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At least 1,351 records · Page 75

On the nonlinear temperature dependence of residual stresses in solid oxide fuel cells

The residual stresses in a dense yttria-stabilized zirconia (YSZ) layer bonded to a porous NiO-YSZ substrate were measured by X-ray diffraction in air between 25°C and 900°C. In this work, it was found that the residual stresses on the outer surface of the YSZ layer were compressive, that their magnitude increased with decreasing temperature, and that the temperature dependence was nonlinear particularly at temperatures below 600°C. An elastic model that incorporates micromechanics and laminate theory was formulated to successfully predicts the nonlinearity of the temperature dependence of the residual stresses by accounting for the effect of the order-disorder transition experienced by YSZ around 600°C and the magnetic transition of NiO at the Néel temperature around 265°C, on the properties of these materials. The implications of the results for the reliability of solid oxide fuel cells are discussed.

25 ENERGY STORAGE↗

Radiation Belt Response to Fast Reverse Shock at Geosynchronous Orbit

Fast reverse shocks (FRSs) cause the magnetosphere to expand, by contrast to the well-known compressions caused by the impact of fast forward shocks (FFS). Usually, FFSs are more geoeffective than FRSs, and consequently the inner magnetosphere dynamic responses to both shock types can be quite different. In this study, we investigate for the first time the radiation belt response to an FRS impact using multi-satellite observations and numerical simulations. Spacecraft on the dayside observed decreases in magnetic field strength and energetic (~40–475 keV) particle fluxes. Timing analysis shows that the magnetic field signature propagated from the dayside to the nightside magnetosphere. Particles with different energies vary simultaneously at each spacecraft, implying a non-dispersive particle response to the shock. Spacecraft located at lower L-shells did not record any significant signatures. The observations indicate a local time dependence of the response associated with the shock inclination, with the clearest signatures being observed in the dusk–midnight sector. Simulations underestimate the amplitude of the magnetic field variations observed on the nightside. The observed decreases in the electron intensities result from a combination of radial gradient and adiabatic effects. The radial gradients in the spectral index appear to be the dominant contributor to the observed variations of electrons seen on the dayside (near noon and dusk) and on the nightside (near midnight). This work shows that even an FRS can affect the radiation belts significantly and provides an opportunity to understand their dynamic response to a sudden expansion of the magnetosphere.

79 ASTRONOMY AND ASTROPHYSICS↗

The configuration of the geomagnetic field.

Spherical harmonic representations of the geomagnetic field based on ground-based and low-altitude spacecraft measurements adequately describe the field within several earth radii of the earth's surface. As the internal field decreases with increasing distance from the earth, external field sources become relatively more important. In the region of 3 to 6 earth radii, magnetospheric plasma inflates the field lines and decreases the field strength by an amount which is typically 10's of gammas and occasionally 100's of gammas. At greater distances on the day side of the earth, the solar wind compresses the field and produces equatorial field strengths of approximately 60 gammas at 10 earth radii. Field lines near the magnetopause intersect the earth at approximately 78 deg latitude in the sunward hemisphere. The solar wind drags high latitude field lines away from the earth in the night hemisphere forming the geomagnetic tail and neutral sheet. Asymmetric field inflation in the magnetosphere occurs during magnetic disturbances with the largest effects concentrated in the evening quadrant. The tail configuration can deviate substantially from the average configuration during magnetic disturbances.

Fairfield, D. H.↗

Magnetosonic ULF Waves With Anomalous Plasma–Magnetic Field Correlations: Standing Waves and Inhomogeneous Plasmas

Ultra-low frequency (ULF) wave observations across the heliosphere often rely on the sign of correlations between plasma (density/pressure) and magnetic field perturbations to distinguish between fast and slow magnetosonic modes. However, the assumptions behind this magnetohydrodynamic result are not always valid, particularly within the magnetosphere which is inhomogeneous and supports standing waves along the geomagnetic field. Through theory and a global simulation, we find both effects can result in anomalous plasma–magnetic field correlations. The interference pattern in standing waves can lead both body and surface magnetosonic waves to have different cross-phases than their constituent propagating waves. Furthermore, if the scale of gradients in the background are shorter than the wavelength or the waves are near-incompressible, then advection by the wave of inhomogeneities can overcome the wave's inherent sense of compression. These effects need to be allowed for and taken into account when applying the typical diagnostic to observations.

MHD Waves↗

Plate impact experiments on DC745U cooled to ~ -60 °C

Using gas-gun driven plate impact experiments, we have measured the U S - u p Hugoniot of the silicone elastomer DC745U cooled to -60 °C. In summary, the initial density changes from p 0 (23°C) = 1.312 ± 0.010 g/cm 3 to p 0 (-60°C) = 1.447 ± 0.011 g/cm 3 . The linear U S - u p Hugoniot changes from U S = 1.62 + 1.74u p km/s at +23°C, to U S = 2.03 ± 0.06 + (2.03 ± 0.06) u p km/s at -60°C. DC745U, therefore is much stiffer at -60°C than at +23°C, probably due to the crystallization that occurs at ~ -50°C. Caveats/deficiencies: 1) This report does not provide an adequate pedigree of the DC745U used. 2) References to unpublished room temperature shock compression data on the elastomer are inadequate. 3) The report has not been fact checked by a DC745 subject matter expert.

36 MATERIALS SCIENCE↗

Sub-photospheric Shocks in Relativistic Explosions

This paper examines the mechanism of internal shocks in opaque relativistic outflows, in particular in cosmological gamma-ray bursts. The shocks produce neutrino emission and affect the observed photospheric radiation from the explosion. They develop from internal compressive waves and can be of different types depending on the composition of the outflow. (1) Shocks in “photon gas,” with negligible plasma inertia, have a unique structure determined by the force-free condition—zero radiation flux in the plasma rest frame. Radiation dominance over plasma inertia suppresses the formation of collisionless shocks mediated by collective electromagnetic fields. (2) If the outflow is sufficiently magnetized, a strong collisionless subshock develops, which is embedded in a thicker radiation-mediated structure. (3) Waves in outflows with a free neutron component lead to dissipation through nuclear collisions. At large optical depths, shocks have a thickness comparable to the neutron free path, with embedded radiation-mediated and collisionless subshocks. The paper also presents first-principles simulations of magnetized flows filled with photons, demonstrating the formation of shocks and their structure. Simple estimates show that magnetized sub-photospheric shocks are efficient producers of photons and have a great impact on the observed photospheric radiation. The shock structure changes as the outflow expands toward its photosphere. The dissipation is accompanied by strong e{sup ±} pair creation, and the e{sup ±}-dressed shock carries the photosphere with it up to two decades in radius, emitting a strong pulse of nonthermal radiation.

79 ASTRONOMY AND ASTROPHYSICS↗

Spiky ion acoustic waves in collisionless auroral plasma

A theory of spiky electric fields in 'inverted V' precipitation regions is elaborated and compared with recent spacecraft observations of solitary waves and double layers. A prediction from the theory is that the electric fields propagate along the magnetic field as perturbed ion acoustic solitons that intensify by exchanging momentum with reflected particles. The solitons have minimum scale lengths of approximately 100 m and maximum electric potential and field amplitudes of 1-10 V and 1-10 mV/m. They propagate at the local ion acoustic speed and are Doppler-shifted by the drift speed of upward flowing cold ions. Both rarefactive and compressive solitons with, respectively, negative and positive electric potentials are possible. It is noted that upward propagating compressive modes intensify when the upward flow of ionospheric ions exceeds approximately 10 times the local ion acoustic speed. The kinematic and dynamic properties of rarefactive solitons are found to be consistent with recent observations.

Lotko, W.↗

Existence regimes for the formation of nonlinear dissipative structures in inhomogeneous magnetoplasmas with non-Maxwellian electrons

Nonlinear dissipative structures are studied in one and two dimensions in nonuniform magnetized plasmas with non-Maxwellian electrons. The dissipation is incorporated in the system through ion-neutral collisions. Employing the drift approximation, nonlinear drift waves are derived in 1D, whereas coupled drift-ion acoustic waves are derived in 2D in the weak nonlinearity limit. It is found that the ratio of the diamagnetic drift velocity to the velocity of nonlinear structure determines the nature (compressive or rarefactive) of the shock structure. The upper and lower bounds for velocity of the nonlinear shock structures are also found. It is noticed that the existence regimes for the drift shock waves in one and two dimensions for Cairns distributed electrons are very distinct from those with kappa distributed electrons. Interestingly, it is found that both compressive and rarefactive shock structures could be obtained for the one dimensional drift waves with kappa distributed electrons.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Pressure-induced spin crossover in a Fe 78 Si 9 B 13 metallic glass

The pressure effect on structures and properties of a Fe 78 Si 9 B 13 metallic glass was investigated by in situ high-pressure synchrotron Fe Kβ x-ray emission spectroscopy and x-ray diffraction, and electrical resistivity measurements up to ~51 GPa. The study reveals a reversible and continuous pressure-induced high- to low-spin crossover of Fe atoms in an amorphous structure. The changes of the local spin moment can be scaled to match its average atomic distance shrinkage very well during compression. The crossover of electronic spin states in the Fe 78 Si 9 B 13 metallic glass resembles that of typical crystalline Fe-bearing materials but without a sharp atomic volume collapse and an abrupt electrical resistivity jump. Furthermore, these findings could help guide applications of Fe-based metallic glasses as a soft ferromagnetic material at extreme conditions and also improve our understanding of magnetism and coupling of its changes with disordered atomic structures and other properties in metallic glasses.

36 MATERIALS SCIENCE↗

Mariner 10 observations of Mercury

The paper reviews Mariner 10 observations of Mercury during the three encounters in March 1974 in a darkside passage at an altitude of 703 km, in September 1974 in a brightside passage at southern latitudes at a distance of some 50,000 km, and in March 1975 in another darkside passage at midnorthern latitudes at a closest approach distance of about 327 km. Evidence for the chemical differentiation of Mercury is found in the morphology and distribution of the smooth plains. The concept of chemical differentiation is shown to be consistent with the observation of global compression in that the crustal shortening observed could readily be explained by a phase change in a large metal-rich core. Extreme ultraviolet observations set an upper limit to the atmosphere at around one trillionth bar, with positive identification of a tenous (10 to the minus 15th bar) He atmosphere. An unexpected finding during the first encounter was the existence of a planet-related magnetic field. The third encounter yielded unequivocal evidence that the field is of internal origin, providing an independent line of evidence that Mercury possesses a large metal-rich core.

Dunne, J. A.↗

Structure of a slow mode shock observed in the plasma sheet boundary layer

A detailed study of the plasma parameters and magnetic field measured using instrumentation aboard ISEE 2 during the recovery phase of a substorm on Apr. 24, 1979, is presented. The purpose of this study was to determine the nature and structure of the lobe-plasma sheet boundary layer. The analysis shows that the lobeward edge of the boundary is consistent with a freestanding slow mode shock. This shock is followed by a slow compression wave containing a trailing ion cyclotron wave which also stands in the flow. Measurement of the cross-tail current in the shock and the current system within the wave gives a shock thickness and wavelength comparable to but larger than both the upstream ion inertial length and the downstream proton gyroradius. Equality of the shock thickness with the standing ion cyclotron wavelength suggests that the steepness of the front is limited by dispersion rather than current-driven anomalous resistivity.

Feldman, W. C.↗

Multiscale Chirping Modes Driven by Thermal Ions in a Plasma with Reactor-Relevant Ion Temperature

A thermal ion driven bursting instability with rapid frequency chirping, considered as an Alfv´enic ion temperature gradient mode, has been observed in plasmas having reactor-relevant temperature in the DIII-D tokamak. The modes are excited over a wide spatial range from macroscopic device size to micro-turbulence size and the perturbation energy propagates across multiple spatial scales. The radial mode structure is able to expand from local to global in ~ 0.1 ms and it causes magnetic topology changes in the plasma edge, which can lead to a minor disruption event. Since the mode is typically observed in the high ion temperature ≳ 10 keV and high-! plasma regime, the manifestation of the mode in future reactors should be studied with development of mitigation strategies, if needed. In conclusion, this is the first observation of destabilization of the Alfv´en continuum caused by the compressibility of ions with reactor-relevant ion temperature.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The cause of two plasma-tail disconnection events in comet P/Haley during the ICE-Halley radial period

The causes of two plasma-tail disconnection events (DEs), which occurred in Halley's comet on March 20-22 and April 11-12, 1986, during the ICE-Halley radial period, are analyzed using the ICE magnetometer and electron plasma data. It is concluded that the DE of March 20-22 was most likely caused by an IMF polarity reversal. The DE of April 11-12 on the other hand, is attributed to either a compression region in the solar wind, an IMF polarity reversal, or a combination of the two. Assuming that the two DEs are due to frontside reconnection after an IMF reversal, it was estimated that the time period between the onset of reconnection and the final disconnection of the tail is between 0.1 and 0.6 day, suggesting that the average speed at which reconnection proceeds through the cometary magnetic field pile-up region is between 1 and 6 km/sec, or several tenths of the local Alfven speed.

Brosius, J. W.↗

A Numerical Study of Resistivity and Hall Effects for a Compressible MHD Model

The effect of resistive, Hall, and viscous terms on the flow structure compared with compressible ideal MHD is studied numerically for a one-fluid non-ideal MHD model. The goal of the present study is to shed some light on the emerging area of non-ideal MHD modeling and simulation. Numerical experiments are performed on a hypersonic blunt body flow with future application to plasma aerodynamics flow control in reentry vehicles. Numerical experiments are also performed on a magnetized time-developing mixing layer with possible application to magnetic/turbulence mixing.

Yee, H. C.↗

Pressure induced modification of electronic and magnetic properties of MnCrNbAl and MnCrTaAl

Spin-gapless semiconductor (SGS) is a new class of material that has been studied recently for potential applications in spintronics. This material behaves as an insulator for one spin channel, and as a gapless semiconductor for the opposite spin. In this work, we present results of a computational study of two quaternary Heusler alloys, MnCrNbAl and MnCrTaAl that have been recently reported to exhibit spin-gapless semiconducting electronic structure. In particular, using density functional calculations we analyze the effect of external pressure on electronic and magnetic properties of these compounds. It is shown that while these two alloys exhibit nearly SGS behavior at optimal lattice constants and at negative pressure (expansion), they are half-metals at equilibrium, and magnetic semiconductors at larger lattice constant. At the same time, reduction of the unit cell volume has a detrimental effect on electronic properties of these materials, by modifying the exchange splitting of their electronic structure and ultimately destroying their half-metallic/semiconducting behavior. Thus, our results indicate that both MnCrNbAl and MnCrTaAl may be attractive for practical device applications in spin-based electronics, but a potential compression of the unit cell volume (e.g. in thin-film applications) should be avoided.

Materials Science↗

On the excitation of cyclotron harmonic waves by newborn heavy ions

Wave measurements in planetary foreshocks and cometary environments show the sporadic occurrence of magnetic spectra with harmonic structure related to ion-cyclotron frequencies. Dilute populations of anisotropic and/or drifting charged particles can excite obliquely propagating modes with spacecraft frequencies close to the observed harmonics. Previous analyses of this generation mechanism are extended to drifting and nondrifting loss-cone-type distributions of heavy ions in a dense hydrogen magnetoplasma, characterizing the complex (real frequency and growth rate) dispersion, polarization, and compressibility of the unstable cyclotron harmonic waves. Solution of the full kinetic dispersion equation shows that it is possible to attain harmonic excitation, both in the drifting and nondrifting regimes. However, the bandwidth inherent to frequency Doppler shifts of obliquely propagating waves might preclude the observation of spectral structure in the spacecraft frame. The Giotto observations in the upstream region of comet Halley provide a reference to discuss the results.

Brinca, Armando L.↗

Strongly transverse-electric-polarized emission from deep ultraviolet AlGaN quantum well light emitting diodes

The optical polarization of emission from ultraviolet (UV) light emitting diodes (LEDs) based on (0001)-oriented Al{sub x}Ga{sub 1−x}N multiple quantum wells (MQWs) has been studied by simulations and electroluminescence measurements. With increasing aluminum mole fraction in the quantum well x, the in-plane intensity of transverse-electric (TE) polarized light decreases relative to that of the transverse-magnetic polarized light, attributed to a reordering of the valence bands in Al{sub x}Ga{sub 1−x}N. Using k ⋅ p theoretical model calculations, the AlGaN MQW active region design has been optimized, yielding increased TE polarization and thus higher extraction efficiency for bottom-emitting LEDs in the deep UV spectral range. Using (i) narrow quantum wells, (ii) barriers with high aluminum mole fractions, and (iii) compressive growth on patterned aluminum nitride sapphire templates, strongly TE-polarized emission was observed at wavelengths as short as 239 nm.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Method of fabricating composite structures

A method of fabricating structures formed from composite materials by positioning the structure about a high coefficient of thermal expansion material, wrapping a graphite fiber overwrap about the structure, and thereafter heating the assembly to expand the high coefficient of thermal expansion material to forcibly compress the composite structure against the restraint provided by the graphite overwrap. The high coefficient of thermal expansion material is disposed about a mandrel with a release system therebetween, and with a release system between the material having the high coefficient of thermal expansion and the composite material, and between the graphite fibers and the composite structure. The heating may occur by inducing heat into the assembly by a magnetic field created by coils disposed about the assembly through which alternating current flows. The method permits structures to be formed without the use of an autoclave.

Sigur, W. A.↗