Methodology for Design and Performance Assessment of Engineered Barrier Systems in a Salt Repository for HLW/SNF.
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This case study describes the implementation of several emerging lighting techniques at the new Chicago offices of IMEG Corp, an engineering and design consulting firm. IMEG collaborated with Pacific Northwest National Lab as part of a study to better understand the physiological and psychological impacts of advanced lighting strategies on occupant comfort, well-being, and energy savings. The project was recognized as part of DOE's Integrated Lighting Campaign.
The NREL-developed Modular Ocean Data Acquisition (MODAQ) system is built from open-source hardware and software. The tool can both collect and store data and even share curated information through the cloud. Marine energy developers can work with NREL's engineers to design their own customized MODAQ and capture high-quality field data to help monitor and improve their technology designs. For example, users could assess how much power their device produces at sea, analyze the durability of a specific device component, or even control their device from a desk halfway around the world.
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The 'Safety and Operation' project is started in 2009 within the framework of Generation-IV International Forum (GIF) Sodium Fast Reactor (SFR) research and development program. In the safety area, the project involves R and D activities on phenomenological model development and experimental programs, conceptual studies in support of the design of safety provisions, preliminary assessment of safety systems, framework and methods for analysis of safety architecture. In the operation area, the project involves R and D activities on fast reactors safety tests and analysis of reactor operations, feedback from decommissioning, in-service inspection technique development, under-sodium viewing and sodium chemistry. This paper presents a summary of such activities and the main achievements. (authors)
The development of a program for managing material aging (MMG) in the nuclear industry requires a new and different perspective. The classical method for MMG is cycle counting, which has been shown to have limited success. The classical method has been successful in satisfying the ductile condition per the America Society of Mechanical Engineers' (ASME) design criteria. However, the defined material failure mechanism has transformed from through-wall cracking and leakage (ASME) to crack initiation (NUREG-6909). This transformation is based on current industry experience with material degradation early in plant life and can be attributed to fabrication issues and environment concerns where cycle counting has been unsuccessful. This new perspective provides a different approach to cycle counting that incorporates all of the information about the material conditions. This approach goes beyond the consideration of a static analysis and includes a dynamic assessment of component health, which is required for operating plants. This health definition should consider fabrication, inspections, transient conditions and industry operating experience. In addition, this collection of information can be transparent to a broader audience that may not have a full understanding of the system design or the potential causes of early material degradation. This paper will present the key points that are needed for a successful fatigue monitoring desktop guide. (authors)
To help meet the need for inexpensive green fuels, we are working on wind turbine design optimization specifically for hydrogen production. We have thus far achieved a 1.53% decrease in LCOH as compared to a turbine optimized for LCOE using the same code, design variables, and models . We accomplished this by optimizing some components of the wind turbine tower, rotor, and drivetrain design with hydrogen production and costs in the design loop.
LATC is an essential part of COSINE code package, which stands for Core and System Integrated Engine for design and analysis. LATC performs 2D multi-group assembly transport calculation and generates few group constants and the required cross-section data for CORE, the core simulator code. LATC is designed to have the capability of modeling the API 000 series assemblies. The development is a continuously improved process. Currently, LATC uses well-proven technology to achieve the key functions. In the next stage, more advanced methods and modules will be implemented. At present, WIMS and WIMS improved format library could be read in LATC code. For resonance calculation, equivalent relation with rational approximations is utilized. For transport calculation, two options are available. One choice is collision probability method in cell homogenization while discrete coordinate method in assembly homogenization, the other is method of characteristics in assembly homogenization directly. For depletion calculation, an improved linear rate 'constant power' depletion method has been developed. (authors)
The performance assessment process and incorporated input assumptions for four active and one planned DOE disposal sites were analyzed using a systems approach. The sites selected were the Savannah River E-Area Slit and Engineered Trenches, Hanford Integrated Disposal Facility, Idaho Radioactive Waste Management Complex, Oak Ridge Environmental Management Waste Management Facility, and Nevada National Security Site Area 5. Each disposal facility evaluation incorporated three overall system components (1) site characteristics (climate, geology, geochemistry, etc.), (2) waste properties (waste form and package), and (3) engineered barrier designs (cover system, liner system). Site conceptual models were also analyzed to identity the main risk drivers and risk insights controlling performance for each disposal facility. (authors)
Jacobs recently completed site preparation work supporting the private commercial development of a world-scale petrochemical complex (an 'ethylene cracker' to produce the primary building block for many forms of plastic) in Monaca, Pennsylvania - the first major U.S. project of its kind outside the Gulf Coast region in 20 years and one of the largest (multi-billion dollar) construction projects in the eastern U.S. Prior to beginning construction on the petrochemical complex, the site's previous large, industrial zinc smelter operations had to be decommissioned and the facilities had to be removed. During the previous 80 years, the smelting operations at the site were used to produce zinc, lead, mercury, and sulfuric acid (a by-product of smelting). The smelting operations left landfills and industrial soil over a large area that had to be removed or closed under regulatory review to allow development across the 81,000 m{sup 2} (200-acre) industrial site located near a major river and local populations. In order to meet Pennsylvania's site-specific Land Recycling Program (commonly referred to as 'Act 2') legislative requirements, the direct contact pathway for landfill soil and slag was removed or mitigated. The site preparation work, or 'Early Works', started in January 2015. As the selected Early Works overall Engineering, Procurement, and Construction Management (EPCM) contractor, Jacobs performed the front end engineering and design. Subsequently, Jacobs had overall responsibility for procurement, construction management, health and safety, quality, security, and environmental services for the entire site and all contractors. The Early Works project included eight separate work scope packages: 1) Site Preparation, 2) Site Development, 3) Marine Works, 4) Rail Works, 5) Road Works and Offsite Utilities, 6) Site Security, 7) Construction Facilities, and 8) High Voltage Line Relocation. The Early Works scope was successfully completed in 2017. The challenges faced by this privately funded commercial project have much in common with large DOE and government construction projects. This paper explores lessons learned from the project and compares how project challenges were addressed on this private commercial project with those anticipated at large DOE/government construction and remediation sites, particularly those in the areas of Safety, Logistics, Infrastructure, and Stakeholder Involvement. The identification of best practices demonstrated on this successful project are shared for the purpose of bringing outside, commercial perspectives to ongoing or planned DOE/government construction projects. (authors)
Computational fluid dynamics (CFD) is used to predict natural circulation flows between a reactor vessel upper plenum and a steam generator during specific severe accidents in a pressurized-water reactor (PWR). The predictions are based on a model for a simplified Combustion Engineering (CE) design. This work is part of a larger study to investigate the potential for severe accident induced steam generator (SG) tube failures in PWRs being conducted by the U.S. Nuclear Regulatory Commission Office of Nuclear Regulatory Research. The CFD model builds upon the lessons learned from previous studies of a generic Westinghouse PWR under similar conditions. The CE SG is significantly larger than the Westinghouse design and geometric differences are expected to reduce the mixing and increase the potential thermal challenge to the SG tubes. The CFD predictions are utilized to improve the basis for simplified flow and mixing models applied in one-dimensional severe accident codes. Parameters are determined to support system code modeling of hot leg and SG inlet plenum mixing, hot leg and SG tube bundle flow rates, and tube inlet temperatures. This updated modeling uses boundary conditions obtained from system analysis code predictions of severe accident behavior in a CE PWR. Model refinements include an improved tube bundle representation and improvements to the thermal boundary conditions. Results indicate less mixing and higher tube inlet temperatures for the CE design compared to previous Westinghouse studies. (author)
This work focuses on a reverse-engineering program design for the cyclic voltammetry (CV) method to help illustrating, enhancing, and providing robustness in detection probability of the reactions during an electrorefining process. Analyzing the reactions from CV plots for 1.07, 2.49, and 4.98 wt% of zirconium chloride (ZrCl{sub 4}) in a LiCl-KCl molten salt at 773 K under different scan rates from Hoover's study has been accomplished. The results provide the current (Amp) versus potential (V) to investigate the optimum probability of the reactions at each peak. All simulations have been done through the commercial software MATLAB by using various experimental values existing in the literature as a first guess (e.g., the diffusion coefficients, and formal potentials). Preliminary results indicate that the zirconium reactions at each peak from cathodic to anodic side for 1.07 wt% are as followed: combination of Zr{sup +2}/Zr and Zr{sup +4}/ Zr{sup +2} at approximately -1.15 V, Zr{sup +2}/Zr at -1.5 V, Zr{sup +4}/Zr at -1.85 V, 70% Zr/Zr{sup +4} and 30% Zr/Zr{sup +2} at -0.5 V, and Zr{sup +2}/ Zr{sup +4} at - 0.25 V. These mentioned peaks are similar for 2.49 wt% at different voltages. In addition, the highest anodic peak for 4.98 wt% is found to be a combination of 30% Zr/Zr{sup +4} and 70% Zr/Zr{sup +2}. (authors)
Extraction of uranium from seawater constitutes an important avenue for ensuring nuclear fuel availability beyond the coming century. With a predicted 100 years of uranium remaining in terrestrial ores, efficient extraction of the 4.5 billion tons of uranium dissolved in ocean water would enable access to an effectively limitless supply. More near-term benefits include establishment of a backstop technology, preventing runaway price inflation for this critical resource. The current state-of-the-art material for seawater extraction of uranium is a polymeric adsorbent composed of a robust trunk material subsequently surface functionalized by copolymerization of polyacrylonitrile and a hydrophilic comonomer. Treatment of this material with hydroxylamine results in the formation of poly-amidoxime functionalities which have been known to bind strongly with uranium since the early 1980's. Despite more than three decades of investigation, many questions remain unanswered regarding how these adsorbents bind uranium in seawater. The physical characteristics of the polymer prohibit many classical characterization techniques, while most spectroscopic approaches are impeded by the relatively low concentration of uranium compared to the polymer itself and other metals extracted by the adsorbent. The traditional approach has been to investigate small molecule analogues of uranyl - dioxouranium (VI), the form of uranium present in seawater - as bound by amidoxime or amidoxime derivatives, and assert the findings to be representative of the larger polymer system. Computational efforts have also been recently leveraged to a similar end. This approach is not without difficulty, as it has been routinely proposed that the treatment with hydroxylamine and subsequent alkaline conditioning results in formation of a cyclic imide dioxime site, which is truly responsible for uranium binding, as opposed to the 'open chain' amidoxime. Further complications ensue from considering the possibility of cooperative binding interactions from the different hydrophilic comonomers which are known to be necessary for optimizing uranium capacity. Finally, application of different surface polymerization techniques has the potential to directly affect the morphology of the surface polymer by influencing the degree of grafting, extent of polymer crosslinking, and polymer density. The impact of these morphological considerations on the uranyl binding environment cannot be easily replicated with small molecule studies or by computation. Ultimately, the precise binding environment of uranium is unknown, but constitutes critical knowledge for the design and engineering of advanced adsorbent materials capable of selective extraction of uranium from seawater. Analysis of the EXAFS fits reveals three of the four polymer morphologies appear to bind uranium in different chemical environments, none of which were predicted by crystallographic study or computational investigation, challenging numerous long-held assumptions. Both AI-8 and AN/HEA spectra possess features which could be attributable to cooperative binding of uranium by comonomers, but this cannot be definitively determined by EXAFS without further investigation. Unlike AF-1, neither AI-8 or AN/HEA require an adjacent μ{sup 2}-oxo-bridged transition metal to obtain a reasonable fit. The fit for Cyclic AF-1 is refined to almost identical parameters to the fit of the original AF-1 adsorbent, with the only difference is the contracting of the light elements in the second coordination sphere. It is thus proposed that the DMSO and heat treatment of the AF-1 fiber does very little to change the uranium binding site, and any differences in uptake are more readily explained by changes in the morphology of the graft polymer. There is no evidence for cyclic amidoxime functionality contributing significantly to the extraction of uranium from seawater, and efforts to maximize the number of these binding sites should be discontinued. While molecular interactions necessarily occur in adsorption processes, these results clearly reveal physical phenomena at the mesoscale play a critical role in adsorbent behavior, even to the extent that the binding environment differs from those predicted by small molecule studies. In contrast to the current paradigm where chemical functionality is varied, improvements in the performance of polymer-based amidoxime-functionalized adsorbents for extraction of uranium from seawater need also be pursued through interrogation and modulation of bulk morphology and improvements in polymer hydrophilicity. (authors)
Introduction: Problems: Mistakes in the field due to a lack of information (Ex: Pump repair failure rate 50%); Avoidable exposure due to multiple employees for procedure adherence and monitoring; Debates over 2D drawings can be more easily resolved. Purpose: Training: Employees can be trained more effectively. Operating: Operations can be carried out more efficiently with fewer workers required with AR. Design Review: Pull the designers and designs into VR. Design: VR: Unreal Engine, Unity, Custom. AR: HoloLens: Unity, Custom - DirectX 12.
The overall objective of this project is to develop a carbon-neutral, microbial dark fermentation technology to convert waste lignocellulosic biomass into H2 with a production cost less than $2/kg-H2 via strain engineering, bioprocess design for scale-up, and integrating fermentation with microbial electrolysis cell (MEC).
The project goal is to demonstrate low-cost, interlocking, and carbon-storing insulation materials with thermal insulation of R5/inch, flexural modulus > 10 MPa, low material price < $ 0.5/ft2 wall area (materials cost for ½” thick panel), and net embodied carbon of 0.8t net CO2e/t (60% reduction compared to gypsum), respectively, which can meet the cost and performance targets of department of energy (DOE)’s 2050 climate target. To achieve this goal, the project plans three tasks, and each has a specific objective: 1) Modular design and engineering analysis of interlocking insulation panel blocks using biogenic materials (cellulose, straw, etc.): with the consideration of potential assembling and recycling. 2) Scalable manufacturing of biogenic-based interlocking insulation panels: scale up the modular panel production using ambient pressure drying and surface superhydrophobic modification at 1ft*1ft with the potential for further scalable mass production of 4ft*4ft. 3) Code-compliant testing, recycling and carbon footprint analysis of manufactured interlocking insulation panels examined using ASTM standards of thermal insulation (ASTM C518), mechanical properties (ASTM C1161), and water vapor transmission (ASTM E96).
The overall objective of this project is to develop a carbon-neutral, microbial dark fermentation technology to convert waste lignocellulosic biomass into H2 with a production cost less than $2/kg-H2 via strain engineering, bioprocess design for scale-up, and integrating fermentation with microbial electrolysis cell (MEC).
This work in progress, innovative practice, paper outlines an interdisciplinary collaborative model utilized by a team of educational researchers, and engineers to design a series of community-centered, place-based learning activities suitable for a middle or high school informal STEM learning environment. Based on the potential applications and benefits of Second-Life Electric Vehicle Batteries, the activities connect cutting-edge STEM research with multidimensional real-world challenges within their communities related to climate change, renewable energy integration and storage, intelligent transportation systems, and optimized energy management, that empowers students to think critically about the role they can play in shaping a more resilient, environmentally sustainable community.