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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,369 records · Page 76
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Relationship Between the Integrity of Lubricating Film and the Tribological Behavior on TiAl-Ag Self-Lubricating Composites

To explore the relationship between the integrity of the lubricating film and the tribological behavior of a metal matrix self-lubricating composite, the friction and wear experiments of TiAl-Ag self-lubricating composites were carried out with a ball-on-disk configuration. Besides, an approximate model was developed for analyzing the relationship based on Blau’s theory. The research results suggest that the friction and wear behavior of the TiAl-Ag self-lubricating composites changes in accordance with the formation conditions of the Ag-rich lubricating film. Specifically, the friction coefficients and wear rates of the TiAl-Ag self-lubricating composites decreased from high levels at full composite–counterface ball contact to low levels at full-film lubrication. Hence, the integrity of the lubricating film is a possible criterion for the self-lubricating property of the self-lubricating composites.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Research on Oxidation Wear Behavior of a New Hot Forging Die Steel

Dry sliding tests for the hot forging die steel DM were performed in air under the test temperature at 400-700 °C and the time of 0.5-4 h by a UMT-3 high-temperature wear tester. The wear behavior and characteristics were studied systematically to explore the general characters in severe oxidation conditions. The results showed that a mild-to-severe oxidation wear transition occurred with an increase in the test temperature and duration. The reason was clarified as the unstable M{sub 6}C carbides coarsening should be responsible for the severe delamination of tribo-oxide layer. More importantly, an intense oxidation wear with lower wear rates was found when the experimental temperature reaches 700 °C or after 4 h of test time at 600 °C, which was closely related to the degradation behavior during wear test. Furthermore, a new schematic diagram of oxidation wear of DM steel was proposed.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Effects of Strain Rate on Tensile Deformation and Fracture Behavior of Directionally Solidified Superalloy DZ125L

The tensile deformation and fracture behavior of directionally solidified superalloy DZ125L were studied with a strain rate ranging from 10{sup −3} to 7 × 10{sup 2} s{sup −1} at room temperature. Results show that the strength of DZ125L alloy presents positive strain rate sensitivity in tested strain rate range which is mainly resulted from the increasing accumulation of dislocations in the matrix. The ductility of the alloy first increases and then it remains insensitive with the increase in strain rates. The enhancement of ductility is primarily due to the increasing amount of broken MC carbides and plastic deformation in the matrix at higher strain rates. The strain rates influence the amount of broken MC carbides and then affect the deformation behavior of the alloy. Based on observations and discussions of the lateral microstructures and dislocations, it is concluded that the MC carbides with sizes larger than 10 μm are easy broken in the early deformation stage and act as crack sources during the proceeding plastic deformation. The growth and connection of microcracks and the propagation of main crack lead to the fracture of the matrix.

36 MATERIALS SCIENCE↗
DOE OSTI2018

The Temperature Effect on the Compressive Behavior of Closed-Cell Aluminum-Alloy Foams

In this research, the mechanical behavior of closed-cell aluminum (Al)-alloy foams was investigated at different temperatures in the range of 25-450 °C. The main mechanical properties of porous Al-alloy foams are affected by the testing temperature, and they decrease with the increase in the temperature during uniaxial compression. From both the constant/serrated character of stress–strain curves and macro/microstructural morphology of deformed cellular structure, it was found that Al foams present a transition temperature from brittle to ductile behavior around 192 °C. Due to the softening of the cellular structure at higher temperatures, linear correlations of the stress amplitude and that of the absorbed energy with the temperature were proposed. Also, it was observed that the presence of inherent defects like micropores in the foam cell walls induced further local stress concentration which weakens the cellular structure’s strength and crack propagation and cell-wall plastic deformation are the dominant collapse mechanisms. Finally, an energy absorption study was performed and an optimum temperature was proposed.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Corrosion Behavior of Weathering Steel Under Thin Electrolyte Layer at Different Relative Humidity

The corrosion behavior of weathering steel under thin electrolyte layer (TEL) at different relative humidity (RH) was investigated by cathodic polarization, electrochemical impedance spectroscopy, electrochemical noise, SEM/EDS, XRD and Raman spectroscopy. The results indicate that during the initial stage, the corrosion rate increases as the RH decreases when the initial thickness of TEL is above 100 μm. During the middle and final corrosion stages, the corrosion behavior of weathering steel is influenced by RH, the initial thickness of TEL and corrosion product. The TEL corrosion is divided into three types, and a weathering steel corrosion model under TEL and bulk solution is also proposed.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Wetting Behavior and Reactivity of Molten Silicon with h-BN Substrate at Ultrahigh Temperatures up to 1750 °C

For a successful implementation of newly proposed silicon-based latent heat thermal energy storage systems, proper ceramic materials that could withstand a contact heating with molten silicon at temperatures much higher than its melting point need to be developed. In this regard, a non-wetting behavior and low reactivity are the main criteria determining the applicability of ceramic as a potential crucible material for long-term ultrahigh temperature contact with molten silicon. In this work, the wetting of hexagonal boron nitride (h-BN) by molten silicon was examined for the first time at temperatures up to 1750 °C. For this purpose, the sessile drop technique combined with contact heating procedure under static argon was used. The reactivity in Si/h-BN system under proposed conditions was evaluated by SEM/EDS examinations of the solidified couple. It was demonstrated that increase in temperature improves wetting, and consequently, non-wetting-to-wetting transition takes place at around 1650 °C. The contact angle of 90° ± 5° is maintained at temperatures up to 1750 °C. The results of structural characterization supported by a thermodynamic modeling indicate that the wetting behavior of the Si/h-BN couple during heating to and cooling from ultrahigh temperature of 1750 °C is mainly controlled by the substrate dissolution/reprecipitation mechanism.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Microstructure, Chemical Composition and Local Corrosion Behavior of a Friction Stud Welding Joint

In this paper, friction stud welding technology was used to join a stud and base metal, which were composed of X65 steel. The scanning vibrating electrode technique (SVET) and localized electrochemical impedance spectroscopy (LEIS) were used to investigate the localized corrosion behaviors of the welded joint. Scanning electron microscopy, metallographic microscopy and a micro-hardness tester were used to observe the microstructure and measure the hardness of the welded sample. Raman spectrometry and energy-dispersive spectrometry were used to measure the composition of the weldment before and after corrosion, respectively. The results show that there are the maximum micro-hardness and the densest microstructure in the welded zone compared with the other zones. In addition, α-Fe{sub 2}O{sub 3} and Fe{sub 3}O{sub 4} are present in the welded zone. The SVET and LEIS data indicate that the welded zone has the lowest current density and the largest impedance due to the presence of iron oxides and the densest microstructure, thus showing the excellent corrosion resistance. The relationship among microstructure, micro-hardness, chemical composition and local electrochemical behavior was discussed.

36 MATERIALS SCIENCE↗
DOE OSTI2018

The Precipitation Behavior and Hot Deformation Characteristics of Electron Beam Smelted Inconel 740 Superalloy

The Inconel 740 superalloy was prepared by the electron beam smelting (EBS) technology, the precipitation behavior and strengthening mechanism were studied, and the hot deformation characteristics of EBS 740 superalloy were investigated. The results indicate that the EBS 740 superalloy is mainly strengthened by the mechanism of weakly coupled dislocation shearing, and the resulting critical shear stress is calculated to be 234.6 MPa. The deformation parameters show a great influence on the flow behavior of EBS 740 superalloy. The strain rate sensitivity exponent increases with the increasing of deformation temperature, and the strain hardening exponent shows a decreasing trend with the increasing of strain. The activation energy of EBS 740 above 800 °C is measured to be 408.43 kJ/mol, which is higher than the 740H superalloy. A hyperbolic-sine-type relationship can be observed between the peak stress and Zener–Hollomon parameter. Nevertheless, the influence of deformation parameters is found to be considerably different at temperatures below and above 800 °C. The size of dynamic recrystallization (DRX) grains decreases with the increasing of strain rate when the strain rate is lower than 1/s, and reverse law can be found at higher strain rate. As a result, a piecewise function is established between the DRX grain size and hot working parameters.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Constitutive Behavior and Processing Map of T2 Pure Copper Deformed from 293 to 1073 K

The deformation behavior of T2 pure copper compressed from 293 to 1073 K with strain rates from 0.01 to 10 s{sup −1} was investigated. The constitutive equations were established by the Arrhenius constitutive model, which can be expressed as a piecewise function of temperature with two sections, in the ranges 293-723 K and 723-1073 K. The processing maps were established according to the dynamic material model for strains of 0.2, 0.4, 0.6, and 0.8, and the optimal processing parameters of T2 copper were determined accordingly. In order to obtain a better understanding of the deformation behavior, the microstructures of the compressed samples were studied by electron back-scattered diffraction. The grains tend to be more refined with decreases in temperature and increases in strain rate.

36 MATERIALS SCIENCE↗
DOE OSTI2018

An Investigation on the Wear and Corrosion Behavior of HVOF-Sprayed WC-12Co-Al{sub 2}O{sub 3} Cermet Coating

The aim of the present study is to develop thermally sprayable WC-12Co and WC-12Co-xAl{sub 2}O{sub 3} (x = 10 and 15 wt.%) cermet coatings on steel substrate (SS 304) by high-velocity oxy fuel (HVOF) method. Influence of Al{sub 2}O{sub 3} addition on the wear and corrosion behavior of WC-12Co coating has been studied. The microstructure and chemical composition of the coatings were analyzed using field emission scanning electron microscope (FESEM), and phase identification was carried out using x-ray diffraction (XRD) studies. The morphology of the coating appears as coarse granular structure. The XRD studies revealed the presence of hexagonal WC phase along with η-Co{sub 6}W{sub 6}C phase. It has been observed from the microhardness measurements, that the values gradually increase from 950 to 1300 HK with the addition of Al{sub 2}O{sub 3} from 0 to 15 wt.%. The wear rate of WC-12Co-15Al{sub 2}O{sub 3} (3.19 × 10{sup −6} mm{sup 3}/Nm) and WC-12Co-10Al{sub 2}O{sub 3} (5.26 × 10{sup −6} mm{sup 3}/Nm) coatings was seen to be one order of magnitude lower than that of WC-12Co (2.9 × 10{sup −5} mm{sup 3}/Nm) coating. The polarization studies revealed that WC-12Co-15Al{sub 2}O{sub 3} cermet coating showed superior corrosion protection than that of WC-12Co-10Al{sub 2}O{sub 3} and WC-12Co coatings. This has been attributed to the gradual decrease in the porosity levels with an increase in Al{sub 2}O{sub 3} content which is supported by morphology studies. The microhardness and wear behavior of WC-12Co-Al{sub 2}O{sub 3} coatings are equivalent to those of hard chrome suggesting the possibility of its replacement.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Effect of Different Cooling Rates on the Corrosion Behavior of High-Carbon Pearlitic Steel

The present work discusses the effect of pearlitic morphology on the corrosion behavior of high-carbon fully pearlitic steel in 3.5% NaCl solution. Four different types of pearlitic steels (furnace-cooled, as-received, air-cooled and forced-air-cooled) consisting of coarse, medium, fine and very fine microstructures, respectively, were tested. Electrochemical behavior of these steels was studied with the help of dynamic and linear polarization and AC impedance spectroscopic tests. The corrosion resistance improved with fineness of the microstructure in general. However, with further reduction in interlamellar spacing beyond a limit, the corrosion resistance reduced slightly. Formation of homogeneous distribution of microgalvanic cells between cementite and ferrite lamellae of fine pearlitic steel improved the corrosion resistance. However, entanglement of the lamellae of pearlite in very fine pearlitic structure as well as breaking of cementite lamellae due to finer pearlitic colonies was attributed to the higher corrosion of the forced-air-cooled steel as compared to the air-cooled steel.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Microstructure and Strain Rate-Dependent Tensile Deformation Behavior of Fiber Laser-Welded Butt Joints of Dual-Phase Steels

The microstructure and tensile deformation behavior of the fiber laser-welded similar and dissimilar dual-phase (DP) steel joints over a wide range of strain rates from 10{sup −3} to 10{sup 3} s{sup −1} were investigated for the further applications on the lightweight design of vehicles. The high strain rate dynamic tensile deformation process and full-field strain distribution of the base metals and welded joints were examined using the digital image correlation method and high-speed photography. The strain rate effects on the stress–strain responses, tensile properties, deformation, and fracture behavior of the investigated materials were analyzed. The yield stress (YS) and ultimate tensile strength (UTS) of the dissimilar DP780/DP980 welded joints were lying in-between those of the DP780 and DP980 base metals, and all materials exhibited positive strain rate dependence on the YS and UTS. Owing to the microstructure heterogeneity, the welded joints showed relatively lower ductility in terms of total elongation (TE) than those of the corresponding base metals. The strain localization started before the maximum load was reached, and the strain localization occurred earlier during the whole deformation process with increasing strain rate. As for the dissimilar welded joint, the strain localization tended to occur in the vicinity of the lowest hardness value across the welded joint, which was in the subcritical HAZ at the DP780 side. As the strain rate increased, the typical ductile failure characteristic of the investigated materials did not change.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Electrochemical Behavior of Sn-9Zn-xTi Lead-Free Solders in Neutral 0.5M NaCl Solution

Electrochemical techniques were employed to study the electrochemical corrosion behavior of Sn-9Zn-xTi (x = 0, 0.05, 0.1, 0.2 wt.%) lead-free solders in neutral 0.5M NaCl solution, aiming to figure out the effect of Ti content on the corrosion properties of Sn-9Zn, providing information for the composition design of Sn-Zn-based lead-free solders from the perspective of corrosion. EIS results reveal that Ti addition was involved in the corrosion product layer and changed electrochemical interface behavior from charge transfer control process to diffusion control process. The trace amount of Ti addition (0.05 wt.%) can refine the microstructure and improve the corrosion resistance of Sn-9Zn solder, evidenced by much lower corrosion current density (i{sub corr}) and much higher total resistance (R{sub t}). Excess Ti addition (over 0.1 wt.%) led to the formation of Ti-containing IMCs, which were confirmed as Sn{sub 3}Ti{sub 2} and Sn{sub 5}Ti{sub 6}, deteriorating the corrosion resistance of Sn-9Zn-xTi solders. The main corrosion products were confirmed as Sn{sub 3}O(OH){sub 2}Cl{sub 2} mixed with small amount of chlorine/oxide Sn compounds.

36 MATERIALS SCIENCE↗
DOE OSTI2018

A Study of Tensile Flow and Work-Hardening Behavior of Alloy 617

The simple power relationship σ = Κε{sub p}{sup n} satisfactorily expresses the tensile flow behavior of many metals and alloys in their uniform plastic strain regime. However, many FCC materials with low stacking fault energy have opposed such power law relationship. Alloy 617, an age-hardenable Ni-based superalloy is also observed not to obey the simple power law relationship neither in its solution-treated nor in its aged conditions. Various flow relationships were used to obtain the best fit for the tensile data, and different relationships were identified for the different aged conditions. The work-hardening rate (θ) demonstrates three distinct regions for all aged conditions, and there is an obvious change in the trend of θ versus σ. In the initial portion, θ decreases rapidly followed by a gradual increase in the second stage and again a decrease in its third stage is perceived in the Alloy 617. These three-stage characteristics are attributed to a commonly known precipitate, γ′: Ni{sub 3}(Ti, Al) which evolves during aging treatment and well recognized under transmission electron microscopy (TEM) observation. TEM results also reveal a slight degree of coarsening in γ′ over aging. The tensile flow and the work-hardening behavior are well correlated with other microstructural evolution during the aging treatments.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Constitutive Modeling of the High-Temperature Flow Behavior of α-Ti Alloy Tube

In the hot metal gas forming process, the deformation conditions, such as temperature, strain rate and deformation degree, are often prominently changed. The understanding of the flow behavior of α-Ti seamless tubes over a relatively wide range of temperatures and strain rates is important. In this study, the stress–strain curves in the temperature range of 973-1123 K and the initial strain rate range of 0.0004-0.4 s{sup −1} were measured by isothermal tensile tests to conduct a constitutive analysis and a deformation behavior analysis. The results show that the flow stress decreases with the decrease in the strain rate and the increase of the deformation temperature. The Fields–Backofen model and Fields–Backofen–Zhang model were used to describe the stress–strain curves. The Fields–Backofen–Zhang model shows better predictability on the flow stress than the Fields–Backofen model, but there exists a large deviation in the deformation condition of 0.4 s{sup −1}. A modified Fields–Backofen–Zhang model is proposed, in which a strain rate term is introduced. This modified Fields–Backofen–Zhang model gives a more accurate description of the flow stress variation under hot forming conditions with a higher strain rate up to 0.4 s{sup −1}. Accordingly, it is reasonable to adopt the modified Fields–Backofen–Zhang model for the hot forming process which is likely to reach a higher strain rate, such as 0.4 s{sup −1}.

36 MATERIALS SCIENCE↗
DOE OSTI2018

A Study on the Corrosion Behavior of Carbon Steel Exposed to a H{sub 2}S-Containing NH{sub 4}Cl Medium

NH{sub 4}Cl corrosion failure often occurs in the overhead systems of hydrotreaters, and this failure is always accompanied by the appearance of H{sub 2}S. A combination of electrochemical and surface spectroscopic (SEM/EDS, AFM, XRD) techniques was used to investigate the effect of different factors, including the surface roughness, temperature, dissolved oxygen, pH and H{sub 2}S concentration, on the corrosion behavior of carbon steel in an NH{sub 4}Cl environment with the presence of H{sub 2}S. The effect of H{sub 2}S concentrations (at the ppm level) on the corrosion behavior of carbon steel was systematically revealed. The experimental results clearly indicated that the corrosion rate reached a minimum value at 10 ppm H{sub 2}S. The steel surface was covered by a uniform corrosion product film in a 10 ppm H{sub 2}S environment, and the corrosion product film was tight and protective. The ammonia from NH{sub 4}Cl helped maintaining the protectiveness of the corrosion films in this environment. Dissolved oxygen mainly accelerated the cathodic reaction. The cathodic limiting current density increased with increasing temperature, and the anodic branch polarization curves were similar at different temperatures. The anodic current density decreased as the pH decreased, and the cathodic current density increased as the pH decreased. The absolute surface roughness (R{sub a}) of carbon steel increased from 132.856 nm at 72 h to 153.973 nm at 144 h, and the rougher surface resulted in a higher corrosion rate. The critical innovation in this research was that multiple influential factors were revealed in the NH{sub 4}Cl environment with the presence of H{sub 2}S.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Study on the Correlation Between Dynamical Behavior and Friction/Wear Mechanism Under the Effect of Grooves

In this work, the interfacial friction and wear and vibration characteristics are studied by sliding a chromium bearing steel ball (AISI 52100) over both multi-grooved and single-grooved forged steel disks (20CrMnMo) at low and high rotating speeds in order to reveal the effect mechanism of groove-textured surface on tribological behaviors. The results show that the grooves modify the contact state of the ball and the disk at the contact interface. This consequently causes variations in the normal displacement, normal force, and friction force signals. The changes in these three signals become more pronounced with increasing groove width at a low speed. The collision behavior between the ball and the groove increase the amplitude of vibration acceleration at a high speed. The test results suggest that grooves with appropriate widths could trap wear debris on the ball surface while avoiding a strong collision between the disk and the ball, resulting in an improvement in the wear states.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Analysis of Microstructure and Sliding Wear Behavior of Co{sub 1.5}CrFeNi{sub 1.5}Ti{sub 0.5} High-Entropy Alloy

Α Co{sub 1.5}CrFeNi{sub 1.5}Ti{sub 0.5} high-entropy alloy (HEA) of the well-known family of CoCrFeNiTi has been designed using empirical parameters. The aim of this design was the production of a HEA with fcc structure that gives ductile behavior and also high strength because of the solid solution effect. The VEC calculations (8.1) supported the fcc structure while the δ factor calculations (4.97) not being out of the limit values, advised a significant lattice distortion. From the other hand, the ΔΗ{sub mix} calculations (− 9.64 kJ/mol) gave strong indications that no intermetallic would be formed. In order to investigate its potential application, the Co{sub 1.5}CrFeNi{sub 1.5}Ti{sub 0.5} HEA was prepared by vacuum arc melting and a primary assessment of its surface degradation response was conducted by means of sliding wear testing using different counterbody systems for a total sliding distance of 1000 m. An effort to correlate the alloy’s wear response with the microstructural characteristics was attempted. Finally, the wear behavior of the Co{sub 1.5}CrFeNi{sub 1.5}Ti{sub 0.5} HEA was compared with that of two commercially used wear-resistant alloys. The results obtained provided some first signs of the high-entropy alloys’ better wear performance when tested under sliding conditions against a steel ball.

36 MATERIALS SCIENCE↗