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AgZr2 crystallizes in the tetragonal I4/mmm space group. The structure is two-dimensional and consists of two AgZr2 sheets oriented in the (0, 0, 1) direction. Zr is bonded in a 12-coordinate geometry to four equivalent Ag atoms. All Zr–Ag bond lengths are 3.05 Å. Ag is bonded in a distorted body-centered cubic geometry to eight equivalent Zr atoms.
UTe3 crystallizes in the orthorhombic Cmcm space group. The structure is two-dimensional and consists of two UTe3 sheets oriented in the (0, 1, 0) direction. U6+ is bonded in a 9-coordinate geometry to nine Te2- atoms. There are a spread of U–Te bond distances ranging from 3.19–3.26 Å. There are three inequivalent Te2- sites. In the first Te2- site, Te2- is bonded in a 2-coordinate geometry to two equivalent U6+ and four equivalent Te2- atoms. All Te–Te bond lengths are 3.12 Å. In the second Te2- site, Te2- is bonded in a 5-coordinate geometry to five equivalent U6+ atoms. In the third Te2- site, Te2- is bonded in a 2-coordinate geometry to two equivalent U6+ and four equivalent Te2- atoms.
AgN3 crystallizes in the orthorhombic Ibam space group. The structure is two-dimensional and consists of two AgN3 sheets oriented in the (0, 0, 1) direction. Ag1+ is bonded in a distorted square co-planar geometry to four equivalent N+0.33- atoms. All Ag–N bond lengths are 2.40 Å. There are two inequivalent N+0.33- sites. In the first N+0.33- site, N+0.33- is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag1+ and one N+0.33- atom. The N–N bond length is 1.19 Å. In the second N+0.33- site, N+0.33- is bonded in a linear geometry to two equivalent N+0.33- atoms.
SrRuO3 crystallizes in the orthorhombic Pnma space group. The structure is two-dimensional and consists of two RuO2 sheets oriented in the (0, 0, 1) direction and two SrO sheets oriented in the (0, 0, 1) direction. In each RuO2 sheet, Ru4+ is bonded in a square co-planar geometry to four equivalent O2- atoms. All Ru–O bond lengths are 1.83 Å. O2- is bonded in a linear geometry to two equivalent Ru4+ atoms. In each SrO sheet, Sr2+ is bonded in a square co-planar geometry to four equivalent O2- atoms. There are two shorter (2.59 Å) and two longer (2.60 Å) Sr–O bond lengths. O2- is bonded in a square co-planar geometry to four equivalent Sr2+ atoms.
InBr crystallizes in the orthorhombic Cmcm space group. The structure is two-dimensional and consists of two InBr sheets oriented in the (0, 1, 0) direction. In1+ is bonded to five equivalent Br1- atoms to form a mixture of edge and corner-sharing InBr5 square pyramids. There are one shorter (3.05 Å) and four longer (3.33 Å) In–Br bond lengths. Br1- is bonded to five equivalent In1+ atoms to form a mixture of edge and corner-sharing BrIn5 square pyramids.
AgO2Cl crystallizes in the orthorhombic Pcca space group. The structure is two-dimensional and consists of one AgO2Cl sheet oriented in the (0, 0, 1) direction. Ag is bonded to six equivalent O atoms to form a mixture of distorted edge and corner-sharing AgO6 pentagonal pyramids. There are a spread of Ag–O bond distances ranging from 2.45–2.66 Å. O is bonded to three equivalent Ag and one Cl atom to form a mixture of edge and corner-sharing OAg3Cl trigonal pyramids. The O–Cl bond length is 1.60 Å. Cl is bonded in a water-like geometry to two equivalent O atoms.
BiOI crystallizes in the tetragonal P4/nmm space group. The structure is two-dimensional and consists of one BiOI sheet oriented in the (0, 0, 1) direction. Bi3+ is bonded in a 4-coordinate geometry to four equivalent O2- and four equivalent I1- atoms. All Bi–O bond lengths are 2.36 Å. All Bi–I bond lengths are 3.41 Å. O2- is bonded to four equivalent Bi3+ atoms to form a mixture of corner and edge-sharing OBi4 tetrahedra. I1- is bonded in a 4-coordinate geometry to four equivalent Bi3+ atoms.
TiOCl crystallizes in the orthorhombic Pmmn space group. The structure is two-dimensional and consists of one TiOCl sheet oriented in the (0, 0, 1) direction. Ti3+ is bonded to four equivalent O2- and two equivalent Cl1- atoms to form a mixture of edge and corner-sharing TiCl2O4 octahedra. The corner-sharing octahedral tilt angles are 19°. There are two shorter (2.02 Å) and two longer (2.12 Å) Ti–O bond lengths. Both Ti–Cl bond lengths are 2.41 Å. O2- is bonded in a distorted see-saw-like geometry to four equivalent Ti3+ atoms. Cl1- is bonded in an L-shaped geometry to two equivalent Ti3+ atoms.
CrSBr crystallizes in the orthorhombic Pmmn space group. The structure is two-dimensional and consists of one CrSBr sheet oriented in the (0, 0, 1) direction. Cr3+ is bonded to four equivalent S2- and two equivalent Br1- atoms to form a mixture of corner and edge-sharing CrS4Br2 octahedra. The corner-sharing octahedral tilt angles are 22°. There are two shorter (2.39 Å) and two longer (2.42 Å) Cr–S bond lengths. Both Cr–Br bond lengths are 2.53 Å. S2- is bonded to four equivalent Cr3+ atoms to form a mixture of distorted corner and edge-sharing SCr4 trigonal pyramids. Br1- is bonded in an L-shaped geometry to two equivalent Cr3+ atoms.
TiOBr crystallizes in the orthorhombic Pmmn space group. The structure is two-dimensional and consists of one TiOBr sheet oriented in the (0, 0, 1) direction. Ti3+ is bonded to four equivalent O2- and two equivalent Br1- atoms to form a mixture of distorted edge and corner-sharing TiBr2O4 octahedra. The corner-sharing octahedral tilt angles are 6°. There are two shorter (2.03 Å) and two longer (2.08 Å) Ti–O bond lengths. Both Ti–Br bond lengths are 2.59 Å. O2- is bonded in a see-saw-like geometry to four equivalent Ti3+ atoms. Br1- is bonded in an L-shaped geometry to two equivalent Ti3+ atoms.
ZrNI crystallizes in the orthorhombic Pmmn space group. The structure is two-dimensional and consists of one ZrNI sheet oriented in the (0, 0, 1) direction. Zr4+ is bonded in a 6-coordinate geometry to four equivalent N3- and two equivalent I1- atoms. There are two shorter (2.17 Å) and two longer (2.18 Å) Zr–N bond lengths. Both Zr–I bond lengths are 2.99 Å. N3- is bonded in a distorted see-saw-like geometry to four equivalent Zr4+ atoms. I1- is bonded in a distorted L-shaped geometry to two equivalent Zr4+ atoms.
YCI crystallizes in the monoclinic C2/m space group. The structure is two-dimensional and consists of one YCI sheet oriented in the (0, 0, 1) direction. Y3+ is bonded in a 1-coordinate geometry to five equivalent C2- and three equivalent I1- atoms. There are a spread of Y–C bond distances ranging from 2.35–2.72 Å. There are two shorter (3.11 Å) and one longer (3.26 Å) Y–I bond lengths. C2- is bonded in a 6-coordinate geometry to five equivalent Y3+ and one C2- atom. The C–C bond length is 1.33 Å. I1- is bonded in a 3-coordinate geometry to three equivalent Y3+ atoms.
I crystallizes in the orthorhombic Cmce space group. The structure is two-dimensional and consists of two I sheets oriented in the (0, 1, 0) direction. I is bonded in a distorted T-shaped geometry to three equivalent I atoms. There are one shorter (2.82 Å) and two longer (3.40 Å) I–I bond lengths.
LaI2 crystallizes in the tetragonal I4/mmm space group. The structure is two-dimensional and consists of two LaI2 sheets oriented in the (0, 0, 1) direction. La2+ is bonded in a body-centered cubic geometry to eight equivalent I1- atoms. All La–I bond lengths are 3.37 Å. I1- is bonded in a 4-coordinate geometry to four equivalent La2+ atoms.
InI crystallizes in the orthorhombic Cmcm space group. The structure is two-dimensional and consists of two InI sheets oriented in the (0, 1, 0) direction. In1+ is bonded to five equivalent I1- atoms to form a mixture of corner and edge-sharing InI5 square pyramids. There are one shorter (3.28 Å) and four longer (3.50 Å) In–I bond lengths. I1- is bonded to five equivalent In1+ atoms to form a mixture of corner and edge-sharing IIn5 square pyramids.
Ta3I7 crystallizes in the orthorhombic Cmce space group. The structure is two-dimensional and consists of two Ta3I7 sheets oriented in the (0, 1, 0) direction. there are two inequivalent Ta sites. In the first Ta site, Ta is bonded in a 4-coordinate geometry to four I atoms. All Ta–I bond lengths are 2.84 Å. In the second Ta site, Ta is bonded in a 5-coordinate geometry to five I atoms. There are a spread of Ta–I bond distances ranging from 2.81–3.18 Å. There are five inequivalent I sites. In the first I site, I is bonded in a 2-coordinate geometry to two equivalent Ta atoms. In the second I site, I is bonded in a 2-coordinate geometry to two equivalent Ta atoms. In the third I site, I is bonded in a 2-coordinate geometry to two Ta atoms. In the fourth I site, I is bonded in a distorted bent 120 degrees geometry to two equivalent Ta atoms. In the fifth I site, I is bonded in a 2-coordinate geometry to two Ta atoms.
UI3 crystallizes in the orthorhombic Cmcm space group. The structure is two-dimensional and consists of two UI3 sheets oriented in the (0, 1, 0) direction. U3+ is bonded in a 8-coordinate geometry to eight I1- atoms. There are a spread of U–I bond distances ranging from 3.12–3.44 Å. There are two inequivalent I1- sites. In the first I1- site, I1- is bonded in a distorted trigonal non-coplanar geometry to three equivalent U3+ atoms. In the second I1- site, I1- is bonded in an L-shaped geometry to two equivalent U3+ atoms.
TbCl3 crystallizes in the orthorhombic Cmcm space group. The structure is two-dimensional and consists of two TbCl3 sheets oriented in the (0, 1, 0) direction. Tb3+ is bonded in a 8-coordinate geometry to eight Cl1- atoms. There are a spread of Tb–Cl bond distances ranging from 2.67–2.94 Å. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a distorted trigonal non-coplanar geometry to three equivalent Tb3+ atoms. In the second Cl1- site, Cl1- is bonded in an L-shaped geometry to two equivalent Tb3+ atoms.