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NASA NTRSDate not supplied

Exploration of A Magma-Sediment Hydrothermal System on Earth: Constraints on the Habitability Potential of Martian Noachian Hydrothermal Systems

The martian crust is predominantly composed of basalt [1] and hosts a large variety of alteration materials caused by wide-ranging processes from volcanic hydrothermal processes to sedimentary and post-magmatic (e.g., see [2] and reference within). Specifically, there is an abundance of evidence that water previously flowed on Mars, ranging from ancient stream beds [3], lake basins [4], sedimentary fans in Jezero crater [5, 6], and clay minerals [7]. These secondary minerals have been observed by landers and rovers [2], from orbit [8], and in martian meteorites [9-11]. Along with low temperature alteration, high temperature hydrothermal systems from volcanic processes, as well as meteorite impacts, should have been present [12,13]. However, finding evidence of high-temperature hydrothermal activity has been challenging. To better understand these processes on Mars, Earth analogs can be used and then compared to potential scenarios and locations on Mars. Therefore, here we investigate a mafic dike and the surrounding metamorphic contact zone that has been hydrothermally altered from contact with ground water as it was emplaced. We will also compare our results to previous work on Robbers Roost Dike, an older mafic dike near our field location that intruded a similar protolith causing a potentially habitable hydrothermal system [14. 15].

R A Slank↗

NASA NTRSDate not supplied

MastCam Multispectral Examination of Rocks in the Sulfate-Bearing Terrain of Marker Band Valley, Gale Crater, Mars

A primary objective of the 4th extended mission of the Mars Science Laboratory rover Curiosity is to characterize the sulfate-bearing beds exposed on the slopes of Mt. Sharp (Aeolis Mons) above the clay-bearing beds of the Glen Torridon region characterized in the 3rd extended mission. Orbital reflectance spectroscopy from CRISM has indicated the presence of polyhydrated Mg sulfates in the portion of Mt. Sharp dubbed “Marker Band Valley” (MBV). The Marker Band is a darker toned, high-Ca pyroxene bearing unit that extends around much of Mt. Sharp above the first exposures of sulfate-bearing beds. Standoff imaging of the Marker Band indicates that it is not monolithic, but contains at least two subunits. Curiosity measures multispectral reflectance in the 430 to 1012 nm range with its Mastcam. While diagnostic spectral features of Mg-sulfates are not present in the Mastcam spectral range, a water overtone feature of some polyhydrated sulfates can be observed as a drop in reflectance in the longest wavelength one to three bands of Mastcam multispectral data. Other minerals associated with sulfate-generating alteration processes, most notably Fe-bearing minerals, are more readily detectable in Mastcam multispectral data.

W H Farrand↗

NASA NTRSDate not supplied

The Role of Olivine in Fe-Carbonate Formation in Gale Crater, Mars

Carbonates have been identified in remote sensing datasets, martian meteorites, and in-situ with rovers at Gale and Jezero craters. In Gale crater, traces of carbonate have been found by the SAM instrument throughout the Mars Science Laboratory mission, e.g., at Rocknest and Pahrump Hills, with models for carbonate formation at Pahrump Hills explored by [9]. Further up-section, CheMin data of clay-rich Glen Torridon (GT) samples show that five out of seven drill samples from GT contain Fe-carbonate alongside phyllosilicates. The GT sediments were deposited in a lacustrine environment and subsequently underwent multiple episodes of diagenesis. In this work, we explore the role of olivine in the formation of carbonates by modelling the interaction of different martian olivines with a previously modeled Gale groundwater. We then explore the incongruent dissolution of host rocks within the GT sediments by mixing olivine with quantities of the Kilmarie drill sample chemical composition as the reactant rock.

S M R Turner↗

NASA NTRS2016

Nitrogen in Ancient Mud: A Biosignature?

Nitrogen is an essential nutrient for all life on Earth and possibly elsewhere. Burial of nitrogen bound to organic matter constitutes the major flux of nitrogen into sediments today, which has led to the inference that nitrogen enrichments in sedimentary rocks may be a biosignature. However, abiotic processes such as lightning or volcanism can fix atmospheric N2 and contribute to sedimentary nitrogen burial in the absence of life. It is therefore uncertain whether observed nitrogen enrichments of up to 430 ppm in Paleoarchean metasedimentary biotite grains are indeed biogenic. This study seeks to address that problem with a numerical model. The NH4(+) concentration of an abiotic ocean is modeled as a function of source fluxes, pH-dependent NH3 volatilization, and equilibrated adsorption of NH4(+) onto clay particles. The results suggest that the observed nitrogen concentrations in Paleoarchean biotite can only be reconciled with purely abiotic processes if the ocean was more acidic (pH <6) and/or if the source fluxes from lightning and volcanism were at least an order of magnitude higher (≥10(exp 12) mol/yr) than previously thought. The bulk of the nitrogen is thus most likely of biological origin. While this does not necessitate a particular metabolism such as biological N2 fixation, the data provide evidence of nitrogen utilization back to 3.8 Gyr. Nitrogen abundances could thus provide useful information in extraterrestrial missions.

Early Earth↗

NASA NTRS2022

X-Ray Amorphous Sulfur-Bearing Phases in Sedimentary Rocks of Gale Crater, Mars

The Curiosity rover in Gale crater is investigating a mineral transition observed from orbit—an older “clay unit” to a younger “sulfate unit”—hypothesized to reflect the aridification of Mars' climate. Below this transition, the rover detected crystalline Ca-sulfates with minor Fe-sulfates but also found that some fraction of a rock's bulk SO 3 is often in the poorly constrained X-ray amorphous component. Here, we characterize the abundances and compositions of the X-ray amorphous sulfur-bearing phases in 19 drilled samples using a mass balance approach, and in a subset of 5 samples using evolved SO 2 gas measured using the SAM instrument. We find that ∼20–90 wt% of a sample's bulk SO 3 is in the X-ray amorphous state and that X-ray amorphous sulfur-bearing phase compositions are consistent with mixtures of Mg-S, Fe-S, and possibly Ca-S phases, likely sulfates or sulfites. These phases reside in the bedrock, perhaps as cementing agents deposited with detrital sediments or during early diagenesis, and in diagenetic alteration halos deposited after lithification during late diagenesis. The likely presence of highly soluble Mg-sulfates in the rocks suggests negligible fluid flow through the bedrock post-Mg-sulfate deposition. The X-ray amorphous sulfur-bearing phases probably became amorphous through dehydration in the current Martian atmosphere or inside the CheMin instrument. X-ray amorphous sulfur-bearing materials likely contribute to orbital spectral detections of sulfates, and so our results help form multiple hypotheses to be tested in the sulfate unit and are important for understanding the evolution of the Martian surface environment at Gale crater.

R. J. Smith↗

NASA NTRS2022

The Curiosity Rover’s Exploration of Glen Torridon, Gale Crater, Mars: An Overview of the Campaign and Scientific Results

The Mars Science Laboratory rover, Curiosity, explored the clay mineral-bearing Glen Torridon region for 1 Martian year between January 2019 and January 2021, including a short campaign onto the Greenheugh pediment. The Glen Torridon campaign sought to characterize the geology of the area, seek evidence of habitable environments, and document the onset of a potentially global climatic transition during the Hesperian era. Curiosity roved 5 km in total throughout Glen Torridon, from the Vera Rubin ridge to the northern margin of the Greenheugh pediment. Curiosity acquired samples from 11 drill holes during this campaign and conducted the first Martian thermochemolytic-based organics detection experiment with the Sample Analysis at Mars instrument suite. The lowest elevations within Glen Torridon represent a continuation of lacustrine Murray formation deposits, but overlying widespread cross bedded sandstones indicate an interval of more energetic fluvial environments and prompted the definition of a new stratigraphic formation in the Mount Sharp group called the Carolyn Shoemaker formation. Glen Torridon hosts abundant phyllosilicates yet remains compositionally and mineralogically comparable to the rest of the Mount Sharp group. Glen Torridon samples have a great diversity and abundance of sulfur-bearing organic molecules, which are consistent with the presence of ancient refractory organic matter. The Glen Torridon region experienced heterogeneous diagenesis, with the most striking alteration occurring just below the Siccar Point unconformity at the Greenheugh pediment. Results from the pediment campaign show that the capping sandstone formed within the Stimson Hesperian aeolian sand sea that experienced seasonal variations in wind direction.

Kristen A Bennett↗

NASA NTRSDate not supplied

Leveraging High Resolution Remotely Sensed Evapotranspiration Data to Assess Water Availability and Vulnerability in the Memphis Aquifer Area in West Tennessee

The Memphis aquifer is an indispensable source of water for municipal, agricultural, and industrial use across west Tennessee. The aquifer's water is thousands of years old and in pristine condition due to the natural geological filtering by the aquifer’s confining clay layers. To sustain the aquifer’s water supply, recharge must happen at a rate efficient enough to keep up with pumping from the aquifer. In partnership with Protect Our Aquifer and the University of Memphis Center for Applied Earth Science and Engineering Research, this project examined multiple factors to discover thriving areas of recharge in west Tennessee. The team used Integrated Multi-satellite Retrievals for GPM (IMERG) precipitation data, ECOsystem Spaceborne Thermal Radiometer on Space Station (ECOSTRESS) evapotranspiration data, Landsat 8 and National Land Cover Database (NLCD) to track landcover change, and the North American Land Data Assimilation System (NLDAS) Noah land surface model to estimate monthly runoff. These factors were averaged seasonally from 2019 to 2022 to understand seasonal relationships within the study area. Precipitation and evapotranspiration data were used to create water balance maps and with the evaporative stress index (ESI), landcover, and runoff maps, the team pinpointed locations that are most conducive to recharge. The team determined that areas where the water balance is low, ESI is high, and where there is sufficient pervious landcover are locations where recharge happens most effectively. Identification of effective recharge locations may be used by the partners to prioritize areas in need of protection before they become impacted by industrialization and urbanization.

Lauren Webster↗

NASA NTRS2022

A Primordial Atmospheric Origin of Hydrospheric Deuterium Enrichment on Mars

The deuterium-to-hydrogen (D/H or 2H/1H) ratio of Martian atmospheric water (~6× standard mean ocean water, SMOW) is higher than that of known sources, requiring planetary enrichment. A recent measurement by NASA’s Mars Science Laboratory rover Curiosity of Hesperian-era (>3 Ga) clays yields a D/H ratio ~3×SMOW, demonstrating that most of the enrichment occurs early in Mars’s history, reinforcing the conclusions of Martian meteorite studies. As on Venus, Mars’s D/H enrichment is widely thought to reflect preferential loss to space of 1H (protium) relative to 2H (deuterium), but both the cause and the global environmental context of large and early hydrogen losses remain to be determined. Here, we apply a recent model of primordial atmosphere evolution to Mars, link the magma ocean of the accretion epoch with a subsequent water-ocean epoch, and calculate the behavior of deuterium for comparison with the observed record. In contrast to earlier works that consider Martian D/H fractionation in atmospheres in which hydrogen reservoirs are present exclusively as H2O or H2, here we consider 2-component (H2O-H2) outgassed atmospheres in which both condensed (H2O) and escaping (H2) components – and their interaction – are explicitly calculated. We find that a a ≈2-3× hydrospheric deuterium-enrichment is produced rapidly if the Martian magma ocean is chemically reducing at last equilibration with the primordial atmosphere, making H2 and CO the initially dominant species, with minor abundances of H2O and CO2. Reducing gases – in particular H2 – can cause substantial greenhouse warming and prevent a water ocean from freezing immediately after the magma ocean epoch. We find that greenhouse warming due to plausible H2 inventories (pH2=1-102 bars) yields surface temperatures high enough (Ts=290-560 K) to stabilize a water ocean and produce an early hydrological cycle through which surface water can be circulated. Moreover, the pressure-temperature conditions are high enough to produce ocean-atmosphere H2O-H2 isotopic equilibrium through gas-phase deuterium exchange such that surface H2O strongly concentrates deuterium relative to H2, which preferentially takes up protium and escapes from the primordial atmosphere. The efficient physical separation of deuterium-rich (H2O) and deuterium-poor (H2) species via condensation permits equilibrium isotopic partitioning and early atmospheric escape to be recorded in modern crustal reservoirs. The proposed scenario of primordial H2-CO-rich outgassing and escape suggests significant durations (>Myr) of chemical conditions on the Martian surface conducive to prebiotic chemistry immediately following magma ocean crystallization.

Mars↗

NASA NTRSDate not supplied

The Complex Refractive Indices of Mineral Aerosols and Why They Matter

Aerosol refractive indices are fundamental parameters that are generally measured by spec-troscopists with specialized knowledge. We in the Earth science community frequently utilizethese refractive indices because they are essential for computing aerosol radiative effects andretrieving aerosol composition. Unfortunately, there are a wide variety of refractive indiceswith significant differences for some aerosol species (e.g., hematite) and a lack of refractiveindex choices for other aerosols (e.g., clay minerals, goethite), and this hinders our ability toaccurately compute the radiative effect of mineral dust. Additionally, the mineral refractiveindices used in atmospheric science are not necessarily linked to the mineral reflectancesused to identify surface mineralogy; this creates a disconnect between the atmosphere andthe surface that frustrates closure analyses.In this talk, we will present an overview of some refractive indices of radiative importancein aeolian dust (illite, kaolinite, montmorillonite, hematite, goethite). We will discuss howmineral refractive indices are used in aerosol retrievals, and how we can use remote sensingretrievals to narrow the range of viable choices. We will also discuss how we can use pub-lished spectroscopic measurements to extrapolate the refractive indices that are inferred ata handful of visible and near-infrared wavelengths to the longwave regime. Finally, we willdiscuss how working groups like MIRA (Models, In situ, and Remote sensing of Aerosols;https://science.larc.nasa.gov/mira-wg/) and community repositories like TAO (Tables ofAerosol Optics) can improve radiative closure by enhancing interactions between the threedisciplines.1

aerosols↗

NASA NTRSDate not supplied

Phyllosilicate Formation on Early Mars Via Open-System Acid Alteration of Basaltic Glass

Smectites are widespread on Mars, but neutral/alkaline conditions favorable for smectite formation have surprisingly not led to abundant carbonates. Smectite formation on Mars could also occur in acidic environments unfavorable for carbonate formation. Acidic smectite formation has been demonstrated in batch (closed hydrologic) systems, however, the mechanisms and octahedral composition of smectite forming in acidic flow-through (open hydrologic) systems are not fully understood. Stapafell basaltic glass was hydrothermally altered (190◦C) at two flow rates corresponding to low and high water to rock ratio (W/R) and initial pH (pH_0) values of 2, 3, 4 and 6, and a batch low W/R experiment was conducted at pH_0 2. Kaolinite, montmorillonite and chlorite formed at pH_0 2 at low W/R; no phyllosilicates formed at pH_0 2 at high W/R; and lizardite formed at pH_0 ≥3 at both W/R ratios. Lizardite, kaolinite, and montmorillonite in these experiments formed by precipitation from solution and chlorite likely formed through alteration of montmorillonite and/or basalt. Saponite formed at pH_0 2 in batch conditions by alteration of basaltic glass. Comparison of experimental data with martian phyllosilicate assemblages indicated that smectite formation on Mars likely occurred under water-limited conditions. Al-rich smectite could form in open-system low W/R subsurface environments under a narrow range of pH (pH <3) while saponite could form in closed low W/R systems under acidic to alkaline conditions. Combined open and closed hydrological regimes could be responsible for development of clay mineral stratigraphies observed on Mars. The acidic conditions required for formation of Al-rich smectite were unfavorable for carbonate precipitation, but carbonate precipitation could occur together with Fe/Mg-smectite in closed systems at pH >4. The lack of carbonates occurring together with Fe/Mg-smectite could be cause by low pCO2 in subsurface closed environments and/or by overall lack of carbonate precipitation despite significant oversaturation.

S J Ralston↗

NASA NTRSDate not supplied

Habitability Potential of Martian Hydrothermal Systems Constrained from Exploration of a Magma-Sediment Hydrothermal System in the Colorado Plateau

Mars has a crust predominately composed of basalt, which displays wide-spread processes including volcanic hydrothermal systems and reference within. There is an abundance of evidence of previous low temperature hydrous alteration; however, finding evidence of high-temperature hydrothermal activity has been challenging. Therefore, we are investigating a mafic dike and the surrounding metamorphic contact zone to constrain how to find such systems on Mars and their habitability potential on Earth and by extension Mars. DC Dike (DCD) is in the Colorado Plateau, in south-central Utah, and intruded the Entrada formation Sandstone between 3.8 and 4.6 Ma. We chose Mars analog instrumentation to make our results directly applicable to those on Mars: Visible-Near Infrared reflectance spectroscopy (VNIR), X-Ray Diffraction (XRD), and Scanning Electron Microscope (SEM). 21 samples were analyzed with an Ore Express VNIR with wavelengths from 350-2500 nm. Bulk mineralogy is determined by using a Panalytical XRD including for clay fraction and soil separation analysis. Finally, samples are prepped as thin sections and will be analyzed using a SEM. All these techniques will be used to constrain: the mineralogy of the system, how the hydrothermal system cooled, the habitability of the cooling system, and how DCD relates to similar dikes in the area and on Mars. All of these results will then be compared to similar systems Mars, and if they too could have been habitable environments.

R. A. Slank↗

NASA NTRSDate not supplied

Spectral Characterization of Organics and Carbonates in Carbonaceous Chondrites: Implications for Bennu Returned Samples

On September 24th, 2023, the OSIRIS-REx mission returned samples to Earth from the B-type asteroid (101955) Bennu, a carbon- and water-rich asteroid. The preliminary analysis of the Bennu sample shows that this asteroidal material is rich in clay and sulfide minerals, carbon (~5 wt%), and iron oxides. These preliminary results agree with remote sensing observations of Bennu by the OSIRIS-REx Visible and Infrared Spectrometer (OIVRS) instrument. Global remote sensing observations of Bennu revealed that this primitive asteroid is hydrated with a deep 3-µm band (~20%) centered at ~2.74 µm, attributed to OH in phyllosilicates and most similar CM-type carbonaceous chondrites. As part of a NASA Laboratory Analysis of Returned Samples study, we plan to analyze Bennu samples to evaluate the relationship between organic and carbonate phases and their relationship to aqueous processes on the asteroid's parent body. To that end and to constrain the evolution of carbon reservoirs during the secondary processing events (e.g., aqueous alteration) experienced by Bennu, we will use multiple analytical techniques, including reflectance spectroscopy.

Asteroid samples↗

NASA NTRSDate not supplied

Advances in X-ray Instruments to Support Mars Sample Return

The Mars 2020 Perseverance rover is currently collecting drill cores of ancient igneous and sedimentary rock in and around Jezero crater for potential transport to Earth. These samples from the martian surface will enable detailed mineralogical, geochemical, and petrological measurements to characterize ancient depositional and diagenetic environments, quantitatively age-date the samples, and identify the building blocks for life or evidence for life itself. Furthermore, these drill cores are especially precious because they may represent the most pristine samples from the martian surface and our best chance at identifying martian life, as future sample return missions may be conducted by humans that can introduce biological contaminants to the samples. Because of the importance of these samples, we must take great care in their handling, curation, and preliminary analyses so that they are preserved for scientific measurements for decades to come. In-situ measurements by Perseverance have identified minerals that further warrant special treatment of the returned samples. Hydrated sulfate carbonate, swelling clay minerals, and oxychlorine salts are extremely sensitive to changes in temperature and relative humidity. The structures of hydrated sulfates and oxychlorine minerals, in particular, readily change when exposed to different conditions, meaning the mineral assemblage of the as-returned samples may be lost if the samples aren’t handled properly. Characterizing the as-returned mineral assemblage, particularly of the salts, is essential for reconstructing past aqueous conditions and habitability. To characterize the as-returned mineral assemblage, the samples must be analyzed rapidly before phase changes occur and/or under controlled conditions (e.g., within a glove box). Significant recent advances in X-ray instrumentation for robotic exploration of the solar system have resulted in high-resolution miniaturized instruments that would provide mineralogical, geochemical, and petrological information on the returned martian samples without degradation of the mineral assemblage. Here, we describe a combined X-ray diffractometer/X-ray fluorescence spectrometer (XRD/XRF), an X-ray computed tomographic (XCT) instrument, and a scanned beam XRF mapping instrument that could be used in a glove box so that the martian samples remain under controlled conditions.

E. B. Rampe↗

NASA NTRS2024

Substrate Matters: Ionic Silver Alters Lettuce Growth, Nutrient Uptake, and Root Microbiome in a Hydroponics System

Ionic silver (Ag+) is being investigated as a residual biocide for use in NASA spacecraft potable water systems on future crewed missions. This water will be used to irrigate future spaceflight crop production systems. We have evaluated the impact of three concentrations (31 ppb, 125 ppb, and 500 ppb) of ionic silver biocide solutions on lettuce in an arcillite (calcinated clay particle substrate) and hydroponic (substrate-less) growth setup after 28 days. Lettuce plant growth was reduced in the hydroponic samples treated with 31 ppb silver and severely stunted for samples treated at 125 ppb and 500 ppb silver. No growth defects were observed in arcillite-grown lettuce. Silver was detectable in the hydroponic-grown lettuce leaves at each concentration but was not detected in the arcillite-grown lettuce leaves. Specifically, when 125 ppb silver water was applied to a hydroponics tray, Ag+ was detected at an average amount of 7 μg/g (dry weight) in lettuce leaves. The increase in Ag+ corresponded with a decrease in several essential elements in the lettuce tissue (Ca, K, P, S). In the arcillite growth setup, silver did not impact the plant root zone microbiome in terms of alpha diversity and relative abundance between treatments and control. However, with increasing silver concentration, the alpha diversity increased in lettuce root samples and in the water from the hydroponics tray samples. The genera in the hydroponic root and water samples were similar across the silver concentrations but displayed different relative abundances. This suggests that ionic silver was acting as a selective pressure for the microbes that colonize the hydroponic water. The surviving microbes likely utilized exudates from the stunted plant roots as a carbon source. Analysis of the root-associated microbiomes in response to silver showed enrichment of metagenomic pathways associated with alternate carbon source utilization, fatty-acid synthesis, and the ppGpp (guanosine 3′-diphosphate 5′-diphosphate) stringent response global regulatory system that operates under conditions of environmental stress. Nutrient solutions containing Ag+ in concentrations greater than 31 ppb in hydroponic systems lacking cation-exchange capacity can severely impact crop production due to stunting of plant growth.

lettuce↗

NASA NTRSDate not supplied

Demonstration of Fluid Dynamics for Plant Growing Systems in Varied Gravity Environments Through Scaled Capillary Models

The development of reliable and bioregenerative crop growth production systems is vital for human exploration into deep space. As humans prepare for space travel beyond LEO, scientists need to find a way to provide reliable and adequate water delivery for all stages of the plant's life cycle. Past production systems struggled with this and often led to overwatering in the system. To better understand this issue, NASA's Plant Water Management (PWM) experiments were able to model fluid flow through granular substrates, specifically a clay-based material arcilite, in 0-G. The PWM study can help researchers to predict fluid flow through the systems, however their model only works for an arcilite based system and was unable to account for different stages of plant growth. For future missions, payload requirements to support crop production system will need to be limited, leading to the use of in situ resources. This project aims to validate the PWM experiments as well as incorporate various materials into the design for growth systems. To meet these objectives, a series of terrestrial experiments will be deployed to mimic all gravities. By modifying the material, fluid, and size of the test subjects, the effect of Earth's gravity can be minimized. This project will aid researchers in the design of future crop production systems for surface missions by creating a refined model that can be used at all stages of plant growth and utilize in situ resources.

Plant Biology↗

NASA NTRS2024

Modeling Impacts of Dust Mineralogy on Fast Climate Response

Mineralogical composition drives dust impacts on Earth's climate systems. However, most climate models still use homogeneous dust, without accounting for the temporal and spatial variation in mineralogy. To quantify the radiative impact of resolving dust mineralogy on Earth's climate, we implement and simulate the distribution of dust minerals (i.e., illite, kaolinite, smectite, hematite, calcite, feldspar, quartz, and gypsum) from Claquin et al. (1999) (C1999) and activate their interaction with radiation in the GFDL AM4.0 model. Resolving mineralogy reduces dust absorption compared to the homogeneous dust used in the standard GFDL AM4.0 model that assumes a globally uniform hematite volume content of 2.7 % (HD27). The reduction in dust absorption results in improved agreement with observation-based single-scattering albedo (SSA), radiative fluxes from CERES (the Clouds and the Earth's Radiant Energy System), and land surface temperature from the CRU (Climatic Research Unit) compared to the baseline HD27 model version. It also results in distinct radiative impacts on Earth's climate over North Africa. Over the 19-year (from 2001 to 2019) modeled period during JJA (June–July–August), the reduction in dust absorption in AM4.0 leads to a reduction of over 50 % in net downward radiation across the Sahara and approximately 20 % over the Sahel at the top of the atmosphere (TOA) compared to the baseline HD27 model version. The reduced dust absorption weakens the atmospheric warming effect of dust aerosols and leads to an alteration in land surface temperature, resulting in a decrease of 0.66 K over the Sahara and an increase of 0.7 K over the Sahel. The less warming in the atmosphere suppresses ascent and weakens the monsoon inflow from the Gulf of Guinea. This brings less moisture to the Sahel, which combined with decreased ascent induces a reduction of precipitation. To isolate the effect of reduced absorption compared to resolving spatial and temporal mineralogy, we carry out a simulation where the hematite volume content of homogeneous dust is reduced from 2.7 % to 0.9 % (HD09). The dust absorption (e.g., single-scattering albedo) of HD09 is comparable to that of the mineralogically speciated model on a global mean scale, albeit with a lower spatial variation that arises solely from particle size. Comparison of the two models indicates that the spatial inhomogeneity in dust absorption resulting from resolving mineralogy does not have significant impacts on Earth's radiation and climate, provided there is a similar level of dust absorption on a global mean scale before and after resolving dust mineralogy. However, uncertainties related to emission and distribution of minerals may blur the advantages of resolving minerals to study their impact on radiation, cloud properties, ocean biogeochemistry, air quality, and photochemistry. On the other hand, lumping together clay minerals (i.e., illite, kaolinite, and smectite), but excluding externally mixed hematite and gypsum, appears to provide both computational efficiency and relative accuracy. Nevertheless, for specific research, it may be necessary to fully resolve mineralogy to achieve accuracy.

Soil dust↗

NASA NTRSDate not supplied

Mineralogical Characterization of a Potential Mars-Analog Field Site: Gypsum- and Carbonate-Bearing Formations in the Quebradas Back Country, New Mexico, USA

The Quebradas Back Country field site is located approximately six miles east of Socorro, NM, USA and provides access to Pennsylvanian and Permian age sedimentary formations that record environments ranging from lacustrine to hypersaline supratidal mudflats in deposits of carbonate, sulfate, and clay minerals. These deposits demonstrate a critical climate transition from cold and wet to largely arid conditions, which may parallel the drying of ancient Mars. The Quebradas sulfate and carbonate deposits can provide insight into the formation and weathering of Mars-relevant sulfates and elucidate potential causes for the prevalence of calcium sulfate and paucity of calcium carbonate on Mars. Deciphering the environmental cues held within evaporites is particularly timely now with mounting evidence for sulfate-rich fluids in Jezero crater and the Curiosity rover analyzing the sulfate-bearing unit in Gale crater.

S J Ralston↗

NASA NTRS2026

Diverse organic molecules on Mars revealed by the first SAM TMAH experiment

The search for organic matter on Mars has rapidly evolved in the past decade with simple aromatic, S-heterocycles, and aliphatic organic molecules detected in Gale crater. We report the in situ detection of >20 organic molecules from clay-bearing sandstones in the ~3.5-billion-year-old Knockfarrill Hill member of Glen Torridon, Gale crater, by the Sample Analysis at Mars instrument suite onboard the Curiosity rover. These molecules were liberated by the onboard tetramethylammonium hydroxide wet chemistry experiment. Diverse thermochemolysis products, including benzothiophene, methyl benzoate, and single and dicyclic aromatic molecules were released and detected by evolved gas analysis and gas chromatography-mass spectrometry. Results indicate the experiment successfully released molecules preserved in ancient macromolecular or free organic matter within Martian bedrock despite ~3.5 billion years of diagenesis and radiation exposure.

Amy J Williams↗