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At least 1,369 records · Page 76
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Mobile sampler for use in acquiring samples of terrestrial atmospheric gases

Samples of terrestrial atmospheric gasses from a free body of such gasses using a device characterized by a plurality of tubular bodies adapted to be mounted in side by side relation on a motorized highway vehicle in mutual parallelism with the axis of the normal path of travel for the vehicles. Each of the bodies is of a cylindrical configuration and has an axial opening at each of its opposite ends through which a linear flow path is defined. A pair of pivotally supported, spring-biased sealing caps is mounted adjacent to the ends of the body and continuously urged into a hermetic sealing relationship. A restraint for securing the caps against spring-urged pivotal displacement, includes a separable, normally tensioned line interconnecting the caps and an operable release mechanism for simultaneously releasing the caps for spring-urged displacement. A hot wire cutter is included for separating the line, whereby samples of air are trapped in the body as the caps are spring-driven to assume an hermetically sealed relation with the openings defined in each of the opposite ends of the body.

Tucker, C. E.↗
NASA NTRS1983

Aircraft measurements of trace gases and particles near the tropopause

Research activities which were performed using atmospheric constituent data obtained by the NASA Global Atmospheric Sampling Program are described. The characteristics of the particle size spectrum in various meteorological settings from a special collection of GASP data are surveyed. The relationship between humidity and cloud particles is analyzed. Climatological and case studies of tropical ozone distributions measured on a large number of flights are reported. Particle counter calibrations are discussed as well as the comparison of GASP particle data in the upper troposphere with other measurements at lower altitudes over the Pacific Ocean.

Falconer, P.↗
NASA NTRS1983

Io escape and ionization of atmospheric gases

Exploratory model calculations for the Io atomic oxygen cloud have provided two-dimensional sky-plane intensities for the 6300 A, 1304 A and 880 A lines, where volume excitation and ionization rates are determined by impact collisions with Io plasma torus electrons. Comparison of model results with observations at 6300 A suggests an isotropic oxygen flux from Io of about 1.5x109 atoms 1 sq cm/sec. The effects of including a neutral sulfur cloud and also of including charge exchange reactions between plasma torus ions and neutral OI and SI were evaluated to be significant and were roughly estimated to increase the required oxygen flux to 1.2 x 10 to the 10th atoms/sq cm/sec. In addition, increases in the estimates for the ion loading, cloud mass loss, plasma mass loading and ion energy input rates were also made. Model calculations for an Io sulfur cloud, excluding charge exchange reactions but assuming an SI flux of 7.5 x 10 to the 8th atoms/sq cm/sec (i.e., half of the oxygen flux), were also performed and provided sky plane intensities for a number of visible and IR emission lines.

Smyth, W. H.↗
NASA NTRS1982

Noble gases in planetary atmospheres - Implications for the origin and evolution of atmospheres

The radiogenic and primordial noble gas contents of the Venus, earth, and Mars atmospheres are compared with one another and with the noble gas content of other extraterrestrial samples, particularly meteorites. Key trends in the primordial noble gas content of terrestrial planetary atmospheres are shown to include: (1) a several-orders-of-magnitude decrease in Ne-20 and Ar-36 from Venus to earth to Mars; (2) a nearly constant Ne-20/Ar-36 ratio, which is comparable to that found in the more primitive carbonaceous chondrites and which is two orders of magnitude smaller than the solar ratio; (3) a sizable fractionation of Ar, Kr, and Xe from their solar ratios, though the degree of fractionation (especially for Ar-36/Xe-132) appears to decrease systematically from carbonaceous chondrites to Mars to earth to Venus; and (4) large differences in Ne and Xe isotopic ratios among earth, meteorites, and the sun. It is suggested that the grain-accretion hypothesis can explain all four trends, though the assumptions needed to achieve this agreement are far from proven.

Pollack, J. B.↗
NASA NTRS1982

Sulfuric acid vapor and other cloud-related gases in the Venus atmosphere - Abundances inferred from observed radio opacity

It is suggested that the absorbing characteristics of sulfuric acid vapor appear to reconcile what had been thought to be an inconsistency among measurements and deductions regarding the constituents of the Venus atmosphere and radio occultation, radar reflection, and radio emission measurements of its opacity. Laboratory measurements of sulfuric acid, sulfur dioxide, water vapor, and carbon dioxide are used to model relative contributions to opacity as a function of height in a way that is consistent with observations of the constituents and absorbing properties of the atmosphere. It is concluded that sulfuric acid vapor is likely to be the principal microwave absorber in the 30-50 km altitude range of the middle atmosphere of Venus.

Steffes, P. G.↗
NASA NTRS1983

Martian gases in an Antarctic meteorite?

Significant abundances of trapped argon, krypton, and xenon have been measured in shock-altered phases of the achondritic meteorite Elephant Moraine 79001 from Antarctica. The relative elemental abundances, the high ratios of argon-40 to argon-36 (equal to or greater than 2000), and the high ratios of xenon-129 to xenon-132 (equal to or greater than 2.0) of the trapped gas more closely resemble Viking data for the Martian atmosphere than data for noble gas components typically found in meteorites. These findings support earlier suggestions, made on the basis of geochemical evidence, that shergottites and related rare meteorites may have originated from the planet Mars.

Bogard, D. D.↗
NASA NTRS1983

Remote sensing of tropospheric gases and aerosols with airborne DIAL system

The multipurpose airborne DIAL system developed at NASA Langley Research Center is characterized, and the published results of tropospheric O3, H2O, and aerosol-backscatter remote-sensing experiments performed in 1980 and 1981 are summarized. The system comprises two tunable dye lasers pumped by frequency-doubled Nd:YAG lasers, dielectric-coated steering optics, a 36-cm-diameter Cassegrain receiver telescope, gateable photomultiplier tubes, and a minicomputer data-processing unit for real-time calculation of gas concentrations and backscattering profiles. The transmitted energy of the 100-microsec-separated dye-laser pulses is 40, 80, or 50 mJ/pulse at around 300, 600, or 720-nm wavelength, respectively. Good agreement was found between DIAL-remote-sensed and in-situ H2O and O3 profiles of the lower troposphere and O3 profiles of the tropopause region, and the usefulness of DIAL backscattering measurements in the study of boundary-layer and tropospheric dynamics is demonstrated. The feasibility of DIAL sensing of power-plant or urban plume SO2, of urban-area (or rural-area column-content) NO2, and of temperature and H2O (simultaneously using a third laser) has been suggested by simulation studies.

Browell, E. V.↗
NASA NTRS1983

CO2 DIAL sensitivity studies for measurements of atmospheric trace gases

An analysis is presented of the accuracy of infrared differential absorption lidar (DIAL) measurements of trace constituents in the atmosphere. Expressions are derived for the signal-to-noise ratios applicable in the detection of a signal from a scattering cell for the cases of single-detection heterodyne detection and direct detection. Results of computer simulations of the expectation value of the measured return for various measurement conditions are presented which illustrate the sensitivities of plume measurements for horizontal range-resolved and vertical content measurements of NH3 in heterodyne and direct detection. Advantages for long-range measurements of the use of rare isotope laser frequencies, tuning by collision broadening, and closely spaced on and off frequencies are pointed out.

Brockman, P.↗
NASA NTRS1985

Conserving Purge Gases

Two-step flow control adjusts to dimensional changes in purged equipment. Two pressure actuated valves provide two-step control. When turbopump starts, helium flows through both valves. As pump operates its parts expand, clearance decrease and back pressure builds up on valves. At preset back pressure value, one valve closes, reducing helium flow.

Kan, K.↗
NASA NTRS1983

Analysis of an effusive sampling device for analysis of boundary layer gases

The effect of suction, through an opening in a surface, upon a stream of flowing gas is determined. The quantity of interest is the maximum distance, Y, from the surface that the main stream is affected by the applied suction. The fraction of this distance Y of the boundary layer thickness sigma is determined as a function of tubing radius and length, gas pressure, temperature and stream velocity. The shape of the flow in the high velocity stream is assumed to be determined by means of a parameter which is an unknown function of the distance from the leading edge of the surface.

Brown, K. G.↗
NASA NTRS1983

Io: Escape and ionization of atmospheric gases

The partitioning of the major ion densities throughout the torus is described. This description is required as input information for the Io oxygen and sulfur cloud models. In the radial interval from 4.9 to 5.4 Rj ion partitioning information is used to initially explore that impact of charge exchange reactions between the neutral gas clouds and the plasma torus ions. Because of the spatial distribution of torus ions, these reactions may be able to introduce a magnetic longitudinal effect in the plasma torus properties. Modeling efforts for the Io oxygen and sulfur clouds and for the sodium cloud data are also discussed.

Smyth, W. H.↗
NASA NTRS1984

Measurement of H2O and other trace gases in the stratosphere using a high resolution far-infrared spectrometer at 28 km

Data analysis results from the 1983 BIC 1 and 2 balloon flights are presented, with emphasis on H2O2, OH, HCL, O3, O2, and H2O. A 2 sigma limit on H2O2 abundance was set, as a function of altitude. This is comparable to or less than the theoretically predicted winter abundances from the 2-D models of Dupont, with a large enough summer maximum to facilitate concentration profile measurements. There is a definite drop in OH concentration from day to night following two model profiles. There was general agreement between HF measurements. The dominant role of the far wings of H2O lines in low altitude spectra was recognized. The strength of these wings exceeds that of many molecular line cores, including O3 and O2, especially near the long wavelength end of the spectra (100 cm (-1)). Newly measured positions for O3 and H2O were obtained.

Traub, W. A.↗
NASA NTRS1984

Colloidally separated samples from Allende residues - Noble gases, carbon and an ESCA-study

Results are presented which strengthen the hypothesis of heterogeneity among the carbon- and nitrogen-bearing phases of the Allende meteorite. These data also highlight the possibility of performing physical separations yielding samples in which some of the noble gas- and carbon-bearing phases are extraordinarily predominant over others. The conclusion, based on mass and isotope balance arguments, that a significant portion of the carbonaceous matter in Allende is likely to be gas-poor or gas-free need not weaken the case for carbonaceous carriers for the major noble gas components. The concept that acid-soluble carbonaceous phases contain a multiplicity of components, each of which may have formed under a multiplicity of different physical-chemical conditions, is reemphasized by the results of the present study.

Ott, U.↗
NASA NTRS1984

On the abiotic formation of amino acids. I - HCN as a precursor of amino acids detected in extracts of lunar samples. II - Formation of HCN and amino acids from simulated mixtures of gases released from lunar samples

Two studies on the abiotic formation of amino acids are presented. The first study demonstrates the role of hydrogen cyanide as a precursor of amino acids detected in extracts of lunar samples. The formation of several amino acids, including glycine, alanine, aspartic acid, and glutamic acid, under conditions similar to those used for the analysis of lunar samples is demonstrated. The second study investigates the formation of hydrogen cyanide as well as amino acids from lunar-sample gas mixtures under electrical discharge conditions. These results extend the possibility of synthesis of amino acids to planetary bodies with primordial atmospheres less reducing than a mixture of methane, ammonia, hydrogen and water.

Yuasa, S.↗
NASA NTRS1983

Velocity-changing collisional effects in nonlinear atomic spectroscopy and photon echo decay in gases

A general theory of atomic dipole coherence under the influence of collisional phase changes, inelastic effects and optically active atom velocity changes, including those due to anisotropic interactions is presented. Velocity change effects are obtained in closed form. Line shapes appear as convolutions of standard pressure broadening contours with velocity-change contours. Width and shift parameters for the He-broadened Na D lines at 2 m bar pressure, 380 K are calculated, as are He-induced photon echo decay rates for these lines. Overall agreement with xperiment is reasonably good.

Herman, R. M.↗
NASA NTRS1984

Possible production by lightning of aerosols and trace gases in Titan's atmosphere

Although lightning has not yet been observed in Titan's atmosphere, the presence of condensable vapors and the deposition of a significant amount of solar energy at the surface suggest the possibility of lightning activity. Based on an understanding of the relationship of lightning activity to the amount of convective energy available on Titan, a lightning energy dissipation rate of 4 x 10 to the -6th W/sq m can be expected. This value is much lower than that for earth or Jupiter, and is a result of both the reduced solar flux at Titan and the absorption of sunlight by the aerosols that lie above the convective layer. For this dissipation rate, the amount of HCN and C2N2 produced by lightning should be greater than that by solar UV, but could be less than that produced by electron precipitation and galactic cosmic rays. Equilibrium calculations indicate that large mole fractions of elemental solid phase carbon will also be produced. Using a simplified model of aerosol formation, coagulation, and settling, it is estimated that a lightning-produced aerosol could have a typical optical depth of 0.01, with values as high as 0.1. The accumulation of soot over geological time might reach a meter or more in depth.

Borucki, W. J.↗
NASA NTRS1984

Soft X-ray opacity in hot and photoionized gases

New calculations are presented of the soft X-ray opacity of gas having cosmic elemental abundances, but in a variety of ionization states. Coronal ionization equilibrium is considered over the range of temperatures 10 to the 4th to 3 x 10 to the 8th K and photoionization equilibrium with power-law and thermal bremsstrahlung spectra over a wide range of ionization parameters. The results are displayed in illustrative figures. For temperatures and ionization parameters commonly found in astrophysical plasmas, the opacity (particularly to photons of equal to or less than 1 keV) can be diminished by substantial factors relative to the state in which all atoms are neutral. As the dominant ionization stages change, the positions and contrasts of prominent K-edges also change.

Krolik, J. H.↗
NASA NTRS1985

Laboratory simulation of meteoritic noble gases. II - Sorption of xenon on carbon: Etching and heating experiments

The release of trapped Xe from amorphous-C phases of meteorites is simulated experimentally by HNO3 etching of carbon-black and pyrolyzed polyvinylidene chloride samples exposed to Xe-127 for 0.5-240 h at 100-1000 C and then degassed for 9 h or more at the same temperatures, as reported by Wacker et al. (1985). The results are presented in tables and graphs and characterized in detail. Samples exposed at 100-200 C are found to lose most of their Xe after etching to a depth of only about 20 pm, while those exposed at 800-1000 C exhibit a second more tightly bound component extending to a depth of 3 nm, indicative of diffusion of Xe during exposure and resembling planetary Xe. The higher noble-gas concentrations measured in meteorites are attributed to rate-controlled Xe uptake over a long period in the solar nebula.

Zadnik, M. G.↗