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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,351 records · Page 75

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DOE OSTI2020

Cluster Expansion Analysis of Atomic Order in Li-Ion Battery Cathode Material LiCo y Ni 1-y O 2

A modified cluster-expansion treatment was developed recently to analyze atomic order in LiCo y Ni 1-y O 2 , a model cathode material for Li-ion batteries. In this treatment, referred to as a “spin-atom” cluster expansion, the occupant of a lattice site is identified by its spin state as well as its atomic species. Further, Effective Cluster Interaction (ECI) coefficients are derived from a large training data set (i.e., the set of atomic arrangements for which DFT calculations are performed) which is filtered by an anomaly detection algorithm to eliminate poorly converged DFT calculations. The cluster expansion incorporates Li-Ni (LN) exchange as well as intralayer Co-Ni (CN) exchange. Monte Carlo simulations based on the cluster expansion were applied to the Ni-rich part of the phase diagram. The simulations predict a miscibility gap between y = 0.05 and y = 0.65.

25 ENERGY STORAGE↗

DOE OSTI2019

Seismic Noise Induced by Wind Turbine Operation and Wind Gusts

Improved seismic noise characterization, due to varied sources, may benefit traditional applications. Some examples are earthquake detection, Earth structure research, and nuclear testing. This improvement could also permit use of seismic data in transdisciplinary research such as wind gust detection and wind turbine (WT) condition monitoring. However, it is a challenging task to unambiguously quantify relationships between potential sources of seismic noise and the actual seismic response. In this article, we analyze seismic and meteorological data (wind speed and pressure), measured at a remote site in a complex terrain area in eastern Portugal, to examine seismic signatures from WT operational status and wind gusts. Results presented herein show the following: (1) WT signatures in seismic data can be used to accurately determine WT-operational status. Attenuation of WT signatures in seismic data exhibits an exponential decay with distance, with attenuation coefficients that scale with frequency. (2) After WT signatures are removed from seismic power spectra, wind gust signatures remain. Analyses of these data further indicate that it may be possible to extract quantitative wind gust estimates from seismic data and decompose them into pressure and shear stress drivers of this coupling.

Geochemistry & Geophysics↗

NASA NTRS1977

Site Alteration Effects from Rocket Exhaust Impingement During a Simulated Viking Mars Landing. Part 2: Chemical and Biological Site Alteration

Chemical and biological alteration of a Mars landing site was investigated experimentally and analytically. The experimental testing was conducted using a specially designed multiple nozzle configuration consisting of 18 small bell nozzles. The chemical test results indicate that an engine using standard hydrazine fuel will contaminate the landing site with ammonia (50-500ppm), nitrogen (5-50ppm), aniline (0.01-0.5ppm), hydrogen cyanide (0.01-0.5ppm), and water. A purified fuel, with impurities (mostly aniline) reduced by a factor of 50-100, limits the amount of hydrogen cyanide and aniline to below detectable limits for the Viking science investigations and leaves the amounts of ammonia, nitrogen, and water in the soil unchanged. The large amounts of ammonia trapped in the soil will make interpretation of the organic analysis investigation results more difficult. The biological tests indicate that the combined effects of plume gases, surface heating, surface erosion, and gas composition resulting from the retrorockets will not interfere with the Viking biology investigation.

Husted, R. R.↗

NASA NTRS1982

Climate studies from satellite observations - Special problems in the verification of earth radiation balance, cloud climatology, and related climate experiments

A body of techniques that have been developed and planned for use during the Earth Radiation Budget Experiment (ERBE), the International Satellite Cloud Climatology Project (ISCCP), and related climate experiments of the 1980's are reviewed. Validation and verification methods must apply for systems of satellites. They include: (1) use of a normalization or intercalibration satellite, (2) special intensive observation areas located over ground-truth sites, and (3) monitoring of sun and earth by several satellites and/or several instruments at the same time. Since each climate application area has a hierarchy of user communities, validation techniques vary from very detailed methods to those that simply assure high relative accuracy in detecting space and time variations for climate studies. It is shown that climate experiments generally require more emphasis on long-term stability and internal consistency of satellite data sets than high absolute accuracy.

Vonder Haar, T. H.↗

NASA NTRS1987

Estimating key forest ecosystem parameters through remote sensing

Forest canopy chemistry and biomass indicators of ecosystem photosynthesis and decomposition processes are presently studied in view of Airborne Imaging Spectrometer data, which generated spectra from averaged 3 x 3 pixel areas for each of 20 sites for mutual qualitative comparison. Vegetation spectra were strongly differentiated from other cover types by an apparent absorption feature at 1500-1700 nm. Preliminary work with stepwise regression suggests that lignin may play a role in canopy reflectance, and that there is potential for remote detection of forest canopy lignin.

Wessman, Carol A.↗

NASA NTRS1992

Environmental projects. Volume 15: Environmental assessment: Proposed 1-megawatt radar transmitter at the Mars site

The Goldstone Deep Space Communications Complex (GDSCC), located in the Mojave Desert about 64.5 km (40 mi) north of Barstow, California. and about 258 km (160 mi) northeast of Pasadena, California, is part of the National Aeronautics and Space Administration's (NASA's) Deep Space Network (DSN), one of the world's larger and more sensitive scientific telecommunications and radio navigation networks. The Goldstone Complex is managed, technically directed, and operated for NASA by the Jet Propulsion Laboratory (JPL) of the California Institute of Technology in Pasadena, California. Activities at the GDSCC support the operation of six parabolic dish antennas located at five separate sites called Deep Space Stations (DSS's). Four sites, named Echo, Mars, Uranus, and Apollo, are operational for space missions, while the remaining Venus Site is devoted to research and development activities. The Mars Site at the GDSCC contains two antennas: the Uranus antenna (DSS 15, 34 m) and the Mars antenna (DSS 14, 70 m). This present volume deals solely with the DSS-14 Mars antenna. The Mars antenna not only can act as a sensitive receiver to detect signals from spacecraft, but it also can be used in radar astronomy as a powerful transmitter to send out signals to probe the solar system. At present, the Mars antenna operates as a continuous-wave microwave system at a frequency of 8.51 GHz at a power level of 0.5 MW. JPL has plans to upgrade the Mars antenna to a power level of 1 MW. Because of the anticipated increase in the ambient levels of radio frequency radiation (RFR), JPL retained Battelle Pacific Northwest Laboratories (BPNL), Richland, Washington, to conduct an environmental assessment with respect to this increased RFR. This present volume is a JPL-expanded version of the BPNL report titled Environmental Assessment of the Goldstone Solar System Radar, which was submitted to JPL in Nov. 1991. This BPNL report concluded that the operation of the upgraded Mars antenna at the GDSCC, with its increased potential electromagnetic radiation hazards and interferences, would have no significantly adverse biological, physical, or socioeconomic effects on the environment. Thus, a Finding of No Significant Impact (FONSI) is appropriate in accordance with local, State, Federal, and NASA environmental rules and regulations.

Source record↗

DOE OSTI2020

Assessment of Cold Spraying Mild-Steel Powder onto Mild-Steel Substrate for Development of Waste Tank Repair System - 20515

Infrastructure for nuclear waste storage and processing (e.g., waste tanks, transfer pipelines, evaporators) at the U.S. Department of Energy (DOE) Hanford Site has been in service well beyond its original design life. Past corrosion control methods at Hanford for waste tanks have not been fully successful, as evidenced by leaks forming in tank AY-102, the first double-shell tank (DST) constructed, and significant degradation detected in the primary tanks of AP-102 and AY-101. Failure of infrastructure components can pose a significant risk to the environment, worker safety, and project schedules. Therefore, remotely deployable methods for repairing and extending the service life of the existing tank waste infrastructure are needed. Cold spray has been identified as a potential technique for performing in situ repairs and material buildup for life extension of waste storage and processing infrastructure. Cold-spray repair methods and technology are well-established and are used extensively by industry and the military for making repairs using dissimilar materials. Pacific Northwest National Laboratory is evaluating the process of making repairs using mild-steel powder applied to a mild-steel substrate to minimize the galvanic corrosion potential. This paper presents the initial results for a feasibility ('go/no-go') assessment as to whether low-density deposits with sound metallurgic bonds, to build-back steel plate material, can be achieved using existing commercial cold-spray equipment. An assessment of steel-on-steel deposit is necessary to determine if cold spray is a viable candidate for DST carbon steel plate restoration/repair and thus DST service life extension. Powder properties and preparation requirements have been investigated and operating conditions and parameters for depositing a cold-spray buildup of mild steel on a mild-steel substrate have been determined. Soundness of metallurgic bonding as a function of the operating parameters exercised and results from applying cold spray to lay a deposit over simulated small-diameter flaws in 1/2-inch mild-steel plate are presented. Application of in situ cold-spray repair to the DOE complex has the potential to reduce cost and schedule impacts associated with component failures and the need to procure and construct replacement infrastructure. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2023

Preliminary report on applications of machine learning techniques to the Nevada play fairway analysis

We are applying machine learning (ML) techniques, including training set augmentation and artificial neural networks, to mitigate key challenges in the Nevada play fairway project. The study area includes ~85 active geothermal systems as potential training sites and >12 geologic, geophysical, and geochemical features. The main goal is to develop an algorithmic approach to identify new geothermal systems in the Great Basin region. Major objectives include: 1) integrate ML techniques into the geothermal community; 2) develop open community datasets, whereby all play fairway and ML datasets and algorithms are publicly released and available for modification by various user groups; 3) identify data acquisition targets with high value for future work; 4) identify new signatures to detect blind geothermal systems; and 5) foster new capabilities for characterizing subsurface temperature and permeability. Initially, ML techniques are being applied to the same play fairway datasets and workflow. ML will then be applied to both enhanced and additional datasets, with modification of the PFA workflow to incorporate the new datasets. Finally, ML will be applied to define new workflows using the enhanced and additional datasets. An algorithmic approach that empirically learns to estimate weights of influence for diverse parameters can potentially scale and perform better than the play fairway analysis. Initial work on this project has involved 1) evaluating potential positive and negative training sites, 2) transformation of datasets into formats suitable for ML, and 3) initial development and testing of ML techniques.

58 GEOSCIENCES↗

DOE OSTI2023

Allosterically coupled conformational dynamics in solution prepare the sterol transfer protein StarD4 to release its cargo upon interaction with target membranes

Complex mechanisms regulate the cellular distribution of cholesterol, a critical component of eukaryote membranes involved in regulation of membrane protein functions directly and through the physiochemical properties of membranes. StarD4, a member of the steroidogenic acute regulator-related lipid-transfer (StART) domain (StARD)-containing protein family, is a highly efficient sterol-specific transfer protein involved in cholesterol homeostasis. Its mechanism of cargo loading and release remains unknown despite recent insights into the key role of phosphatidylinositol phosphates in modulating its interactions with target membranes. We have used large-scale atomistic Molecular dynamics (MD) simulations to study how the dynamics of cholesterol bound to the StarD4 protein can affect interaction with target membranes, and cargo delivery. We identify the two major cholesterol (CHL) binding modes in the hydrophobic pocket of StarD4, one near S136&S147 (the Ser-mode), and another closer to the putative release gate located near W171, R92&Y117 (the Trp-mode). We show that conformational changes of StarD4 associated directly with the transition between these binding modes facilitate the opening of the gate. To understand the dynamics of this connection we apply a machine-learning algorithm for the detection of rare events in MD trajectories (RED), which reveals the structural motifs involved in the opening of a front gate and a back corridor in the StarD4 structure occurring together with the spontaneous transition of CHL from the Ser-mode of binding to the Trp-mode. Further analysis of MD trajectory data with the information-theory based NbIT method reveals the allosteric network connecting the CHL binding site to the functionally important structural components of the gate and corridor. Mutations of residues in the allosteric network are shown to affect the performance of the allosteric connection. These findings outline an allosteric mechanism which prepares the CHL-bound StarD4 to release and deliver the cargo when it is bound to the target membrane.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2022

Detection and attribution of long-term and fine-scale changes in spring phenology over urban areas: A case study in New York State

Spring phenology plays an essential role in climate change, terrestrial ecosystem, and public health. Field-based monitoring and understanding of changes in spring phenology for long periods and in large regions are challenging due to the limited in-site observations. Space-based remotely sensed observations offer great potentials for monitoring decadal spring phenology changes from regional to global scales. However, the coarse-scale remotely sensed observations are insufficient to capture fine-scale spring phenology dynamics, especially in urban areas, and this makes it challenging for understanding the combined effects of climate change and urbanization on spring phenology. We derived the start of phenology season (SOS) in New York State using 30 m Landsat observations from 1990 to 2015 to understand the impact of the environment and urbanization on SOS. The results show that SOS for different years reveals heterogeneous spatial distribution. Most regions of New York State have been experiencing significant spring phenology changes in form of earlier onset of vegetation greening, ranging from 0.2 to 0.6 day/year during 1990 to 2015, and this trend varies slightly with latitudes and urbanization levels. Further, spatial correlation analysis shows that the increase in temperature and urbanization could both promote the advancement of SOS. However, the effect of urbanization (partial correlation coefficient (R) ranges from −0.289 to −0.542) on SOS is greater than the effect of temperature (R ranges from 0.006 to −0.192). The study generates a high spatio-temporal resolution spring phenology dataset for ecological, environmental and public health studies, especially in urban areas, and reveals the importance of better accounting for the urbanization effects when quantifying the SOS dynamics in phenology models.

Landsat↗

NASA NTRSDate not supplied

A Simulated Drilling Mission to Search for Bio-molecular Signatures of Life on Mars Performed in the Atacama Desert (Chile): Demonstrating Drilling, Sample Handling, and Life-Detection Instruments Remotely Operated with Mission-like Protocols

The search for evidence of life on Mars requires accessing materials that are protected from the oxidizing and irradiated conditions at the surface. Mars rovers Curiosity and Perseverance have performed shallow (few cm) drilling to access relevant samples. The upcoming ExoMars mission will acquire samples from up to 2 meters depth. Field experiments in Mars analog sites help prepare for this and other future deep drilling missions. In Sept. 2019 the ARADS (Atacama Rover Astrobiology Drilling Studies project (Glass et al. 2022) conducted a rover-based drilling mission to search for bio-molecular evidence of life in a Mars analog site in Atacama Chile.

Carol R. Stoker↗

NASA NTRSDate not supplied

A Simulated Drilling Mission to Search for Biomolecular Signatures of Life on Mars Performed in the Atacama Desert (Chile): Demonstrating Drilling, Sample Handling, and Life-Detection Instruments Remotely Operated with Mission-like Protocols

The search for evidence of life on Mars requires accessing materials that are protected from the oxidizing and irradiated conditions at the surface. Mars rovers Curiosity and Perseverance have performed shallow (few cm) drilling to access relevant samples. The upcoming ExoMars mission will acquire samples from up to 2 meters depth. Field experiments in Mars analog sites help prepare for this and other future deep drilling missions. In Sept. 2019 the ARADS (Atacama Rover Astrobiology Drilling Studies project (Glass et al. 2022) conducted a roverbased drilling mission to search for biomolecular evidence of life in a Mars analog site in Atacama, Chile.

Carol R. Stoker↗

DOE OSTI2024

Diaspora: Resilience-Enabling Services for Real-Time Distributed Workflows

The need for real-time processing to enable automated decision making and experimental steering has driven a shift from high-performance computing workflows on a centralized system to a distributed approach that integrates remote data sources, edge devices, and diverse compute facilities. Under this paradigm, data can be processed close to the source where it is generated, thus reducing latency and bandwidth usage. System resilience is thus a key challenge, requiring distributed workflows to survive component failures and to meet stringent quality-of-service requirements, which results in the need to mitigate anomalies such as congestion and low availability of resources. To address these challenges, we propose Diaspora, a unified resilience framework that is inspired by event-driven communication patterns used in public clouds. Specifically, we propose an event fabric that extends across sites, facilities, and computations to provide timely, reliable, and accurate information about data, application, and resource status. On top of the event fabric, we build resilience-enabling services that combine QoS-aware data streaming, resilient data views, resilient compute and data resources, and anomaly detection and prediction, all of which collectively enhance workflow resilience for these scientific cases.

Rao, Nageswara↗

DOE OSTI2019

Draft Discharge Permit 1132 [Slides]

This presentation covers site hydrogeologic setting (including geologic setting and faults and fractures), groundwater monitoring for RLWTF, monitoring well locations, monitoring suite and frequency, quality of wells, and defense in depth – groundwater monitoring coupled with use of engineering controls and visual inspections. The objectives of groundwater monitoring are early detection of any future noncompliant releases, providing additional safety net to support extensive administrative and engineering controls, and monitoring to characterize extent of groundwater effected by noncompliant discharge.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1973

Detection of moisture and moisture related phenomena from Skylab

The author has identified the following significant results. This is a preliminary report on the ability to detect soil moisture variation from the two different sensors on board Skylab. Initial investigations of S190A and Sl94 Skylab data and ground truth has indicated the following significant results. (1) There was a decrease in Sl94 antenna temperature from NW to SE across the Texas test site. (2) Soil moisture increases were measured from NW to SE across the test site. (3) There was a general increase in precipitation distribution and radar echoes from NW to SE across the site for the few days prior to measurements. This was consistent with the soil moisture measurements and gives more complete coverage of the site. (4) There are distinct variations in soil textures over the test site. This affects the moisture holding capacity of soils and must be considered. (5) Strong correlation coefficients were obtained between S194 antenna temperature and soil moisutre content. As the antenna temperature decreases soil moisture increases. (6) The Sl94 antenna temperature correlated best with soil mositure content in the upper two inches of the soil. A correlation coefficient of .988 was obtained. (7) Sl90A photographs in the red-infrared region were shown to be useful for identification of Abilene clay loam and for determining the distribution of this soil type.

Eagleman, J. R.↗

NASA NTRS1975

Nearshore coastal mapping

Two test sites of different water quality and bottom topography were used to test for maximum water depth penetration using the Skylab S-192 MSS for measurement of nearshore coastal bathymetry. Sites under investigation lie along the Lake Michigan coastline where littoral transport acts to erode sand bluffs and endangers developments along 1,200 miles of shore, and on the west coast of Puerto Rico where unreliable shoal location and depth information constitutes a safety hazard to navigation. The S-192 and S-190A and B provide data on underwater features because of water transparency in the blue/green portion of the spectrum. Depth of 20 meters were measured with the S-192 in the Puerto Rico test site. The S-190B photography with its improved spatial resolution clearly delineates the triple sand bar topography in the Lake Michigan test site. Several processing techniques were employed to test for maximum depth measurement with least error. The results are useful for helping to determine an optimum spectral bandwidth for future space sensors that will increase depth measurements for different water attenuation conditions where a bottom reflection is detectable.

Polcyn, F. C.↗

NASA NTRS1989

Mars Rover Sample Return: A sample collection and analysis strategy for exobiology

For reasons defined elsewhere it is reasonable to search for biological signatures, both chemical and morphological, of extinct life on Mars. Life on Earth requries the presence of liquid water, therefore, it is important to explore sites on Mars where standing bodies of water may have once existed. Outcrops of layered deposits within the Valles Marineris appear to be ancient lake beds. Because the outcrops are well exposed, relatively shallow core samples would be very informative. The most important biological signature to detect would be organics, microfossils, or larger stromato-like structures, although the presence of cherts, carbonates, clays, and shales would be significant. In spite of the limitations of current robotics and pattern recognition, and the limitations of rover power, computation, Earth communication bandwidth, and time delays, a partial scenario was developed to implement such a scientific investigation. The rover instrumentation and the procedures and decisions and IR spectrometer are described in detail. Preliminary results from a collaborative effort are described, which indicate the rover will be able to autonomously detect stratification, and hence will ease the interpretation burden and lead to greater scientific productivity during the rover's lifetime.

Sims, M. H.↗

NASA NTRS1993

Automated propellant leak detection

An automated hydrogen leak detection system is being developed for earth-to-orbit rocket engine applications. The system consists of three elements, a sensor array, a signal processing unit, and a diagnostic processor. The sensor array consists of discrete solid state sensors which are located at specific potential leak sites and in potential leak zones. The signal processing unit provides excitations power for the sensors and provides analog to digital data conversion of the sensor signals. The diagnostic computer analyzes the sensor outputs to determine leak sources and magnitude. Leak data from the sensor network is interpreted using knowledge based software and displayed on-line through a graphical user interface including 3-D leak visualization. The system requirements have been developed assuming eventual application to the Space Shuttle Main Engine which requires approximately 72 measurement locations. A prototype system has been constructed to demonstrate the operational features of the system. This system includes both prototype electronics and data processing software algorithms. Experiments are in progress to evaluate system operation at conditions which simulate prelaunch and flight. The prototype system consists of a network using 16 sensors within a testbed which simulates engine components. Sensor response, orientation, and data analysis algorithms are being evaluated using calibrated leaks produced within the testbed. A prototype flight system is also under development consisting of 8 sensors and flight capable electronics with autonomous control and data recording.

Makel, D. B.↗