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At least 1,369 records · Page 76

Can We Rely on Satellite Visible/Infrared Microphysical Retrievals of Boundary Layer Clouds in Partially Cloudy Scenes? Implications for Climate Research

This study addresses the longstanding question of the reliability of gridded visible/infrared satellite cloud properties in partially cloudy scenes. By using in-situ cloud probes and airborne Research Scanning Polarimeter (RSP) observations, we analyze bias changes in satellite retrievals from the Spinning Enhanced Visible Infra-Red Imager (SEVIRI) geostationary sensor during the ORACLES campaign. Biases in cloud optical depth (τ) and droplet effective radius (r e ) modestly change for cloud area fraction greater than 35%. The agreement between SEVIRI and RSP r e substantially improves when the retrievals are averaged after removing pixels with τ < 3.0, yielding biases indistinguishable from overcast scenes. In addition, satellite and RSP show an excellent agreement for closed- and open-cell stratocumulus clouds, showing that the satellite retrievals capture spatial changes of r e , and confirming that satellites can faithfully reproduce real physical features for optically thick and partially cloudy scenes. We demonstrate that a simple methodology can minimize uncertainties in satellite-based climate studies.

Painemal, David [NASA Langley Research Center, Ham↗

Polariton panorama

Abstract In this brief review, we summarize and elaborate on some of the nomenclature of polaritonic phenomena and systems as they appear in the literature on quantum materials and quantum optics. Our summary includes at least 70 different types of polaritonic light–matter dressing effects. This summary also unravels a broad panorama of the physics and applications of polaritons. A constantly updated version of this review is available at https://infrared.cni.columbia.edu .

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Remote Sensing of Cloud Top Heights Using the Research Scanning Polarimeter

Clouds cover roughly two thirds of the globe and act as an important regulator of Earth's radiation budget. Of these, multilayered clouds occur about half of the time and are predominantly two-layered. Changes in cloud top height (CTH) have been predicted by models to have a globally averaged positive feedback, however observational changes in CTH have shown uncertain results. Additional CTH observations are necessary to better and quantify the effect. Improved CTH observations will also allow for improved sub-grid parameterizations in large-scale models and accurate CTH information is important when studying variations in freezing point and cloud microphysics. NASA's airborne Research Scanning Polarimeter (RSP) is able to measure cloud top height using a novel multi-angular contrast approach. RSP scans along the aircraft track and obtains measurements at 152 viewing angles at any aircraft location. The approach presented here aggregates measurements from multiple scans to a single location at cloud altitude using a correlation function designed to identify the location-distinct features in each scan. During NASAs SEAC4RS air campaign, the RSP was mounted on the ER-2 aircraft along with the Cloud Physics Lidar (CPL), which made simultaneous measurements of CTH. The RSPs unique method of determining CTH is presented. The capabilities of using single and combinations of channels within the approach are investigated. A detailed comparison of RSP retrieved CTHs with those of CPL reveal the accuracy of the approach. Results indicate a strong ability for the RSP to accurately identify cloud heights. Interestingly, the analysis reveals an ability for the approach to identify multiple cloud layers in a single scene and estimate the CTH of each layer. Capabilities and limitations of identifying single and multiple cloud layers heights are explored. Special focus is given to sources of error in the method including optically thin clouds, physically thick clouds, multi-layered clouds as well as cloud phase. When determining multi-layered CTHs, limits on the upper clouds opacity are assessed.

Cloud height indicators↗

Platform for probing radiation transport properties of hydrogen at conditions found in the deep interiors of red dwarfs

We describe an experimental concept at the National Ignition Facility for specifically tailored spherical implosions to compress hydrogen to extreme densities (up to ∼800× solid density, electron number density ne∼4×1025 cm−3) at moderate temperatures (T∼200 eV), i.e., to conditions, which are relevant to the interiors of red dwarf stars. The dense plasma will be probed by laser-generated x-ray radiation of different photon energy to determine the plasma opacity due to collisional (free–free) absorption and Thomson scattering. The obtained results will benchmark radiation transport models, which in the case for free–free absorption show strong deviations at conditions relevant to red dwarfs. This very first experimental test of free–free opacity models at these extreme states will help to constrain where inside those celestial objects energy transport is dominated by radiation or convection. Moreover, our study will inform models for other important processes in dense plasmas, which are based on electron–ion collisions, e.g., stopping of swift ions or electron–ion temperature relaxation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Observation of Reverse Saturable Absorption of an X-ray Laser

A nonlinear absorber in which the excited state absorption is larger than the ground state can undergo a process called reverse saturable absorption. It is a well-known phenomenon in laser physics in the optical regime, but is more difficult to generate in the x-ray regime, where fast nonradiative core electron transitions typically dominate the population kinetics during light matter interactions. Here, we report the first observation of decreasing x-ray transmission in a solid target pumped by intense x-ray free electron laser pulses. The measurement has been made below the K-absorption edge of aluminum, and the x-ray intensity ranges are 10 16 –10 17 W=cm 2 . It has been confirmed by collisional radiative population kinetic calculations, underscoring the fast spectral modulation of the x-ray pulses and charge states relevant to the absorption and transmission of x-ray photons. The processes shown through detailed simulations are consistent with reverse saturable absorption, which would be the first observation of this phenomena in the x-ray regime. These light matter interactions provide a unique opportunity to investigate optical transport properties in the extreme state of matters, as well as affording the potential to regulate ultrafast x-ray freeelectron laser pulses.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Gamma Irradiation of Novel Optical Glasses at Elevated Temperature

Advanced Small Modular Reactors (AdvSMRs) are considered important future energy sources. However, in-vessel radiation fluxes are high and demands infrared (IR) optical fiberbased chemical sensing at temperatures that often exceed 400°C. This is a challenging environment for many current IR glasses, including covalently-bonded selenides and tellurides, such as As2Se3 and GeTe2, due their glass transition temperatures (Tg) being on the order of 200-350 °C. This work focuses on ?-irradiation affects at high temperatures on refractory ionic bonding based chalcogenide glasses in the BaS-La2S3-GeS2 system. Optical and selected physical properties were characterized before and after irradiation. It was found that both GeS2 and the 20BaS + 20La2S3 + 60GeS2 composition (in mole%) have minimal property changes when irradiated at 2.5 MGy cumulative dose at 300 °C. Sample density showed the largest characteristic change where densities initially decreased at 2 kGy dose, and then recovered at the highest dose of 2.5 MGy, resulting in an overall density change between 0.3 to 2%, depending on sample and composition. This work suggests the BaS-La2S3-GeS2 system as one for continued exploration as high temperature IR fiber sensors in radiation environments.

Gamma Irradiation, Novel Optical Glasses, Elevated↗

Crystal growth of new high light yield halide perovskite scintillator RbSrI 3

X-ray radiography systems are a key national security technology enabling non-invasive cargo screening. However, the scintillators currently used in these systems have limitations in performance that prompt research for new suitable materials. Here, in this work, crystal growth, physical properties, and optical and scintillation properties of a new halide perovskite scintillator RbSrI 3 were investigated for the first time. The melting point was determined to be 453 °C. Divalent europium and ytterbium were investigated as potential luminescent activators. Light yield and energy resolution of RbSrI 3 :Eu 5 mol% was 78,700 ph/MeV and 2.8 % at 662 keV, and that of RbSrI 3 :Yb 0.5 mol% was 24,000 ph/MeV and 4.9 % at 662 keV.

36 MATERIALS SCIENCE↗

Environmentally friendly preparation of nanoparticles for organic photovoltaics

Aqueous nanoparticle dispersions were prepared from a conjugated polymer poly[thiophene-2,5-diyl-alt-5,10-bis((2-hexyldecyl)oxy)dithieno[3,2-c:3',2'-h][1,5]naphthyridine-2,7-diyl] (PTNT) and fullerene blend utilizing chloroform as well as a non-chlorinated and environmentally benign solvent, o-xylene, as the miniemulsion dispersed phase solvent. The nanoparticles (NPs) in the solid-state film were found to coalesce and offered a smooth surface topography upon thermal annealing. Organic photovoltaics (OPVs) with photoactive layer processed from the nanoparticle dispersions prepared using chloroform as the miniemulsion dispersed phase solvent were found to have a power conversion efficiency (PCE) of 1.04%, which increased to 1.65% for devices utilizing NPs prepared from o-xylene. Physical, thermal and optical properties of NPs prepared using both chloroform and o-xylene were systematically studied using dynamic mechanical thermal analysis (DMTA) and photoluminescence (PL) spectroscopy and correlated to their photovoltaic properties. The PL results indicate different morphology of NPs in the solid state were achieved by varying miniemulsion dispersed phase solvent.

14 SOLAR ENERGY↗

High-Throughput Open-Air Plasma Activation of Metal-Oxide Thin Films with Low Thermal Budget

Sputter-processed oxide films are usually annealed at high temperature (activation process) to achieve stable electrical characteristics through the formation of strong metal-oxide chemical bonds. For instance, indium– gallium–zinc oxide (IGZO) films typically need a thermal treatment at 300 °C for ≥1 h as an activation process. We introduce an open-air plasma treatment (OPT) to rapidly and effectively activate sputter-processed IGZO films. The OPT effectively induces metal-oxide chemical bonds in IGZO films at temperatures as low as 240 °C, with a dwell time on the order of a second. Furthermore, by controlling the plasma-processing conditions (scan speed, distance α between plasma nozzle and samples, and gas flow rate), the electrical characteristics and the microstructure of the IGZO films can be easily tuned. Finally, OPT can be utilized to implement a selective activation process. Plasma-treated IGZO thin-film transistors (TFTs) display comparable electrical characteristics to those of conventionally thermal treated IGZO TFTs. Through in-depth optical, chemical, and physical characterizations, we validate that OPT simultaneously dissociates weak chemical bonds by UV radiation and ion bombardment and reestablishes the metal-oxide network by radical reaction and OPT-induced heat.

36 MATERIALS SCIENCE↗

Accessing the exceptional points of parity-time symmetric acoustics

Parity-time (PT) symmetric systems experience phase transition between PT exact and broken phases at exceptional point. These PT phase transitions contribute significantly to the design of single mode lasers, coherent perfect absorbers, isolators, and diodes. However, such exceptional points are extremely difficult to access in practice because of the dispersive behaviour of most loss and gain materials required in PT symmetric systems. Here we introduce a method to systematically tame these exceptional points and control PT phases. Our experimental demonstration hinges on an active acoustic element that realizes a complex-valued potential and simultaneously controls the multiple interference in the structure. The manipulation of exceptional points offers new routes to broaden applications for PT symmetric physics in acoustics, optics, microwaves and electronics, which are essential for sensing, communication and imaging.

42 ENGINEERING↗

Morphology and mixing state of individual freshly emitted wildfire carbonaceous particles

Biomass burning is one of the largest sources of carbonaceous aerosols in the atmosphere, significantly affecting earth’s radiation budget and climate. Tar balls, abundant in biomass burning smoke, absorb sunlight and have highly variable optical properties, typically not accounted for in climate models. Here we analyse single biomass burning particles from the Las Conchas fire (New Mexico, 2011) using electron microscopy. We show that the relative abundance of tar balls (80%) is 10 times greater than soot particles (8%). We also report two distinct types of tar balls; one less oxidized than the other. Furthermore, the mixing of soot particles with other material affects their optical, chemical and physical properties. We quantify the morphology of soot particles and classify them into four categories: B50% are embedded (heavily coated), B34% are partly coated, B12% have inclusions andB4% are bare. Inclusion of these observations should improve climate model performances.

09 BIOMASS FUELS↗

Links between physical and chemical weathering inferred from a 65-m-deep borehole through Earth’s critical zone

Abstract As bedrock weathers to regolith – defined here as weathered rock, saprolite, and soil – porosity grows, guides fluid flow, and liberates nutrients from minerals. Though vital to terrestrial life, the processes that transform bedrock into soil are poorly understood, especially in deep regolith, where direct observations are difficult. A 65-m-deep borehole in the Calhoun Critical Zone Observatory, South Carolina, provides unusual access to a complete weathering profile in an Appalachian granitoid. Co-located geophysical and geochemical datasets in the borehole show a remarkably consistent picture of linked chemical and physical weathering processes, acting over a 38-m-thick regolith divided into three layers: soil; porous, highly weathered saprolite; and weathered, fractured bedrock. The data document that major minerals (plagioclase and biotite) commence to weather at 38 m depth, 20 m below the base of saprolite, in deep, weathered rock where physical, chemical and optical properties abruptly change. The transition from saprolite to weathered bedrock is more gradational, over a depth range of 11–18 m. Chemical weathering increases steadily upward in the weathered bedrock, with intervals of more intense weathering along fractures, documenting the combined influence of time, reactive fluid transport, and the opening of fractures as rock is exhumed and transformed near Earth’s surface.

58 GEOSCIENCES↗

Magnetoresistance of galfenol-based magnetic tunnel junction

The manipulation of ferromagnetic layer magnetization via electrical pulse is driving an intense research due to the important applications that this result will have on memory devices and sensors. In this study we realized a magnetotunnel junction in which one layer is made of Galfenol (Fe{sub 1-x}Ga{sub x}) which possesses one of the highest magnetostrictive coefficient known. The multilayer stack has been grown by molecular beam epitaxy and e-beam evaporation. Optical lithography and physical etching have been combined to obtain 20x20 micron sized pillars. The obtained structures show tunneling conductivity across the junction and a tunnel magnetoresistance (TMR) effect of up to 11.5% in amplitude.

36 MATERIALS SCIENCE↗

A multi-probe thermophoretic soot sampling system for high-pressure diffusion flames

Optical diagnostics and physical probing of the soot processes in high pressure combustion pose challenges that are not faced in atmospheric flames. One of the preferred methods of studying soot in atmospheric flames is in situ thermophoretic sampling followed by transmission electron microscopy imaging and analysis for soot sizing and morphology. The application of this method of sampling to high pressures has been held back by various operational and mechanical problems. In this work, we describe a rotating disk multi-probe thermophoretic soot sampling system, driven by a microstepping stepper motor, fitted into a high-pressure chamber capable of producing sooting laminar diffusion flames up to 100 atm. Innovative aspects of the sampling system design include an easy and precise control of the sampling time down to 2.6 ms, avoidance of the drawbacks of the pneumatic drivers used in conventional thermophoretic sampling systems, and the capability to collect ten consecutive samples in a single experimental run. Proof of principle experiments were performed using this system in a laminar diffusion flame of methane, and primary soot diameter distributions at various pressures up to 10 atm were determined. High-speed images of the flame during thermophoretic sampling were recorded to assess the influence of probe intrusion on the flow field of the flame.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Quantum-optical influences in optoelectronics—An introduction

This focused review discusses the increasing importance of quantum optics in the physics and engineering of optoelectronic components. Two influences relating to cavity quantum electrodynamics are presented. One involves the development of low threshold lasers, when the channeling of spontaneous emission into the lasing mode becomes so efficient that the concept of lasing needs revisiting. The second involves the quieting of photon statistics to produce single-photon sources for applications such as quantum information processing. An experimental platform, consisting of quantum-dot gain media inside micro- and nanocavities, is used to illustrate these influences of the quantum mechanical aspect of radiation. An overview is also given on cavity quantum electrodynamics models that may be applied to analyze experiments or design devices.

Chow, Weng W.↗

Thermoluminescence and phototransferred thermoluminescence dosimetry on mobile phone protective touchscreen glass

Thermoluminescence and phototransferred thermoluminescence measurements of protective glass from smartphones are described. Samples of Gorilla Glass were examined from nine different manufacturers and 40 different phone models. Additionally, 12 glasses believed to be original equipment manufacturer replacements, as well as three glass samples from U.S. finishers, were also studied. Altogether, 99 different Gorilla Glass samples were examined. The radiation-induced thermoluminescence signal produced glow curve shapes specific to the Gorilla Glass generations and could be used to distinguish between them. A background thermoluminescence (and phototransferred thermoluminescence) signal was found in all unirradiated samples. Its intensity and shape were found to be dependent on the Gorilla Glass generation, phone manufacturer, and phone model. The background signal was demonstrated to be produced by ultraviolet light exposure; the shape of the background signal was able to be reproduced by the combined exposure to a broad-spectrum solar simulator and a 302 nm ultraviolet light source. The background signal intensity was found to vary with the location from which it was taken on the glass. It was also found to be dependent on the depth within the Gorilla Glass due to absorption of the ultraviolet light as it traversed the medium. Removal of the glasses’ surface layers was found to be an inadequate method for removing the background signal. In some samples, the background signal intensity was large enough to significantly contribute to the total thermoluminescence (and phototransferred thermoluminescence) signal; therefore, a matrix deconvolution method was introduced to separate the background signal and radiation-induced signal. This method was found to enable dose reconstruction using the radiation-induced signal alone.

61 RADIATION PROTECTION AND DOSIMETRY↗