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At least 1,351 records · Page 75

Physics for the Correction of a Calibrated Airborne Scanner, Visible to Thermal Bands

To use remote sensing modalities in a reproducible manner it is essential that extraneous phenomena be removed from the signal. For those interested in the surface of the Earth, airborne and satellite systems, which are sensitive in wavelengths ranging from the visible to the infrared are significantly degraded by the atmosphere. The authors have developed a series of mathematical models to describe and correct the degradation. The models are based directly on the physics of the systems and are computationally tractable. Modeling of the atmosphere is done using public domain code, loaded with data and configured using information form systems developed by Schiller and Luvall. The results of this are then integrated with a physical model of the sensor to permit reduction of data to geophysically meaningful units. The components of the overall modeling, the logic of the components, and the limitations of the approach are discussed. The authors are employing there technology on applications ranging from measurements of urban heat islands to precision agriculture.

Rickman, Doug L.↗

Low Carbon Technology Strategies: Large Office

This document includes steps that building owners and operators can implement to achieve smart, healthy, and low-carbon large office buildings within their existing building portfolios. Large offices are typically over 50,000 square feet and often include complex heating and cooling systems.

analytics↗

Solar–Driven CO 2 Conversion via Optimized Photothermal Catalysis in a Lotus Pod Structure

Photothermal CO 2 reduction is one of the most promising routes to efficiently utilize solar energy for fuel production at high rates. However, this reaction is currently limited by underdeveloped catalysts with low photothermal conversion efficiency, insufficient exposure of active sites, low active material loading, and high material cost. Herein, we report a potassium-modified carbon-supported cobalt (K + –Co–C) catalyst mimicking the structure of a lotus pod that addresses these challenges. As a result of the designed lotus-pod structure which features an efficient photothermal C substrate with hierarchical pores, an intimate Co/C interface with covalent bonding, and exposed Co catalytic sites with optimized CO binding strength, the K + –Co–C catalyst shows a record-high photothermal CO 2 hydrogenation rate of 758 mmol gcat –1 h –1 (2871 mmol gCo –1 h –1 ) with a 99.8 % selectivity for CO, three orders of magnitude higher than typical photochemical CO 2 reduction reactions. Here, we further demonstrate with this catalyst effective CO 2 conversion under natural sunlight one hour before sunset during the winter season, putting forward an important step towards practical solar fuel production.

36 MATERIALS SCIENCE↗

Hingeless rotor theory and experiment on vibration reduction by periodic variation of conventional controls

The reduction of the n per rev. pitch-, roll- and vertical vibrations of an n-bladed rotor by n per rev. sinusoidal variations of the collective and cyclic controls is investigated. The numerical results presented refer to a four-bladed, 7.5-foot model and are based on frequency response tests conducted under an Army-sponsored research program. The following subjects are treated: extraction of the rotor transfer functions (.073R hub flapping and model thrust versus servo valve command, amplitude and phase), calculation of servo commands (volts) required to compensate .073R hub flapping (3P and 5P) and model thrust (4P), evaluation of the effect of the vibratory control inputs on blade loads, and theoretical prediction of the root flapbending moments generated by 0 to 5P perturbations of the feathering angle and rotor angle of attack. Five operating conditions are investigated covering advance ratios from approximately 0.2 to 0.85. The feasibility of vibration reduction by periodic variation on conventional controls is evaluated.

Sissingh, G. J.↗

Energy, economic, and environmental analysis of integration of thermal energy storage into district heating systems using waste heat from data centres

Data centres produce waste heat, which can be utilized in district heating systems. However, the mismatch between data centres’ heat supply and district heating systems’ heat demands limits its utilization. Further, high peak loads increase the operation cost of district heating systems. This study aimed to solve these problems by introducing thermal energy storages. A water tank and a borehole thermal energy storage system were selected as the short-term and long-term thermal energy storage, respectively. Energy, economic, and environmental indicators were introduced to evaluate different solutions. The case study was a campus district heating system in Norway. Results showed that the water tank could shave the peak load by 31% and save the annual energy cost by 5%. The payback period was lower than 15 years when the storage efficiency remained higher than 80%. However, it had no obvious benefits in terms of mismatch relieving and CO emissions reduction. In contrast, the borehole thermal energy storage increased the waste heat utilization rate to 96% and reduced the annual CO emissions by 8%. However, the payback period was more than 17 years. These results provide guidelines for the retrofit of district heating systems, where data centres’ waste heat is available.

25 ENERGY STORAGE↗

Nonlinear Interface Reduction for Time-Domain Analysis of Hurty/Craig-Bampton Superelements with Frictional Contact

Virtual prototyping in engineering design relies today on modern numerical models of contacting structures with accurate resolution of interface mechanics, which strongly affect the system-level stiffness and energy dissipation due to frictional losses. High-fidelity modeling within the localized interfaces is required to resolve local quantities of interest that may drive design decisions. The high-resolution finite element meshes necessary to resolve inter-component stresses tend to be computationally expensive, particularly when the analyst is interested in response time histories. The Hurty/Craig-Bampton (HCB) transformation is a widely used method in structural dynamics for reducing the interior portion of a finite element model while having the ability to retain all nonlinear contact degrees of freedom (DOF) in physical coordinates. These models may still require many DOF to adequately resolve the kinematics of the interface, leading to inadequate reduction and computational savings. This study proposes a novel interface reduction method to overcome these challenges by means of system-level characteristic constraint (SCC) modes and properly orthogonal interface modal derivatives (POIMDs) for transient dynamic analyses. Both SCC modes and POIMDs are computed using the reduced HCB mass and stiffness matrices, which can be directly computed from many commercial finite element analysis software. Comparison of time history responses to an impulse-type load in a mechanical beam assembly indicate that the interface-reduced model correlates well with the HCB truth model. Localized features like slip and contact area are well-represented in the time domain when the beam assembly is loaded with a broadband excitation. The proposed method also yields reduced-order models with greater critical timestep lengths for explicit integration schemes.

42 ENGINEERING↗

Assessing and Reducing Plug and Process Loads in Office Buildings

Plug and process loads (PPLs) account for 33% of U.S. commercial building electricity consumption (McKenney et al. 2010). (See Figure 1.) Minimizing these loads is a significant challenge in the design and operation of an energy-efficient building. Lobato et al. (2011) and Lobato et al. (2012) define PPLs as energy loads that are not related to general lighting, heating, ventilation, cooling, and water heating, and that typically do not provide comfort to the occupants. The percentage of total building energy use from PPLs is increasing. According to the U.S. Department of Energy (DOE), by 2030, commercial building energy consumption is expected to increase by 24%; PPL energy consumption is anticipated to increase by 49% in the same time frame (DOE 2010). These trends illustrate the importance of PPL energy reduction to achieve an overall goal of reducing whole-building energy consumption.

30 DIRECT ENERGY CONVERSION↗

Effect of Data Reduction and Fiber-Bridging on Mode I Delamination Characterization of Unidirectional Composites

Reliable delamination characterization data for laminated composites are needed for input in analytical models of structures to predict delamination onset and growth. The double-cantilevered beam (DCB) specimen is used to measure fracture toughness, GIc, and strain energy release rate, GImax, for delamination onset and growth in laminated composites under mode I loading. The current study was conducted as part of an ASTM Round Robin activity to evaluate a proposed testing standard for Mode I fatigue delamination propagation. Static and fatigue tests were conducted on specimens of IM7/977-3 and G40-800/5276-1 graphite/epoxies, and S2/5216 glass/epoxy DCB specimens to evaluate the draft standard "Standard Test Method for Mode I Fatigue Delamination Propagation of Unidirectional Fiber-Reinforced Polymer Matrix Composites." Static results were used to generate a delamination resistance curve, GIR, for each material, which was used to determine the effects of fiber-bridging on the delamination growth data. All three materials were tested in fatigue at a cyclic GImax level equal to 90% of the fracture toughness, GIc, to determine the delamination growth rate. Two different data reduction methods, a 2-point and a 7-point fit, were used and the resulting Paris Law equations were compared. Growth rate results were normalized by the delamination resistance curve for each material and compared to the nonnormalized results. Paris Law exponents were found to decrease by 5.4% to 46.2% due to normalizing the growth data. Additional specimens of the IM7/977-3 material were tested at 3 lower cyclic GImax levels to compare the effect of loading level on delamination growth rates. The IM7/977-3 tests were also used to determine the delamination threshold curve for that material. The results show that tests at a range of loading levels are necessary to describe the complete delamination behavior of this material.

Murri, Gretchen B.↗

Illuminating the mechanistic impacts of an Fe-quaterpyridine functionalized crystalline poly(triazine imide) semiconductor for photocatalytic CO 2 reduction

The strategy of incorporating earth-abundant catalytic centers into light-absorbing architectures is desirable from the viewpoint of low cost, low toxicity, and versatility for activating small molecules to produce solar-based fuels. Herein, we show that an Fe-quaterpyridine molecular catalyst can be anchored to a light-absorbing, crystalline, carbon nitride (PTI), to yield a molecular-catalyst/material hybrid, Fe-qpy-PTI, capable of facilitating CO 2 reduction to CO selectively (up to ∼97–98%) in aqueous solution under low-intensity light irradiation. This hybrid material leverages the ability of the Fe-qpy catalyst to bind CO 2 upon a one-electron reduction, as achieved by transfer of excited electrons from the carbon-nitride semiconductor. At a low incident power density of only 50 mW cm −2 , the catalytic activity of the hybrid material was measured across a range of catalyst loadings from 0.1–3.8 wt%, yielding CO rates of up to 596 μmol g −1 h −1 for a 3.8 wt% loading during a 3 h experiment. Over the course of 8 h, the hybrid material attained a CO evolution rate of 608 μmol g −1 h −1 and 305 turnovers for a TOF of ∼38 h −1 and an apparent quantum yield of 2.6%. Higher light intensities provided an initial increase in activity but negatively impacted photocatalytic rates with time, with an AQY of 0.6% at 150 mW cm −2 and 0.4% at 250 mW cm −2 . Transient absorption spectroscopy results showed electron survival probabilities consistent with the trends in observed product rates. Computational modeling was also used to evaluate and understand the mechanistic pathway of the high product selectivity for CO versus H 2 . These results thus help unveil key factors for leveraging the mechanistic understanding of molecular catalysts for CO 2 reduction for pairing with light absorbing semiconductors and establishing optimal conditions to attain maximal rates in aqueous solution.

McGuigan, Scott [Baylor University, Waco, TX (Unit↗

Dispersion of sulfur creates a valuable new growth medium formulation that enables earlier sulfur oxidation in relation to iron oxidation in Acidithiobacillus ferrooxidans cultures

Abstract Acidithiobacillus ferrooxidans is an acidophilic chemolithoautotroph that is commonly reported to exhibit diauxic population growth behavior where ferrous iron is oxidized before elemental sulfur when both are available, despite the higher energy content of sulfur. We have discovered sulfur dispersion formulations that enables sulfur oxidation before ferrous iron oxidation. The oxidation of dispersed sulfur can lower the culture pH within days below the range where aerobic ferrous iron oxidation can occur. Thus, ferric iron reduction can be observed quickly which had previously been reported over extended incubation periods with untreated sulfur. Therefore, we demonstrate that this substrate utilization pattern is strongly dependent on the cell loading in relation to sulfur concentration, sulfur surface hydrophobicity, and the pH of the culture. Our dispersed sulfur formulation, lig‐sulfur, can be used to support the rapid antibiotic selection of plasmid‐transformed cells, which is not possible in liquid cultures where ferrous iron is the main source of energy for these acidophiles. Furthermore, we find that media containing lig‐sulfur supports higher production of green fluorescent protein compared to media containing ferrous iron. The use of dispersed sulfur is a valuable new tool for the development of engineered A. ferrooxidans strains and it provides a new method to control iron and sulfur oxidation behaviors.

Inaba, Yuta↗

Power generation-cooling water Nexus: Impacts of cooling water shortage on power system operation - a simulation case study in Illinois, U.S

Cooling water shortage, frequently attributed to drought and heat waves, poses a significant threat to the operations of thermoelectric power plants and further poses a challenge for the entire power system and environmental stakeholders. Recognizing the critical nexus between power generation and cooling water availability and the potential ability of power generations to adjust generation schedules during cooling water shortages, this paper introduces a security-constrained unit commitment and economic dispatch model considering water-energy nexus. In specific, the model is augmented with a unit-level cooling water requirement (CWR) model and multi-level cooling water availability (CWA) constraints. The unit-level CWR model quantifies the cooling water withdrawal per MWh of power generation, taking into account factors such as thermoelectric generation technologies, cooling system technologies, and environmental parameters. The multi-level CWA constraints incorporate pump-level, plant-level, watershed-level, and forced minimum power constraints, utilizing data derived from actual-based cooling water shortage scenarios. Using a simulation case study in Illinois, United States, this research examines the reliability, economic, and environmental implications of cooling water shortages on power system operations. The results show that Illinois may experience 10-15% daily load curtailment and severe congestion between certain regions from the east to central during cooling water shortages, while once-through and wet-tower units experience a 52% and 17% reduction in power generation. In conclusion, overall cooling water withdrawal decreases by 24-38% as severity intensifies.

Cooling water shortage↗

Facet-dependent strong metal-support interactions control the C–O bond activation

Reducible metal oxides are selective and effective for C–O bond scission of hydrodeoxygenation reactions via the reverse Mars-van Krevelen mechanism. Creating efficient redox centers while minimizing metal surfaces leads to highly selective catalysts. Single noble metal atoms activate the surface M–O bond, but the catalyst activity is limited due to low loading. Here, we report that the strong metal-support interaction between Ir and CeO 2 is facet sensitive, and certain facets regulate the C–O bond cleavage. At 300°C reduction, Ir is mostly encapsulated on an octahedron by (111) facets but remains exposed by (110) facets. The former is selective, whereas the latter is not. In conclusion, density functional theory indicates that Ir encapsulation is favored on (111) under reaction conditions, and oxygen vacancies more readily form on encapsulated Ir than on pristine ceria.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Rejuvenation as the origin of planar defects in the CrCoNi medium entropy alloy

Abstract High or medium- entropy alloys (HEAs/MEAs) are multi-principal element alloys with equal atomic elemental composition, some of which have shown record-breaking mechanical performance. However, the link between short-range order (SRO) and the exceptional mechanical properties of these alloys has remained elusive. The local destruction of SRO by dislocation glide has been predicted to lead to a rejuvenated state with increased entropy and free energy, creating softer zones within the matrix and planar fault boundaries that enhance the ductility, but this has not been verified. Here, we integrate in situ nanomechanical testing with energy-filtered four-dimensional scanning transmission electron microscopy (4D-STEM) and directly observe the rejuvenation during cyclic mechanical loading in single crystal CrCoNi at room temperature. Surprisingly, stacking faults (SFs) and twin boundaries (TBs) are reversible in initial cycles but become irreversible after a thousand cycles, indicating SF energy reduction and rejuvenation. Molecular dynamics (MD) simulation further reveals that the local breakdown of SRO in the MEA triggers these SF reversibility changes. As a result, the deformation features in HEAs/MEAs remain planar and highly localized to the rejuvenated planes, leading to the superior damage tolerance characteristic in this class of alloys.

36 MATERIALS SCIENCE↗

Series FACTS Devices for Increasing Resiliency in Severe Weather Conditions

Severe weather conditions are low-probability, high-impact events that affect grid operations. The majority of power outages are caused by severe weather conditions. Grid resiliency to weather events can be enhanced by decreasing the reliance on its affected sections. One way to do this is to reduce the power flow through lines vulnerable to severe weather. If a line is disconnected, its initial power flow is distributed through the neighbor lines, which may cause congestion in the grid. FACTS devices can be used to control the power flow of lines that have a higher chance of power outages. Most previous works do not consider weather events in power flow control. In this work, a linearized optimal power flow (OPF)–based algorithm is developed to minimize the real power flow of vulnerable lines considering the thermal limits of lines to prevent infeasible solutions; the simulation is fast, making it suitable for large-scale systems. The proposed optimization problem is presented as a mixed-integer linear program (MILP), making it capable of using short-term load forecasting due to its high solution speed. The proposed optimization problem considers multiple lines with different outage probabilities and the uncertainties of the weather forecast. Moreover, it estimates the power reduction in vulnerable lines due to changes in the series FACTS devices. The performance of the proposed optimization problem is tested on IEEE 14-, 30-, and 118-bus systems for several scenarios. The results are validated with the AC power flow results from MATPOWER.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Life and reliability models for helicopter transmissions

Computer models of life and reliability are presented for planetary gear trains with a fixed ring gear, input applied to the sun gear, and output taken from the planet arm. For this transmission the input and output shafts are co-axial and the input and output torques are assumed to be coaxial with these shafts. Thrust and side loading are neglected. The reliability model is based on the Weibull distributions of the individual reliabilities of the in transmission components. The system model is also a Weibull distribution. The load versus life model for the system is a power relationship as the models for the individual components. The load-life exponent and basic dynamic capacity are developed as functions of the components capacities. The models are used to compare three and four planet, 150 kW (200 hp), 5:1 reduction transmissions with 1500 rpm input speed to illustrate their use.

Savage, M.↗

Modeling and analysis of the space shuttle nose-gear tire with semianalytic finite elements

A computational procedure is presented for the geometrically nonlinear analysis of aircraft tires. The Space Shuttle Orbiter nose gear tire was modeled by using a two-dimensional laminated anisotropic shell theory with the effects of variation in material and geometric parameters included. The four key elements of the procedure are: (1) semianalytic finite elements in which the shell variables are represented by Fourier series in the circumferential direction and piecewise polynominals in the meridional direction; (2) a mixed formulation with the fundamental unknowns consisting of strain parameters, stress-resultant parameters, and generalized displacements; (3) multilevel operator splitting to effect successive simplifications, and to uncouple the equations associated with different Fourier harmonics; and (4) multilevel iterative procedures and reduction techniques to generate the response of the shell. Numerical results of the Space Shuttle Orbiter nose gear tire model are compared with experimental measurements of the tire subjected to inflation loading.

Kim, Kyun O.↗

Assessment Of The Stirling Power Option for Space Science Applications

Free-piston Stirling technology efforts in the past typically were intended to address power needs in the multi-kilowatt range. The Stirling power option was attractive primarily because of the high conversion efficiency and potential for long life. In recent years, several technology efforts have focused on the free-piston Stirling power d convertor for space power applications, however the more recent efforts are intended to provide power at levels far below one kilowatt. Through a variety of projects funded by both NASA and DOE, the free-piston Stirling convertor technology has successfully demonstrated high efficiency and long life. Other areas of concern, such as control of multi-convertor systems, and vibration reduction have also been addressed. Efforts are being initiated to address issues such as electro-magnetic interference (EMI), radiation tolerance of organic materials, and the ability to operate through launch loads and survive with integrity. The status of the technology in these areas will be briefly discussed in this paper.

Schreiber, Jeffrey G.↗

Dual-Spool Turbine Facility Design Overview

The next generation of aircraft engines, both commercial and military, will attempt to capitalize on the benefits of close-coupled, vaneless, counter-rotating turbine systems. Experience has shown that significant risks and challenges are present with close-coupled systems in terms of efficiency and durability. The UEET program needs to demonstrate aerodynamic loading and efficiency goals for close-coupled, reduced-stage HP/LP turbine systems as a Level 1 Milestone for FY05. No research facility exists in the U.S. to provide risk reduction for successful development of close-coupled, high and low pressure turbine systems for the next generations of engines. To meet these objectives, the design, construction, and integrated systems testing of a Dual-Spool Turbine Facility (DSTF) facility has been initiated at the NASA Glenn Research Center. The facility will be a warm (-IOOO'F), continuous flow facility for overall aerodynamic performance and detailed flow field measurement acquisition. The facility will have state-of-the-art instrumentation to capture flow physics details. Accurate and reliable speed control will be achieved by utilizing the existing Variable Frequency Drive System. Utilization of this and other existing GRC centralized utilities will reduce the overall construction costs. The design allows for future installation of a turbine inlet combustor profile simulator. This presentation details the objectives of the facility and the concepts used in specifying its capabilities. Some preliminary design results will be presented along with a discussion of plans and schedules.

Giel, Paul↗