well-established end-of-life (EOL) strategy that promises significant savings in energy and carbon emissions. However, the current design practices are not remanufacturing-inclusive, i.e., the majority of products are designed for a single life cycle. As a result, potential products that can sustain multiple life cycles are deprived of additional benefits of being designed for remanufacturing, such as reduced material usage, lower cost, and improved environmental impact. Moreover, the uncertainty in design, material selection, and economics are not considered to produce remanufacturable designs. Accordingly, this research proposes a design for remanufacturing (DfRem) framework that accounts for design uncertainty and material price volatility. The framework systematically explores the design space, performs design optimization under uncertainty, followed by topology optimization to provide additional mass savings, and finally, a price volatility analysis for plausible design material choices. The candidate designs are evaluated based on their design mass, material price volatility, failure mode characteristics, carbon footprint, and embodied energy impacts. The proposed framework's utility is demonstrated via the use of an engine cylinder head case study subjected to thermo-mechanical loads along with fatigue and wear failure. Considering grey cast iron and aluminum alloy as the design material choices, it was found that the cast iron design reduced the initial design mass by 6% as opposed to a 5% decrease for aluminum. On the other hand, about 8% area of the cast iron design failed due to fatigue, compared to 3% for aluminum. Here, we further observed that although the aluminum design provided better mechanical performance than the cast iron design, this material was more expensive and volatile in price.

36 MATERIALS SCIENCE↗
DOE OSTI2012

Isolation of rat adrenocortical mitochondria

Highlights: Black-Right-Pointing-Pointer A method for isolation of adrenocortical mitochondria from the adrenal gland of rats is described. Black-Right-Pointing-Pointer The purified isolated mitochondria show excellent morphological integrity. Black-Right-Pointing-Pointer The properties of oxidative phosphorylation are excellent. Black-Right-Pointing-Pointer The method increases the opportunity of direct analysis of adrenal mitochondria from small animals. -- Abstract: This report describes a relatively simple and reliable method for isolating adrenocortical mitochondria from rats in good, reasonably pure yield. These organelles, which heretofore have been unobtainable in isolated form from small laboratory animals, are now readily accessible. A high degree of mitochondrial purity is shown by the electron micrographs, as well as the structural integrity of each mitochondrion. That these organelles have retained their functional integrity is shown by their high respiratory control ratios. In general, the biochemical performance of these adrenal cortical mitochondria closely mirrors that of typical hepatic or cardiac mitochondria.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2013

A 2.5D boundary element formulation for modeling damped waves in arbitrary cross-section waveguides and cavities

Highlights: •Dispersive properties of viscoelastic waveguides and cavities are computed using a regularized 2.5D BEM. •Linear viscoelasticity is introduced at the constitutive level by means of frequency dependent complex moduli. •A contour integral algorithm is used to solve the nonlinear eigenvalue problem. •The Sommerfeld radiation condition is used to select the permissible Riemann sheets. •Attenuation of surface waves in cavities approaches the attenuation of Rayleigh waves. -- Abstract: A regularized 2.5D boundary element method (BEM) is proposed to predict the dispersion properties of damped stress guided waves in waveguides and cavities of arbitrary cross-section. The wave attenuation, induced by material damping, is introduced using linear viscoelastic constitutive relations and described in a spatial manner by the imaginary component of the axial wavenumber. The discretized dispersive wave equation results in a nonlinear eigenvalue problem, which is solved obtaining complex axial wavenumbers for a fixed frequency using a contour integral algorithm. Due to the singular characteristics and the multivalued feature of the wave equation, the requirement of holomorphicity inside the contour region over the complex wavenumber plane is fulfilled by the introduction of the Sommerfeld branch cuts and by the choice of the permissible Riemann sheets. A post processing analysis is developed for the extraction of the energy velocity of propagative guided waves. The reliability of the method is demonstrated by comparing the results obtained for a rail and a bar with square cross-section with those obtained from a 2.5D Finite Element formulation also known in literature as Semi Analytical Finite Element (SAFE) method. Next, to show the potential of the proposed numerical framework, dispersion properties are predicted for surface waves propagating along cylindrical cavities of arbitrary cross-section. It is demonstrated that the attenuation of surface waves approaches asymptotically the attenuation of Rayleigh waves.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2026

59 Co(p,X) spallation reaction cross sections for 250 MeV to 2 GeV protons

Cobalt is an advantageous target for probing the physics of nuclear spallation, because it is a naturally mono-isotopic element ( 59 Co), and its per-nucleon binding energy (BE/A = 8.768 MeV) is near the maximum value for all nuclei. We measured nuclear spallation cross sections for the 59 Co(p,X) reaction at five kinetic energies ranging from 250 MeV to 2 GeV. Cross sections for the production of 58 Co, 57 Co, 57 Mn, 56 Co, 56 Mn, 56 Cr, 55 Fe, 53 Fe, 54 Mn, 52 Mn, 51 Cr, 49 Cr, 48 V, 47 Sc, 46 Sc, 44 Sc, and 44 Scm are reported. Where comparable data exist in the EXFOR reaction database, we find that our measured cross sections generally agree. In many cases, we provide data for reactions or energies not currently reported in EXFOR. Our cross sections also provide evidence for the presence of α-clusters within the 59 Co nucleus, a surprising result given the asymmetry in Z (27) and N (32) for this nucleus. Finally, we use our measurements to evaluate the accuracy of spallation cross section simulations from GEANT4-based radiation transport toolkit, performed with the INCLXX-, Bertini-, and Binary-ion-cascade (BIC) based physics lists. This benchmarking activity revealed that the simulations overestimated the cross sections by a factor of ∼2–4 on average, and that the INCL-XX physics list provides the most reliable results. This evaluation informs the selection of the GEANT4 physics lists used for the analysis of data from NASA’s Psyche mission, which will measure γ rays and neutrons resulting from spallation reactions occurring on the surface of an asteroid whose surface is thought to be rich in iron-nickel metal.

43 PARTICLE ACCELERATORS↗
DOE OSTI2019

Estimation of Syringyl Units in Wood Lignins by FT-Raman Spectroscopy

Syringyl (S) lignin content and the syringyl-to-guaiacyl (S/G) lignin ratio are important characteristics of wood and lignocellulosic biomass. While numerous methods are available for estimating S lignin units and the S/G ratio, in this work, a new method based on Raman spectroscopy that uses the 370 cm –1 Raman band-area intensity (370-area) was developed. The reliability of the Raman method for determining S content was first tested by the quantitative analysis of three syringyl lignin models by sampling them, separately, in dioxane and in Avicel. Good linear correlations between the 370 cm –1 intensity and model concentrations were obtained. Next, the percent syringyl (%S) lignin units in various woods were measured by correlating the 370 cm –1 Raman intensity data with values of S units in lignin determined by three regularly used methods, namely, thioacidolysis, DFRC, and 2D-HSQC NMR. The former two methods take into account only the monomers cleaved from β–O–4-linked lignin units, whereas the NMR method reports S content on the whole cell wall lignin. When the 370-area intensities and %S values from the regularly used methods were correlated, good linear correlations were obtained (R 2 = 0.767, 0.731, and 0.804, respectively, for the three methods). The correlation with the highest R 2 , i.e., with the 2D NMR approach, is introduced for estimating S units in wood lignins by Raman spectroscopy as, in principle, both represent the whole cell wall lignin and not just the portion of lignin that gets cleaved to release monomers. The Raman analysis method is quick, uses minimal harmful chemicals, is carried out nondestructively, and is insensitive to the wet or dry state of the sample. The only limitations are that the sample of wood contains at least 30% S and not be significantly fluorescent, although the latter can be mitigated in some cases.

09 BIOMASS FUELS↗