SEARCH · Engineering Papers
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Bulk amorphous spheres of Pd(77.5)Si(16.5)Cu(6), 1.5 mm in diameter, have been produced in free-fall containerless solidification. The experiments were conducted in the 32-m drop tube at Marshall Space Flight Center. The samples appear to be at least as stable (if not more so) as those produced during water quench.
The gradual heating of the nucleus of a comet approaching the sun may produce solid-state phase changes that are of particular importance for new comets, which may never have been heated before. The water-ice component of new comets is expected to be amorphous rather than crystalline, and its subsequent crystallization should produce gaseous tails and flareups at heliocentric distances about 70% greater than those expected for crystalline nuclei. These distances and the size of the flareups depend strongly on the inclination of the rotation axis and on the porosity of the ice. The effect should be weaker for older comets, but it may be related to the behavior of P/Schwassmann-Wachmann 1 if the layers of the crystallized ice peel off.
The viscosity of the molten alloy Pd(77.5)Si(16.5)Cu(6) has been determined from 744 to 1000 C using an oscillating cup viscometer. Using these data (together with other pertinent physical data available for this alloy) in existing crystallization theory indicates that it could be made amorphous at cooling rates as low as 5-10 K/sec. This analysis assumes strictly homogeneous nucleation. Containerless solidification will be one good testing ground for the results of this analysis.
The graphoepitaxial alignment of vapor-deposited discrete metal crystallites is investigated in the nucleation and growth stages and during annealing by in situ UHV/TEM techniques. Various stages of nucleation, growth and coalescence of vapor deposits of Au, Ag, Pb, Sn, and Bi on amorphous, topographically structured C substrates are analyzed by advanced dark-field techniques to detect preferred local orientations. It is found that the topography-induced orientation of metal crystallites depends strongly on their mobility and their respective tendency to develop pronounced crystallographic shapes. Lowering of the average surface free energies and increasing the crystallographic surface energy anisotropies cause generally improved graphoepitaxial alignments.
The research approach undertaken by the authors relative to the subject, and examples of results from the authors are reviewed. The studies include programs in adhesion, friction, and various wear mechanisms (adhesive and abrasive wear). The materials which have been studied include such ceramic and metallic materials as silicon carbide, ferrites, diamond, and amorphous alloys.
It is pointed out that the identity of the chemical species responsible for the yellow coloration of the clouds of Venus and for the dark features which dapple the planet at ultraviolet wavelengths has long been a mystery. Independent pieces of evidence, discovered recently, suggest now that amorphous sulfur is the so-called UV absorber. A review of earlier ideas and controversies is presented, and attention is given to a new physical-chemical model of the Venus clouds which shows that sulfur should form there. A description is provided of physical characteristics of the cloud particles that, in comparison with model predictions, indicate the presence of sulfur. Optical data suggesting that elemental sulfur occurs in the clouds is discussed, and cloud morphological evidence for sulfur is considered.
The results of experiments intended for defining the vapor phase condensation of refractory materials are reported, and the usefulness of applying laboratory data to astrophysical conditions is assessed. The testing apparatus used produced Mg-SiO smokes by boiling powders in an evaporator. Critical temperatures for the onset of nucleation were measured for SiO-H2 and Mg-SiO-H2 systems. Spectroscopic examination of the grains produced were determined to be similar to the spectra obtained from both carbonaceous chondrites and several stratospheric micrometeorites. The experiments demonstrated that direct nucleation of refractory silicates from the vapor phase yielded amorphous, metastable particles, resembling more circumstellar grains than a chondritic matrix. It is suggested that the formation of SiO(x) may control nucleation in oxygen-rich stars.
Amorphous, 'diamond-like' carbon films have been deposited on Si substrates, using ion-beam sputtering. The interfacial properties are studied using capacitance and conductance measurements. Data are analyzed using existing theories for interfacial electrical properties. The density of electronic states at the interface, along with corresponding time constants are determined.
The microstructure and corrosion behavior of magnetron sputter deposited amorphous metallic films of (Mo6ORu40)82B18 under varying sputtering atmospheres have been investigated. The microstructural details and topology of the films have been studied by scanning electron microscopy and correlated with the deposition conditions. By reducing the pressure of pure argon gas, the characteristic features of rough surface and columnar growth full of vertical voids can be converted into a mirror-smooth finish with very dense deposits. Films deposited in the presence of O2 or N2 exhibit columnar structure with vertical voids. Film deposited in pure argon at low pressure show remarkably high corrosion resistance due to the formation of a uniform passive surface layer. The influence of the microstructure and surface texture on the corrosion behavior is discussed.
Procedures and compositions for producing metallic glasses in bulk at slow cooling rates were investigated. An attempt was made to form the amorphous phase of the tetrahedrally coordinated elements (Si or Ge) by undercooling the melt. The crystal nucleation behavior of pure liquids and glass formers were examined.
By the application of a new technique, the viscosity of amorphous silica fibers was determined in the 1100-1350 C temperature range. An equation was derived that describes the kinetics of shrinkage of the fibers in terms of their radius, viscosity, and surface tension.
Amorphous coatings of refractory metal/metalloid-based alloys deposited by magnetron sputtering provide extraordinary hardness and wear resistance. Sputtering target fabricated by thoroughly mixing powders of tungsten, rhenium, and boron in stated proportions and pressing at 1,200 degrees C and 3,000 lb/in. to second power (21 MPa). Substrate lightly etched by sputtering before deposition, then maintained at bias of - 500 V during initial stages of film growth while target material sputtered onto it. Argon gas at pressure used as carrier gas for sputter deposition. Coatings dense, pinhole-free, extremely smooth, and significantly resistant to chemical corrosion in acidic and neutral aqueous environments.
A failure analysis of thin film amorphous silicon solar cell modules was conducted. The purpose of this analysis is to provide information and data for appropriate corrective action that could result in improvements in product quality and reliability. Existing techniques were expanded in order to evaluate and characterize degradational performance of a-Si solar cells. Microscopic and macroscopic defects and flaws that significantly contribute to performance degradation were investigated.
Amorphous silicon solar cells were irradiated with 1 MeV electrons at the Space Environmental Effects Laboratory of the NASA Langley Research Center. The cells accumulated a total fluence of 10 to the 14th, 10 to the 15th, and 10 to the 16th electrons per square centimeter and exhibited increasing degradation with each irradiation. This degradation was tracked by evaluating the I-V curves for AM0 illumination and the relative spectral response. The observed radiation damage was reversed following an anneal of the cells under vacuum at 200 C for 2 hours.
Hard protective coatings in the W-Re-B and Mo-Ru-B alloy systems have been deposited by magnetron sputtering onto soda-lime glass and heat-treated AISI 52100 steel substrates. X-ray diffraction has confirmed the amorphous nature of the as-deposited coatings, and their crystallization temperatures were determined by differential thermal analysis to be 1000 and 790 C for W-Re-B and Mo-Ru-B coatings, respectively. Both coatings exhibit high microhardness; Mo-Ru-B, in addition, has excellent corrosion resistance by comparison with pure Mo at high anodic potentials. Attention is given to the influence of internal stresses on the protective properties of the coatings deposited under different conditions.
By using metallic glass compositions with a high relative glass transition temperature, such as Pd40Ni40P20, homogeneous nucleation also becomes negligible. Large (5g) masses of this alloys were obtained using a molten B2O3 flux. Presently, bulk glass formation in iron based glasses is being investigated. It is expected that if an undercooling of about 250K can be achieved in a Ge or Si melt, formation of the amorphous semiconductor phase (rather than the crystal) may be kinetically favored. The volumetric behavior of undercooled liquid Ga droplet dispersion is investigated by dilatometry. A theoretical model (both analytical and numerical) was developed for transient nucleation in glass forming melts. The model, originally designed for isothermal conditions, was extended to continuous quenching. It is being applied to glass formation in various metallic and oxide systems. A further refinement will be the inclusion of diffusion controlled interfacial rearrangements governing the growth of the crystal embryos.
In July of 1984, Hughes and JPL initiated a contract for Hughes to design, fabricate and test 10 thin film Amorphous Silicon (a-Si) photovoltaic power modules. These modules were to be 1 ft x 4 ft in size. They were to be preceded by the delivery of 10 a-Si 4 in. square test devices. This effort is very timely since thin film PV development has progressed to the point where intermediate load power applications are on the horizon. It is important to know if current a-Si submodule design and manufacturing processes yield a product that is compatible with the packaging needed to meet a 20 to 30 year life span expectancy. The term submodule is assigned to an interconnected assembly of 28 a-Si cells deposited on a 1 foot square glass superstrate. These assemblies are equipped with electrical terminations, i.e., copper tabs at the four corners of the inverted submodules. It is these submodules that are to be interconnected and packaged into power modules, as opposed to the interconnected individual crystalline cells packaged into todays PV modules. A discussion of the fabrication methods and results follows.
The broad interstellar IR extinction features located at 9.7 and 18 microns wavelength are believed to originate from silicate dust grains. Cosmic abundances suggest that the silicate should have a chemical composition similar to that of olivine, (Mg,Fe)2 SiO4. Olivine is a very common terrestrial silicate mineral of crystalline structure. However, crystalline olivine grains do not fit the interstellar features well. Based on spectroscopic data obtained in laboratory studies and astronomical observations it was concluded that the interstellar silicate grains consist of a material with amorphous rather than crystalline structure. The astronomical arguments and the results obtained in our laboratory experiments which support this view are reviewed.