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At least 1,351 records · Page 75

Microwave emission above steady and moving sunspots

Two-dimensional maps of radio brightness temperature and polarization, computed assuming thermal emission with free-free and gyroresonance absorption, are compared with observations of active region 2502, performed at Westerbork at lambda = 6.16 cm during a period of 3 days in June 1980. The computation is done assuming a homogeneous model in the whole field of view and a force-free extrapolation of the photospheric magnetic field observed at MSFC with a resolution of 2.34 arcsec. The mean results are the following: (1) a very good agreement is found above the large leading sunspot of the group, assuming a potential extrapolation of the magnetic field and a constant conductive flux in the transition region ranging from .2 x 10 to the 6th to 10 to the 7th erg/sq cm 5; (2) a strong radio source, associated with a new-born moving sunspot, cannot be ascribed to thermal emission. It is suggested that this source may be due to synchrotron radiation by mildly relativistic electrons accelerated by resistive instabilities occurring in the evolving magnetic configuration. An order-of-magnitude computation of the expected number of accelerated particles seems to confirm this hypothesis.

Drago, F. Chiuderi↗

Lower-Hybrid Wave Structures and Interactions With Electrons Observed in Magnetotail Reconnection Diffusion Regions

We investigate waves close to the lower-hybrid frequency in 12 magnetotail reconnection electron diffusion region (EDR) events with guide field levels of near-zero to 30%. In about half of the events, the wave vector has a small component along the current sheet normal, consistent with known lower-hybrid drift wave properties, but the perpendicular magnetic field fluctuations can be comparable or greater than the parallel component, a feature unique to the waves inside and adjacent to EDRs. Another new wave property is that the wave vector has a significant component along the current sheet normal in some events and completely along the normal for one event. In 1/4of the events, the ∇∙𝑷(sub 𝑒) term has a significant contribution to the wave electric field, possibly a feature of lower-hybrid waves more likely to exist in the diffusion region than further away from the X-line. Electron temperature variations are correlated with the wave potential, due to wave electric field acceleration and crossings at the corrugated separatrix region with different amounts of mixing between reconnection inflowing and outflowing populations. The latter also leads to the anti-correlation between parallel and perpendicular temperature components. Using four-spacecraft measurements, the magnetic field line twisting is demonstrated by the correlated fluctuations in (∇×𝑽(sub 𝐸×𝐵))||and (∇×𝐁)||. The lower-hybrid wave in the EDR of weak guide field reconnection may be generated near separatrices and penetrate to the mid-plane or locally generated, and the latter possibility is beyond the prediction of previous reconnection simulations.

Magnetic reconnection↗

Switching of electrochemical selectivity due to plasmonic field-induced dissociation

Electrochemical reactivity is known to be dictated by the structure and composition of the electrocatalyst–electrolyte interface. Here, we show that optically generated electric fields at this interface can influence electrochemical reactivity insofar as to completely switch reaction selectivity. We study an electrocatalyst composed of gold–copper alloy nanoparticles known to be active toward the reduction of CO 2 to CO. However, under the action of highly localized electric fields generated by plasmonic excitation of the gold–copper alloy nanoparticles, water splitting becomes favored at the expense of CO 2 reduction. Real-time time-dependent density functional tight binding calculations indicate that optically generated electric fields promote transient-hole-transfer-driven dissociation of the O─H bond of water preferentially over transient-electron-driven dissociation of the C─O bond of CO 2 . These results highlight the potential of optically generated electric fields for modulating pathways, switching reactivity on/off, and even directing outcomes.

Alcorn, Francis M.↗

Formation of field-induced breakdown precursors on metallic electrode surfaces

Understanding the underlying factors responsible for higher-than-anticipated local field enhancements required to trigger vacuum breakdown on pristine metal surfaces is crucial for the development of devices capable of withstanding intense operational fields. In this study, we investigate the behavior of nominally flat copper electrode surfaces exposed to electric fields of hundreds of MV/m. Our novel approach considers curvature-driven diffusion processes to elucidate the formation of sharp breakdown precursors. To do so, we develop a mesoscale finite element model that accounts for driving forces arising from both electrostatic and surface-tension-induced contributions to the free energy. Our findings reveal a dual influence: surface tension tends to mitigate local curvature, while the electric field drives mass transport toward regions of high local field density. This phenomenon can trigger the growth of sharper protrusions, ultimately leading to a rapid enhancement of local fields and, consequently, to a runaway growth instability. We delineate supercritical and subcritical regimes across a range of initial surface roughness. Our numerical results are in qualitative agreement with experimentally reported data, indicating the potential practical relevance of field-driven diffusion in the formation of breakdown precursors.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Theory of electron-positron showers in double radio sources

A black hole of mass of about 300 million solar masses is assumed to be present in the nucleus of an active galaxy or quasar. With an axial magnetic field near 1000 gauss, a potential drop 10 to the 19th volts is generated by the unipolar induction of a rotating accretion disk surrounding the black hole. The possibility that the acceleration of electrons or positrons in the unipolar fields initiates an electromagnetic cascade shower at distances at least 10 to the 16th cm from the black hole is investigated. The scattering medium for the shower is considered to be the spectrum of low energy photons originating from the inner region of the disk. It is found that at completion of the cascade, power-law energy spectra of relativistic electrons and positrons and of gamma-rays emerge under appropriate conditions. If the cascade-initiating particles are collimated, the electrons and positrons emerge in a collimated beam. Such beams may power extragalactic double radio sources.

Burns, M. L.↗

Elucidating Electric Field-Induced Rate Promotion of Brønsted Acid-Catalyzed Alcohol Dehydration

Applied potentials have been demonstrated as a powerful tool to promote heterogeneous Brønsted acid catalysis by orders of magnitude, leveraging interfacial electric fields to stabilize protonated intermediates. However, the use of flat two-dimensional electrodes with inherently low active site densities limits the application of conventional thermochemical characterization techniques that can probe the nature of catalytic active sites. Here, we use kinetic analyses with an electrostatics-based model to elucidate the intricacies of potential-induced rate promotion, employing liquid-phase dehydration of 1-methylcyclopentanol catalyzed by carboxylic acid groups on carbon nanotubes as a probe system. By using a basket electrode to directly polarize catalyst powder, we demonstrate that thermocatalytic reaction rates can be promoted by 100,000-fold, exhibiting a log–linear dependence on applied potential with rate-potential scalings as high as 125 ± 4 mV per 10-fold rate increase. In agreement with model predictions, we show that lower ionic strengths attenuate potential sensitivity, resulting from a weakening of the interfacial electric field that interacts with the acidic proton. Furthermore, we experimentally confirm the model-predicted “isokinetic potential” (at ∼0.6 V vs Ag/AgCl)─the potential at which all rate scaling lines at various ionic strengths intersect, making the rate independent of ionic strength. Base titrations reveal that only ∼8% of the carboxylic acid sites are catalytically active, yet these same active sites are operational at the highest and lowest potentials. Collectively, our results provide a key methodology for modeling catalytic effects of electric fields, quantifying active sites under applied potential, and demonstrating fundamental principles of electric field-induced rate promotion.

Catalysts↗

Current–Induced Ion Concentration Polarization at a Perfect Ion–Exchange Patch in an Infinite Insulating Wall

This research examines theoretically the ion concentration polarization, ion fluxes, and electrostatic fields near an ion exchange patch in the wall of an electrified fluidic channel. These phenomena are important in related microfluidic ion-preconcentration systems. Under an electric field, counterions enter the ion-exchange patch at one side and leave at the other, with salt depletion occurring near the entrance and accumulation near the exit. Furthermore, the high patch conductivity and the concentration profiles lead to local electric field perturbations that may facilitate preconcentration. This study includes analytical expressions of ion concentrations and electrochemical potentials at small to moderate electric fields, as well as numerical simulations. Additionally, a simple matrix of polynomial coefficients (obtained via fitting of numerical data) enables analytical calculation of the 2-dimensional concentration profiles at all electric fields within the range investigated in the numerical simulations. This is possible because a single dimensionless parameter controls this problem.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

AL-ASMR: Active Learning of Atomistic Surrogate Models for Rare Events

Atomistic simulation with artificial intelligence (AI) is an emerging tool for understanding materials' properties and behaviors and predicting novel materials with optimized/targeted properties. Neural network potentials (NNPs) are outstanding in this field as they have shown a comparable accuracy to ab initio electronic structure calculations for reproducing potential energy surfaces while being several orders of magnitude faster. However, such NNPs can perform poorly outside of their training domain and typically fail catastrophically in the prediction of rare events in molecular dynamics (MD) simulations. For effective AL loops to distinguish the informative data from enhanced sampled configurations, we developed a decision engine by configurational similarity and uncertainty quantification (UQ) with data augmentation.

Jung, Gang Seob↗

Phase Field Sintering Simulations of Tagged UO 2

Isotopic taggants are being considered as an additive for UO 2 manufacturing to improve nuclear security. Before taggants can be adopted, it must be determined whether taggants have any effect on the fuel microstructure or performance. As part of this effort, a grand potential formulation of the phase field method was used to model untagged, Cr-tagged, and Fe-tagged UO 2 . The simulations were compared to determine whether the taggants had any effect on fuel density or grain size. The results suggest that the taggants will not affect the density or grain size, but these findings may not be reliable because of high uncertainty. Causes of the uncertainty were discussed, and future work is proposed to reduce the model uncertainty.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A Perturbative Solution for Nonlinear Stratified Upwelling over a Frictional Slope

Abstract A perturbative solution of simplified primitive equations for nonlinear weakly stratified upwelling over a frictional slope is found that resolves the vertical structure of velocity fields and can satisfy Ertel’s potential vorticity conservation in the stratified inviscid interior. The solution uses assumptions consistent with the model proposed by Lentz and Chapman, including a steady-state, constant cross-shore density gradient, no alongshore gradients, laterally inviscid, and consideration of cross-shore advection of alongshore momentum. The solution resolves the vertical structure of velocity fields (including subsurface maxima of compensational flow, not resolved by Lentz and Chapman) and can satisfy Ertel’s potential vorticity conservation in the stratified inviscid interior. The dynamics are similar to Lentz and Chapman; bottom stress balances alongshore wind stress in a homogeneous density ocean and is replaced by nonlinear cross-shore transport of alongshore momentum as the Burger number (S=αN/f, whereα,N, andfare the bottom slope, buoyancy frequency, Coriolis frequency, respectively) increases. When the solution uses the empirical relation between cross-shore and vertical density gradients proposed by Lentz and Chapman, vorticity conservation is not satisfied and the nonlinear momentum transport estimated by the solution linearly increases withS, asymptotically matching Lentz and Chapman forS< 1. When the solution conserves interior potential vorticity, the momentum transport is proportional toS 2 forS< 1 and is in better agreement with numerical simulations.

Oceanography↗

Eucalyptus Are Unlikely to Escape Plantations and Invade Surrounding Forests Managed with Prescribed Fire in Southeastern US

Woody biomass production can increase through establishment of non-native tree species exhibiting greater growth potential than traditional native species. Interest in growing Eucalyptus in the southeastern US has raised concern over its potential spread and invasion, which could impact ecosystem properties and functions. Within the matrix of land use where Eucalyptus establishment is being considered in the southeastern US, surrounding pine forests managed with fire represent a likely pathway for invasion. We used greenhouse and field experiments to evaluate the potential invasion risk of Eucalyptus benthamii. We were specifically interested in determining if seeds could successfully germinate in fire-maintained pine forests and if fire-return intervals influenced germination through impacts on litter accumulation and light availability. The greenhouse experiment investigated the influence of light availability on germination success, whereas the field study investigated the influence of time since fire, and thus litter accumulation and light availability, on germination success. Percent germination was similar under non-shaded controls and moderate shade, but complete shade resulted in low germination rates. Germination was lower in the field compared to the greenhouse and was influenced by litter and light availability, which varied according to fire-return intervals. Litter increased, and light availability decreased, with time since burn. Germination was negatively related to litter depth and positively related to light availability, thereby decreasing with time since fire. Germination increased with litter removal but remained positively related to light availability after litter removal. Higher germination with litter removal suggests germination is influenced by litter, but higher germination with increased light availability, regardless of raking, suggests germination is also influenced by light availability. Despite these relationships, no seedlings persisted through the growing season. The low germination rates under a variety of field conditions coupled with the lack of persistence suggests establishment may be unlikely, regardless of the surrounding land matrix.

54 ENVIRONMENTAL SCIENCES↗

Thaw Transitions and Redox Conditions Drive Methane Oxidation in a Permafrost Peatland

Thawing permafrost, ground that has been frozen for 2 or more years, often results in wet conditions that promote the production of methane (CH 4 ). Methane is a greenhouse gas that is over 30 times more powerful than carbon dioxide at warming the atmosphere. Microorganisms called methanotrophs can consume a substantial portion of this CH 4 before it reaches the atmosphere, but the extent of this consumption is not well understood. Methanotrophs are affected by environmental conditions, such as oxygen availability, that change with permafrost thaw. We used laboratory experiments to measure how quickly methanotrophs consume CH 4 from sites within a permafrost peatland with little, intermediate, and full permafrost thaw. We found that CH 4 consumption increased as permafrost thawed and that sites transitioning between thaw stages had a different potential to consume CH 4 than intact and fully thawed sites. Methane consumption was also high in locations with low dissolved oxygen, which suggests that methanotrophs in these sites may tolerate low oxygen conditions in the field. We found that redox potential, a measurement that describes the tendency for a compound to be oxidized or reduced, was a strong predictor of CH 4 consumption in partially and fully thawed sites. Overall, these measurements highlight the potential for methanotrophs to mitigate CH 4 emissions in peatlands with thawing permafrost and provide new insights to modeling CH 4 dynamics across the full thaw gradient.

54 ENVIRONMENTAL SCIENCES↗

Open magnetic fields in active regions

Soft X-ray images and magnetograms of several active regions and coronal holes are examined which support the interpretation that some of the dark X-ray gaps seen between interconnecting loops and inner cores of active regions are foot points of open field lines inside the active regions. Characteristics of the investigated dark gaps are summarized. All the active regions with dark X-ray gaps at the proper place and with the correct polarity predicted by global potential extrapolation of photospheric magnetic fields are shown to be old active regions, indicating that field opening is accomplished only in a late phase of active-region development. It is noted that some of the observed dark gaps probably have nothing in common with open fields, but are either due to the decreased temperature in low-lying portions of interconnecting loops or are the roots of higher and less dense or cooler loops.

Svestka, Z.↗

Integrating collapsible plasmonic gaps on near-field probes for polarization-resolved mapping of plasmon-enhanced emission in 2D material

Scanning near-field optical microscopy (SNOM) is an important technique used to study the optical properties of material systems at the nanoscale. In previous work, we reported on the use of nanoimprinting to improve the reproducibility and throughput of near-field probes including complicated optical antenna structures such as the ‘campanile’ probe. However, precise control over the plasmonic gap size, which determines the near-field enhancement and spatial resolution, remains a challenge. Here, we present a novel approach to fabricating a sub-20 nm plasmonic gap in a near-field plasmonic probe through the controlled collapse of imprinted nanostructures using atomic layer deposition (ALD) coatings to define the gap width. The resulting ultranarrow gap at the apex of the probe provides a strong polarization-sensitive near-field optical response, which results in an enhancement of the optical transmission in a broad wavelength range from 620 to 820 nm, enabling tip-enhanced photoluminescence (TEPL) mapping of 2-dimensional (2D) materials. We demonstrate the potential of this near-field probe by mapping a 2D exciton coupled to a linearly polarized plasmonic resonance with below 30 nm spatial resolution. This work proposes a novel approach for integrating a plasmonic antenna at the apex of the near-field probe, paving the way for the fundamental study of light-matter interactions at the nanoscale.

Zhou, Junze (ORCID:000000020682767X)↗

Wind tunnel investigation of aerodynamic and tail buffet characteristics of leading-edge extension modifications to the F/A-18

The impact of leading-edge extension (LEX) modifications on aerodynamic and vertical tail buffet characteristics of a 16-percent scale F/A-18 model has been investigated in the NASA Langley 30-foot by 60-foot tunnel. Modifications under consideration include variations in LEX chord and span, addition of upper surface fences, and removal of the LEX. Both buffeting and high-angle-of-attack aerodynamics are found to be strongly dependent upon the LEX geometry, which directly influences the strength, position, and breakdown characteristics of the vortex flow field. Concepts aimed at influencing the development of vortical flow field are considered to have much greater potential in design application than those geared toward altering already established flow fields. It is recommended that configuration effects on structural and aerodynamic characteristics be evaluated in parallel, so that trade-off studies can be conducted to ensure adequate structural fatigue life and desired high-angle-of-attack stability and control characteristics in the design of future high performance aircraft.

Shah, Gautam H.↗

Measurement of accreted helium ion velocity using Doppler spectroscopy in the CTIX compact-toroid plasma accelerator

A compact-toroid (CT) accelerator is a device for the production of plasma bodies which contain a relatively strong internal magnetic field, which permits the plasma body to withstand large forces of acceleration while retaining its magnetic field structure. Typically, the CT occupies an annular region between inner and outer radii, defined by coaxial inner and outer electrodes, across which a large electric potential is applied. The internal magnetic fields of the CT contain both a toroidal and poloidal component, as shown in Fig. 1(a). These fields are typically of comparable magnitude. Because of the effective rigidity provided by internal magnetic fields, the CT can be accelerated to high velocities in short distances. Since internal fields increase in proportion to accelerating magnetic field, there is no strength at which the accelerating magnetic fields overcome the internal field (blow-by). Because of this, the kinetic energy density of CTs can be made to exceed the energy density of magnetic fields typical of plasma containment devices such as tokamaks. CTs have the potential to be launched into the interior of such devices for either delivering fuel (typically deuterium or hydrogen), or to deliver particles of high atomic number (high-Z). An important application of high-Z CT injection into tokamaks is to aid in plasma quenching by radiation, to mitigate the effects of plasma disruptions and prevent damage to the plasma confinement device. In addition, high-Z CTs may be used as sources of kinetic energy density for plasma-compression experiments. In this case, the use of plasma species of high atomic number is also desirable, since kinetic energy density is proportional to atomic number for given CT velocity and electron density gas puffing.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Integration of the Radiation Belt Environment Model Into the Space Weather Modeling Framework

We have integrated the Fok radiation belt environment (RBE) model into the space weather modeling framework (SWMF). RBE is coupled to the global magnetohydrodynamics component (represented by the Block-Adaptive-Tree Solar-wind Roe-type Upwind Scheme, BATS-R-US, code) and the Ionosphere Electrodynamics component of the SWMF, following initial results using the Weimer empirical model for the ionospheric potential. The radiation belt (RB) model solves the convection-diffusion equation of the plasma in the energy range of 10 keV to a few MeV. In stand-alone mode RBE uses Tsyganenko's empirical models for the magnetic field, and Weimer's empirical model for the ionospheric potential. In the SWMF the BATS-R-US model provides the time dependent magnetic field by efficiently tracing the closed magnetic field-lines and passing the geometrical and field strength information to RBE at a regular cadence. The ionosphere electrodynamics component uses a two-dimensional vertical potential solver to provide new potential maps to the RBE model at regular intervals. We discuss the coupling algorithm and show some preliminary results with the coupled code. We run our newly coupled model for periods of steady solar wind conditions and compare our results to the RB model using an empirical magnetic field and potential model. We also simulate the RB for an active time period and find that there are substantial differences in the RB model results when changing either the magnetic field or the electric field, including the creation of an outer belt enhancement via rapid inward transport on the time scale of tens of minutes.

Glocer, A.↗

Microwave bistatic reflectivity dependence on the moisture content and matric potential of bare soil

Results are presented of an experimental program to determine the functional dependence of the microwave reflectivity of nonvegetated soil surfaces upon volumetric soil moisture and matric potential. A combination evaporation-drainage field experiment was conducted on a bare Captina slit loam with reflectivity, soil moisture content, and matric potential monitored for extended time periods. Results show that for a restricted pressure range (approximately -0.05 to -0.75 bar) there is excellent linear correlation between the log of bistatic reflectivity and both volumetric moisture content and matric potential. Layering effects due to steep moisture content (and matric potential) gradients in the profile are demonstrated to have two distinct and significant effects on the reflectivity response. At near saturation of rough surfaces a very thin dry surface layer appears to modify the effective roughness. This leads to a saturation of reflectivity at high moisture contents. As the surface proceeds to dry further, deeper layers produce coherent interference patterns in the reflectivity response, particularly at the higher frequencies.

Waite, W. P.↗