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At least 1,351 records · Page 75

Heterogeneous Morphologies and Hardness of Co-Sputtered Thin Films of Concentrated Cu-Mo-W Alloys

Heterogeneous microstructures in Cu-Mo-W alloy thin films formed by magnetron co-sputtering immiscible elements with concentrated compositions are characterized using scanning transmission electron microscopy (STEM) and nanoindentation. In this work, we modified the phase separated structure of a Cu-Mo immiscible system by adding W, which impedes surface diffusion during film growth. The heterogeneous microstructures in the Cu-Mo-W ternary system exhibited bicontinuous matrices and agglomerates composed of Mo(W)-rich phase. This is unique, as these are the slower-diffusing species, contrasting past reports of binary Cu-Mo thin films that exhibited Cu-rich agglomerates. The bicontinuous matrices comprised of Cu-rich and Mo(W)-rich phases exhibited bilayer thicknesses of less than 5 nm. The hardness of these thin films measured using nanoindentation is reported and compared to similar multilayers and nanocomposites in binary systems.

36 MATERIALS SCIENCE↗

Interface Science Using Ambient Pressure Hard X-ray Photoelectron Spectroscopy

The development of novel in situ/operando spectroscopic tools has provided the opportunity for a molecular level understanding of solid/liquid interfaces. Ambient pressure photoelectron spectroscopy using hard X-rays is an excellent interface characterization tool, due to its ability to interrogate simultaneously the chemical composition and built-in electrical potentials, in situ. In this work, we briefly describe the “dip and pull” method, which is currently used as a way to investigate in situ solid/liquid interfaces. By simulating photoelectron intensities from a functionalized TiO2 surface buried by a nanometric-thin layer of water, we obtain the optimal photon energy range that provides the greatest sensitivity to the interface. We also study the evolution of the functionalized TiO2 surface chemical composition and correlated band-bending with a change in the electrolyte pH from 7 to 14. Our results provide general information about the optimal experimental conditions for characterizing the solid/liquid interface using the “dip and pull” method, and the unique possibilities offered by this technique.

Favaro, Marco (ORCID:0000000235028332)↗

Spectro-timing study of GX 339-4 in a hard intermediate state

We present an analysis of Nuclear Spectroscopic Telescope Array observations of a hard intermediate state of the transient black hole GX 339−4 taken in 2015 January. With the source softening significantly over the course of the 1.3 day long observation we split the data into 21 sub-sets and find that the spectrum of all of them can be well described by a power-law continuum with an additional relativistically blurred reflection component. The photon index increases from ∼1.69 to ∼1.77 over the course of the observation. The accretion disk is truncated at around nine gravitational radii in all spectra. We also perform timing analysis on the same 21 individual data sets, and find a strong type-C quasi-periodic oscillation (QPO), which increases in frequency from ∼0.68 to ∼1.05 Hz with time. The frequency change is well correlated with the softening of the spectrum. We discuss possible scenarios for the production of the QPO and calculate predicted inner radii in the relativistic precession model as well as the global disk mode oscillations model. We find discrepancies with respect to the observed values in both models unless we allow for a black hole mass of ∼100 M{sub ⊙}, which is highly unlikely. We discuss possible systematic uncertainties, in particular with the measurement of the inner accretion disk radius in the relativistic reflection model. We conclude that the combination of observed QPO frequencies and inner accretion disk radii, as obtained from spectral fitting, is difficult to reconcile with current models.

79 ASTRONOMY AND ASTROPHYSICS↗

MODELING THE EARLY AFTERGLOW IN THE SHORT AND HARD GRB 090510

The bright, short, and hard GRB 090510 was detected by all instruments aboard the Fermi and Swift satellites. The multiwavelength observations of this burst presented similar features to the Fermi -LAT-detected gamma-ray bursts. In the framework of the external shock model of early afterglow, a leptonic scenario that evolves in a homogeneous medium is proposed to revisit GRB 090510 and explain the multiwavelength light curve observations presented in this burst. These observations are consistent with the evolution of a jet before and after the jet break. The long-lasting LAT, X-ray, and optical fluxes are explained in the synchrotron emission from the adiabatic forward shock. Synchrotron self-Compton emission from the reverse shock is consistent with the bright LAT peak provided that the progenitor environment is entrained with strong magnetic fields. It could provide compelling evidence of magnetic field amplification in the neutron star merger.

79 ASTRONOMY AND ASTROPHYSICS↗

EBL Inhomogeneity and Hard-Spectrum Gamma-Ray Sources

The unexpectedly hard very-high-energy (VHE; E > 100 GeV) γ -ray spectra of a few distant blazars have been interpreted as evidence of a reduction of the γγ opacity of the universe due to the interaction of VHE γ -rays with the extragalactic background light (EBL) compared to the expectation from current knowledge of the density and cosmological evolution of the EBL. One of the suggested solutions to this problem involves the inhomogeneity of the EBL. In this paper, we study the effects of such inhomogeneity on the energy density of the EBL (which then also becomes anisotropic) and the resulting γγ opacity. Specifically, we investigate the effects of cosmic voids along the line of sight to a distant blazar. We find that the effect of such voids on the γγ opacity, for any realistic void size, is only of the order of ≲1% and much smaller than expected from a simple linear scaling of the γγ opacity with the line-of-sight galaxy underdensity due to a cosmic void.

79 ASTRONOMY AND ASTROPHYSICS↗

A Hard Look at the Neutron Stars and Accretion Disks in 4U 1636-53, GX 17+2, and 4U 1705-44 with NuStar

We present NuSTAR observations of neutron star (NS) low-mass X-ray binaries: 4U 1636-53, GX 17+2, and 4U 1705-44. We observed 4U 1636-53 in the hard state, with an Eddington fraction, F{sub Edd}, of 0.01; GX 17+2 and 4U 1705-44 were in the soft state with fractions of 0.57 and 0.10, respectively. Each spectrum shows evidence for a relativistically broadened Fe K{sub α} line. Through accretion disk reflection modeling, we constrain the radius of the inner disk in 4U 1636-53 to be R{sub in}=1.03±0.03 ISCO (innermost stable circular orbit), assuming a dimensionless spin parameter a{sub ∗}=cJ/GM{sup 2}=0.0, and R{sub in}=1.08±0.06 ISCO for a{sub ∗}=0.3 (errors quoted at 1σ). This value proves to be model independent. For a{sub ∗}=0.3 and M=1.4 M{sub ⊙}, for example, 1.08 ± 0.06 ISCO translates to a physical radius of R=10.8±0.6 km, and the NS would have to be smaller than this radius (other outcomes are possible for allowed spin parameters and masses). For GX 17+2, R{sub in}=1.00--1.04 ISCO for a{sub ∗}=0.0 and R{sub in}=1.03--1.30 ISCO for a{sub ∗}=0.3. For a{sub ∗}=0.3 and M=1.4 M{sub ⊙}, R{sub in}=1.03--1.30 ISCO translates to R=10.3--13.0 km. The inner accretion disk in 4U 1705-44 may be truncated just above the stellar surface, perhaps by a boundary layer or magnetosphere; reflection models give a radius of 1.46–1.64 ISCO for a{sub ∗}=0.0 and 1.69–1.93 ISCO for a{sub ∗}=0.3. We discuss the implications our results may have on the equation of state of ultradense, cold matter and our understanding of the innermost accretion flow onto NSs with low surface magnetic fields, and systematic errors related to the reflection models and spacetime metric around less idealized NSs.

79 ASTRONOMY AND ASTROPHYSICS↗

NuSTAR Survey of Obscured Swift/BAT-selected Active Galactic Nuclei. II. Median High-energy Cutoff in Seyfert II Hard X-Ray Spectra

Broadband X-ray spectroscopy of the X-ray emission produced in the coronae of active galactic nuclei (AGNs) can provide important insights into the physical conditions very close to their central supermassive black holes. The temperature of the Comptonizing plasma that forms the corona is manifested through a high-energy cutoff that has been difficult to directly constrain even in the brightest AGN because it requires high-quality data at energies above 10 keV. In this paper we present a large collection of coronal cutoff constraints for obscured AGNs based on a sample of 130 AGNs selected in the hard X-ray band with Swift/BAT and observed nearly simultaneously with NuSTAR and Swift/XRT. Additionally, we find that under a reasonable set of assumptions regarding partial constraints the median cutoff is well constrained to 290 ± 20 keV, where the uncertainty is statistical and given at the 68% confidence level. We investigate the sensitivity of this result to our assumptions and find that consideration of various known systematic uncertainties robustly places the median cutoff between 240 and 340 keV. The central 68% of the intrinsic cutoff distribution is found to be between about 140 and 500 keV, with estimated uncertainties of 20 and 100 keV, respectively. In comparison with the literature, we find no clear evidence that the cutoffs in obscured and unobscured AGNs are substantially different. Our analysis highlights the importance of carefully considering partial and potentially degenerate constraints on the coronal high-energy cutoff in AGNs.

79 ASTRONOMY AND ASTROPHYSICS↗

A Model of Double Coronal Hard X-Ray Sources in Solar Flares

A number of double coronal X-ray sources have been observed during solar flares by RHESSI, where the two sources reside at different sides of the inferred reconnection site. However, where and how these X-ray-emitting electrons are accelerated remains unclear. Here we present the first model of the double coronal hard X-ray (HXR) sources, where electrons are accelerated by a pair of termination shocks driven by bidirectional fast reconnection outflows. We model the acceleration and transport of electrons in the flare region by numerically solving the Parker transport equation using velocity and magnetic fields from the macroscopic magnetohydrodynamic simulation of a flux rope eruption. We show that electrons can be efficiently accelerated by the termination shocks and high-energy electrons mainly concentrate around the two shocks. The synthetic HXR emission images display two distinct sources extending to >100 keV below and above the reconnection region, with the upper source much fainter than the lower one. The HXR energy spectra of the two coronal sources show similar spectral slopes, consistent with the observations. Our simulation results suggest that the flare termination shock can be a promising particle acceleration mechanism in explaining the double-source nonthermal emissions in solar flares.

79 ASTRONOMY AND ASTROPHYSICS↗

Hard X-Ray to Radio Multiwavelength SED Analysis of Local U/LIRGs in the GOALS Sample with a Self-consistent AGN Model including a Polar-dust Component

We conduct hard X-ray to radio multiwavelength spectral energy distribution (SED) decomposition for 57 local luminous and ultraluminous infrared galaxies observed with the Nuclear Spectroscopic Telescope Array and/or Swift/Burst Alert Telescope in the GOALS sample. We modify the latest SED-fitting code X-CIGALE by implementing the infrared (IR) CLUMPY model, allowing us to conduct the multiwavelength study with the X-ray torus model XCLUMPY self-consistently. Adopting the torus parameters obtained by the X-ray fitting, we estimate the properties of the host galaxies, active galactic nucleus (AGN) tori, and polar dust. The star formation rates (SFRs) become larger with merger stage and most of them are above the main sequence. The SFRs are correlated with radio luminosity, indicating starburst emission is dominant in the radio band. Although polar-dust extinction is much smaller than torus extinction, the UV-to-IR (mainly IR) polar dust luminosities are ~2 times larger than the torus ones. The polar-dust temperature decreases while the physical size, estimated by the temperature and dust sublimation radius, increases with AGN luminosity from a few tens of parsec (early mergers) to kiloparsec scales (late mergers), where the polar dust likely comes from expanding (i.e., evolving) dusty outflows. A comparison between the SFRs and intrinsic AGN luminosities suggests that starbursts occur first and AGNs arise later, and overall their growth rates follow the simultaneous coevolution local galaxy–SMBH mass relation. We confirm the coexistence of intense starbursts, AGNs, and large-scale outflows in late mergers, supporting a standard AGN feedback scenario.

79 ASTRONOMY AND ASTROPHYSICS↗

A hard ionizing spectrum in z = 3–4 Lyα emitters with intense [O III] emission: analogs of galaxies in the reionization era?

We present Keck/MOSFIRE spectra of the diagnostic nebular emission lines [O iii]λλ5007,4959, [O ii]λ3727, and Hβ for a sample of 15 redshift z≃3.1--3.7 Lyα emitters (LAEs) and Lyman break galaxies (LBGs). In conjunction with spectra from other surveys, we confirm earlier indications that LAEs have a much higher [O iii]/[O ii] line ratio than is seen in similar redshift LBGs. By comparing their distributions on a [O iii]/[O ii] versus R23 diagram, we demonstrate that this difference cannot arise solely because of their lower metallicities but most likely is due to a harder ionizing spectrum. Using measures of Hβ and recombination theory, we demonstrate, for a subset of our LAEs, that ξ{sub ion}—the number of Lyman continuum photons per UV luminosity—is indeed 0.2–0.5 dex larger than for typical LBGs at similar redshifts. Using photoionization models, we estimate the effect this would have on both [O iii]/[O ii] and R23 and conclude such a hard spectrum can only partially explain such intense line emission. The additional possibility is that such a large [O iii]/[O ii] ratio is in part due to density rather than ionization bound nebular regions, which would imply a high escape fraction of ionizing photons. We discuss how further observations could confirm this possibility. Clearly LAEs with intense [O iii] emission represent a promising analog of those z>7 sources with similarly strong lines that are thought to be an important contributor to cosmic reionization.

79 ASTRONOMY AND ASTROPHYSICS↗

Adiabatic Non-resonant Acceleration in Magnetic Turbulence and Hard Spectra of Gamma-Ray Bursts

We introduce a non-resonant acceleration mechanism arising from the second adiabatic invariant in magnetic turbulence and apply it to study the prompt emission spectra of gamma-ray bursts (GRBs). The mechanism contains both the first- and second-order Fermi acceleration, originating from the interacting turbulent reconnection and dynamo processes. It leads to a hard electron energy distribution up to a cutoff energy at the balance between the acceleration and synchrotron cooling. The sufficient acceleration rate ensures a rapid hardening of any initial energy distribution to a power-law distribution with the index p∼1, which naturally produces a low-energy photon index α∼−1 via the synchrotron radiation. For typical GRB parameters, the synchrotron emission can extend to a characteristic photon energy on the order of ∼100 keV.

79 ASTRONOMY AND ASTROPHYSICS↗

Hard Synchrotron Spectra from Magnetically Dominated Plasma Turbulence

Synchrotron emission from astrophysical nonthermal sources usually assumes that the emitting particles are isotropic. By means of large-scale two- and three-dimensional particle-in-cell simulations, we demonstrate that the dissipation of magnetically dominated (${\sigma }_{0}\gg 1$) turbulence in pair plasmas leads to strongly anisotropic particle distributions. At Lorentz factors $\sim {\sigma }_{0}{\gamma }_{\mathrm{th}0}$ (here, ${\gamma }_{\mathrm{th}0}$ is the initial Lorentz factor), the particle velocity is preferentially aligned with the local magnetic field; instead, the highest energy particles are preferentially oriented in the plane perpendicular to the field. This energy-dependent anisotropy leads to a synchrotron spectral flux $\nu {F}_{\nu }\propto {\nu }^{s}$ that is much harder than for isotropic particles. Remarkably, for ${\sigma }_{0}\gg 1$ we find that the angle-integrated spectral slope in the slow cooling regime is $s\sim 0.5-0.7$ for a wide range of turbulence fluctuations, $0.25\lesssim \delta {B}_{\mathrm{rms}0}^{2}/{B}_{0}^{2}\lesssim 4$, despite significant variations in the power-law energy spectrum of nonthermal particles. This is because weaker turbulence levels imprint a stronger degree of anisotropy, thereby counteracting the effect of the steeper particle spectrum. The synchrotron spectral slope may be even harder, $s\gtrsim 0.7$, if the observer is in the plane perpendicular to the mean magnetic field. Our results are independent of domain size and dimensionality. Further, our findings may help explain the origin of hard synchrotron spectra of astrophysical nonthermal sources, most notably the radio spectrum of pulsar wind nebulae.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The Role of Second Phase Hard Particles on Hole Stretchability of two AA6xxx Alloys

The hole stretchability of two Aluminum Alloys (AA6111 and AA6022) are studied by using a two stages integrated finite element framework where the edge geometry and edge damages from the hole piercing processes were considered in the subsequent hole expansion processes. Experimentally it has been found that AA6022 has higher hole expansion ratios than those of AA6111. This observation has been nicely captured by finite element simulations. The main cause of differences have been identified to the volume fractions of the random distributed second phase hard particles which play a critical role in determining the fracture strains of the materials.

Hu, Xiaohua↗

Solving Hard Problems with AI: Dramatically Accelerating Drug Discovery Through A Unique Public-Private Partnership

Dramatic disruptions in technologies can result in the creation of new markets, the emergence of new paradigms, and the displacement of entrenched approaches and business models. This can be especially pronounced when multiple technologies converge to create something new. Today, artificial intelligence (“AI”) is acting as an accelerant for such technology transformations. Still, the scope and depth of its impact will depend in part on our ability to address challenging problems that are surfacing without solutions. Industries will pursue AI for their corporate missions and to create shareholder value. But the timescales and applications can be incongruent with important public needs and with the longer research horizons required to make real progress. Public-Private partnerships are an important mechanism for tackling these rapidly emerging new, complex, challenging problems. Finally, this paper examines our experience gained by creating a unique public-private partnership to apply AI to one example of a hard problem that is particularly timely today-- dramatically accelerating drug discovery.

59 BASIC BIOLOGICAL SCIENCES↗

Supporting Data: Inverse Trans Influence and Uranium-Arene σ-Bonding Drive Molecular Geometry: Ligand Modification from Hard to Soft Flips the Oxide from Axial to Equatorial

Supporting Computational Data from the manuscript titled "ITI and Uranium-Arene s-Bonding Drive Molecular Geometry: Ligand Modification from Hard to Soft Flips the Oxide from Axial to Equatorial" by Benedikt Kestel, Daniel Pividori, Sabyasachi Roy Chowdhury, Frank W. Heinemann, Bess Vlaisavljevich, and Karsten Meyer published in J. Am. Chem. Soc. (DOI: 10.1021/jacs.5c05029).

Chowdhury, Sabyasachi Roy [Department of Chemistry↗