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At least 1,369 records · Page 76

Resolving Graphite‐Electrolyte Interphase of Lithium‐Ion Batteries using Air‐Tight Ambient Mass Spectrometry

Abstract The formation of a stable solid electrolyte interphase (SEI) at graphite electrode is necessary for lithium‐ion batteries (LIB) to prevent excessive degradation of electrolytes. Until now, the exact organic composition of SEI has not been decisively determined with lithium ethylene mono‐carbonate (LEMC) being one of the debated components. An air‐tight ambient mass spectrometry (MS) platform is developed to directly characterize the air‐sensitive organic components present in SEI. Ionization occurs via a solvent‐free field‐induced process at atmospheric pressure. Our experimental data, based on tandem MS analysis, revealed LEMC to be the major organic component in SEI. This result resolves a long‐standing mystery surrounding the composition of native SEI in LIB, where no trace of the other debated compound, lithium ethylene dicarbonate, was detected. The energetics of fragmentation of LEMC and the corresponding stabilities of various ionic species detected during the air‐tight ambient MS analysis were calculated using density functional theory (DFT). Our findings confirmed favorable protonation energies and suggested the molecular structures for many of the detected species. Solvent (i. e., ethylene carbonate)‐induced stabilization effects observed during the ionization process were also confirmed by DFT. The reported study encourages the routine use of ambient mass spectrometry to characterize both anodic and cathodic electrodes of all battery types as well as to study other air‐sensitive materials in their native state.

25 ENERGY STORAGE↗

Semileptonic tau decays beyond the Standard Model

Hadronic τ decays are studied as probe of new physics. We determine the dependence of several inclusive and exclusive τ observables on the Wilson coefficients of the low-energy effective theory describing charged-current interactions between light quarks and leptons. The analysis includes both strange and non-strange decay channels. The main result is the likelihood function for the Wilson coefficients in the tau sector, based on the up-to-date experimental measurements and state-of-the-art theoretical techniques. The likelihood can be readily combined with inputs from other low-energy precision observables. We discuss a combination with nuclear beta, baryon, pion, and kaon decay data. In particular, we provide a comprehensive and model-independent description of the new physics hints in the combined dataset, which are known under the name of the Cabibbo anomaly.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

A human antibody epitope map of Pfs230D1 derived from analysis of individuals vaccinated with a malaria transmission-blocking vaccine

Pfs230 domain 1 (Pfs230D1) is an advanced malaria transmission-blocking vaccine antigen demonstrating high functional activity in clinical trials. However, the structural and functional correlates of transmission-blocking activity are not defined. Here, we characterized a panel of human monoclonal antibodies (hmAbs) elicited in vaccinees immunized with Pfs230D1. These hmAbs exhibited diverse transmission-reducing activity, yet all bound to Pfs230D1 with nanomolar affinity. We compiled epitope-binning data for seventeen hmAbs and structures of nine hmAbs complexes to construct a high-resolution epitope map and revealed that potent transmission-reducing hmAbs bound to one face of Pfs230D1, while non-potent hmAbs bound to the opposing side. The structure of Pfs230D1D2 revealed that non-potent transmission-reducing epitopes were occluded by the second domain. The hmAb epitope map delineated binary hmAb combinations that synergized for extremely high-potency, transmission-reducing activity. Finally, this work provides a high-resolution guide for structure-based design of enhanced immunogens and informs diagnostics that measure the transmission-reducing response.

60 APPLIED LIFE SCIENCES↗

The dark matter halo masses of elliptical galaxies as a function of observationally robust quantities

Context. The assembly history of the stellar component of a massive elliptical galaxy is closely related to that of its dark matter halo. Measuring how the properties of galaxies correlate with their halo mass can therefore help to understand their evolution. Aims. We investigate how the dark matter halo mass of elliptical galaxies varies as a function of their properties, using weak gravitational lensing observations. To minimise the chances of biases, we focus on the following galaxy properties that can be determined robustly: the surface brightness profile and the colour. Methods. We selected 2409 central massive elliptical galaxies (log M*/M ⊙ ≳ 11.4) from the Sloan Digital Sky Survey spectroscopic sample. We first measured their surface brightness profile and colours by fitting Sérsic models to photometric data from the Kilo-Degree Survey (KiDS). We fitted their halo mass distribution as a function of redshift, rest-frame r-band luminosity, half-light radius, and rest-frame u - g colour, using KiDS weak lensing measurements and a Bayesian hierarchical approach. For the sake of robustness with respect to assumptions on the large-radii behaviour of the surface brightness, we repeated the analysis replacing the total luminosity and half-light radius with the luminosity within a 10 kpc aperture, L r, 10 , and the light-weighted surface brightness slope, Γ 10 . Results. We did not detect any correlation between the halo mass and either the half-light radius or colour at fixed redshift and luminosity. Using the robust surface brightness parameterisation, we found that the halo mass correlates weakly with L r,10 and anti-correlates with Γ 10 . At fixed redshift, L r, 10 and Γ 10 , the difference in the average halo mass between galaxies at the 84th percentile and 16th percentile of the colour distribution is 0.00 ± 0.11 dex. Conclusion. Our results indicate that the average star formation efficiency of massive elliptical galaxies has little dependence on their final size or colour. This suggests that the origin of the diversity in the size and colour distribution of these objects lies with properties other than the halo mass.

79 ASTRONOMY AND ASTROPHYSICS↗

Harnessing the predicted maize pan-interactome for putative gene function prediction and prioritization of candidate genes for important traits

Abstract The recent assembly and annotation of the 26 maize nested association mapping population founder inbreds have enabled large-scale pan-genomic comparative studies. These studies have expanded our understanding of agronomically important traits by integrating pan-transcriptomic data with trait-specific gene candidates from previous association mapping results. In contrast to the availability of pan-transcriptomic data, obtaining reliable protein–protein interaction (PPI) data has remained a challenge due to its high cost and complexity. We generated predicted PPI networks for each of the 26 genomes using the established STRING database. The individual genome-interactomes were then integrated to generate core- and pan-interactomes. We deployed the PPI clustering algorithm ClusterONE to identify numerous PPI clusters that were functionally annotated using gene ontology (GO) functional enrichment, demonstrating a diverse range of enriched GO terms across different clusters. Additional cluster annotations were generated by integrating gene coexpression data and gene description annotations, providing additional useful information. We show that the functionally annotated PPI clusters establish a useful framework for protein function prediction and prioritization of candidate genes of interest. Our study not only provides a comprehensive resource of predicted PPI networks for 26 maize genomes but also offers annotated interactome clusters for predicting protein functions and prioritizing gene candidates. The source code for the Python implementation of the analysis workflow and a standalone web application for accessing the analysis results are available at https://github.com/eporetsky/PanPPI.

Genetics & Heredity↗

Constraints on the $\chi_\mathrm{c1}$ versus $\chi_\mathrm{c2}$ Polarizations in Proton-Proton Collisions at $\sqrt{s} =$ 8 TeV

The polarizations of promptly produced χc1 and χc2 mesons are studied using data collected by the CMS experiment at the LHC, in proton-proton collisions at s=8 TeV. The χc states are reconstructed via their radiative decays χc→J/ψγ, with the photons being measured through conversions to e+e−, which allows the two states to be well resolved. The polarizations are measured in the helicity frame, through the analysis of the χc2 to χc1 yield ratio as a function of the polar or azimuthal angle of the positive muon emitted in the J/ψ→μ+μ- decay, in three bins of J/ψ transverse momentum. While no differences are seen between the two states in terms of azimuthal decay angle distributions, they are observed to have significantly different polar anisotropies. The measurement favors a scenario where at least one of the two states is strongly polarized along the helicity quantization axis, in agreement with nonrelativistic quantum chromodynamics predictions. This is the first measurement of significantly polarized quarkonia produced at high transverse momentum.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Observation of Enhanced Long-Range Elliptic Anisotropies Inside High-Multiplicity Jets in p p Collisions at s = 13 TeV

A search for collective effects inside jets produced in proton-proton collisions is performed via correlation measurements of charged particles using the CMS detector at the CERN LHC. The analysis uses data collected at a center-of-mass energy of s = 13 TeV , corresponding to an integrated luminosity of 138 fb − 1 . Jets are reconstructed with the anti- k T algorithm with a distance parameter of 0.8 and are required to have transverse momentum greater than 550 GeV and pseudorapidity | η jet | < 1.6 . Two-particle correlations among the charged particles within the jets are studied as functions of the particles’ azimuthal angle and pseudorapidity separations ( Δ ϕ * and Δ η * ) in a jet coordinate basis, where particles’ η * , ϕ * are defined relative to the direction of the jet. The correlation functions are studied in classes of in-jet charged-particle multiplicity up to N ch j ≈ 100 . Fourier harmonics are extracted from long-range azimuthal correlation functions to characterize azimuthal anisotropy for | Δ η * | > 2 . For low- N ch j jets, the long-range elliptic anisotropic harmonic, v 2 * , is observed to decrease with N ch j . This trend is well described by Monte Carlo event generators. However, a rising trend for v 2 * emerges at N ch j ≳ 80 , hinting at a possible onset of collective behavior, which is not reproduced by the models tested. This observation yields new insights into the dynamics of jet evolution in the vacuum. © 2024 CERN, for the CMS Collaboration 2024 CERN

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Machine-learning-informed scattering correlation analysis of sheared colloids

We have carried out theoretical analysis, Monte Carlo simulations and machine-learning analysis to quantify microscopic rearrangements of dilute dispersions of spherical colloidal particles from coherent scattering intensity. Both monodisperse and polydisperse dispersions of colloids were created and underwent a rearrangement consisting of an affine simple shear and non-affine rearrangement using the Monte Carlo method. We calculated the coherent scattering intensity of the dispersions and the correlation function of intensity before and after the rearrangement and generated a large data set of angular correlation functions for varying system parameters, including number density, polydispersity, shear strain and non-affine rearrangement. Singular value decomposition of the data set shows the feasibility of machine-learning inversion from the correlation function for the polydispersity, shear strain and non-affine rearrangement using only three parameters. A Gaussian process regressor is then trained on the data set and can retrieve the affine shear strain, non-affine rearrangement and polydispersity with relative errors of 3%, 1% and 6%, respectively. Altogether, our model provides a framework for quantitative studies of both steady and non-steady microscopic dynamics of colloidal dispersions using coherent scattering methods.

Gaussian process regression↗

AFUE Analysis Software Tool

The Annual Fuel Utilization Efficiency (AFUE) analysis of residential and light commercial furnaces follows ANSI/ASHRAE Standard 103-2017 (i.e., Method of Testing for Annual Fuel Utilization Efficiency of Residential Central Furnaces and Boilers) . The analysis is a complex, comprehensive method based on furnace configuration and specific components equipped, requiring detailed furnace testing and measurement data. For this reason, an AFUE Analysis Tool using Microsoft Excel enabled with Visual Basic for Applications (VBA) was developed with a user-friendly interface and comprehensive coverage. The tool consists of three worksheets: unit and configuration selection, geometry and measurement data input, and AFUE plus key results. This tool can be used to estimate the AFUE of both condensing and noncondensing furnaces with single-stage, two-stage, and step-modulating functions. The tool was validated with experimental data from Oak Ridge National Laboratory’s natural gas furnace projects that are commercially available. The results indicate the tool is reasonably accurate in the evaluation of a new R&D modified furnace unit.

Gao, Zhiming [Oak Ridge National Laboratory (ORNL)↗

Reservoir Sediment Management and Monitoring Database

Overview This dataset compiles dam sediment management and monitoring information from surveys, case studies, and journal articles. Additionally, features described by the National Inventory of Dams (i.e., presence of sluice gates) are included to indicate known infrastructure features that may address sediment releases. The location and description of records from downstream monitoring gages are catalogued in order to help with tracking conditions over time (e.g., before and after management actions, as operations change, etc.). The data help address national scale understanding of challenges and solutions related to the accumulation of sediment behind a dam as well as downstream passage. Sediment trapping causes problems as it reduces storage capacity, disrupts dam and reservoir function, impedes access for recreation, alters water quality/habitat conditions, and contributes to riverbank and coastal erosion within the reservoir. Data compilation from a variety of sources is a first step towards assessing system-wide efficacy of management solutions. This dataset was developed under the Water Power Technologies Office funded effort which began as a Seedling on Reservoir Sedimentation Data, and was supported by the Reservoir Sedimentation Modeling Framework and Data Analysis project. These projects have addressed challenges in describing sediment transport, trapping, and management at dams throughout the US. Methodology An outer join on dams/reservoirs with surveys and survey reports (documented in the RESSED database, USBR or USACE databases, project websites, etc.) with the National Inventory of Dams, based on the NIDID to determine dams with documented management and/or sluice gates. Additional dams with documented management activity were identified through review of technical articles from the past 25 years in Journal of Hydrology, Journal of Water Resources Planning and Management, Geomorphology, Journal of Hydraulic Engineering, Water, Journal of Cleaner Production, International Journal of Sediment Research, Nature Scientific Reports, Earth Surface Processes and Landforms, and Environmental Science and Pollution Research. Individual records were created for each survey or management activity documented. To evaluate downstream sediment monitoring records, the nhdPlusTools and dataRetrieval packages in R were used to find gages within 10km of each dam in the management database. Length of record and location of matched gages were retrieved for those parameters relevant to sediment concentration or total sediment discharge.

Hansen, Carly [ORNL] (ORCID:0000000193280838)↗

Transverse Enhancement, Longitudinal Quenching and Coulomb Sum Rule in e-$^{12}$C and e-$^{16}$O Scattering

We present a short summary of a phenomenological analysis of all available electron scattering data on 12 C 12 C (about 6600 differential cross section measurements) and on 16 O 16 O (about 250 measurements) within the framework of the quasielastic superscaling model (including Pauli blocking). All quasielastic and inelastic cross section measurements are included down to the lowest momentum transfer ? q (including photo-production data). We find that there is enhancement of the transverse quasielastic response function and quenching of the longitudinal response function at low ? q (in addition to Pauli blocking). We extract parameterizations of a ? ? ? ? ? ? ? ? ? ? ? ? ? ? multiplicative low ? q "Longitudinal Quenching Factor" and an ? ? ? ? ? ? ? ? additive "Transverse Enhancement" contribution. Additionally, we find that the excitation of nuclear states contribute significantly (up to 30\%) to the Coulomb Sum Rule. We extract the most accurate determination of the sum rule to date and find it to be in disagreement with random phase approximation based calculations but in reasonable agreement with recent theoretical calculations such as "First Principle Green's Function Monte Carlo".

Bodek, Arie↗

Simulating Continuum-based Redshift Measurement in the Roman’s High Latitude Spectroscopic Survey

We investigate the capability of the Nancy Grace Roman Space Telescope’s (Roman) Wide-Field Instrument G150 slitless grism to detect red, quiescent galaxies based on the current reference survey. We simulate dispersed images for Roman reference High-Latitude Spectroscopic Survey (HLSS) and analyze two-dimensional spectroscopic data using the grism Redshift and Line Analysis (Grizli) software. This study focus on assessing Roman grism’s capability for continuum-level redshift measurement for a redshift range of 0.5 ≤ z ≤ 2.5. The redshift recovery is assessed by setting three requirements of: σ z = $\frac{|z–z_{true}|}{1+z}$ ≤ 0.01, signal-to-noise ratio≥ 5 and the presence of a single dominant peak in redshift likelihood function. We find that, for quiescent galaxies, the reference HLSS can reach a redshift recovery completeness of ≥50% for F158 magnitude brighter than 20.2 mag. We also explore how different survey parameters, such as exposure time and the number of exposures, influence the accuracy and completeness of redshift recovery, providing insights that could optimize future survey strategies and enhance the scientific yield of the Roman in cosmological research.

Astronomical simulations↗

RTN-095: The Vera C. Rubin Observatory Data Preview 1

We present Rubin Data Preview 1 (DP1), the first release of data from the NSF-DOE Vera C. Rubin Observatory, consisting of raw and calibrated single-epoch images, coadds, difference images, detection catalogs, and other derived data products. DP1 is based on 1792 science-grade optical/near-infrared exposures acquired over 48 distinct nights by the Rubin Commissioning Camera, LSSTComCam, on the Simonyi Survey Telescope at the Summit Facility on Cerro Pachón, Chile during the first on-sky commissioning campaign in late 2024. DP1 covers a total of ~15 sq. deg. over seven roughly equally-sized non-contiguous fields, each independently observed in six broad photometric bands, ugrizy, spanning a range of stellar densities and latitudes and overlapping with external reference datasets. The median image quality across all bands, measured by the FWHM of the point-spread function, is approximately 1.13 arcseconds, with the sharpest images reaching about 0.65 arcseconds. DP1 contains approximately 2.3 million distinct astrophysical objects, of which 1.6 million are extended in at least one band, and 431 solar system objects, of which 93 are new discoveries. DP1 is approximately 3.5 TB in size and available to Rubin data rights holders via the Rubin Science Platform, a cloud-based environment for the analysis of petascale astronomical data. While small compared to future LSST releases, its high quality and diversity of data support a broad range of early science investigations across all four LSST themes, providing a valuable opportunity to engage with Rubin data ahead of the start of full operations in late 2025.

79 ASTRONOMY AND ASTROPHYSICS↗

Blackout Diffusion: Generative Diffusion Models in Discrete-State Spaces

Typical generative diffusion models rely on a Gaussian diffusion process for training the backward transformations, which can then be used to generate samples from Gaussian noise. However, real world data often takes place in discrete-state spaces, including many scientific applications. Here, we develop a theoretical formulation for arbitrary discrete-state Markov processes in the forward diffusion process using exact (as opposed to variational) analysis. We relate the theory to the existing continuous-state Gaussian diffusion as well as other approaches to discrete diffusion, and identify the corresponding reverse-time stochastic process and score function in the continuous-time setting, and the reverse-time mapping in the discrete-time setting. As an example of this framework, we introduce “Blackout Diffusion”, which learns to produce samples from an empty image instead of from noise. Numerical experiments on the CIFAR-10, Binarized MNIST, and CelebA datasets confirm the feasibility of our approach. Generalizing from specific (Gaussian) forward processes to discrete-state processes without a variational approximation sheds light on how to interpret diffusion models, which we discuss.

Santos, Javier E.↗

Dark Energy Survey Year 3 Results: Deep Field optical + near-infrared images and catalogue

ABSTRACT We describe the Dark Energy Survey (DES) Deep Fields, a set of images and associated multiwavelength catalogue (ugrizJHKs) built from Dark Energy Camera (DECam) and Visible and Infrared Survey Telescope for Astronomy (VISTA) data. The DES Deep Fields comprise 11 fields (10 DES supernova fields plus COSMOS), with a total area of ∼30 sq. deg. in ugriz bands and reaching a maximum i-band depth of 26.75 (AB, 10σ, 2 arcsec). We present a catalogue for the DES 3-yr cosmology analysis of those four fields with full 8-band coverage, totalling 5.88 sq. deg. after masking. Numbering 2.8 million objects (1.6 million post-masking), our catalogue is drawn from images coadded to consistent depths of r = 25.7, i = 25, and z = 24.3 mag. We use a new model-fitting code, built upon established methods, to deblend sources and ensure consistent colours across the u-band to Ks-band wavelength range. We further detail the tight control we maintain over the point-spread function modelling required for the model fitting, astrometry and consistency of photometry between the four fields. The catalogue allows us to perform a careful star–galaxy separation and produces excellent photometric redshift performance (NMAD = 0.023 at i < 23). The Deep-Fields catalogue will be made available as part of the cosmology data products release, following the completion of the DES 3-yr weak lensing and galaxy clustering cosmology work.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Morphological traits for allometric scaling of the European Sea Bass Dicentrarchus labrax (Linnaeus, 1758) from Southern Portugal population

Abstract The present study aimed to determine the allometric scaling among a selection of morphological traits in European sea bass ( Dicentrarchus labrax ) to estimate fish body weight. A set of morphological traits (fish body weight, length, height, and width) were directly measured in 146 fish of a recirculating aquaculture system, with body weights ranging from 17.11 to 652.21 g. In addition, a collection of digital imagery of each anesthetized fish from the side and top views were used to estimate other traits (indirect measures). Multiple regression analysis and regression coefficients were calculated using all possible combinations of biometric data (predictors) to estimate fish body weight, applying different numerical fitting models (linear, log‐linear, quadratic, exponential). The results showed that the best combination of traits for estimating fish body weight were fish body width, length and height, collected from direct measure ( R 2 = 0.995), for a log‐linear model fitting, which revealed more accurate determinations than the most commonly used length–weight relationship. Nevertheless, other combinations of morphological traits and fitting models were also found to be suitable in successfully predict fish body weight, with variability ranging between 92.5% and 98.5%. For indirect measures, the best predictor was a combination of traits from top view (width, eye distance and area without fins) fitted with a log‐linear function. These results comprise a relevant baseline in supporting the high potential of noninvasive methods to accurately follow the growth of European sea bass juveniles, recurring to imagery analysis of anesthetized fish. It has major potential applications in feeding consumption trials and fish growth models, as it allows for continuously following up fish growth under different experimental conditions without therein distress derived from manipulation.

Azevedo, Ana↗

Multi‐season analysis reveals hundreds of drought‐responsive genes in sorghum

Persistent drought affects global crop production and is becoming more severe in many parts of the world in recent decades. Deciphering how plants respond to drought will facilitate the development of flexible mitigation strategies. Sorghum bicolor L. Moench (sorghum), a major cereal crop and an emerging bioenergy crop, exhibits remarkable resilience to drought. To better understand the molecular traits that underlie sorghum's remarkable drought tolerance, we undertook a large-scale sorghum gene expression profiling effort, totaling nearly 1500 transcriptome profiles, across a 3-year field study with replicated plots in California's Central Valley. This study included time-resolved gene expression data from roots and leaves of two sorghum genotypes, BTx642 and RTx430, with different pre-flowering and post-flowering drought-tolerance adaptations under control and drought conditions. Quantification of genotype-specific drought tolerance effects was enabled by de novo sequencing, assembly, and annotation of both BTx642 and RTx430 genomes. These reference-quality genomes were used to construct a pangene set for characterizing conserved and genotype-specific expression. By integrating time-resolved transcriptomic responses to drought in the field across three consecutive years, we identified a set of 726 drought-responsive genes that responded similarly in all 3 years of our field study. Functional enrichment analysis identified abiotic stress, secondary cell wall-related processes and metabolism as particularly affected under both types of drought stress. We also found that some glyoxylate cycle pathway genes, including malate synthase and isocitrate lyase, are differentially regulated particularly during post-flowering drought stress, implicating this pathway as potentially important for drought responsiveness. This expansive dataset represents a unique resource for sorghum and drought research communities and provides a methodological framework for the integration of multi-faceted time-resolved transcriptomic datasets.

Cole, Benjamin [USDOE Joint Genome Institute (JGI)↗

Impact of LHC vector boson production in heavy ion collisions on strange PDFs

Abstract The extraction of the strange quark parton distribution function (PDF) poses a long-standing puzzle. Measurements from neutrino-nucleus deep inelastic scattering (DIS) experiments suggest the strange quark is suppressed compared to the light sea quarks, while recent studies of $$W^\pm /Z$$ W ± / Z boson production at the LHC imply a larger strange component at small x values. As the parton flavor determination in the proton depends on nuclear corrections, e.g. from heavy-target DIS, LHC heavy ion measurements can provide a distinct perspective to help clarify this situation. In this investigation we extend the nCTEQ15 nPDFs to study the impact of the LHC proton-lead $$W^\pm /Z$$ W ± / Z production data on both the flavor differentiation and nuclear corrections. This complementary data set provides new insights on both the LHC $$W^\pm /Z$$ W ± / Z proton analyses and the neutrino-nucleus DIS data. We identify these new nPDFs as nCTEQ15WZ . Our calculations are performed using a new implementation of the nCTEQ code ( nCTEQ++ ) based on C++ which enables us to easily interface to external programs such as HOPPET, APPLgrid and MCFM. Our results indicate that, as suggested by the proton data, the small x nuclear strange sea appears larger than previously expected, even when the normalization of the $$W^{\pm }/Z$$ W ± / Z data is accommodated in the fit. Extending the nCTEQ15 analysis to include LHC $$W^\pm /Z$$ W ± / Z data represents an important step as we advance toward the next generation of nPDFs.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗