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At least 1,369 records · Page 76

Molecular dynamics of liquid SiO2 under high pressure

The molecular dynamics of pure SiO2 liquids was investigated up to pressures of 20 GPa at 4000 K using 252, 498, 864, and 1371 particles. The results obtained suggest that the pressure-induced maxima in the self-diffusion coefficients of both oxygen and silicon are dependent on the system size. In the case of larger systems, the maximum decreases and shifts to lower pressures. Changes in the velocity autocorrelation function with increasing pressure are described. The populations of anomalously coordinated silicon and oxygen are then discussed as a function of pressure and system size.

Rustad, James R.↗

Shock tube investigation of dynamic response of pressure transducers for validation of rotor performance measurements

For some time now, NASA has had a program under way to aid in the validation of rotor performance and acoustics codes associated with the UH-60 rotary-wing aircraft; and to correlate results of such studies with those obtained from investigations of other selected aircraft rotor performance. A central feature of these studies concerns the dynamic measurement of surface pressure at various locations up to frequencies of 25 KHz. For this purpose, fast-response gauges of the Kulite type are employed. The latter need to be buried in the rotor; they record surface pressures which are transmitted by a pipette connected to the gauge. The other end of the pipette is cut flush with the surface. In certain locations, the pipette configuration includes a rather sharp right-angle bend. The natural question has arisen in this connection: In what way are the pipettes modifying the signals received at the rotor surface and subsequently transmitted to the sensitive Kulite transducer element. The basic details and results of the program performed and recently completed in the High Pressure Shock Tube Laboratory of the Department of Aeronautics and Astronautics at Stanford University are given.

Bershader, Daniel↗

On the dynamic response of pressure transmission lines in the research of helium-charged free piston Stirling engines

The signal distortion inherent to pressure transmission lines in free-piston Stirling engine research is discussed. Based on results from classical analysis, guidelines are formulated to describe the dynamic response properties of a volume-terminated transmission tube for applications involving the helium-charged free-piston Stirling engines. The underdamped flow regime is described, the primary resonance frequency is derived, and the pressure phase and amplitude distortion are discussed. The scope and limitation of the dynamic response analysis are considered.

Miller, Eric L.↗

Subdiffusive High-Pressure Hydrogen Gas Dynamics in Elastomers

We report elastomeric rubber materials serve a vital role as sealing materials in the hydrogen storage and transport infrastructure. With applications including O-rings and hose liners, these components are exposed to pressurized hydrogen at a range of temperatures, cycling rates, and pressure extremes. High-pressure exposure and subsequent rapid decompression often lead to cavitation and stress-induced damage of the elastomer due to localization of the hydrogen gas. Here, we use all-atom classical molecular dynamics simulations to assess the impact of compositional variations on gas diffusion within the commonly used elastomer ethylene–propylene–diene monomer (EPDM). With the aim to build a predictive understanding of precursors to cavitation and to motivate material formulations that are less sensitive to hydrogen-induced failure, we perform systematic simulations of gas dynamics in EPDM as a function of temperature, gas concentration, and cross-link density. Our simulations reveal anomalous, subdiffusive hydrogen motion at pressure and intermediate times. We identify two groups of gas with different mobilities: one group exhibiting high mobility and one group exhibiting low mobility due to their motion being impeded by the polymer. With decreasing temperatures, the low-mobility group shows increased gas localization, the necessary precursor for cavitation damage in these materials. At lower temperatures, increasing cross-link density led to greater hydrogen gas mobility and a lower fraction of caged hydrogen, indicating that increasing cross-link density may reduce precursors to cavitation. Finally, we use a two-state kinetic model to determine the energetics associated with transitions between these two mobility states.

36 MATERIALS SCIENCE↗

Effect of Aeropropulsive Interactions and Design Sensitivities on Optimal Hypersonic Ascent Trajectories

In this paper, trajectory optimization is used as a tool to better understand the performance characteristics of hypersonic Single-Stage-To-Orbit(SSTO) vehicle exhibiting significant aeropropulsive interactions. The energy state approximation is used to determine a straightforward method of determining the scramjet-powered phase of the mission. The energy state method is then used to generate fuel-optimal trajectory results over this portion of the mission for a vehicle configuration of this class. The fuel-optimal unconstrained trajectory is marked by low-altitude acceleration, while a dynamic pressure-constrained trajectory is seen to ride the dynamic pressure constraint for the entire scramjet mission phase. The significance of aeropropulsive interactions in affecting vehicle performance is also investigated.

Lovell, T. Alan↗

Experimental evaluation of shear modulus scaling of dynamic strength at extreme pressures

Recent progress in the development of dynamic strength experimental platforms is allowing for unprecedented insight into the assumptions used to construct constitutive models operating in extreme conditions. In this work, we make a quantitative assessment of how tantalum strength scales with its shear modulus to pressures of hundreds of gigapascals through a cross-platform examination of three dynamic strength experiments. Specifically, we make use of Split–Hopkinson pressure bar and Richtmyer–Meshkov instability experiments to assess the low-pressure strain and strain rate dependence. Concurrent examination of magnetically driven ramp-release experiments up to pressures of 350GPa allows us to examine the pressure dependence. In this work, using a modern description of the shear modulus, validated against both ab initio theory and experimental measurements, we then assess how the experimentally measured pressure dependence scales with shear modulus. Furthermore, we find that the common assumption of scaling strength linearly with the shear modulus is too soft at high pressures and offer discussion as to how descriptions of slip mediated plasticity could result in an alternative scaling that is consistent with the data.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

The effect of nonsymmetric pressure stiffness on the dynamic characteristics of Solid Rocket Motors

This paper discusses the effect of pressure on the dynamics of pre-stiffened structures such as the Advanced Solid Rocket Motor (ASRM). Previous work in which the stiffness terms resulting from constant pressure were derived has been extended to enable modeling of nonconstant pressure applied over nonenclosed volumes. These conditions will result in nonsymmetric terms in the global stiffness matrix which will not cancel out. Three new pressure stiffness elements incorporating these nonsymmetric terms have been implemented as dummy elements in COSMIC NASTRAN and have been tested on various simple examples as well as an existing ASRM NASTRAN finite element model. The results indicate that for all load cases of practical interest to the ASRM program, the nonsymmetric terms have very little effect on the dynamic characteristics. In addition, the pressure stiffness elements developed in the previous work which assumed constant pressure gave virtually the same results as the new elements even for problems in which the pressures are not constant. The original elements appear to work well as long as the pressure gradient across any individual element is no larger than about 0.75 psi/inch. The new elements are therefore most useful for determining the conditions under which the original pressure stiffness elements can be used.

Christensen, Eric R.↗

Final Report DE-FE0031785 Mohsen Ahmadian, Ph.D. Demonstration of Proof of Concept of a Multiphysics Approach for Real-Time Remote Monitoring of Dynamic Changes in Pressure and Salinity in Hydraulically Fractured Networks

Hydraulic fracturing has evolved into a multistep process with varying flow rates, carrier fluids (e.g., gel or slickwater), proppant loadings, and proppant grain sizes. As a result, primary recovery from a hydraulically fractured tight-oil reservoir is often a tiny fraction of the original oil in place, ranging between 5 and 10%. As stated in the FOA1990, “part of this problem is due to the inability of current well completion processes to effectively stimulate the entire reservoir volume in contact with the wellbore. Innovative technologies are needed that can help improve the effectiveness of reservoir completion methods, maximize stimulated reservoir volumes, and optimize recovery over the entire producing life span of a well”. We first need to enhance the current fracture diagnostic techniques to improve a well-completion design. However, detecting and delineating a subsurface hydraulic fracture is extremely difficult because the induced fracture network is only fractionally propped, and these propped fractures are generally very thin. Microseismic and tiltmeter monitoring techniques can provide information on the fracture extent but provide little or no information on the movement and final distribution of proppant or production fluids. On the other hand, electromagnetic (EM) imaging has shown the capability to monitor proppant distribution throughout the fracture area, especially in the presence of Electrically Active Proppants (EAPs). A previous EM survey of hydraulic fracturing at the Devine Fracture Pilot Site (DFPS) and subsequent EM code developments demonstrated this survey as a robust technique to remotely interrogate the extent of the EAP-filled hydraulic fracture during its propagation. The objectives of the project were threefold: (1) to capitalize on the material properties of an EAP to demonstrate remote monitoring of relative changes in pressure, pressure, and flow that are commonly encountered during production from a hydraulically fractured reservoir; (2) to evaluate EM imaging tools, to achieve Objective 1 in near real-time; and (3) to develop a multi-physics joint inversion approach to precisely predict flow patterns and physiochemical changes within an EAP-filled fracture network. This research project was built upon our previous work at the Devine Test Site managed by the Bureau of Economic Geology (BEG) at The University of Texas at Austin (UT-Austin). It also leveraged a significant investment from the Advanced Energy Consortium (AEC) to address the DOE's interest in subsurface flow, containment, and characterization by multiple signals. This three-year and three-month project succeeded in demonstrating the feasibility of a real-time dynamic fluid flow mapping technique at Technology Readiness Level 5 (TRL5) by utilizing a commercially available surface-based Controlled-Source Electromagnetic (CSEM) method (Objectives 1, 2). We demonstrated that injections into an EAP-filled fracture could be successfully coupled with real-time electric field measurements on the surface, leading to remote monitoring of dynamic changes within the EAP-filled fracture. Furthermore, the observed electric field in our study is influenced by bottomhole pressure, flow rate, and salinity, which is demonstrated by comparing these parameters with the electrical field potentials. EM simulations solely based on assumptions of fracture conductivity changes during injection did not reproduce the whole measured electric field magnitudes. Preliminary estimates showed that including Streaming Potential (SP) in our geophysical model is likely needed to reduce the simulation misfit.

02 PETROLEUM↗

Passive Stabilization of Rotating Spacecraft Using Dynamic Fluid-Pressure Equilibrium

Rotating spacecraft can provide artificial gravity for long-term space missions, but the design of a Guidance and Control scheme for these vehicles is nuanced. For a three-segment vehicle with the propulsion element located at the center of mass, the vehicle must stabilize itself about this point even in the event of various off-nominal circumstances. Thus, a robust and passive spin stabilization system is needed. In this paper, the dynamics of this system are explored and constraints are placed on the performance and controllability. A controller is thus developed based on assumptions regarding the fluid transfer between elements, and the result is simulated. Generalized methodology is then extracted and extended applications are explored, such as a conceptual fluid ring and active mass displacement for attitude control.

Rotating↗

Molecular Dynamics of High Pressure Tin Phases I: Strength and deformation evaluations of empirical potentials [Slides]

Multi-phase problems have so many more unknowns, we’d like to have a tool to constrain some open questions related to microstructure and twin & dislocation behavior. We want an atomistic scale perspective on aspects of strength. Some multi-scale questions accessible to atomistic study: What lattice-specific behavior influences dislocation production/mobility and/or twinning? Do the phase transformations wipe-out, modify or preserve grain size and orientation? Does plastic strain reset at phase transition? If so under what conditions? Tin is the material chosen for the effort because it is non-hazardous and has multiple accessible solid phases at relatively low pressures.

36 MATERIALS SCIENCE↗