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At least 1,351 records · Page 75

Manipulating Conjugated Polymer Backbone Dynamics through Controlled Thermal Cleavage of Alkyl Side Chains

The morphological stability of an organic photovoltaic (OPV) device is greatly affected by the dynamics of donors and acceptors occurring near the device's operational temperature. These dynamics can be quantified by the glass transition temperature (T g ) of conjugated polymers (CPs). Because flexible side chains possess much faster dynamics, the cleavage of the alkyl side chains will reduce chain dynamics, leading to a higher T g . In this work, the T g s for CPs are systematically studied with controlled side chain cleavage. Isothermal annealing of polythiophenes featuring thermally cleavable side chains at 140 °C, is found to remove more than 95% of alkyl side chains in 24 h, and raise the backbone T g from 23 to 75 °C. Coarse grain molecular dynamics simulations are used to understand the T g dependence on side chain cleavage. X-ray scattering indicates that the relative degree of crystallization remains constantduring isothermal annealing process. The effective conjugation length is not influenced by thermal cleavage; however, the density of chromophore is doubled after the complete removal of alkyl side chains. Here, the combined effect of enhancing T g and conserving crystalline structures during the thermal cleavage process can provide a pathway to improving the stability of optoelectronic properties in future OPV devices.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Unraveling the multi-step crystallization mechanism of polytetrafluoroethylene, modified polytetrafluoroethylene, and their nanocomposites with boron nitride nanobarbs: Experimental insights and theoretical analysis

The non-isothermal crystallization behavior and kinetics of polytetrafluoroethylene (PTFE) composites with boron nitride nanobarb (BNNB), a new generation nanostructure with unique surface morphology and mechanical “barbs” have been analyzed, understanding these properties is essential for their high-end applications as thermal interface materials (TIM) for microwave, 5G and microelectronic devices. The analysis of the crystallization parameters includes crystallization onset, peak and end temperatures, crystallization half-life and overall crystallinity of PTFE, modified PTFE and their BNNB composites. The results were further analyzed using theoretical models such as the combined Avrami-Ozawa model. It was found that BNNB supports crystallization in the modified PTFE but shows minimal effect on the crystallization of PTFE. Due to the limitation of the classical theoretical models used above in fully characterizing the multi-step crystallization process of PTFE, an in-depth analysis using the model-free advanced isoconversional computation was used to characterize the PTFE crystallization based on the evolution of activation energy with fractional crystallinity and for the first time with temperature. Three kinetic regions were identified in the crystallization mechanism. Here, this study investigated the molecular organization and microstructural evolution of PTFE, modified PTFE and their composites during non-isothermal crystallization using advanced X-ray scattering measurements. An insight into the changes undergone by the material's microstructural units including crystallite size and morphology, lamellar thickness and lamellar interfacial layer thickness, and crystallographic phase dynamics during non-isothermal cooling from the melt, was provided here in this work. The effect of copolymer modification of PTFE and the inclusion of pristine and functionalized BNNB (a thermally conductive and electrically insulating ceramic) are both new investigations that provide valuable knowledge for the development of materials with strong matrix-nanofiller interaction and guidance for optimizing sintering and cooling cycles, two key steps in PTFE processing that largely affect the material microstructural features. Overall, the result of the three-part investigation demonstrates that BNNB supports crystallization in the modified PTFE up to 20 wt% concentration and at low and high cooling rates typically used in the industrial processing of PTFE.

36 MATERIALS SCIENCE↗

Side Chain Engineering of Near-IR Aza-BODIPY Dyes Enables Processable Films with High Hole Mobility in Diodes

Boron chelated azadipyrromethene (Aza-BODIPY) derivatives are promising candidates for near-infrared optoelectronic applications due to their tunable absorption, electron-deficient core, and strong π-conjugation. Here, in this work, we synthesized and studied a series of 1-naphthylethynyl-substituted aza-BODIPY molecules featuring hexyl or hexyloxy solubilizing groups at either the proximal or the distal phenyl positions. These substitutions were designed to improve the solubility, film formation, and optoelectronic properties. We found that solubilizing groups not only enabled uniform solution-processed films but also fine-tuned key properties, such as absorption onset, oxidation potential, and energy levels. Charge transport analysis showed consistently high hole mobilities (∼10 –3 cm 2 /V s) across all substituted derivatives when CuI was used as the hole transport layer, regardless of film morphology. In contrast, electron mobilities tended to be low and inconsistent, partly because of the relatively poor-quality films on the ZnO electron transport layer. Overall, we have shown that solubilizing groups enable film solution-casting and can fine-tune the properties of these near-infrared aza-BODIPY derivatives.

36 MATERIALS SCIENCE↗

Jovian large-scale stratospheric circulation

An attempt is made to diagnose the annual-average mean meridional residual Jovian large-scale stratospheric circulation from observations of the temperature and reflected sunlight that reveal the morphology of the aerosol heating. The annual mean solar heating, total radiative flux divergence, mass stream function, and Eliassen-Palm flux divergence are shown. The stratospheric radiative flux divergence is dominated the high latitudes by aerosol absorption. Between the 270 and 100 mbar pressure levels, where there is no aerosol heating in the model, the structure of the circulation at low- to midlatitudes is governed by the meridional variation of infrared cooling in association with the variation of zonal mean temperatures observed by IRIS. The principal features of the vertical velocity profile found by Gierasch et al. (1986) are recovered in the present calculation.

West, R. A.↗

Evidence for Hesperian Impact-Induced Hydrothermalism on Mars

Several hydrated silicate deposits on Mars are observed within craters and are interpreted as excavated Noachian material. Toro crater (71.8 deg E, 17.0 deg N), located on the northern edge of the Syrtis Major Volcanic Plains, shows spectral and morphologic evidence of impact-induced hydrothermal activity. Spectroscopic observations were used to identify extensive hydrated silicate deposits, including prehnite, chlorites, smectites, and opaline material, a suite of phases that frequently results from hydrothermal alteration in terrestrial craters and also expected on Mars from geochemical modeling of hydrothermal environments. When combined with altimetry and high-resolution imaging data, these deposits appear associated predominantly with the central uplift and with portions of the northern part of the crater floor. Detailed geologic mapping of these deposits reveals geomorphic features that are consistent with hydrothermal activity that followed the impact event, including vent-like and conical mound structures, and a complex network of tectonic structures caused by fluid interactions such as fractures and joints. The crater age has been calculated from the cumulative crater size-frequency distributions and is found to be Early Hesperian. The evidence presented here provides support for impact-induced hydrothermal activity in Toro crater, that extends phyllosilicate formation processes beyond the Noachian era.

Marzo, Giuseppe A.↗

Automated Image Segmentation and Processing Pipeline Applied to X–Ray Computed Tomography Studies of Pitting Corrosion in Aluminum Wires

Understanding pitting corrosion is critical, yet its kinetics and morphology remain challenging to study from X-ray computed tomography (XCT) due to manual segmentation barriers. To address this, an automated pipeline leveraging deep learning for efficient large-scale XCT analysis is developed, revealing new corrosion insights. The pipeline enables pit segmentation, 3D reconstruction, statistical characterization, and a topological transformation for visualization. Here, the pipeline is applied to 87 648 XCT images capturing commercial purity aluminum (1100 Al) wire exposed to sodium chloride (NaCl) salt particles over a period of 122 h. The pipeline achieves complete feature extraction and statistical quantification across the entire XCT dataset, leveraging distributed computing environment for high efficiency. Global growth kinetics such as high-level stepwise sigmoidal volume loss patterns and granular individual pit developments are both captured for 36 detected pits. By combining automation, computer vision, and extensive XCT datasets, this research accelerates precise corrosion assessment to enable materials science discoveries at scale.

36 MATERIALS SCIENCE↗

Rapid Solidification Effects in Additively Manufactured Si and SiGe Compositions

SiGe alloys have a proven track record as robust high-temperature thermoelectric materials, powering NASA missions like SNAP-10A, LES-9, and Voyager 1 and 2. Enhancing thermoelectric efficiency hinges on minimizing thermal conductivity while preserving electrical conductivity. Rapid solidification via LPBF can generate microstructural features such as subgrain cellular boundaries and twinning, which may help reduce thermal conductivity while preserving semiconducting behavior. Here, this study investigates the potential of laser powder bed fusion (LPBF) additive manufacturing to fabricate nanostructured Si and SiGe thermoelectric materials. High cooling rates (10 5 to 10 7 K/s) rates inherent to the LPBF process are conducive to forming such nanostructures. Moreover, this fabrication technique could also be suitable for fabricating complex geometries needed to achieve improved device level performance. Process mapping of commercial Si powder with irregular morphology was first performed to understand the LPBF processing behavior of this semiconductor material. Subsequent studies included in-house synthesized B-doped (p-type) Si7 8 Ge 22 spherical powder that was produced via ultrasonic atomization. Scan strategies involved multiple laser exposures to mitigate solidification cracking: a high density of >98% was achieved, but solidification cracking could not be fully eliminated. Subsequently, a high electrical resistivity (i.e., low conductivity) was observed, but the measured Seebeck coefficient, ∼230 μV/K @ 500 °C, proved that good semiconductor material was being fabricated. A subgrain cellular structure (5–10 μm) was observed as defined by Ge segregation to the intercellular boundaries. The remelting strategies helped lower the cooling rates in processing SiGe, but this still resulted in high residual stresses, which induced a remarkably high density of twins (78–95%) to accommodate the deformation. This unique grain structure offers an avenue for phonon scattering and potential improvements in thermoelectric performance.

figure of merit↗

An experimental and computational study of thin-layer Rayleigh–Taylor instability development during deceleration with and without an externally applied magnetic field

The importance of mitigating the Rayleigh–Taylor instability (RTI) in inertial confinement fusion (ICF) is critical to successfully achieve high gain fusion yield. Consequently, understanding the seed mechanisms of RTI and the potential evolution of RTI in ICF relevant conditions is crucial. Single feature perturbations consistently demonstrate non-linear RTI evolution, for which an experimental platform on OMEGA-EP is developed. Manufacturing defects introduced into the target design require exploration of unanticipated changes to RTI development and an identification of targets that will still render quantifiable physics results. Consequently, it is presented that the inherent 3D nature of experimental targets necessitates 3D modeling for accurate design work and predictive modeling of experimental targets, especially when high resolution imaging diagnostics, like Fresnel Zone Plates, are utilized. A study of the morphology of the RTI evolution due to changing initial conditions and the presence of an externally applied magnetic field are also explored. Experimental data show thin-layer RTI morphology comparable to resistive magneto hydrodynamic 3D results. A discussion on the impacts of an externally applied magnetic field makes the case for continued efforts to observe a magnetic field's impact on RTI morphology.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Geology of Southern Guinevere Planitia, Venus, based on analyses of Goldstone radar data

The ensemble of 41 backscatter images of Venus acquired by the S Band (12.6 cm) Goldstone radar system covers approx. 35 million km and includes the equatorial portion of Guinevere Planitia, Navka Planitia, Heng-O Chasma, and Tinatin Planitia, and parts of Devana Chasma and Phoebe Regio. The images and associated altimetry data combine relatively high spatial resolution (1 to 10 km) with small incidence angles (less than 10 deg) for regions not covered by either Venera Orbiter or Arecibo radar data. Systematic analyses of the Goldstone data show that: (1) Volcanic plains dominate, including groups of small volcanic constructs, radar bright flows on a NW-SE arm of Phoebe Regio and on Ushas Mons and circular volcano-tectonic depressions; (2) Some of the regions imaged by Goldstone have high radar cross sections, including the flows on Ushas Mons and the NW-SE arm of Phoebe Regio, and several other unnamed hills, ridged terrains, and plains areas; (3) A 1000 km diameter multiringed structure is observed and appears to have a morphology not observed in Venera data (The northern section corresponds to Heng-O Chasma); (4) A 150 km wide, 2 km deep, 1400 km long rift valley with upturned flanks is located on the western flank of Phoebe Regio and extends into Devana Chasma; (5) A number of structures can be discerned in the Goldstone data, mainly trending NW-SE and NE-SW, directions similar to those discerned in Pioneer-Venus topography throughout the equatorial region; and (6) The abundance of circular and impact features is similar to the plains global average defined from Venera and Arecibo data, implying that the terrain imaged by Goldstone has typical crater retention ages, measured in hundreds of millions of years. The rate of resurfacing is less than or equal to 4 km/Ga.

Arvidson, R. E.↗

Models of the Cartwheel ring galaxy: Spokes and starbursts

Recent observations of this famous ring galaxy, including optical and near-infrared CCD surface photometry, and VLA radio continuum and 21 cm line mapping (Higdon 1992b, in prep.), have inspired a renewed modeling effort. Toomre's (1978, in The Large-scale Structure of the Universe, eds. Longair and Einasto) series of restricted three-body simulations demonstrated how the multiple rings could be produced in a nearly head-on galaxy collision. New models with a halo-dominated potential based on the 21 cm rotation curve are able to reproduce such details as the spacing between rings, ring widths, offset of the nucleus, and several kinematical features, thus providing strong support for the collisional theory. The new observations have shown there are little or no old stars in Cartwheel; it may consist almost entirely of gas and stars produced as a result of compression in the ring wave. To model this process Smooth Particle Hydrodynamics (SPH) simulations of the Cartwheel disk have been performed. Fixed gravitational potentials were used to represent the Cartwheel and a roughly 30 percent mass collision partner. The interaction dynamics was treated as in the usual restricted three-body approximation, and the effects of local self-gravity between disk particles were calculated. We are particularly interested in testing the theory that enhanced star formation in waves is the result of gravitational instability in the compressed region (see e.g. Kennicutt 1989, ApJ 344, 685). The gas surface density in a number of simulations was initialized to a value slightly below the threshold for local gravitational instability throughout most of the disk. The first ring wave produces relatively modest compressions (a factor of order a few), triggering instability in a narrow range of wavelengths. Self-gravity in the disk is calculated over a comparable range of scales. Simulations were run with isothermal, adiabatic, and adiabatic with radiative cooling characterized by a relatively short timescale. The isothermal approximation is good except in the vicinity of the strong second (inner) ring, and several snapshots from one case are shown in the figure below. Flocculent spiral segments are present before the collision, and these are compressed into dense knots in the ring wave. These knots are likely to be sites of vigorous star formation. In the strong rarefaction behind the outer ring most of the knots are radially stretched and sheared, giving rise to spoke-like features. A few dense knots are evidently very tightly bound, because they retain their coherence and are stretched relatively little through the rarefaction. This is in accord with evidence for continuing star formation in some spokes (Marcum, Appleton and Higdon 1992). The number and spacing of spokes is a direct function of the scale of the gravitational instability in the disk. Thus, the gravitational instability theory, together with the hypothesis that massive stars are only formed in dense knots of gas, can account for most of the distinct morphology of the Cartwheel.

Struck-Marcell, Curtis↗

The megageomorphology of the radar rivers of the eastern Sahara

The Eastern Sahara is devoid of surface drainage; this unusual characteristic distinguishes its morphology from that of most other desert regions where running water dominates landscape development. A map derived from SIR-A/B and LANDSAT images and the literature, shows the major presently known paleodrainages in the Eastern Sahara. This compilation permits consideration of the key questions: Where did the radar rivers come from and where did they go? Analysis of SIR-A data led McCauley et al. to suggest that the radar rivers, because of their southwestward trends, once flowed into the Chad basin. This key North African feature is a regional structural low formed in the Early Cretaceous in response to initial opening of the South Atlantic. The problem of the origin of headwaters for the radar rivers was less tractable. The idea that the source areas of the radar rivers might originally have been the same as those later captured by the Nile was proposed tentatively. A more extensive review of the Cenozoic tectonic history of North Africa reveals no reason now to suppose that the Central African tributaries of the present Nile were ever connected to the large alluvial valleys in southwestern Egypt and northwestern Sudan. formed in the Early Cretaceous in response to initial opening of the South Atlantic. The problem of the origin of headwaters for the radar rivers was less tractable. The idea that the source areas of the radar rivers might originally have been the same as those (The Ethiopian Highlands) later captured by the Nile was proposed tentatively. A more extensive review of the Cenozoic tectonic history of North Africa reveals no reason now to support that the Central African tributaries of the present Nile were ever connected to the large alluvial valleys in southwestern Egypt and northwestern Sudan.

Mccauley, John F.↗

Structural breakdown in high power GaN-on-GaN p-n diode devices stressed to failure

The morphology of GaN-on-GaN vertical p-i-n diode devices after reverse-bias electrical stressing to breakdown has been investigated. All failed devices had irreversible structural damage, showing large surface craters that were ∼15–35 μm deep with lengthy surface cracks. Cross-sectional electron micrographs of failed devices showed substantial concentrations of threading dislocations around the cracks and near the crater surfaces. Progressive ion-milling across damaged devices revealed high densities of threading dislocations and the presence of voids beneath the surface cracks; these features were not observed in any unstressed devices. These results should serve as a useful reference for future reliability studies of vertical high-power GaN devices.

Peri, Prudhvi (ORCID:000000022338441X)↗

Magnetic shear. I - Hale region 16918

The present investigation is concerned with a study of the large-scale morphological and dynamical properties of selected active areas of the sun, taking into account a combination of data from the UVSP experiment on the Solar Maximum Mission (SMM) spacecraft and ground-based data. The area considered comprises NOAA active regions 2516, 2517, and 2519 (Hale regions 16918 and the nothern portions of 16923), whose disk passage occurred during rotation 1696 in the latter half of June 1980. The method of analysis is discussed, and the general characteristics of the regions are examined. Attention is given to the designation of features, magnetograms, spectroheliograms, Dopplergrams, H-alpha filaments, and H-alpha fibrils.

Athay, R. G.↗

Phosphate Biomineralization of Cambrian Microorganisms

As part of a long term study of biological markers (biomarkers), we are documenting a variety of features which reflect the previous presence of living organisms. As we study meteorites and samples returned from Mars, our main clue to recognizing possible microbial material may be the presence of biomarkers rather than the organisms themselves. One class of biomarkers consists of biominerals which have either been precipitated directly by microorganisms, or whose precipitation has been influenced by the organisms. Such microbe-mediated mineral formation may include important clues to the size, shape, and environment of the microorganisms. The process of fossilization or mineralization can cause major changes in morphologies and textures of the original organisms. The study of fossilized terrestrial organisms can help provide insight into the interpretation of mineral biomarkers. This paper describes the results of investigations of microfossils in Cambrian phosphate-rich rocks (phosphorites) that were found in Khubsugul, Northern Mongolia.

McKay, David S.↗

The Unusual X-Ray Collision Morphology of NGC 4782/4783 (3C 278)

Deep ROSAT HRI (High-Resolution Imager) imaging of the X-ray-emitting gas associated with the colliding elliptical galaxy pair NGC 4782/4783 reveals for the first time the complexity of the hot gas distribution in a pair of close interacting galaxies. The HRI image of NGC 4782/4783 shows hot gas around each galaxy, a high surface brightness X-ray bridge connecting the galaxy pair, tidal-like tails emerging from the two galaxies, and a sheet of gas at the interaction interface between the two galaxies. The hot gas distributions do not peak at the optical centers of the galaxies but are displaced in the same sense as the tidal distensions seen in the optical luminosity distributions. All of these remarkable features show the complexity of structure that develops in the hot gas distribution when both hydrodynamical and tidal forces come into play during collisions between ellipticals with hot gas components. Models by Borne and Colina of the bent two-sided radio jet 3C 278 (associated with NGC 4782) indicated that there must be a strong interaction between the hot gas components of NGC 4782,/4783 and that the deflection of the radio jets is likely caused by the ram pressure exerted on the jet plasma by the hot gas associated with the passing companion NGC 4783. These conclusions are qualitatively confirmed by the HRI image and substantiate the major role played by the hot interstellar medium, and its asymmetries, in the propagation and entrainment of radio jets in colliding radio host ellipticals.

Colina, Luis↗

Impact Cratering Calculations

We examined the von Mises and Mohr-Coulomb strength models with and without damage effects and developed a model for dilatancy. The models and results are given in O'Keefe et al. We found that by incorporating damage into the models that we could in a single integrated impact calculation, starting with the bolide in the atmosphere produce final crater profiles having the major features found in the field measurements. These features included a central uplift, an inner ring, circular terracing and faulting. This was accomplished with undamaged surface strengths of approximately 0.1 GPa and at depth strengths of approximately 1.0 GPa. We modeled the damage in geologic materials using a phenomenological approach, which coupled the Johnson-Cook damage model with the CTH code geologic strength model. The objective here was not to determine the distribution of fragment sizes, but rather to determine the effect of brecciated and comminuted material on the crater evolution, fault production, ejecta distribution, and final crater morphology.

Ahrens, Thomas J.↗

Whistlers Observed Outside the Plasmasphere: Correlation to Plasmaspheric/Plasmapause Features and Implications for the Scattering of Radiation-Belt Electrons

Magnetospherically reflected, lightning-generated whistler waves are an important potential contributor to pitch-angle scattering loss processes of the electron radiation belts. While lightning-generated whistlers are a common feature at, and just inside, the plasmapause, they are infrequently observed outside the plasmasphere. As such, their potential contribution to outer radiation belt loss processes is more tenuous. Recently, Platino et al. [2005] has reported on whistlers observed outside the plasmasphere by Cluster. Here, we present correlative global observations of the plasmasphere, for the reported periods of Cluster-observed whistlers outside the plasmasphere, using IMAGE-EUV data. The intent of this study is to seek the underlying mechanisms that result in whistlers outside the plasmasphere and consequently the anticipated morphology and significance these waves may have on radiation belt dynamics.

Adrian, Mark L.↗

The 1991 November 9 flare at 03.2 UT: Observations from Yohkoh

We discuss X-ray spectra and soft X-ray images of an M1.9 flare that occurred on 1991 November 9 near 03.2 UT. These data were obtained with instrumentation on the Japanese Yohkoh spacecraft. They cover the entire rise phase and peak flare emission, and the beginning of the decay phase. We determine the dynamics, temperature, and emission measure of the flare as inferred from the X-ray line profiles of resonance lines of Fe XXV, Ca XIX, and S XV. We discuss the morphology of the flare as inferred from the soft X-ray images. The November 9 flare is atypical in that a stronger than usual blueshifted emission component (relative to the stationary component) is observed for the resonance lines at flare onset. We discuss several methods for deconvolving the blueshifted component from the stationary component. The X-ray line profiles are consistent with predictions of numerical simulations of chromospheric evaporation. The X-ray images reveal a flare with a complicated loop geometry that is not fully understood. Many of the features in the images are moving upwards at speeds ranging from a few km/s to about 800 km/s. The blueshifted emission begins near the onset of hard X-ray emission, implying that particle acceleration and upflowing plasma have a common energy source.

Doschek, G. A.↗