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Satellite Power Systems (SPS) concept definition study (Exhibit D). Volume 4: Operations analyses

Using a coplanar, end-mounted antenna as a baseline, various configuration trades were performed to select a preferred solid state concept. The increase in efficiency that could be realized by use of multi bandgap solar cells, either with klystron or solid state antenna was evaluated. Satellite configurations were developed to exploit the sandwich antenna concept wherein solar cells are located on one side of the antenna panel and solid state dc/RF converters on the other side. These concepts entailed various primary and secondary reflector arrangements for directing solar energy to the solar cell side of the antenna with higher concentration ratios than used on the coplanar configurations. Operations analysis included development of a satellite construction scenario, a concept for the SCB, a top-level satellite construction operation, construction operation, construction timelines and crew sizes, mass flows to orbit, and a satellite maintenance scenario. The list of materials required for satellite construction was updated to identify significant differences relevant to the solid state satellite concept. Means of decommissioning satellites at the end of their design life were studied.

Hanley, G. M.↗

GaAs and 3-5 compound solar cells status and prospects for use in space

Gallium arsenide solar cells equal or supass the best silicon solar cells in efficiency, radiation resistance, annealability, and in the capability to produce usable power output at elevated temperatures. NASA has been involved in a long range research and development program to capitalize on these manifold advantages, and to explore alternative III-V compounds for additional potential improvements. The current status and future prospects for research and development in this area are reviewed and the progress being made toward development of GaAs cells suitable for variety of space missions is discussed. Cell types under various stages of development include n(+)/p shallow homojunction thin film GaAs cells, x100 concentration ratio p/n and n/p GaAs small area concentrator cells, mechanically-stacked, two-junction tandem cells, and three-junction monolithic cascade cells, among various other cell types.

Flood, D. J.↗

Observation of [VCu1–Ini2+VCu1–] Defect Triplets in Cu-Deficient CuInS2

Copper indium disulfide (CuInS2) is a semiconductor with a direct energy band gap of 1.53 eV, an optimal value for highly efficient thin-film solar cells. But it has reached only ~ 11 % power conversion efficiency, far less than the theoretically achievable value of ~ 30 %. The cause of this low performance is not understood. A single crystal grown from 1 mol% Cu-deficient melt was studied, using atomic resolution high-angle annular dark-field (HAADF) scanning transmission electron microscopy (STEM) and electron dispersive spectroscopy (EDS). While the bulk crystal is exactly stoichiometric CuInS2, it contains nanometer-thick, structurally coherent, Cu-deficient interphases that form along rotational twin boundaries in the {112} plane. Transition zones from bulk crystal to interphase are observed, where In is seen to move from its normal site InIn in the chalcopyrite structure to a tetrahedral interstitial site Ini, while Cu remains in its normal CuCu position. Two InIn rows of the bulk crystal merge into one row of Ini, causing excess Ini in the interphase. The concentrations of CuCu and Ini reflect a ratio of Cu vacancies, VCu, to excess Ini of ~ 2. Their relative lattice positions, and the high electrical resistivity of the crystal, suggests that VCu and excess Ini ‘precipitate’ as self-compensating, electrically neutral, [VCu1- Ini2+ VCu1-] defect triplets. This is the first atomic-level observation of the ordered defect that has been invoked as the basic structural modifier in chalcopyrite compound homologs. The interphases introduce an optical gap of 1.47 eV. Electron trapping in band tail states, evident from a photoconductivity exponent of 0.54, is the likely cause of an unusually low electron mobility of 0.1 cm2V-1s-1. The overall result is that making CuInS2 slightly copper-poor inserts nanometer-thick layers of the interphase into the bulk crystal. This study shows that apparently conflicting results of the effect of Cu deficiency on CuInS2 thin-film solar cells may be resolved by analyzing structure and composition at nanometer spatial resolution.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Enhanced Depolarized Electro-Membrane System (EDEMS) for Direct Capture of Carbon Dioxide from Ambient Air (Final Report)

The goal of this final project report is to summarize the work conducted on project DE-FE0031962. In accordance with the Statement of Project Objectives (SOPO), the University of Kentucky Center for Applied Energy Research (UK CAER) (Recipient) developed an intensified process to capture CO2 from ambient conditions (400 ppm CO2). The process combines low-temperature solvent-aided membrane capture with electrochemically-mediated solvent regeneration to simultaneously capture ambient CO2 while regenerating the solvent. The technology employs only two primary units (regenerator and absorber/contactor) while generating high purity hydrogen as a co-product that can be sold, used for energy storage, or cost-saving depolarization of the direct air capture (DAC) system during the grid peak demand, allowing for flexible operation. When depolarization is employed, the operating voltage is reduced by more than 1 V. Since the technology is powered directly by DC electricity, it can seamlessly tie in with power sources like solar cells without the need for AC/DC converters, therefore allowing for a remote operation to further mitigate greenhouse gas generation toward deploying a negative carbon emissions technology that is completely decoupled from the carbon emissions from the power source for the DAC unit. The project results verified that UK CAER’s integrated approach addressed the complexities of incumbent DAC systems by demonstrating at ambient conditions, including (1) low gas-side pressure-drop facile CO2 capture via a membrane contactor with in-situ generated hydroxide as capture solvent, (2) multi-functional electrochemical regenerator for hydroxide regeneration, CO2 concentration and hydrogen production, and (3) depolarization using cathode-produced hydrogen to reduce energy requirement. The EH&S Assessment of the process did not identify any obvious concern for the bench-scale operation and no apparent barriers to implementing UK CAER’s carbon capture and solvent regeneration system at a larger scale.

20 FOSSIL-FUELED POWER PLANTS↗

Parabolic dish systems at work - Applying the concepts

An overview is given of parabolic dish solar concentrator application experiments being conducted by the U.S. Department of Energy. The 'engineering experiments' comprise the testing of (1) a small-community powerplant system, in conjunction with a grid-connected utility; (2) stand-alone applications at remote sites such as military installations, radar stations and villages; and (3) dish modules that can deliver heat for direct use in industrial processes. Applicability projections are based on a dish and receiver that use a Brayton engine with an engine/generator efficiency of 25% and a production level of up to 25,000 units per year. Analyses indicate that parabolic-dish power systems can potentially replace small, oil-fired power plants in all regions of the U.S. between 1985 and 1991.

Marriott, A. T.↗

Process in manufacturing high efficiency AlGaAs/GaAs solar cells by MO-CVD

Manufacturing technology for mass producing high efficiency GaAs solar cells is discussed. A progress using a high throughput MO-CVD reactor to produce high efficiency GaAs solar cells is discussed. Thickness and doping concentration uniformity of metal oxide chemical vapor deposition (MO-CVD) GaAs and AlGaAs layer growth are discussed. In addition, new tooling designs are given which increase the throughput of solar cell processing. To date, 2cm x 2cm AlGaAs/GaAs solar cells with efficiency up to 16.5% were produced. In order to meet throughput goals for mass producing GaAs solar cells, a large MO-CVD system (Cambridge Instrument Model MR-200) with a susceptor which was initially capable of processing 20 wafers (up to 75 mm diameter) during a single growth run was installed. In the MR-200, the sequencing of the gases and the heating power are controlled by a microprocessor-based programmable control console. Hence, operator errors can be reduced, leading to a more reproducible production sequence.

Yeh, Y. C. M.↗

Space-based laser-powered orbital transfer vehicle (Project SLICK)

A conceptual design study of a laser-powered orbital transfer vehicle (LOTV) is presented. The LOTV, nicknamed SLICK (Space Laser Interorbital Cargo Kite), will be utilized for the transfer of 16000 kg of cargo between Low Earth Orbit (LEO) and either Geosynchronous Earth Orbit (GEO) or Low Lunar Orbit (LLO). This design concentrates primarily on the LEO/GEO scenario, which will have typical LEO-to-GEO trip time of 6 days and two return versions. One version uses an all propulsive return while the other utilizes a ballute aerobrake for the return trip. Furthermore, three return cargo options of 16000 kg, 5000 kg (standard option), and 1600 kg are considered for this scenario. The LEO/LLO scenario uses only a standard, aerobraked version. The basic concept behind the LOTV is that the power for the propulsion system is supplied by a source separate from the LOTV itself. For the LEO/GEO scenario the LOTV utilizes a direct solar-pumped iodide laser and possibly two relay stations, all orbiting at an altitude of one Earth radius and zero inclination. An additional nuclear-powered laser is placed on the Moon for the LEO/LLO scenario. The propulsion system of the LOTV consists of a single engine fueled with liquid hydrogen. The laser beam is captured and directed by a four mirror optical system through a window in the thrust chamber of the engine. There, seven plasmas are created to convert the laser beam energy into thermal energy at an efficiency of at least 50 percent. For the LEO/LLO scenario the laser propulsion is supplemented by LH2/LOX chemical thrusters.

Source record↗

34% Efficient InGaP/GaAs/GaSb Cell-Interconnected-Circuits for Line-Focus Concentrator Arrays

While monolithic multi-junction cells are preferred for flat plate arrays, mechanically stacked multi-junction cells are superior for solar concentrator applications. Reasons for this are that the mechanical stacked configuration with high efficiency Gallium Antimonide cells allows utilization of a much wider range of the solar energy spectrum, and the ability to use voltage matched interconnects results in full use of low bandgap cell currents. Herein, data are presented for simple two terminal voltage-matched circuits using InGaP/GaAs/GaSb stacked cells showing 34% average circuit efficiency for a lot of 12 circuits given prismatic covers. These circuits have been designed to fit into the ultralight Stretched Lens Array being developed by NASA. With these new cell-interconnected-circuits, we project that the power density at GEO operating temperature can be increased from 296 W/m2 to 350 W/m2 while maintaining the specific power at 190 W/kg at the full wing level.

Fraas, L. M.↗

Distributed Solar Adoption in Orlando: A Household-Level Model for Distribution Resource Planning

Potential for rooftop solar in Florida is massive (47% of retail sales, 3rd overall nationally), yet adoption lags (12th nationally). A 2018 Florida Public Service Commission ruling authorizing solar third-party ownership (leasing) has substantially increased attention on distributed solar in the state. The city of Orlando has committed to a 100% clean-energy target by 2050 and deployment of solar and storage are expected to contribute significantly to reaching the goal. Deployment of customer-adopted solar, unlike utility-procured solar, is uncertain, but known to be spatially correlated with demographic factors and existing adoption. We develop a new method to adapt NREL's dGen model in order to represent building-level agents in adoption forecasts for the Orlando Utility Commission (OUC) service territory. Using the agent-based model we develop projections of solar adoption, subject to scenarios varying future solar costs and valuation, and aggregate adoption predictions by OUC distribution feeder. We find substantial spatial heterogeneity in the projected level of adoption by OUC distribution feeder. For instance, 25% of all projected adoption through 2050 would be concentrated on just 5% of feeders and 88% of projected adoption on 50% of feeders. Because of the uncertainty in adoption, bottoms-up solar adoption forecasting methods at the household-level are integral to long-term resource planning by anticipating system needs as customers increasingly adopt distributed solar, storage, electric vehicles, and other distributed energy resources.

14 SOLAR ENERGY↗

Luminescent Enhancement for Combined Solar and Commercial Agriculture. Final Report

This proposal will develop a new racking / mounting system combined with a new agriculture-tuned luminescent solar panel for low cost high tunnel implementation to produce both crops and electricity for small local farms. Crop trials performed under this specialized panel/racking system can be extended to open field agriculture with standard utility scale racking system in phase II. The US agricultural industry uses about 300 billion KW-hr of energy / year. Of this energy consumption, roughly 20% goes towards food production and 20% goes towards food processing. This proposal will allow farm land to simultaneously generate electricity, food AND provide jobs. Employment is one of the largest hurdles for the introduction of solar into rural areas. The ability to provide agricultural jobs in addition to solar energy from a plot of land will pave the way for greater adoption of photovoltaics in rural areas. A cost effective and highly durable hybrid power generating high tunnel greenhouse will be developed that generates electricity at less than $2.50/watt INSTALLED cost and can be used for crop production of high values crops. The high tunnel will use a new design of Soliculture greenhouse integrated luminescent solar panels to selectively absorb the green portion of the solar spectrum that is not used by plants and convert the light to red light with higher photosynthetic efficiency and to enhance power output of solar cells. Green light is selectively downshifted to red light using luminescent materials that match the photosythetically active region for plants and the efficiency maximum of Si photovoltaic cells. The color tuning associated with converting green light to red light has been shown to facilitate fruit production in commercial greenhouses growing cucumbers, lettuce and herbs.

14 SOLAR ENERGY↗

Grand challenges of wind energy science – meeting the needs and services of the power system

The share of wind power in power systems is increasing dramatically, and this is happening in parallel with increased penetration of solar photovoltaics, storage, other inverter-based technologies, and electrification of other sectors. Recognising the fundamental objective of power systems, maintaining supply–demand balance reliably at the lowest cost, and integrating all these technologies are significant research challenges that are driving radical changes to planning and operations of power systems globally. In this changing environment, wind power can maximise its long-term value to the power system by balancing the needs it imposes on the power system with its contribution to addressing these needs with services. A needs and services paradigm is adopted here to highlight these research challenges, which should also be guided by a balanced approach, concentrating on its advantages over competitors. The research challenges within the wind technology itself are many and varied, with control and coordination internally being a focal point in parallel with a strong recommendation for a holistic approach targeted at where wind has an advantage over its competitors and in coordination with research into other technologies such as storage, power electronics, and power systems.

17 WIND ENERGY↗

Quantum-well lasers for direct solar photopumping

Semiconductor lasers directly photopumped by focused sunlight may be viable sources of coherent light for intersatellite communications and other low-power spaceborne applications. In this work, we theoretically explore the possibility of realizing such devices. We specifically assess solar pumped operation of separate-confinement-quantum-well heterostructure (SCQWH) lasers based on InGaAs, GaAs, and AlGaA, as fabrication technology for these lasers is mature and they can operate at very low thresholds. We develop a model for step-index single-well SCQWH lasers photopumped by sunlight, examine how threshold solar photoexcitation intensities depend upon material and structure parameters, design optimum structures for solar-pumped operation, and identify design tradeoffs. Our results suggest that laser action should be possible in properly designed structures at readily achievable solar concentrations and that optimum designs for solar-pumped SCQWH lasers differ significantly from those for analogous current injection devices.

Unnikrishnan, Sreenath↗

Selection of Solar Simulator for Solar Dynamic Ground Test

The 2 kWe Solar Dynamic (SD) Ground Test Demonstration (GTD) experiment will be conducted in 1995 at NASA Lewis Research Center (LeRC). This solar dynamic power system test will be conducted in a simulated space environment and will require an artificial sun. To address the solar simulator requirements for the GTD, Arnold Engineering Development Center (AEDC) was hired under contract to review and visit four existing solar simulator facilities. The four facilities included, AEDC's Mark 1 Chamber, NASA-JSC Chamber A, AEDC's 12V Chamber, and NASA-JPL Space Simulator Chamber. Two design concepts were considered following several months of evaluating existing solar simulator facilities throughout the United States. To satisfy system requirements for the SD GTD experiment the solar simulator needs to provide a uniform light flux to the SD concentrator, provide the light within a subtense angle of one degree, and provide an intensity of one solar constant (1.37 kW/sq m) at airmass zero. Most solar simulators are designed for supplying heat loads to spacecraft where a cone angle as large as 3 degrees is acceptable. It was also concluded that a solar simulator, such like these considered in the AEDC study, would require major facility modifications for NASA LeRC and result in significant impacts to the program. The advanced solar simulator concept developed by NASA LeRC will meet the system requirements for the SD GTD experiment Since SD GTD solar simulator requirements could not be addressed by existing simulator, an advanced concept was considered.

Tolbert, Carol M.↗

A New Fitting Procedure for the Blended He I 1083 nm Multiplet

The He I 1083 nm multiplet is a powerful tool for observing the outer solar atmosphere but is difficult to analyze because the lines are weak, highly variable, and spectrally blended, both internally and with other neighboring solar and telluric lines. After separation from nearby spectral features, two components of the He I multiplet are resolved. Fitting these lines with two unconstrained Gaussian profiles always gives a ratio of major to minor component of less than half the value which would be expected for optically thin lines. One possibility for explaining the discrepancy between the weakness of the lines and the ratio of the spectral components is to assume that the line formation regions are concentrated in laterally unresolved, optically thick structures with small filling factor. However, we present here a least-squares fitting technique using cubic splines with fixed breakpoints with the constraint that the blend is the sum of three identically shaped profiles shifted in wavelength according to the atomic structure of the blend and weighted by the corresponding statistics weights, in agreement with optically thin line formation. The basis functions for the fitting procedure have no built-in spectral symmetry or shape. The resulting underlying profiles tend to be asymmetric with excess absorption to the blue, consistent with formation by "hot" and "cool" spatial elements within the observed volume, with the hotter regions having differential motion toward the observer. The results agree well with NASA/XSO Spectromagnetograph observations in quiet sun and coronal holes. Partial funding of this research was provided through the NASA Sun-Earth Connection SR&T program.

Jones, H. P.↗

An update on SCARLET hardware development and flight programs

Solar Concentrator Array with Refractive Linear Element Technology (SCARLET) is one of the first practical photovoltaic concentrator array technologies that offers a number of benefits for space applications (i.e. high array efficiency, protection from space radiation effects, a relatively light weight system, minimized plasma interactions, etc.) The line-focus concentrator concept, however, also offers two very important advantages: (1) low-cost mass production potential of the lens material; and (2) relaxation of precise array tracking requirements to only a single axis. These benefits offer unique capabilities to both commercial and government spacecraft users, specifically those interested in high radiation missions, such as MEO orbits, and electric-powered propulsion LEO-to-GEO orbit raising applications. SCARLET is an aggressive hardware development and flight validation program sponsored by the Ballistic Missile Defense Organization (BMDO) and NASA Lewis Research Center. Its intent is to bring technology to the level of performance and validation necessary for use by various government and commercial programs. The first phase of the SCARLET program culminated with the design, development and fabrication of a small concentrator array for flight on the METEOR satellite. This hardware will be the first in-space demonstration of concentrator technology at the 'array level' and will provide valuable in-orbit performance measurements. The METEOR satellite is currently planned for a September/October 1995 launch. The next phase of the program is the development of large array for use by one of the NASA New Millenium Program missions. This hardware will incorporate a number of the significant improvements over the basic METEOR design. This presentation will address the basic SCARLET technology, examine its benefits to users, and describe the expected improvements for future missions.

Jones, P. Alan↗

VIPER Mission Traverse Planning – Design, Strategies, and Dynamics

The Volatiles Investigation Polar Exploration Rover (VIPER) is a lunar polar volatiles prospecting mission developed through NASA’s Science Mission Directorate (SMD) Planetary Science Di-vision[1].VIPER is scheduled to land on Mons Mouton near the lunar South Pole in late 2024. VIPER’s primary mission goal is to characterize the distribution of water and volatiles across a range of thermal environments. This characterization aims to assist in understanding the origin of lunar polar volatiles and also help evaluate the In-Situ Resource Utilization (ISRU) potential of the lunar poles. The VIPER rover is a four-wheeled robotic vehicle weighing ~450 kg. It is solar-powered and teleoperated from Earth over a line-of-sight radio link. The rover can move at up to 20 cm/s on flat terrain. Accounting for commanding, localization, navigation, and obstacle-avoidance delays, however, the effective speed is closer to 1 cm/s. This effective speed is known as “Speed Made Good” (SMG), adopted from maritime culture, and kept as a key performance metric for VIPER oper-ations planning, execution, and evaluation. The mission duration is anticipated to be more than 90 Earth days and involves up to 20 km of driving. VIPER’s prospecting payload consists of spectrometers to detect volatiles and assess concentrations, context imagers, and a drill for sub-surface measurements down to one meter depth [2]. Mobility, combined with the prospecting and drill instrument suite, makes VIPER an analytically powerful resource mapper.

Volatiles Investigation Polar Exploration Rover (V↗

A Framework for Assessing Economic and Environmental Trade-offs of Internalized Emission Costs in ERCOT Grid Planning

The power grid is on the cusp of a massive transition driven by three major areas: 1) the growth in demand for electricity, 2) efforts to decarbonize the United States economy, and 3) a desire to mitigate social disparities from the impact of electricity generation on local populations. However, most studies of the electricity sector do not include equity impacts in their models. This study seeks to do so by developing a comprehensive and generalizable model tailored to the Electric Reliability Council of Texas (ERCOT) grid, designed to incorporate the equity impacts of electricity generation in a decarbonized and resilient framework. To integrate equity into our research, we incorporate environmental externalities into our capacity expansion model of ERCOT. Specifically, we factor in intermediate-level local marginal damages of precursor pollutants (NH3, NOx, primary PM2.5, SO2, and VOC) and global pollutant CO2 into the cost of generating electricity. We do this by taking into account county population, county ambient pollution concentration, and generator emission rates. Leveraging open-source modeling tools, such as PowerGenome, pyGRETA, and GenX we construct a county-level model to account for these costs. We integrate these marginal damages into the variable operations and maintenance costs of generators, for both existing and potential future builds. This study’s findings suggest that the value of a dynamic social cost of carbon (SSC) will cover criteria pollutant marginal damages within the ERCOT grid and solar and wind is expected to increase out to 2035. Key metrics evaluated within this research include fuel mix distribution across technologies, transmission and grid infrastructure costs, CO2 emissions, local pollutants marginal damages, and the variation in generation capacity built by the model. These results and framework can be used to support grid decisions that explicitly include distributional and procedural equity within a decarbonized and sustainable grid framework.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Comparative performance of diffused junction indium phosphide solar cells

A comparison is made between indium phosphide solar cells whose p-n junctions were processed by open tube capped diffusion, and closed tube uncapped diffusion, of sulfur into Czochralski grown p-type substrates. Air mass zero, total area, efficiencies ranged from 10 to 14.2 percent, the latter value attributed to cells processed by capped diffusion. The radiation resistance of these latter cells was slightly better, under 1 MeV electron irradiation. However, rather than being process dependent, the difference in radiation resistance could be attributed to the effects of increased base dopant concentration. In agreement with previous results, both cells exhibited radiation resistance superior to that of gallium arsenide. The lowest temperature dependency of maximum power was exhibited by the cells prepared by open tube capped diffusion. Contrary to previous results, no correlation was found between open circuit voltage and the temperature dependency of Pmax. It was concluded that additional process optimization was necessary before concluding that one process was better than another.

Weinberg, I.↗