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All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Overview of advanced plasma-facing materials testing for Fusion Pilot Plants at DIII-D

Characterization and testing of advanced plasma-facing materials (PFMs) for Fusion Pilot Plants (FPP) is being conducted at the DIII-D National Fusion Facility through the ongoing two-year FPP Candidate Materials Thrust. Year one tested 17 novel materials utilizing the Divertor Materials Evaluation System (DiMES), with samples analyzed pre- and post-experiment via SEM, EDS, and confocal microscopy. Repeatable reference discharges were developed to ensure uniformity between experiments, including a new strike-point rastering scenario to provide more uniform heat/particle flux across DiMES during ELMing H-mode discharges. Various sample geometries and temperatures were used to achieve FPP-relevant conditions, including samples angled 10° towards the incident plasma flux and pre-heating up to 500 °C. The first exposure of liquid lithium (Li) capillary porous structures in a tokamak demonstrated uniform emission of Li vapor and suppression of Li droplets in H-mode when preheated to 350 °C. Dispersoid-strengthened W with 1 wt% TaC, TiC, and ZrC exposed to H-mode showed cracking and dispersoid ejection for all varieties except TiC, providing a clear down-selection. Ultra-high temperature ceramic materials TiB 2 and ZrB 2 showed minimal degradation under L-mode exposure. Silicon carbide (SiC) fiber composites showed arcing along edges, while CVD SiC remained pristine. Atmospheric plasma-sprayed W and SiC coatings endured H-mode exposure without macroscopic delamination; SiC exhibited granular ejection, while W showed increased outgassing. Additional W-based alloys were stress tested in H-mode, including Ni-based W heavy alloys, W f SiC f /W composites, W multi-principle element alloys, and functionally-graded W/SiC, to varying degrees of success.

DIII-D↗
DOE OSTI2022

A scale-wise analysis of intermittent momentum transport in dense canopy flows

We investigate the intermittent dynamics of momentum transport and its underlying time scales in the near-wall region of the neutrally stratified atmospheric boundary layer in the presence of a vegetation canopy. This is achieved through an empirical analysis of the persistence time scales (periods between successive zero-crossings) of momentum flux events, and their connection to the ejection–sweep cycle. Using high-frequency measurements from the GoAmazon campaign, spanning multiple heights within and above a dense canopy, the analysis suggests that, when the persistence time scales ( $t_p$ ) of momentum flux events from four different quadrants are separately normalized by $\varGamma _{w}$ (integral time scale of the vertical velocity), their distributions $P(t_p/\varGamma _{w})$ remain height-invariant. This result points to a persistent memory imposed by canopy-induced coherent structures, and to their role as an efficient momentum-transporting mechanism between the canopy airspace and the region immediately above. Moreover, $P(t_p/\varGamma _{w})$ exhibits a power-law scaling at times $t_{p}<\varGamma _{w}$ , with an exponential tail appearing for $t_{p} \geq \varGamma _{w}$ . By separating the flux events based on $t_p$ , we discover that around 80 % of the momentum is transported through the long-lived events ( $t_{p} \geq \varGamma _{w}$ ) at heights immediately above the canopy, while the short-lived ones ( $t_{p} < \varGamma _{w}$ ) only contribute marginally ( $\approx 20\,\%$ ). To explain the role of instantaneous flux amplitudes in momentum transport, we compare the measurements with newly developed surrogate data and establish that the range of time scales involved with amplitude variations in the fluxes tends to increase as one transitions from within to above the canopy.

Mechanics↗
DOE OSTI2026

Achieving Phase Control of Polymorphic Tungsten Carbide Catalysts

The polymorphism of tungsten carbide (W x C) and the challenge of selectively synthesizing pure phases have impeded a precise understanding of catalytic structure−property relationships. This study establishes a framework for phase-selective synthesis of W x C through controlling carburization kinetics. By maintaining particle sizes below 10 nm, β-W 2 C is selectively synthesized using gaseous carbon precursors (CH 4 /H 2 ) via temperature-programmed carburization (TPC). Our findings reveal that W 2 C stabilization is predominantly dictated by particle size and carburization kinetics rather than support interactions, providing a tunable approach to synthesize tungsten carbide catalysts. We elucidate the mechanistic pathway of WO x carburization, demonstrating that CH 4 activation occurs at mild temperatures via lattice oxygen. Our reactor studies establish ex situ synthesized β- W 2 C as an active and stable catalyst for the reverse water-gas shift (RWGS) reaction. However, the need for passivation and reduction pretreatment leads to a complex surface structure with diminished intrinsic activity. In contrast, our in situ synthesis protocol for β-W 2 C eliminates the need for passivation and exhibits increased CO STY during RWGS, illustrating the intrinsically higher activity compared to metallic W, WC 1−x (0.5 < x < 1), and stoichiometric WC.

CO2 conversion↗
DOE OSTI2025

Synthesis and Photodriven Hydrogenation of Tungsten Nitride Complexes Prepared from Dinitrogen Cleavage

Oxidation of the Chatt-type tungsten dinitrogen compound, trans-(depe) 2 W(N 2 ) 2 (depe = Et 2 PCH 2 CH 2 PEt 2 ), with [(η 5 -C 5 H 5 ) 2 Fe][BAr F 4 ] (BAr F 4 = B(3,5-(CF 3 ) 2 C 6 H 3 ) 4 ) resulted in isolation of [(depe) 2 WN][BAr F 4 ], a rare example of a tungsten(IV) nitride prepared from N 2 cleavage. A bimetallic μ-N 2 ditungsten intermediate supported by terminal N 2 ligands was identified, and irradiation with visible light promoted dinitrogen cleavage and formation of [(depe) 2 WN][BAr F 4 ]. Performing the analogous one-electron oxidation of the related tungsten dinitrogen compound, trans-(dppe) 2 W(N 2 ) 2 (dppe = Ph 2 PCH 2 CH 2 PPh 2 ), furnished the corresponding cationic, 17-electron tungsten dinitrogen complex, [(dppe) 2 W(N 2 ) 2 ][BAr F 4 ], that was characterized by X-ray diffraction and vibrational and EPR spectroscopies. The generation of [(dppe) 2 W(N)][BAr F 4 ] was observed in low yield from the in situ formed mixed N 2 -bridged compound, [(N 2 )(depe) 2 W(μ-N 2 )W(dppe) 2 (N 2 )][BAr F 4 ] 2 , and was confirmed by independent synthesis using 1-azidoadamantane. Addition of ammonia or water to [(depe) 2 WN][BAr F 4 ] resulted in formation of the cationic imide and hydroxide complexes, [(depe) 2 W(NH)(X)][BAr F 4 ] (X = NH 2 , OH). Irradiation of [(depe) 2 WN][BAr F 4 ] with 440 nm visible light in the presence of Ir(ppy) 3 (ppy = 2-phenylpyridine) under 4 atm of dihydrogen resulted in hydrogenation of the tungsten nitride to the cationic tungsten pentahydride, [(depe) 2 WH 5 ][BAr F 4 ], with the release of free ammonia in 21% yield, a rare example of ammonia generation from dinitrogen and dihydrogen from a well-defined tungsten nitride.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Optimized attenuated interaction: Enabling stochastic Bethe–Salpeter spectra for large systems

We develop an improved stochastic formalism for the Bethe–Salpeter equation (BSE), based on an exact separation of the effective-interaction W into two parts, W = (W – vW) + vW, where the latter is formally any translationally invariant interaction, vW(r – r'). When optimizing the fit of the exchange kernel vW to W, using a stochastic sampling W, the difference W – vW becomes quite small. Then, in the main BSE routine, this small difference is stochastically sampled. Furthermore, the number of stochastic samples needed for an accurate spectrum is then largely independent of system size. While the method is formally cubic in scaling, the scaling prefactor is small due to the constant number of stochastic orbitals needed for sampling W.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2021

Predicted Heat Flux Performance of Actively Cooled Tungsten-Armored Graphitic Foam Monoblocks

Tungsten (W)–armored graphitic foam monoblocks were developed for applications requiring high-Z plasma-facing material in long-pulse fusion experiments and ultimately deuterium-tritium fusion reactors. The monoblocks are an integrated material system combining the advantages of a chemical vapor deposited (CVD) W coating with a high-conductivity graphitic foam. The W is a high-melting-point, high-Z material with low tritium retention. The graphitic foam coupled to a swirl tube serves as a high-thermal-conductivity heat sink that cannot melt, although it can sublime at much higher temperatures than copper melts. Together, they comprise a robust plasma-facing component (PFC) weighing roughly 5% of an all-W component or 17% of a traditional W-coated copper heat sink.A single-channel mock-up consisting of four graphitic foam monoblocks equipped with a water-cooled swirl tube was fabricated for eventual testing in the 60-kW, EB-60, rastered electron beam at the Applied Research Laboratory of The Pennsylvania State University. Two monoblocks have a thin 50-μm-thick coating of pure W chemically vapor deposited over NbC and pure Nb interlayers. Two others have a 2-mm-thick pure W coating CVD on graphitic monoblocks using the same interlayers. The mock-up will be cooled with available 10 m/s, 0.7 MPa water with a 22°C inlet temperature and subjected to varying uniform heat loads up to 20 MW/m 2 . It is equipped with type-K thermocouples at various depths, and calibrated infrared thermography and spot pyrometry will be used to characterize the heated surface. Real-time water calorimetry will be used to ascertain the absorbed steady-state power and infer the heat flux during testing. Since testing cannot be done under prototypic divertor flow conditions, it is necessary to predict the thermal response of this novel PFC system and investigate the power sharing between radiation and convection at divertor heat flux levels and its inherent ability to avoid critical heat flux. Results are reported for predictions obtained from computational fluid dynamics models up to 30 MW/m 2 of steady-state uniform heat flux. Leading-edge heat loads of 30 MW/m 2 on a 2-mm-wide side strip were also investigated to ascertain if coating delamination is likely.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

The effectiveness of D 2 pellet injection in reducing intra-ELM and inter-ELM tungsten divertor erosion rates in DIII-D during the Metal Rings Campaign

Abstract Edge localized modes (ELMs) in H-mode plasmas erode plasma-facing components (PFCs) and lead to impurities in the core, reducing confinement. This study analyzes D 2 pellet injection on the DIII-D fusion experiment used as an ELM mitigation technique applied during the 2016 tungsten Metal Rings Campaign to reduce W erosion during ELMs. The 400.9 nm photon wavelength line emission intensity of tungsten atoms (WI) filterscope channels and Langmuir probes were used to infer the gross erosion rate of tungsten-coated tiles installed in the divertor of DIII-D. D 2 mass injection rates ranging from 34 to 41 arbitrary units (A.U.) and no D 2 injection resulted in a similar total W erosion rate during ELMs (intra-ELM). On average, results show a 29% increase in the total gross W erosion rate with intermediate mass injection rates (∼13–23 A.U.) compared to the no pellets and the highest injection rate cases. On average, the fast D 2 mass injection rate cases had 15% less erosion in the inter-ELM phase than the case with no pellets. Generally, higher D 2 mass injection rates increased the ELM frequency, and the highest injection rates reduced the average erosion per ELM and fractional carbon impurities at the top of the pedestal by nearly 40% when compared to the no-pellet case. As expected, a higher D 2 pellet injection rate led to a higher plasma density and lower plasma temperature in the divertor. Additionally, an increasing divertor inter-ELM plasma electron density directly correlated to more frequent pellet injection and a decrease in both the average gross intra-ELM W erosion and the total gross intra-ELM W erosion rate. Simulations of intra-ELM erosion using the ‘free-streaming plus recycling model’ (FSRM) underestimate W erosion during pellet injection by about 30% on average. The discrepancies between the experimental measurements and the FSRM intra-ELM W erosion predictions are postulated to be due to C/W material mixing. A simple analytic mixed-material model is presented and results in better agreement with the experimental data. These results highlight the importance of incorporating the effects of a mixed-material layer in the analysis of PFC erosion.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Understanding tungsten erosion during inter/intra-ELM periods in He-dominated JET-ILW plasmas

Tungsten erosion was quantified during inter/intra-ELM periods in He-dominated JET-ILW plasmas by optical emission spectroscopy. The intra-ELM tungsten sputtering in helium plasmas, which dominates the total W source, prevails by a factor of about 4 over inter-ELM sputtering in the investigated ELM frequency range from 90 Hz–120 Hz. He ions are mainly responsible for the W erosion during the ELMs in He plasmas. The strong in/out asymmetry of the ELM-induced W erosion is observed in He plasmas even at high ELM frequencies beyond 100 Hz. In Ohmic/L-mode plasmas and during the H-mode inter-ELM plasma phases both He 2+ and Be 2+ ionic species are major contributors to the W erosion. Their contribution depends on the electron temperature in the divertor: for T e > 15 eV both species cause significant W sputtering, for T e < 15 eV, B e 2+ ions are solely responsible for the W erosion. Tungsten erosion during in both inter and intra-ELM periods in He-dominated plasmas are significantly larger than in deuterium plasmas. It is 15–25 times larger during the inter-ELM phase and in L-mode discharges at T e = 25–30 eV. On the other hand, the ELM-induced W source is by a factor of 3 larger than in D plasmas.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Twisted bilayer graphene. VI. An exact diagonalization study at nonzero integer filling

Using exact diagonalization, we research the projected Hamiltonian with the Coulomb interaction in the eight flat bands of first magic angle twisted bilayer graphene. Employing the U(4) [U(4) × U(4)] symmetries in the nonchiral (chiral) flat band limit, we reduced the Hilbert space to an extent that allows for study around ν = ±3,±2,±1 fillings. In the first chiral limit w 0 /w 1 = 0, where w 0 (w 1 ) is the A A (AB) stacking hopping, we find that the ground states at these fillings are extremely well-described by Slater determinants in a so-called Chern basis, and the exactly solvable charge ±1 excitations found in Bernevig et al. [Phys. Rev. B 103, 205415 (2021)] are the lowest charge excitations up to system sizes 8 × 8 (for restricted Hilbert space) in the chiral-flat limit. We also find that the flat metric condition (FMC) used by Bernevig et al. [Phys. Rev. B 103, 205411 (2021)], Song et al. [Phys. Rev. B 103, 205412 (2021)], Bernevig et al. [Phys. Rev. B 103, 205413 (2021)], Lian et al. [Phys. Rev. B 103, 205414 (2021)], and Bernevig et al. [Phys. Rev. B 103, 205415 (2021)] for obtaining a series of exact ground states and excitations holds in a large parameter space. For ν = -3, the ground state is the spin and valley polarized Chern insulator with ν C = ±1 at w 0 /w 1 ≲ 0.9 (0.3) with (without) FMC. At ν = -2, we can only numerically access the valley polarized sector, and we find a spin ferromagnetic phase when w 0 /w 1 ≳ 0.5 t where t ϵ [0,1] is the factor of rescaling of the actual TBG bandwidth, and a spin singlet phase otherwise, confirming the perturbative calculation [Lian. et al., Phys. Rev. B 103, 205414 (2021), Bultinck et al., Phys. Rev. X 10, 031034 (2020)]. The analytic FMC ground state is, however, predicted in the intervalley coherent sector which we cannot access [Lian et al., Phys. Rev. B 103, 205414 (2021), Bultinck et al., Phys. Rev. X 10, 031034 (2020)]. For ν = -3 with/without FMC, when w 0 /w 1 is large, the finite-size gap Δ to the neutral excitations vanishes, leading to phase transitions. Further analysis of the ground state momentum sectors at ν = -3 suggests a competition among (nematic) metal, momentum M M (π) stripe and K M -CDW orders at large w 0 /w 1 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Nuclear suppression of coherent J / ψ photoproduction in heavy-ion ultraperipheral collisions and leading twist nuclear shadowing

We determine the nuclear suppression factor S Pb ( x ) , where x = M J / ψ 2 / W γ p 2 with M J / ψ the J / ψ mass and W γ p the photon-nucleon energy, for the cross section of coherent J / ψ photoproduction in heavy-ion ultraperipheral collisions at the Large Hadron Collider and Relativistic Heavy Ion Collider by performing the χ 2 fit to all available data on the cross section d σ A A → J / ψ A A / d y as a function of the J / ψ rapidity y and the photoproduction cross section σ γ A → J / ψ A ( W γ p ) as a function of W γ p . We find that while the d σ A A → J / ψ A A / d y data alone constrain S Pb ( x ) for x ≥ 10 − 3 , the combined d σ A A → J / ψ A A / d y and σ γ A → J / ψ A ( W γ p ) data allow us to determine S Pb ( x ) in the wide interval 10 − 5 < x < 0.05 . In particular, the data favor S Pb ( x ) , which decreases with a decrease of x in the 10 − 4 < x < 0.01 interval and can be both decreasing or constant for x < 10 − 4 . Identifying S Pb ( x ) with the ratio of the gluon distributions in Pb and the proton R g ( x , Q 0 2 ) = g A ( x , Q 0 2 ) / [ A g p ( x , Q 0 2 ) ] , we demonstrate that the leading twist approximation for nuclear shadowing provides a good description of all the data on d σ A A → J / ψ A A / d y and σ γ A → J / ψ A ( W γ p ) as well as on the experimental values for S Pb ( x ) derived from σ γ A → J / ψ A ( W γ p ) . We also show that modern nuclear parton distributions reasonably reproduce S Pb ( x ) as well. Published by the American Physical Society 2024

Guzey, V. (ORCID:0000000223938507)↗
NASA NTRS1972

Magnetospheric electric fields deduced from drifting whistler paths.

Results of a study in which the amplitude of the E-W component E sub w of the convection electric field in the nightside magnetosphere has been inferred from the observed cross-L motions of whistler ducts within the plasmasphere, and several ducts distributed over 1 to 2 earth radii in L space and over plus or minus deg 15 around the longitude of the Eights, Antarctica, whistler station have been tracked simultaneously. The method appears capable of resolving fluctuations in E sub w with period T equal to approximately 15 min and rms amplitude as low as 0.05 mV/m. For variations with T greater than 1 hour the method has a sensitivity of the order of 0.01 mV/m. Three case studies are presented, two of which illustrate convection activity associated with relatively isolated substorms. In these two cases E sub w reversed from westward to eastward for a period following the decay of substorm bay activity. In the third case the substorm bay activity was prolonged, and E sub w remained westward and at enhanced levels until local dawn. Evidence was found that, at least in a limited longitudinal sector, perturbing substorm E sub w fields can penetrate deep within the plasmasphere. In two of the case studies comparisons of E sub w and the interplanetary magnetic-field theta component show evidence of a possible relation based on brief (less than or equal to 1 hour) southward excursions but not on long preceding southward events.

Carpenter, D. L.↗
NASA NTRS1987

Equatorial long-wave characteristics determined from satellite sea surface temperature and in situ data

SST maps and imagery derived from the NOAA 6 satellite AVHRR for June and July 1981 in the eastern tropical Pacific portray the wavelike structure of the cool water along the equator from 93 deg W to 125 deg W. Cusped waves of approximately 1000-km zonal wavelength and 25-day period propagated westward with a phase speed of 40 km/day. The observed meridional extent between the crest and trough of the waves is about 300 km. Details in the imagery show cooler water at the cusps advected north and then east with the north equatorial countercurrent (NECC), consistent with the suggestion of a series of anticyclonic eddies occupying the shear zone between the NECC and the westward flowing south equatorial current. Absolute SST estimates from the AVHRR data agree to within 0.6 C with shipboard data taken along 110 deg W between 5 deg N and 5 deg S. The wavelike structures in the SST maps are also in agreement at the surface with a vertical expendable bathythermograph temperature section made along the equator between 93 deg W and 125 deg W, which shows the phase of the waves tilting westward with increasing depth over the upper 75 m. Such a phase shift, if it extended 100-200 km meridionally in either direction from the equator, would be associated with an equatorward flux of heat. Similar phase shifts appear in temperature time series at depths of 20 and 50 m, from a mooring at 0-deg 33-min N, 110-deg 30-min W. Near-surface currents measured at this and a second mooring on the equator at 109-deg 40-min W indicate a regular pattern of northward advection when wave cusps pass them, followed by southwest flow during the passage of wave troughs, again consistent with an equatorward flux of heat, as well as with earlier theoretical and drift buoy findings.

Pullen, Patricia E.↗
NASA NTRS1988

Observations of 20-day period meridional current oscillations in the upper ocean along the Pacific Equator

Prominent oscillations of the meridional current, with a mean period of approximately 20 days, is observed in the upper ocean from May 1979 to October 1985 using moored current measurements along the Pacific equator at 95, 110, 124, 140, and 152 deg W, as well as off (but near) the equator at 110 and 140 deg W. The fluctuations are relatively narrowband in frequency. A 95 percent statistically significant peak in the power spectra of the meridional current occurs at 110, 124, and 140 deg W, but not at 95 and 152 deg W where the spectral peaks are smaller. The dominant wave period decreases by about 4 percent from 110 to 140 deg W. The wave amplitude decreases with depth, and the wave is essentially confined to the upper 80 m. The penetration depth of the oscillation is greatest at 110 deg W and least at 140 deg W.

Halpern, David↗
NASA NTRS1993

Yana ring structure, North-Eastern Siberia: A possible counterpart of coronae on Venus

An arch of Verkhoyansky Range in NE Siberia, Russia is considered as W and S parts of the rim of the large ring structure, referred hereafter as Yana Ring Structure (YRS). It has general appearance similar to coronae on Venus and could be considered as the terrestrial counter part of coronae. The structure is located between 63 and 70 deg N, 125 and 140 deg E. The outer diameter of YRS (between the rim feet) is 680-700 km. The rim crest diameter is 500-520 km. The inner diameters (between the inner feet of the rim) is 320-350 km. The rim of YRS consist of the following topographic features: W segment is Orulgan Range (N part of Verkhoyansky Range), SW and S segments consist of S part of Verkhoyansky Range, SE segment is Elginskoye Ploskogorye (Tableland), E segment is Chersky Range (its part W of Indigirka River), NE segment is Selennyakhsky Range, and NW segment is Kular Range. Inside this ring of mountains Yanskoye Ploskogorye (Tableland) is located. The circular outlines of YRS are marked with the large river valleys located outside: Lena River (lower of Aldan River mouth) is located W from YRS, Aldan River (lower of Amga River mouth) is from S, Indigirka River (between 64 and 67 deg N lat) is from E, and Selennyakh River (the part running N to S) is from NE. The ring patterns inside the mountaineous rim of YRS are marked with the tributaries of Yana River. The largest ring here, 300 km in diameter, consists of Bytangay (with Bellyakh) River at W, Nelgese and Derbeke Rivers at S/SE, and Tuostakh River at E. The typical altitudes of YRS mountain rim are 1000-2000 m. The maximal ones are: 2400 m in W part of the rim, 2300 m in S, 1600 m in SE, 2200-2500 m in E, and 1300-1500 m in N. The central part of YRS have typical altitudes of 400-600 m. There are lowlands with altitudes 50-200 m to the S, W, N, and NW outside YRS Oymyakonskoye Nagorye (Highland) is located SE of YRS at 500-1500 m altitudes. It should be recognized from this description YRS have a general appearance of circular highland with its central plateau located 1000-2000 m lower than surrounding mountain rim, but 300-400 m higher than plains of lowlands located outside the rim. Such topographic patterns are typical for coronae on Venus. The diameter of YRS is equal to the largest coronae on Venus. There are only 3 or 4 structures of such or larger size on the whole Venus. This calls to compare morphology and geologic evolution of YRS with morphology and models of coronae evolutions especially the largest ones, to search the similarities and/or differences in geologic histories of the structures on the Earth and Venus.

Burba, G. A.↗
NASA NTRS1993

Tensile and stress-rupture behavior of hafnium carbide dispersed molybdenum and tungsten base alloy wires

The tensile strain rate sensitivity and the stress-rupture strength of Mo-base and W-base alloy wires, 380 microns in diameter, were determined over the temperature range from 1200 K to 1600 K. Three molybdenum alloy wires; Mo + 1.1w/o hafnium carbide (MoHfC), Mo + 25w/o W + 1.1w/o hafnium carbide (MoHfC+25W) and Mo + 45w/o W + 1.1w/o hafnium carbide (MoHfC+45W), and a W + 0.4w/o hafnium carbide (WHfC) tungsten alloy wire were evaluated. The tensile strength of all wires studied was found to have a positive strain rate sensitivity. The strain rate dependency increased with increasing temperature and is associated with grain broadening of the initial fibrous structures. The hafnium carbide dispersed W-base and Mo-base alloys have superior tensile and stress-rupture properties than those without HfC. On a density compensated basis the MoHfC wires exhibit superior tensile and stress-rupture strengths to the WHfC wires up to approximately 1400 K. Addition of tungsten in the Mo-alloy wires was found to increase the long-term stress rupture strength at temperatures above 1400 K. Theoretical calculations indicate that the strength and ductility advantage of the HfC dispersed alloy wires is due to the resistance to recrystallization imparted by the dispersoid.

Yun, Hee Mann↗
NASA NTRS1993

Scientific studies in association with the Shuttle Solar Backscatter Ultraviolet (SSBUV) project

During the past reporting period efforts focused on performing detailed comparisons between measurements made by the SBUV/2 V instruments carried on NOAA-9 and NOAA-11 and the first three flights of the Shuttle Solar Backscatter Ultraviolet (SSBUV) project. The quantities to be compared are the measurables, being the ratio of emergent radiance (I) in the vertical direction to the incoming solar irradiance (F). The backscatter albedo, A(w,j), was defined by: A(w,j) = I(w,j)/F(w,j) where w = 1,2,..., 12 refers to wavelength, and j indicates the instrument and flight on which the data were obtained. The comparisons to be made are NOAA-9 to SSBUV-1, NOAA-11 to SSBUV-2, and NOAA-11 to SSBUV-3. For the comparisons the N-values contained in the data files supplied by GSFC were converted to albedos via: A(w,j) = 10(exp N(w,j)/100). The comparisons described were designed to characterize the differences between the NOAA and SSBUV data sets.

Frederick, John E.↗
NASA NTRS1995

Nonaxisymmetric secular instabilities driven by star/disk coupling

We determine conditions for the onset of nonaxisymmetric secular instabilities in polytropes with a wide range of angular momentum distributions using Lagrangian techniques, and then calculate the growth rate of such instabilities when driven by the coupling of the perturbed star to a circumstellar disk. We use Langrangian displacement vectors with azimuthal dependence proportional to exp (im phi), where m is an integer and phi is the azimuthal coordinate. The onset of secular instability in terms of the quantity T/absolute value of W, the ratio of rotational kinetic energy to gravitational potential energy, is affected by both the compressibility and the angular momentum distribution of the polytrope. The largest effects occur when the angular momentum distribution is varied. For polytropic index n = 3/2, the onset of secular instability for the m = 2 mode (the bar mode), as determined by its neutral point, shifts from T/absolute value of W = 0.141 to 0.093, while the m = 5 mode neutral point shifts from T/absolute value of W = 0.088 to 0.031 over the range of angular momentum distributions we consider. The smallest critical T/absolute value of W-values occur for the angular momentum distributions which are the most peaked toward the equator. For the angular momentum distribution of a Maclaurin spheroid, as the polytropic index n is increased from 3/2 to 5/2, the neutral point for m = 2 shifts from T/absolute value of W = 0.141 to 0.144 and the netural point for m = 5 shifts from T/absolute value of W = 0.069 to 0.078. The netural points for m = 2 and 5 for the Maclaurin sequence (n = 0) are 0.137 and 0.0629, respectively. As the angular momentum distribution becomes more peaked toward the equatorial radius of the polytropes, the critical T/absolute value of W-values generally become less sensitive to the compressibility of the polytrope. Star/disk coupling can drive the secular instability in systems where the star is surrounded by a massive disk and, if the instability can grow to moderate amplitude, then the coupling can transport significant amounts of angular momentum from the star into the circumstellar disk. We find, for the particular case of rotating protostars during the accretion phase, that the instability growth time can be shorter than the accretion time. Further, if the instability can grow to amplitudes on the order of several percent, the star/disk coupling can remove angular momentum from the forming star faster than it is added by accretion.

Imamura, James, N.↗
NASA NTRS1996

Multilevel Algorithm for Atmospheric Data Assimilation

A multiscale algorithm for the problem of optimal statistical interpolation of observed data has been developed. This problem includes the calculation of the vector of the 'analyzed' (best estimated) atmosphere flow field w(sup a) by the formula: w(sup a) = w(sup f) + P(sup f) H(sup T) y, where the quantity y is defined by the equation (H P(sup f) H(sup T) + R)y = w(sup o) - H w(sup f), using the given model forecast first guess w(sup f) and the vector of observations w(sup o); H is an interpolation operator from the regular grid to the observation network, P(sup f) is the forecast error covariance matrix, and R is the observation error covariance matrix. At this initial stage the case of univariate analysis of single level radiosonde height data is considered. The matrix R is assumed to be diagonal, and the matrix P(sup f) is assumed to be given by the formula P(sub ij)(sup f) = sigma(sub i)(sup f) mu(sub ij) sigma(sub j)(sub f), where mu(sub ij) is a smooth, decreasing function of the distance between the i-th and the j-th points. In this paper we describe a multiscale iterative process based on a multiresolution, simultaneous displacement technique and a localized variational calculation of iteration parameters.

Brandt, Achi↗