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At least 1,369 records · Page 76

A simulation of I 2 S-LWR selected transients

The Integral Inherently Safe (I 2 S-LWR) reactor was designed to improve the safety performance of PWR types reactors, and several design basis accidents were eliminated using innovative approaches to the I 2 S-LWR plant layout. However, some accidents such as station blackout (SBO), main steam line break (MSLB) type accident – the secondary hot leg break (SHLB) – were deemed statistically relevant, and the work performed here was to simulate these events using the system thermal–hydraulics code RELAP5 coupled to the 3D spatial kinetics code PARCS. The safety response of the reactor to a station blackout is predicted to be acceptable at both beginning of cycle (BOC) and end of cycle EOC core conditions with either the UO 2 or U 3 Si 2 fuel options considered here. In the analysis of the SHLB performed here, an unprotected (no SCRAM) condition was assumed to highlight the I 2 S-LWR capabilities. Results indicate that with the UO 2 core, the fuel temperatures rise notably, but no fuel melting was predicted and departure from nucleate boiling ratio (DNBR) limits were not exceeded. Similarly, the U 3 Si 2 fuel performed well, but with lower fuel temperatures and decreased DNBR. Following the break of the steam line in the I 2 S-LWR, shutdown is achieved after about two minutes via negative reactivity from loss of primary flow. In all cases considered, the I 2 S-LWR appears to accomplish the goals of increased safety performance. Further design improvements and other fuel options may marginally improve on the observed safety performance. Additionally, higher fidelity analysis with the next generation subchannel, Computational Fluid Dynamics (CFD), or full core transport may be useful in refining the prediction of the peak fuel and cladding temperatures, as well limiting DNBR during the accidents.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Sensitivity analysis of VERA-CS and FRAPCON coupling in a multiphysics environment

A demonstration and description of the LOCA Toolkit for US light water reactors (LOTUS) is presented. Through LOTUS, the core simulator VERA-CS developed by CASL is coupled with the fuel performance code FRAPCON. The coupling is performed with consistent uncertainty propagation with all model inconsistencies being well-documented. Monte Carlo sampling is performed on a single 17 × 17 fuel assembly with a three cycle depletion case. Both uncertainty quantification (UQ) and sensitivity analysis (SA) are used at multiple states within the simulation to elucidate the behavior of minimum departure from nucleate boiling ratio (MDNBR), maximum fuel centerline temperature (MFCT), and gap conductance at peak power (GCPP). The SA metrics used are the Pearson correlation coefficient, Sobol sensitivity indices, and the density-based, delta moment independent measures. Results for MDNBR show consistency among all SA measures, as well for all states throughout the fuel lifecycle. MFCT results contain consistent rankings between SA measures, but show differences throughout the lifecycle. GCPP exhibits predominantly linear relations at low and high burnup, but highly nonlinear relations at intermediate burnup due to abrupt shifts between models. As a result, such behavior is largely undetectable to traditional regression or variance-based methods and demonstrates the utility of density-based methods.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Investigation of rotating mode behavior in BWR out-of-phase limit cycle oscillations – Part 2: TRACE/PARCS model and physical explanation

Previous neutronic/thermal-hydraulic (TH) coupled numerical simulations using full-core TRACE/PARCS and SIMULATE-3K boiling water reactor (BWR) models have shown evidence of a specific “rotating mode” behavior (steady rotation of the symmetry line, i.e. constant phase shift of approximately 90° between the first two azimuthal modes) in BWR out-of-phase limit cycle oscillations, regardless of initial conditions and even if the first two azimuthal modes have different natural frequencies. This suggests a nonlinear coupling between these modes; otherwise, the phase shift between these modes would change at a constant rate during the limit cycle. The previous paper (“Part 1”) presented a series of results to examine this rotating behavior with a reduced-order model. The goal of the present study is to provide additional analyses of the predicted rotating mode behavior using higher-fidelity numerical modeling, as well as a physical explanation for why this mode is favored over side-to-side or other oscillatory behaviors from a TH perspective. Results are presented using TRACE and TRACE/PARCS for a small number of parallel channels, which confirmed that the conclusions developed from the reduced-order model remain applicable when applying a full two-fluid, six-equation, finite-volume modeling approach. From these results, a physical explanation has been put forth to explain why the rotating symmetry line behavior is preferred from a TH standpoint, demonstrating that predominantly out-of-phase unstable systems are most unstable when the variation in the total inlet flow rate is minimized (which minimizes the effective single-phase to two-phase pressure drop ratio) and that the rotating mode is the most successful in minimizing this total flow rate variation as compared with the side-to-side case or any other oscillation pattern. The conclusion is that the rotating mode will be favored for any out-of-phase unstable system of parallel channels with no neutronic feedback or relatively weak neutronic feedback. Here, previous analyses have indicated that systems with sufficiently strong neutronic coupling may favor the side-to-side oscillation mode over the rotating mode; this topic is left as a subject of future investigation.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Four equation k-omega based turbulence model with algebraic flux for supercritical flows

Hydrocarbon and nuclear fuels will contribute substantially to the growing global energy portfolio for some time to come. At the same time atmospheric carbon levels and economic concerns are increasingly shaping the power generation environment. Supercritical fluid technologies are being investigated to address both concerns. For example, direct fired supercritical CO 2 power cycles offer key advantages for carbon capture and thermal efficiency. Additionally, the supercritical water reactor Generation IV nuclear reactor allows higher power densities and more efficient operation than current pressurized or boiling water reactors. As these technologies are developed, a need exists for accurate, yet cost-effective modeling and simulation solutions to assist with design and safety calculations. Supercritical fluid properties are strongly dependent on temperature which results in a number of unique flow features. Among these features are the complex buoyancy and buoyancy-turbulence interaction behaviors exhibited by supercritical flows that are not found in liquid or gas flows. Therefore, standard turbulence models with current model coefficient values are not likely to be applicable to supercritical fluid flows. The subject of this paper is efficient modeling and simulation of supercritical flows to support nascent technologies growing to maturation and operational deployment. We present a framework for developing Reynolds-Averaged Navier-Stokes turbulence models specifically equipped for the challenges of supercritical flows. A novel formulation of the algebraic heat flux model of the buoyancy production of turbulence term is used with a traditional shear stress transport model. To produce a new turbulence model for supercritical channel flows, the empirical coefficients of the resulting four equation model were calculated from data previously published by other authors regarding upward supercritical flow through heated pipes. The presented SST k t - ω t approach was validated against heated tube experiments to show predictive capabilities in moderate flow conditions, where buoyancy effects are important but not dominating of inertial effects.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

The SCALE/AMPX multigroup cross section processing for fast reactor analysis

The SCALE/AMPX multigroup (MG) cross section processing procedure has been updated to minimize reactivity differences for fast reactor designs and boiling water reactors (BWRs) with very high void fractions to provide excellent agreement with continuous-energy reference calculations. SCALE MG calculations are widely applied to thermal spectrum light-water reactor (LWR) systems as well as fast spectrum metallic systems of interest to National Nuclear Security Administration. With growing interest from industry and regulators in applying SCALE for the design of fast spectrum reactors, both sodium and molten salt, and in the licensing of power up rates for BWRs, it is desirable to review the SCALE/AMPX procedure for unresolved resonance self-shielded data and high energy neutron spectra. The data were improved by generating MG unresolved resonance data based on the analytic probability table method with the narrow resonance approximation as well as the use of a very fine group structure typically used in fast system analysis. This study focused on verifying the probability table and the SCALE/AMPX MG cross section processing procedure by performing reaction rate analysis and benchmark calculations for various fast reactor and high void BWR systems. Here, results indicate that the improved SCALE/AMPX MG cross section processing provides excellent results for the fast reactor analysis.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Development of the multigroup cross section library for the CASL neutronics simulator MPACT: Method and procedure

The MPACT neutronics module of the Consortium for Advanced Simulation of Light Water Reactors (CASL) core simulator is a 3D whole core transport code being developed for the CASL toolset known as the Virtual Environment for Reactor Analysis (VERA). Key characteristics of the MPACT code include a subgroup method for resonance self-shielding and a whole-core transport solver with a 2D/1D synthesis method. The AMPX and SCALE code packages have been significantly improved to include intermediate resonance parameters, as well as new modules to enhance the accuracy of resonance data and scattering matrices for the Bondarenko approach and transport cross sections of hydrogen. In addition, CASL XSTools have been developed to generate the MPACT multigroup cross section library. A simple super-homogenization method for 238U has been developed to resolve reaction rate discrepancy issues caused by angle-dependent total cross sections, poor scattering matrices, and a poor resonance interference model at coarse group structure. Here, due to the limitation of computing capacity that can occur even in high performance computing, a new 51-group structure has been developed for efficient simulation that is applicable for both pressurized water reactor (PWR) and boiling water reactor (BWR) simulations. A new ENDF/B-VII.1 MPACT 51-group library has been developed using the AMPX/SCALE and XSTools code packages, and it has been verified and validated by performing various benchmark calculations.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Initial development of an RIA envelope for dispersed nuclear fuel

A reactivity insertion accident (RIA) is a design basis accident in which reactivity is rapidly injected as a result of a control rod ejection or blade drop scenario. The resultant power increase can result in fuel rod failure and subsequent release of radioactive material into the reactor’s primary system. For light water reactors, failure under RIAs is typically a result of fuel melt, pellet-cladding interaction, or rod over-pressurization. Fuel melt occurs when the fuel system is unable to transport heat out of the fuel system. Pellet-cladding interaction occurs when an aggressive fuel pellet expansion pushes on an embrittled cladding beyond its strain limit. Rod over-pressurization occurs when a fuel rod exceeds the critical heat flux and departs from nucleate boiling, causing the rod internal pressure to rapidly increase, exceeding the systems pressure, and balloon until it bursts. To prevent failure, regulators have developed safety requirements that limit the injected enthalpy based on the state of the fuel system. However, dispersed fuel could enable the removal or relaxation of regulator-imposed safety criteria. Dispersed fuel embeds fuel particles in a highly conductive metal. Dispersed particles can have a particle radius of 1 µm to greater than 100 µm. Traditional fuel systems are plagued by poor thermal conductivity, especially at higher burnups, thus reducing the ability of the fuel system to respond to an RIA. However, dispersed fuel could improve the ability of the fuel system to transport injected energy away from the fissile material and into the coolant more efficiently. Furthermore, dispersing the fuel particles mitigates hard contact that typically occurs in the traditional zirconium-uranium dioxide fuel system, thus removing pellet-cladding mechanical interaction as a potential failure mechanism. This paper evaluates fuel particles dispersed in a metal matrix using the BISON fuel performance code to develop an initial failure threshold based on melt temperature of the fuel particle and/or cladding material as a function of fission density for beginning-of-life and end-of-life conditions. BISON results show that (1) reducing the size of the particles allows fission density to increase as a function of time, (2) particle-to-particle proximity must be considered to evaluate the limiting conditions, and (3) improving the fuel particle thermal conductivity improves thermal performance.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Lattice physics calculations using the embedded self-shielding method in polaris, Part II: Benchmark assessment

Polaris is a 2D multigroup lattice physics capability in the SCALE code system used for the analysis of light water reactor fuel designs. In this work, verification and validation results of Polaris in SCALE 6.2 are presented. The SCALE/KENO continuous-energy Monte Carlo code is used as a reference to compare the results of more than 2,000 combinations of pressurized water reactor and boiling water reactor lattice designs and state points. Radiochemical assay measurements were also used to assess the accuracy of depletion calculations. Results show that Polaris, with ENDF/B-VII.1 cross section library, produces accurate lattice physics data for core simulators.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Sensitivity analysis of in-pile critical heat flux experiments in TREAT for characterization of RIA power-transient effects

A reactivity-initiated accident (RIA) is one type of postulated design basis accident (DBA) that can cause a departure from nucleate boiling (DNB) event in pressurized-water reactors (PWRs). A DNB occurrence and its consequences depend on the thermophysical properties of the fuel components and coolant, characteristics of the transient energy insertion into the fuel rod, and the onset of the critical heat flux (CHF) phenomenon. To leverage the restart of the Transient Reactor Test (TREAT) Facility, an effort is currently underway to better understand the cladding-to-coolant heat transfer mechanisms and the CHF phenomenon under fast-transient irradiation conditions. This paper characterizes the impact of power transients on the thermal-hydraulic behavior of a TREAT Facility reactor heater rodlet CHF experiment to provide the priority of parameters that need to be investigated for an improved CHF model. Sobol sensitivity analysis methods and the Reactor Excursion and Leak Analysis Program (RELAP5-3D) code were used to identify key input parameters on the uncertainty in the prediction of peak outer- and inner-surface temperatures of the heater tube, as well as the time of the DNB event. A series of sensitivity analyses revealed the total energy deposition on the tube and the transient effects of power pulse had large impacts on the maximum temperatures. The CHF multiplier had the largest impact on the time occurrence of CHF. The overall results show the energy deposition rate in the tube is the most influencing factor to the manifestation of CHF and the resulting thermal-hydraulic behaviors of the tube. The multiplier for the CHF, which is interpreted as the predicted CHF value, has the largest Sobol indices for the time of the CHF in all cases, since it directly determines the occurrence of CHF. It is inferred that the uncertainties in the thermal-hydraulic behaviors of fuels increase with respect to the key parameters as the power pulse becomes broader, and an accurate estimation of the energy deposition rate is required to reduce the uncertainty in the evaluation of the integrity of fuel if the CHF is expected to occur near the peak power. Therefore, the outputs are expected to provide rigorous interpretation of ongoing in-pile CHF experiments in the TREAT Facility reactor regarding thermal-hydraulic behavior of the fuel system aiming for a new transient in-pile CHF model.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Two-zone stratified wetwell model development and implementation for RELAP-7

The Reactor Core Isolation Cooling (RCIC) system consists of a turbine, pump and wetwell and is used in many US Boiling Water Reactors (BWRs) as an important heat removal system. The wetwell is a major heat sink within containment. Experimental investigations have shown that thermal stratification may occur in the wetwell during RCIC operation. Current systems-level analysis codes lack stratified wetwell models. Here, this paper describes the development of a stratified wetwell model for the RELAP-7 code. This paper uses a simple two-zone model for the wetwell water that can capture thermal stratification. This model assumes that a buoyant plume transports heat and mass from the steam injection site to the upper water zone. The buoyant plume assumption requires that steam is injected at a low enough rate so it adds negligible momentum. Model validation against experimental data shows similar trends of temperature field development in the suppression pool.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Extension of SCALE/Sampler’s sensitivity analysis

Nuclear data are a major source of uncertainties in reactor physics calculations. The propagation of nuclear data uncertainties to important system responses is instrumental when determining appropriate safety margins in reactor safety analyses. It is also important to understand the major contributors to the observed uncertainties to make recommendations for further measurements and evaluations and aid in the understanding of the studied system. The SCALE code system allows for nuclear data uncertainty analysis based on the random sampling approach as implemented in SCALE’s Sampler sequence. Sampler was recently extended by a sensitivity analysis in terms of the calculation of two correlation-based sensitivity indices. This analysis allows for the identification of the top contributing nuclear reactions to any analyzed output uncertainty. This paper presents the sensitivity indices, along with their interpretation and limitations. It demonstrates the application in an eigenvalue and decay heat analysis for a boiling water reactor fuel assembly.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

A study on the impact of using a subchannel resolution for modeling of large break loss of coolant accidents

The nuclear industry is investigating the feasibility of transitioning from 18- to 24-month fuel cycles because of the positive impact it would have on the operational costs for the current fleet of light-water reactors. A challenge to making this change is the increased risk of fuel fragmentation, relocation, and dispersal (FFRD) due to the known potential for ceramic fuel to pulverize into fine particles at the higher discharge burnups. Previous work has been performed by the Nuclear Energy Advanced Modeling and Simulation program to assess FFRD risk in high-burnup cores using the BISON fuel performance code and a coarse mesh thermal hydraulics (T/H) solution for a loss-of-coolant accident (LOCA) using the TRACE system T/H code. Because of the importance of the T/H solution for FFRD assessment, this study seeks to investigate the impact of using higher-fidelity subchannel techniques for modeling of the LOCA transient. CTF was used to model a subregion of a high-burnup core that was depleted by the Virtual Environment for Reactor Applications (VERA) multiphysics core simulator. Both coarse-mesh and pin-resolved models were created in CTF, and a consistent coarse-mesh TRACE model was also developed to allow for benchmarking the code results. Further, a large-break loss-of-coolant accident (LBLOCA) reflood transient was simulated using these three models, and results were compared. Results showed some consistent differences between the CTF and TRACE coarse models, including a higher peak cladding temperature (PCT) prediction in CTF and later quenching in CTF; however, the transient clad temperature behavior was similar, and these differences are likely due to post-critical heat flux heat transfer modeling differences and minimum film boiling temperature model differences. The pin-resolved results indicate that the PCT in the lumped model is often under-predicted by as much as 70 °C and that PCT occurs at a different location than the high-power pin in the assembly. The lumped model predicts a difference of 10 °C or less between the average and hot pins in the assembly, whereas the pin-resolved model predicts a range of over 100 °C. These results indicate that higher-fidelity T/H results may have an impact on predicted core behavior during LOCA, which may be important to consider when assessing FFRD risk.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Impact of U-10Mo HALEU fuel element tolerances on the Massachusetts Institute of Technology reactor safety and operational performance – Thermal hydraulics

The U.S. is coordinating efforts for the conversion of six U.S. High Performance Research Reactors (USHPRR) including one critical facility from highly enriched uranium (HEU) to low-enriched uranium (LEU). In order to continue the mission of these reactors, including the Massachusetts of Institute of Technology Reactor (MITR), and achieve similar performance, high-assay low-enriched uranium (HALEU) with a high-density metallic alloy of uranium with 10 wt% molybdenum (U-10Mo) is being evaluated. The impact of the fabrication specification and tolerances was assessed following the preliminary design of the MITR LEU fuel elements using the U-10Mo monolithic alloy. This research focuses on the analysis of fabrication specification impact on thermal hydraulics (TH) characteristic of the MITR LEU core as a function of the variation of the relevant fuel specification parameters (e.g., coolant channel gap thickness, fuel plate thickness, etc.). The analyses are performed based on an all-fresh LEU fuel conversion plan identified in a preliminary safety analysis report submitted to the Nuclear Regulatory Commission. The reactor power margin to the onset of nucleate boiling (ONB) is assessed under the limiting safety system settings (LSSS), where a scram occurs, to ensure there is sufficient margin to the reactor safety limit, which is defined by the onset of flow instability that occurs after the ONB. The best estimate plus uncertainty approach is employed to analyze this TH characteristic, which yields realistic results while maintaining adequate conservatism, utilizing a statistical uncertainty propagation method with the STAT7 code. The TH characteristic is analyzed as a function of the variability of the specification parameters resulting from the fabrication process. The main findings of this study show that the MITR core can meet the TH safety and operational requirements at the all-LEU initial core startup (cycle 1), selected transition cycles (most reactive cycle and most limiting cycle: cycle 3 and 5, respectively) and equilibrium (cycle 14) cores under all limiting fabrication parameter combinations considered. In addition, the analyses show that the dependency of the core power margin to ONB on those specification parameters that have the most direct impact on TH performance is non-linear but monotonically decreasing within the specification tolerances. The third order polynomial fit curves are reported in detail for selected limiting cases and can serve as a powerful tool for future MITR fuel management in cases such as when HALEU supply is established that may allow additional cycle length or other operational benefits.

Conversion↗

Design-informed neutronics assessment of long-lived fission product transmutation in a tokamak fusion reactor blanket

This study presents a neutronics-based assessment of the feasibility and viability of transmuting six major long-lived fission products (LLFPs) from light-water reactors, namely 99 Tc, 129 I, 79 Se, 93 Zr, 126 Sn, and 135 Cs, within the blanket region of a tokamak fusion reactor, using the MIT ARC design as a concrete fusion configuration. Monte Carlo neutronics simulations were performed to evaluate LLFP transmutation and to compare the results with a reference boiling water reactor (BWR). The results indicate that transmutation of all six LLFPs is neutronics-feasible in fusion reactors, with transmutation half-lives significantly shorter than their natural decay half-lives. For elemental targets, transmutation of 135 Cs, 126 Sn, and 93 Zr was found potentially viable, as the net mass transmuted exceeded that achievable in the reference BWR under identical target volume and irradiation time. When isotopically separated targets were considered, transmutation of 126 Sn and 93 Zr appeared potentially viable. A parametric study demonstrated that plasma geometry modifications can enhance local neutron flux, increasing the transmuted 93 Zr mass by approximately 33% and reducing the transmutation half-life from approximately 240 years to 180 years. Repositioning the target and adjusting material layer thickness reduced the transmutation half-life of 93 Zr to 67 years and increased the net mass transmuted by a factor of 50. Furthermore, these results demonstrate that fusion reactors can enable LLFP transmutation beyond the practical limits of thermal fission reactors and highlight the critical role of reactor and blanket design optimization. Engineering and fuel-cycle considerations required for deployment are beyond the scope of this neutronics-focused study.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Renewable diesel via hydrothermal liquefaction of oleaginous yeast and residual lignin from bioconversion of corn stover

A major barrier to profitable bioconversion of cellulosic biomass to hydrocarbon fuel precursors is the difficulty in breaking down feedstock lignin into carbon substrates that can be easily metabolized by industrial microbes. Hydrothermal liquefaction (HTL) of cellulosic biomass effectively breaks down and converts lignin into biocrude oil products, but provides relatively low yields of biocrude from feedstock carbohydrates. In the present study, bioconversion and HTL were integrated into a new hybrid system that employs the best of both processes to produce high quality fuel in high quantity. Bioreactor cultivation of the oleaginous yeast Lypomyces starkeyi produced dry cell mass yields up to 0.43 g/g of sugar and yields of intracellular triglyceride lipids (measured as fatty acid methyl esters) of up to 0.26 g/g of sugar in pretreated corn stover hydrolysate or simulated hydrolysate media. The lipid-rich bioreactor broth was mixed with pretreated corn stover lignin, and then co-fed to an HTL reactor to produce 0.40 g of biocrude oil per gram of feed on a dry weight basis. Optimizing the separation of HTL biocrude and the HTL aqueous phase could significantly increase the biocrude yield. Hydrotreating of the biocrude produced a high quality, renewable hydrocarbon fuel blendstock, with the majority of the product boiling in the distillate range. The estimated cost of production could be reduced to $3/gasoline gallon equivalent through addressing identified research gaps. Our results provide a proof-of-concept for a new hybrid biorefinery design that could enhance domestic production of renewable diesel, jet, and marine fuel in the United States.

Biomass, Continuous hydrothermal liquefaction, Bio↗

Two-phase operation of a Terry steam turbine using air and water mixtures as working fluids

Terry steam turbines are employed in the safety systems of many nuclear Boiling Water Reactors to drive pumps and provide cooling water to the nuclear reactor core. While the turbine efficiency is low, the more important feature is high reliability under off-normal conditions. An important aspect of reliability is the ability to function with two-phase steam-water injection into the turbine, as most likely occurred in the Fukushima Dai-ichi nuclear accidents. This study investigates the characteristics of a Terry turbine during air-water injection with gas mass fractions ranging from 1 (dry gas) to 0.05 (wet gas), to better understand the Terry turbine’s true operational capabilities and provide justification for extended Terry turbine use for reactor safety. Other parameters investigated are the inlet pressure, the exhaust backpressure and the turbine’s rotational speed. The turbine performance is presented in terms of dynamometer loading and pump performance change as functions of the gas mass fraction.

42 ENGINEERING↗

Ammonia-based chemisorption heat pumps for cold-climate heating applications: A comprehensive review

This paper reviews the state of the art of chemisorption heat pumps that use ammonia as the refrigerant for cold-climate heating applications. In such a system, ammonia vapor is adsorbed by the solid salt through reversible chemisorption reactions, and the thermal effect of the reaction and ammonia phase change is used to extract heat from a cold environment and supply heat to a warm environment. With the high latent heat and low boiling point of ammonia as a low-temperature refrigerant and the high sorption capacity of ammonia-based chemisorption reactions, chemisorption heat pumps have the potential to produce high-efficiency heating, particularly for cold climates. This review first briefly introduces the basics of ammonia-based chemisorption heat pump systems. Then, the latest development of sorbent materials, including ammoniate salts and heat-conductive porous matrix materials, are summarized with the focus on low-temperature heating conditions. The design of system components, as well as cycle configurations, in the literature are summarized. This review concludes with highlights of recent developments on these topics and suggestions of areas for further research.

42 ENGINEERING↗

Co-processing catalytic fast pyrolysis oil in an FCC reactor

Here, studies of co-processing catalytic fast pyrolysis (CFP) oil with vacuum gas oil (VGO) are conducted in a Davison Circulating Riser (DCR). The CFP oil (CFPO) for this study was produced by upgrading fast-pyrolysis vapors from pine in an ex-situ fixed-bed reactor. CFPOs were co-processed at up to a volume fraction of 0.05 with VGO at 521 degrees C and 257 kPa. The yields of oil, aqueous phase, tail gas, and coke were measured. The amount of coke was determined from the carbon containing components in the regenerator flue gas. A compositional analysis was conducted with gas chromatography and elemental analyzers. The organic liquids were distilled into gasoline, jet-fuel, diesel, and resid fractions. A biocarbon analysis was conducted on the organic phase and its individual boiling-point fractions. The results show a small decrease in liquid yield and a generally increased gas yield when co-processing CFPO with VGO. The experiments showed that 75%-100% of biocarbon is incorporated into liquid fuels relative to fossil carbon, depending on catalyst and CFPO. The measurements indicate that cracked CFPO components are predominantly included in the jet-fuel and diesel fractions. A techno-economic analysis (TEA) estimated the minimum fuel selling price (MSFP) for fuel-range products derived from FCC co-processing of CFPO at 24 to 29 $\$$/GJ ($\$$2.90 to $\$$3.50 per gasoline-gallon equivalent; GGE) at a yield of 4.87-7.14 GJ/t(biomass) or 40-58 GGE/t.

09 BIOMASS FUELS↗