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NASA NTRSDate not supplied

Refined Analysis of CO2 Emissions in Urban Air Mobility Networks

In this study, we examine the environmental impact of Urban Air Mobility (UAM) operations as measured via carbon dioxide (CO2) emissions by leveraging a computational model from previous studies that has been refined and expanded. Several scenarios are examined in which total transportation emissions for a representative day in a metro area are distributed differently among vehicle types and transportation modes. Specifically, we investigate the use of electric air vehicles in a UAM network; the increasing presence of electric ground vehicles for ground transportation; the impacts from implementing ridesharing in the UAM mode; and the effects of varying the electricity grid emissions. Results for a case study in the Chicago, IL metro area indicate that incorporating electric ground vehicles and UAM ridesharing can both lead to reduced CO2 emissions. These preliminary results indicate that carbon emissions from a UAM system leveraging ridesharing and all-electric aircraft may not be a practical operational limit on UAM, though further improvements to the modeling are warranted.

advanced air mobility↗

NASA NTRSDate not supplied

Sea Surface Air Pressure Retrieval with MBARS

Global meteorological observations are essential in initialization and assimilation of numerical weather prediction (NWP) models. Many key weather variables such as temperature, humidity, and wind can be relatively well observed by in-situ and remote techniques from surface, suborbital and orbital platforms. However, sea surface air pressure cannot be well-sampled. Over open oceans, the pressure can only be observed by very limited buoys, ships, and oceanic platforms. There is no operational remote sensing method available for the crucial dynamic variable of the Earth’s climate and weather systems. Advanced techniques for global sea level pressure (SLP) observations are urgently needed for improving NWP models, particularly for improvement of severe weather forecasts. Recent studies on the space and airborne Microwave BArometric Radar and Sounder (MBARS) systems provide a great potential to fill the SLP observational gap. The systems studied have three channels with center frequencies at 65.5, 67.76 and 70 GHz. These channels are designed to operate at atmospheric oxygen (O2) absorption bands for column O2 mass measurements. When sea surface returns of spectrally closely-spaced paired channels are measured, surface reflection and atmospheric attenuation other than O2 are very similar, but the difference in O2 absorption is substantial. Thus, the differential absorption loss of this frequency pair leads to measures of atmospheric O2 amount. For the residual absorption loss caused by other agents, a third frequency having the same spectral space to the weak absorption frequency of the first pair can be used, which forms the second pair and produces the same residual as the first pair. Removal of the residual of this second pair from the first pair can further mitigate environmental impacts. Thus, this 3-channel approach will provide precise O2 amount retrievals. Since oxygen is well mixed in the atmosphere, the column air mass or SLP can be obtained. Currently, MBARS is rapidly maturing its advanced technology. An upcoming airborne field flight campaign is planned in late 2024. The 3-channel approach will be use in SLP retrievals. This MBARS team will discuss the physics-based SLP retrieval technique and report latest progresses in this upcoming AGU annual meeting.

O2 differential absorption↗

NASA NTRSDate not supplied

Reduction of Aircraft Noise Uncertainty for a Notional Supersonic Business Jet

NASA supported a study by the International Civil Aviation Organization on the environmental impact of adding supersonic aircraft to the existing global fleet by designing a notional 55-tonne supersonic business jet. The aircraft is referred to as the Supersonic Technology Concept Aeroplane (STCA) and has been used in a multitude of studies over the past few years. One of the many studies on this aircraft was the noise produced by the STCA during landing and take-off (LTO) operations. The LTO noise for the STCA was assessed using contemporary noise prediction tools that have been primarily developed for and utilized by subsonic aircraft, resulting in a high level of uncertainty for the STCA noise predictions. NASA has recently been conducting research and developing tools to reduce the uncertainty for airport noise predictions of supersonic aircraft. The initial focus of the uncertainty reduction was on the jet and inlet-radiated fan noise produced by supersonic engine systems since these sources are dominant during take-off and landing operations for supersonic jets. The results of these efforts are discussed and applied to the STCA model to update the airport noise predictions and associated uncertainty metrics. It is shown that by using new noise source prediction models, the overall system-level cumulative noise uncertainty of the study vehicle is reduced from a standard deviation of 7.8 EPNdB to 2.0 EPNdB.

uncertainty↗

DOE OSTI2020

High-Temperature Stability of Aqueous Foams as Potential Waterless Hydrofracking Fluid for Geothermal Reservoir Stimulation

Hydraulic fracturing is the process of fracturing rock formations with high-pressure water-based fluids. In Enhanced Geothermal Systems (EGS) hydraulic fracturing is carried out by injecting high-pressure fluids into the Hot Dry Rocks (HDR) under carefully controlled conditions. The fluid used for fracturing is an important component for EGS, not only concerning the technical approch but also environmental impact. Recent research has been carried out to develop waterless fracturing technologies for EGS, including foam-based hydrofracking, where foams are mixtures of gas and liquid fluids. Foam fracturing fluids have potential benefits over water-based fluids because of less water consumption, less damage in water sensitive formations, and less liquid to recover and handle after fracturing process. One challenge for implementing foam fracturing in EGS is to achieve stable foams at high temperatures, as the foam stability tends to decay with increase in temperature.This research is focused on investigating the stability of foams at high temperatures. Preliminary results show that 1) N2 foams are more stable compared to CO2 foams, 2) foams containing only surfactants were not stable at high temperatures, and 3) addition of different stabilizing agents increased the thermal stability of all the foams. It was observed that different stabilizing agents interacted differently with anionic, nonionic, and cationic surfactants. It was further shown that the crosslinking agent with a base solution of pH 6 and graphene oxide dispersion was the most effective stabilizing agent for anionic surfactant AOS, while bentonite clay effectively enhanced thermal stability for another anionic surfactant SDS. SiO2 nanoparticles showed limited improvement in thermal stability at high temperatures compared to other stabilizing agents.

Thakore, Virensinh↗

DOE OSTI2020

DOE Investments in Environmentally Acceptable Lubricants for Hydropower Applications Fact Sheet

Environmentally acceptable lubricants (EALs) are defined as lubricants that meet U.S. Environmental Protection Agency (EPA) standards for “biodegradability, toxicity, and bioaccumulation potential that minimize their likely adverse consequences in the aquatic environment, compared to conventional lubricants.” Restrictions from state, local, and federal agencies, as well as a growing awareness of the environmental risks associated with petroleumbased lubricants, have shifted government and industry to seek out high-performing EALs. The U.S. Department of Energy (DOE) is working to reduce the environmental impacts of hydropower development and operation by investing in tools and methods to develop, demonstrate, and validate EAL materials.

water, environment, hydropower, EALs↗

DOE OSTI2020

Software Coordinates Multiple Smart Devices and User Preferences, Redefining "Smart" Homes

NREL developed foresee™ to achieve users' preferences while simplifying the coordination of when and how a home's connected appliances and electronics use energy. This reduces complexity and improves the consistency and diversity of whole-home outcomes. These include enhanced comfort, convenience, reduced costs, and lower environmental impact based on input from the homeowner. The software accounts for time-of-use rates and is compatible with smart products from any manufacturer.

automation↗

DOE OSTI2020

Superlubricious carbon films derived from natural gas

A nanocomposite coating that in turn extract self-replenishing (or -healing), superlubricious carbon film directly from natural gas or hydrocarbon gas in mechanical systems. The coating deposits on sealing and sliding surfaces reducing friction and wear. The result is a reduction in inefficiency, machine breakdown, and adverse environmental impact.

03 NATURAL GAS↗

DOE OSTI2020

Nanoporous Catalysts for Biomass Conversion

Transforming plant biomass to biofuel and chemicals has become a global effort as results of increasing fuel demand but diminishing fossil-based energy preservation and rising concerns of climate and environmental impact. Various conversion routes involving thermochemical and biological conversions have been established and well-studied. Heterogeneous catalysis is playing a critical role in the biomass conversion and, with some unique catalytic properties, nanoporous catalysts have been extensively utilized in catalytic process of biomass conversion and exhibited exciting catalytic performance. This chapter will be devoted to nanoporous catalysts used in biomass conversion. It will start with a brief introduction of current biomass conversion technologies and then a detailed review of the application of various nanoporous materials in a large diversity of catalytic reactions in biomass conversion. The nanoporous materials include zeolites and zeotypes, metal-organic frameworks (MOFs), nanoporous carbons and carbon nitrides, nanoporous oxides, hydroxides and complex oxide forms, porous organic polymers (POPs), and porous metals.

Shi, Hui↗

DOE OSTI2021

Modeling and Analysis of the Transport and Disposal of Beryllium Moderator Blocks and Greater than Class C (GTCC) Waste

Radioactive waste in the United states is categorized based on its source, radioactivity, and security risk. The categorization method employed by the Nuclear Regulatory Committee (NRC) for low-level radioactive waste is not currently applied to any waste generated by the Department of Energy (DOE) or disposed of in DOE facilities. As a result, there is a large volume of DOE-generated waste with characteristics similar to the NRC’s “Greater than Class C” (GTCC) waste category which presently do not have a path for long-term disposal. Much of this waste cannot undergo the standard commercial disposition process due to it being categorized as Transuranic (TRU) waste under DOE guidelines, due to elevated concentrations of key fission products. Possible solutions to this dilemma are explored in the Environmental Impact Statement for the “Disposal of Greater-Than-Class-C Low Level Radioactive Wave” (EIS-0375). This paper analyzes several EIS possible paths for disposal for this “orphaned” waste. One example that highlights this categorization issue is the spent beryllium cladding that has been extracted from the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL) throughout its operational lifetime. These beryllium blocks surround the reactor’s main chambers and components and serve as neutron moderators. This paper will use this particular waste form to analyze the economic and technological viability of transporting and storing this material under the storage and transportation criteria of the Waste isolation Pilot Plant (WIPP), which was deemed the most feasible disposition path according to the EIS. The example of this waste form used in this paper that highlights this categorization issue is the spent beryllium cladding extracted from Idaho National Laboratory’s (INL) Advanced Test Reactor (ATR). These beryllium blocks surround the reactor’s components and serve as neutron moderators, and thus have accumulated high concentration of high-activity transuranic isotopes. This paper analyzed the viability of transporting and storing this material under the storage and transportation criteria of the five primary disposition paths covered in EIS-0375. An array of calculations was carried out to assess the viability of the various disposition paths for the beryllium shipments as well as other waste shipments that fall within the GTCC category. Modeling with MCNP 6.2 was conducted to determine whether the beryllium blocks could be safely stored and transported within a 72-B cask; the standard shipping container for remote-handled, transuranic waste, while also meeting regulatory limits at various disposition paths. A cost analysis of the transportation and long-term disposal paths mentioned in the EIS was also carried out using available data and information from similar waste shipments. Lastly, a geochemical analysis of the various geological repository discussed in the EIS was also carried out using the Geochemists Workbench Release 14. Long-term disposal of the beryllium blocks at the Waste Isolation Pilot Plant (WIPP) proved to be the most cost-effective long-term disposition option of the ones considered in the EIS. A dose rate calculation at both contact and remote-handling distances indicate that the analyzed beryllium shipments should not exceed the exposure limits at any of the considered locations. Greater-than-class-C waste has been left in a regulatory state of limbo for years, resulting in backlogs of inventory across several research sites in the United States. Due to its high activity and presence of transuranic isotopes, it is imperative to ensure that it remains inaccessible and sequestered both in its short-term interim as well as a long-term geologic time scale. The information and assessments done in the paper could potentially serve as a reference for any future shipments of this waste form at the WIPP facility as well as other disposition paths that may be considered in the future.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2021

BETO 2021 Peer Review - Improving Formate Upgrading by Cupriavidus Necator 2.3.2.111

Formate can be generated by electrocatalytic reduction of CO2 and has been proposed as a soluble intermediate for the storage of carbon and energy. Biological systems capable of assimilating formate could enable conversion of formate generated from low-cost renewable energy and waste CO2 to myriad fuels and chemicals. To that end, the goal of this project is to develop the natural formatotroph Cupriavidus necator as a robust microbial chassis for efficient conversion of formate to value-added products. Using a combination of laboratory evolution and rational engineering, we have identified mutations and genetic deletions that improve its growth rate and biomass yield on formate by 1.2X. Using RNA-seq transcriptomics, we are elucidating the mechanisms that underly these improvements and anticipate this will contribute to our understanding of formate conversion. We have also engineered C. necator to convert formate to the potential polymer precursor 2-hydroxymuconate semialdehyde (2HMS) by introducing an exogenous pathway and deleting competing pathways and demonstrated production and robust growth using a pH-stat bioreactor. Final techno-economic analysis and life-cycle assessment on biological production of 2HMS from formate will enable the DOE and other stake holders to evaluate the economic and environmental impact of this project and related technologies.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

DOE OSTI2021

Lithium Metal as an Anode in Electrochemical Energy Storage

The drastic environmental and economic costs of global warming have driven the necessity to reduce, if not eliminate, a dependency on oil and gas for energy applications. Alternative clean energy reliance has been initiated as a global investment for a more sustainable future. Part of this transitional effort is focused on energy storage via a rechargeable battery. High energy density storage is necessary for utilizing non-dispatchable green energy technologies, as well in the electric transition of our vehicle fleet. Further, understanding methods of extracting, manufacturing, and recycling lithium is necessary to lessen environmental impact. Lithium metal is often considered the “Holy Grail” of battery technology, due to its high theoretical capacity (3,860 mAh/g) and low electrochemical potential (-3.04 V vs. SHE). However, parasitic reactions lead to rapid and dangerous battery failure. Therefore, determining methods of stabilizing lithium metal is paramount for the transition to a greener future.

25 ENERGY STORAGE↗

DOE OSTI2021

High Temperature Stability of Aqueous Foams for Potential Application in Enhanced Geothermal System (EGS)

Enhanced Geothermal Systems (EGS) are typically constructed by injecting high-pressure water into the deep hot dry rocks (HDR) under carefully controlled conditions to create new or re-open existing fractures, which usually utilizes an immense quantity of water. Alternatively, aqueous foam-based fracturing fluids may offer potential advantages over conventional water-based fracturing fluid, including reduced consumption of water and environmental impact. Although foam-based fracturing has shown promising results in oil and gas industries, its applicability to EGS is unknown. Foams are complex mixtures of liquids with gaseous phases that are thermodynamically unstable. Their stability will decrease over time due to liquid drainage, bubble coarsening, and coalescence. Therefore, it is essential to stabilize foam fluids at high temperatures for EGS related applications such as fracking of HDRs.This paper is focused on investigating high-temperature stability of N2-in-water or N2 foams containing different surfactants and stabilizing agents. Foam stability was characterized by the half-life, which is defined as the time a foam decreases to 50% of its original height due to drainage. Surfactants with various concentrations dissolved in deionized water were investigated, including alfa olefin sulfonate (AOS), sodium dodecyl sulfonate (SDS), TergitolTM (NP – 40), and cetyltrimethylammonium chloride (CTAC). Also, the effects of other stabilizing agents, including guar gum, bentonite clay, crosslinker, graphene oxide (GO) dispersion on foam stability were tested. Initial results showed that foam stability decreased dramatically as temperature increased. On the other hand, foams became relatively more stable as pressure increased. Certain stabilizing agents, such as guar gum and crosslinker, can enhance foam stability at a wide range of temperatures. Our results indicate that it may be possible to obtain stable foams at high-temperature, high-pressure conditions with appropriate stabilizing agents.

Thakore, Virensinh↗

DOE OSTI2020

Recycling and Life Cycle Issues for Lightweight Vehicles

This chapter addresses recycling and life cycle considerations related to the growing use of lightweight materials in vehicles. This chapter first addresses the benefit of a life cycle perspective in materials choice, and the role that recycling plays in reducing energy inputs and environmental impacts in a vehicle’s life cycle. Some limitations of life cycle analysis and results of several vehicle- and fleet-level assessments are drawn from published studies. With emphasis on lightweight materials such as aluminum, magnesium, and polymer composites, the status of the existing recycling infrastructure and technological challenges being faced by the industry also are discussed.

Das, Sujit↗

DOE OSTI2020

Lighting Policy Options to Incentivize the Circular Economy

Energy codes and energy efficiency policy are primed for significant shifts in the coming decade. Consumers are increasingly asking manufacturers to take responsibility for products over the course of the product lifespan, including at end-of-life. Consumer demand for social and environmental responsibility may push new codes and policies that incentivize the circular economy. Within the lighting sector, for example, rapid innovations have created large energy savings but also created a complex waste stream. Traditional energy code approaches to lighting efficiency have considered only lighting power density or energy-based metrics. Shifting codes and policy to consider environmental impacts of the product lifecycle could include circular economy mechanisms such as product deposits or service-based business models. In this paper we consider the possible structures for both codes and policies, and provide an analysis of the merits of each policy using life cycle assessment and sustainability index (SI).

Dillon, Heather↗

DOE OSTI2021

Modular High Temperature Gas-Cooled Reactor: Licensing Part III

Recent Licensing Experience- Advanced and Micro- Reactors Recent Designs Additional Designs Licensing Challenges for advanced reactors Functional Containment Emergency Planning Zones Autonomous and Remote Operation Transportation Manufacturing Licenses NRC License vs. DOE Authorization Siting and Environmental Impact

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE OSTI2021

Small-Signal Stability Analysis of Low-Inertia Power Grids with Inverter-Based Resources and Synchronous Condensers: Preprint

With the potential environmental impacts of conventional fossil fuels and the technology advances of grid interactive power electronics, inverter-based resources (IBRs) are playing a crucial role in modern power grids. However, due to the lack of physical inertia, IBRs are vulnerable to system disturbances. Further, conventional grid-following (GFL) inverters cannot actively establish the frequency and voltage, which could not be a appropriate solution for 100% inverter-based power grids. Grid-forming (GFM) control, as an emerging inverter control function, has drawn great attention in recent years, while it is still under development and pre-mature for large-scale field deployment. A potential solution for gradually transitioning into a 100% inverter-based power grid is to combine both IBRs and synchronous machines into a mixed generation portfolio. More importantly, synchronous machines can be operated as synchronous condensers (SCs) until they are retired. It is also worth mentioning that the stability analysis is of great importance to ensure the smooth transition from existing power grids to 100% inverter-based system, which is the main focus of this work with detailed modeling and modal analysis.

100% renewable↗

DOE OSTI2022

Assessment Framework of Marine Hydrokinetic Technologies for Microgrid Applications

Communities in Alaska that are not connected to a regional grid (referred to hereafter as grid-islanded Alaskan communities) rely heavily on stand-alone generators with imported diesel fuel as the primary source of energy. Several of these grid-islanded Alaskan communities have the potential to harness significant wave, tidal, and hydrokinetic power; many also have hydropower or wind potential that could complement these resources. The implementation of marine and hydrokinetic energy focused microgrids in these communities would diversify their energy profiles, with the potential in many communities to keep costs flat while reducing dependance on diesel. This would enhance resilience and reduce environmental impacts. This seedling proposal will systematically identify grid-islanded coastal communities in Alaska with wave, tidal, and hydrokinetic energy potential to add fuel diversity to generation, applying microgrid integration methods and strategies that will meet the community’s needs. This proposal is in partnership with the Alaska Center for Energy and Power (ACEP) and XENDEE Corporation who bring extensive expertise in Alaskan communities and microgrid technoeconomic assessment, respectively. This project will deliver: (1) a database of grid-islanded communities that are candidates for MHK based microgrids, (2) an assessment of possible microgrid integration methods and strategies related to tidal, wave, and hydrokinetic technologies, and (3) a MHK development plan for the XENDEE Microgrid design platform and planning tool that can serve these grid-islanded communities and project developers. In the final stage, the planning tool will allow for the comprehensive comparison between diesel based and MHK based renewable generation.

16 TIDAL AND WAVE POWER↗

DOE OSTI2022

The Future of Building Science Education with the U.S. Department of Energy Solar Decathlon: Preprint

Experience the future of Building Science Education with the U.S. Department of Energy Solar Decathlon, from community-focused designs to real-life innovative zero energy buildings constructed by students. In this paper, we will introduce the Solar Decathlon programs and a reimagined Building Science Education curriculum that is transforming education to inspire future building design professionals and bring sustainable, equitable design and construction strategies to the real world. The Solar Decathlon is a collegiate-level building design competition that challenges students in 10 Contests, from embodied environmental impact to affordability and resilience. We will cover the structure of the competition and its two Challenges - the Build Challenge and the Design Challenge - as well as additional programs that impact all aspects of the buildings industry. These programs include the Solar Decathlon Building Science Education course, a free online video series that provides students and working professionals with building science fundamentals; the Design Partners Program, which connects innovative student design teams and local building owners seeking low-risk, low-cost opportunities to incorporate sustainable design alternatives into their building portfolio; and Solar Decathlon Pro, a program piloted in 2021 that brings Solar Decathlon resources to design professionals. The Solar Decathlon's effective approach to bringing real-world solutions to building science empowers future professionals to do impactful work.

buildings↗