Template Engineering of Metal-to-Insulator Transitions in Epitaxial Bilayer Nickelate Thin Films
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36 MATERIALS SCIENCE↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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CECE: A Deep Throttling Demonstrator Cryogenic Engine for NASA's Lunar Lander
As one of the first technology development programs awarded under NASA's Vision for Space Exploration, the Pratt & Whitney Rocketdyne (PWR) Deep Throttling, Common Extensible Cryogenic Engine (CECE) program was selected by NASA in November 2004 to begin technology development and demonstration toward a deep throttling, cryogenic Lunar Lander engine for use across multiple human and robotic lunar exploration mission segments with extensibility to Mars. The CECE program leverages the maturity and previous investment of a flight-proven hydrogen/oxygen expander cycle engine, the RL10, to develop and demonstrate an unprecedented combination of reliability, safety, durability, throttlability, and restart capabilities in a high-energy, cryogenic engine. NASA Marshall Space Flight Center and NASA Glenn Research Center personnel were integral design and analysis team members throughout the requirements assessment, propellant studies and the deep throttling demonstrator elements of the program. The testbed selected for the initial deep throttling demonstration phase of this program was a minimally modified RL10 engine, allowing for maximum current production engine commonality and extensibility with minimum program cost. In just nine months from technical program start, CECE Demonstrator No. 1 engine testing in April/May 2006 at PWR's E06 test stand successfully demonstrated in excess of 10:1 throttling of the hydrogen/oxygen expander cycle engine. This test provided an early demonstration of a viable, enabling cryogenic propulsion concept with invaluable system-level technology data acquisition toward design and development risk mitigation for both the subsequent CECE Demonstrator No. 2 program and to the future Lunar Lander Design, Development, Test and Evaluation effort.
Giuliano, Victor J.↗
Two-Phased Approach to Synchronize the FERC-USACE Processes for Authorizing Non-Federal Hydropower Projects
Publication summarizing how the United States Army Corps of Engineers (USACE) and Federal Regulatory Energy Commission (FERC) have developed a two-phased, coordinated approach to regulating non-federal hydropower projects.
environmental↗
Investigation of near-field jet stability of a single-hole injector based on fast X-ray phase contrast imaging and image feature matching
Fuel spray is very effective in controlling the combustion process to improve engine performance and reduce emissions. Understanding the spray unstability during the injection process is of importance to improve the control of spray characteristics and engine operation. In this study, near-field biodiesel jets were recorded using fast X-ray phase contrast imaging and the flow features inside the jet were extracted using Speeded Up Robust Features (SURF) method. Here, the image similarity by feature matching was successfully used to represent the near-field jet stability. Based on the jet stability, an injection process can be divided into five stages: an unstable stage at needle opening, a partially stable transition stage at needle opening, a stable stage, a stable transition stage at needle closing and an unstable stage at needle closing. The ranges of needle lift for five stages were also determined. The jet unstability is highly related to the cavitation formation and gas purging process during needle opening. The variation of stable jet feature is dependent on the needle lift at needle closing. Higher needle lift for the similar jet feature at needle opening indicates a hydraulic delay compared to needle closing. Finally, the possible reasons of jet feature formation and feature detection used on the multi-hole injector are discussed.
33 ADVANCED PROPULSION SYSTEMS↗
A review and evaluation of the Langley Research Center's Scientific and Technical Information Program. Results of phase 4: Knowledge and attitudes survey, academic and industrial personnel
Feedback from engineers and scientists in the academic and industrial community provided an assessment of the usage and perceived quality of NASA Langley generated STI and the familiarity and usage of selected NASA publications and services and identified ways to increase the accessibility of Langley STI. The questionnaire utilized both open and closed ended questions and was pretested for finalization. The questions were organized around the seven objectives for Phase IV. From a contact list of nearly 1,200 active industrial and academic researchers, approximately 600 addresses were verified. The 497 persons who agreed to participate were mailed questionnaires. The 381 completed questionnaires received by the cutoff date were analyzed. Based on the survey findings, recommendations were made for increasing the familiarity with and use of NASA and Langley STI and selected NASA publications and services. In addition, recommendations were made for increasing the accessibility of Langley STI.
Pinelli, T. E.↗
Recordings and Analysis of Atomic Ledge and Dislocation Movements in InGaAs to Nickelide Nanowire Phase Transformation
The formation of low resistance and self‐aligned contacts with thermally stable alloyed phases is a prerequisite for realizing reliable functionality in ultrascaled semiconductor transistors. Detailed structural analysis of the phase transformation accompanying contact alloying can facilitate contact engineering as transistor channels approach a few atoms across. Original in situ heating transmission electron microscopy studies are carried out to record and analyze the atomic scale dynamics of contact alloy formation between Ni and In 0.53 Ga 0.47 As nanowire channels. It is observed that the nickelide reacts on the In 0.53 Ga 0.47 As (111) || Ni 2 In 0.53 Ga 0.47 As (0001) interface with atomic ledge propagation along the Ni 2 In 0.53 Ga 0.47 As direction. Ledges nucleate as a train of strained single‐bilayers and propagate in‐plane as double‐bilayers that are associated with a misfit dislocation of . The atomic structure is reconstructed to explain this phase transformation that involves collective gliding of three Shockley partials in In 0.53 Ga 0.47 As lattice to cancel out shear stress and the formation of misfit dislocations to compensate the large lattice mismatch in the newly formed nickelide phase and the In 0.53 Ga 0.47 As layers. This work demonstrates the applicability of interfacial disconnection (ledge + dislocation) theory in a nanowire channel during thermally induced phase transformation that is typical in metal/III–V semiconductor reactions.
Chen, Renjie↗
SSME thrust chamber modeling with Navier Stokes equations
The capability of predicting two-dimensional, compressible and reacting flow in the combustion chamber and nozzle of the Space Shuttle Main Engine (SSME) is demonstrated. A nonorthogonal body fitted coordinate system has been used to represent the combustor and nozzle geometry. The Navier-Stokes equations are solved for the entire thrust chamber with the k-epsilon turbulence model accounting for compressibility and large pressure gradients effects. Results of the computational test cases reveal all expected features of the transonic nozzle flows including location of sonic line, internal shock and boundary layer build-up. Calculated performance parameters such as thrust, flow rate, and specific impulse are also in reasonble agreement with available data. The results show promising potential of solving full Navier-Stokes equations with heat transfer and two-phase combustion in truly comprehensive modeling of rocket engines.
Przekwas, A. J.↗
Total Temperature Measurements Using a Rearward Facing Probe in Supercooled Liquid Droplet and Ice Crystal Clouds
Engine Icing Performance loss: rollback, surge, flameout, and even internal engine damagePartial melting and refreeze of ice inside engine core (Mason et al., 2006). Ingestion of ice crystals and aggregates, mixed-phase droplets, or supercooled liquid dropletsNeed to better understand the conditions and properties that lead to engine icing.Simulation and analysis (physical and computational, and modeling)Test facilities (PSL, NRC, ...). Thermal and computational models and analysisProbesMultiple probes (aerothermal probes and ice cloud characterization probes and techniques). Total temperatureTraditional total temperature probes (vented forward facing)Heated total temperature probes (Goodyear). Rearward facing (developmental). Total temperature relevance. Thermal interaction between the icing cloud and air flow impinging particles contribute to kinetic heating effect (Gent et al., 2000). Measurement considerations Temperature sensor accuracy. Incomplete recovery of total temperature. Thermal surfaces (sources and sinks). Flow effects (viscous losses). Debris contamination, including icing and ice ingestion.
Agui, Juan H.↗
Initial beta-tin stress-strain calibration
This is a strength model calibration of the Preston-Tonks-Wallace (PTW) model of plastic deformation for extreme loading conditions using a multi-phase equation of state for tin, but for the nonce limited to the $\beta$ phase.
42 ENGINEERING↗
Analysis of Lunar Highland Regolith Samples from Apollo 16 Drive Core 64001/2 and Lunar Regolith Simulants - An Expanding Comparative Database
We present modal data from QEMSCAN(registered TradeMark) beam analysis of Apollo 16 samples from drive core 64001/2. The analyzed lunar samples are thin sections 64002,6019 (5.0-8.0 cm depth) and 64001,6031 (50.0-53.1 cm depth) and sieved grain mounts 64002,262 and 64001,374 from depths corresponding to the thin sections, respectively. We also analyzed lunar highland regolith simulants NU-LHT-1M, -2M, and OB-1, low-Ti mare simulants JSC-1, -lA, -1AF, and FJS-1, and high-Ti mare simulant MLS-1. The preliminary results comprise the beginning of an internally consistent database of lunar regolith and regolith simulant mineral and glass information. This database, combined with previous and concurrent studies on phase chemistry, bulk chemistry, and with data on particle shape and size distribution, will serve to guide lunar scientists and engineers in choosing simulants for their applications. These results are modal% by phase rather than by particle type, so they are not directly comparable to most previously published lunar data that report lithic fragments, monomineralic particles, agglutinates, etc. Of the highland simulants, 08-1 has an integrated modal composition closer than NU-LHT-1M to that of the 64001/2 samples, However, this and other studies show that NU-LHT-1M and -2M have minor and trace mineral (e.g., Fe-Ti oxides and phosphates) populations and mineral and glass chemistry closer to these lunar samples. The finest fractions (0-20 microns) in the sieved lunar samples are enriched in glass relative to the integrated compositions by approx.30% for 64002,262 and approx.15% for 64001,374. Plagioclase, pyroxene, and olivine are depleted in these finest fractions. This could be important to lunar dust mitigation efforts and astronaut health - none of the analyzed simulants show this trend. Contrary to previously reported modal analyses of monomineralic grains in lunar regolith, these area% modal analyses do not show a systematic increase in plagiociase/pyroxene as size fraction decreases.
Schrader, Christian M.↗
Matrix converter operating in current control mode using feed forward signals
A matrix converter system having a current control mode operation is provided. The system includes a matrix converter having a switching matrix. The matrix converter is coupled at its low-voltage side to a generator and at its output load side to a load. A controller having a pulse width modulation (PWM) control circuit is configured to control the matrix converter via its switching matrix to increase energy within the internal inductances of the generator when the switching matrix causes a short circuit. A feed forward calculator is configured to calculate a feed forward output phase angle. The feed forward output phase angle is an estimation of an angle between an output current vector and an output voltage vector that represent feedback signals of current and voltage output by the matrix converter. The angular position of the voltage output vector is adjusted as a function of the feed forward output phase angle to align angular position or phase angle of the voltage output vector that represents the voltage output with a selected angular position or phase angle.
42 ENGINEERING↗
Development of volume deposition on cast iron by additive manufacturing
ORNL partnered with Cummins to demonstrate the feasibility of using additive manufacturing techniques to help develop repair techniques for refurbished cast iron engine blocks. Cummins is interested in the refurbished engine business due to the increased cost savings and reduced emissions. It is expected that by refurbishing engines could help reduce the green house gas emissions by as much as 85%. Though such repair techniques are possible in principle there has been no major industry in the automotive sector that has deployed this technology. Therefore phase-1 would seek to evaluate the feasibility of using the laser directed energy deposition technique to repair cast iron engine blocks. The objective of the phase-1 would be to explore various strategies and understand the challenges involved. During phase-1 deposits were made using Inconel-718, Nickel, Nr-Cr-B braze filler. Inconel 718 builds showed significant cracking in the heat-affected zone in the cast iron. Nickel was used to reduce the cracking in the cast iron substrate, however the Ni builds did not wet the substrate sufficiently resulting in poor dimensional tolerance. In order to increase wetting the Ni was alloyed with the Ni-Cr-B braze to decrease the surface tension of Ni. This however resulted in significant cracks in the build due to shrinkage stresses associated with multiple thermal cycling. Hence to reduce the residual stresses in the builds the DMD-103D equipment was modified and the cast iron block was pre heated using cartridge heaters. Inconel-718 alloyed with Ni was deposited on the engine block. The pre-heated deposits showed a reduced susceptibility to cracking. If awarded the phase-2 of the project would aim to develop process parameters to achieve a crack free deposit engine block.
36 MATERIALS SCIENCE↗
Final Scientific / Technical Report: Enabling Technologies for Heavy-Duty Vehicles – Cummins 55BTE
The Cummins 55% BTE (55BTE) program has completed the planned technical work on the project. This work includes the planned engine system demonstration in pursuit of the goal of demonstrating a peak system brake thermal efficiency (BTE) of 55%. The engine system included a high efficiency diesel engine integrated with a state-of-the-art waste heat recovery (WHR) system and an advanced aftertreatment system capable of meeting the current emissions standards. While the ultimate program goal of 55% BTE was not fully achieved due to hardware issues during the final testing phase, the program demonstrated a significant increase in reported engine system BTE for a heavy duty sized engine. The previous demonstrations in the Department of Energy funded SuperTruck 1 programs ranged between 50% - 51% BTE. The Cummins 55% BTE program demonstrated 54% BTE. Additionally, the program established a revised path-to-target showing how the system could be improved to reach the ultimate program goal of 55% BTE with some minor modification to the engine system. The changes in the revised path-to-target were unable to be completed during the course of this program due to time and money constraints placed on the program. The program’s goals were challenging in both scope and timing. Although the program’s goal can be simply stated in terms of demonstrating a system efficiency of 55%, the achievement of a heavy-duty diesel engine capable of full torque curve operation, adequate transient performance, low emissions and high brake thermal efficiency (>51% BTE) had not been previously demonstrated in a heavy-duty engine. The closest efforts to date included the SuperTruck 1 programs referenced earlier. The program made several advancements in all system areas. The combustion system was re-designed for a shorter combustion duration and lower in-cylinder heat loss. This was achieved through optimization of the fuel injection rate shape, number of spray holes, piston bowl shape, compression ratio, piston oil cooling, heat flow through the piston and in-cylinder charge motion. The air handling system was re-designed to provide cooled EGR at virtually no pumping penalty. This was achieved through implementation of a dual loop EGR system, reduction of EGR system pressure drop, and implementation of advanced turbocharger efficiency technologies. The engine friction and parasitic signature was dramatically reduced by the program through adoption of variable flow pumps, advanced rings and coatings, rollerized valvetrain, adoption of low viscosity lubricants and reduction in cylinder line bore distortion. The aftertreatment system was optimized through use of low dP substrates and an ammonia gas injection system. The WHR system development included the use of a dual-entry turbine and a mixed charger cooler. Finding and implementing these solutions in a short two-year program at the budgeted funding provided the greatest challenge for the program.
33 ADVANCED PROPULSION SYSTEMS↗
Novel Temperature Sensors and Wireless Telemetry for Active Condition Monitoring of Advanced Gas Turbines
The objective of the program is to develop and engine test hardware and software technologies that will enable active condition monitoring to be implemented on hot gas path turbine blades in large industrial gas turbines. The specific objectives are (1) to fabricate and install Smart Turbine Blades with thermally sprayed sensors and high temperature wireless telemetry systems in a gas turbine engine, (2) to integrate the component engine test data with remaining useful life (RUL) models and develop an approach for networking the component RUL data with Siemens' Power Diagnostics® engine monitoring system. These significant advances carried out in Phase 1 in temperature wide bandgap telemetry, along with new induced power driver and receiver geometry combined with an innovative approach to transmit digital data wirelessly will enable the opportunity to proceed with more technical innovation. The Phase 2 program focused on validation testing of sensor-wireless telemetry package in spin rig and advanced operation-based assessment (OBA) model utilizing artificial intelligence. Significant efforts were dedicated on the download of the technology onto components to be tested an actual gas turbine engine for full realization of active condition monitoring for Smart Turbine Blades.
03 NATURAL GAS↗
Untapped Benefits of Porous Liquids for Gas Capture: Low-Energy Regeneration
Current liquid-phase gas capture materials incur high operational costs due to energy-intensive regeneration processes, creating an industrial need for alternative materials that retain engineering benefits while reducing energy requirements. Porous liquids (PLs), liquid-phase materials with permanent internal porosity, have emerged as promising replacements with excellent gas absorption capacity and selectivity. Despite these benefits, evaluation of regeneration in PLs remains rare. In this Perspective, we evaluate the effects of solvent interactions, mass transport, and binding site formation that control PL regeneration. While conventional regeneration methods exist in PLs, the diversity of PL compositions allows for novel regeneration processes including light irradiation via use of photosensitive azobenzene-based cages, isostatic compression to collapse internal pore structures, and localized heating via sonication for gas desorption. In conclusion, the wide variability in porous host materials that generate the internal porosity in PLs facilitates innovative low-energy regeneration pathways, positioning them as a transformative solution in separation technologies.
gas capture↗
James Webb Space Telescope Ka-Band Trade
In August 2003 James Webb Space Telescope (JWST) had its Initial Review Confirmation Assessment Briefing with NASA HQ management. This is a major milestone as the project was approved to proceed from Phase A to B, and NASA will commit funds for the project towards meeting its science goals from the Earth-Sun s Lagrange 2 (L2) environment. At this briefing, the Project was asked, "to take another look" into using, the JPL s Deep Space Network (DSN) as the provider of ground stations and evaluate other ground station options. The current operations concept assumes S-band and X-band communications with a daily &hour contact using the DSN with the goal of transmitting over 250 Gigabit (Gb) of data to the ground. The Project has initiated a trade study to look at this activity, and we would like to share the result of the trade in the conference. Early concept trades tends to focus on the "normal" operation mode of supporting telemetry (science and engineering), command and radio metrics. Entering the design phase, we find that we have the unique ranging requirement for our L2 orbit using alternating ground stations located in different hemispheres. The trade must also address emergency operations (which are covered when using the DSN). This paper describes the issues confronting this Project and how the DSN and the JWST Project are working together to find an optimized approach for meeting these issues. We believe this trade is of major interest for future Code S and other L2 missions in that JWST will set the standard.
Gal-Edd, Jonathan↗
Ferroelectric switching pathways and domain structure of SrBi 2 (Ta,Nb) 2 O 9 from first principles
Several families of layered perovskite oxide ferroelectrics exhibit a coupling between polarization and structural order parameters, such as octahedral rotation distortions. This coupling provides opportunities for novel electric field-based manipulation of material properties, and it also stabilizes complex domain patterns and domain-wall vortices. Among layered perovskites with such coupled orders, the Aurivillius-phase oxides SrBi 2 B 2 O 9 (B = Ta,Nb) are well-known for their excellent room-temperature ferroelectric performance. This work combines group theoretic analysis with density functional theory calculations to examine the ferroelectric switching processes of SrBi2B2O9. Low-energy two-step ferroelectric switching paths are identified, with polarization reversal facilitated by structural order-parameter rotations. Analysis of the domain structure reveals how the relative energetics of the coupled order parameters translates into a network of several distinct domain-wall types linked by domain-wall vortex structures. Comparisons are made between the ferroelectric switching and domain structure of SrBi 2 B 2 O 9 and those of the layered n = 2 Ruddlesden-Popper hybrid improper ferroelectrics. The results provide insight into how ferroelectric properties may be optimized by engineering the complex crystal structures of Aurivillius-phase oxides.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
HBU R and D Cask Transportation Options - 20436
The TN-32B HBU Demonstration Cask was successfully loaded in November 2017 with 32 high burnup (HBU) fuel assemblies at Dominion's North Anna Nuclear Plant and is collecting thermal data as intended. The first two phases of this very successful project sponsored by DOE and EPRI was designed to collect thermal data of HBU fuel to support extended storage. The next phase of the project requires the cask be licensed for transportation so the cask can be relocated to a site (to be determined by DOE) to facilitate long term monitoring and additional research on the fuel. This is a unique challenge given the constraints that exist for this particular bolted metal cask. The TN-32B cask is a 234,288 lb. (storage configuration) dry storage system that was selected for this project and it was modified to provide thermal data and the ability to collect gas samples after loading. Several major issues must be addressed to obtain the transport license including protecting the seven lid penetrations that were made to allow for the insertion of the thermocouples into the selected fuel assemblies after the cask was loaded. In order to protect the integrity of the research, the payload must remain as is. Therefore, the cask system must be placed into the transportation configuration without rewetting the fuel, replacing the lid and without removing the thermocouple instrumentation that is currently installed. A critical portion of the design and engineering that was performed in the first two phases of the project was to ensure that future transportation of the cask was integrated into the approach. Efforts were made to accommodate requirements such as containment boundary leakage testing, installation of impact limiter brackets and lid bolts suitable for transportation. Due to the science requirements of the project, the fuel selected was intended to yield the highest payload temperatures permitted to provide the greatest value for the researchers. This resulted in higher than usual external dose rates and surface temperatures that warranted performing as much preparatory work prior to cask loading to ensure ALARA and personnel safety to the greatest extent practical rather than working on a loaded cask. In addition to the work performed prior to cask load, there are remaining challenges such as protecting the modified lid, design and fabrication of impact limiters that accommodate the modified cask lid and preserving the thermocouple connections for continued monitoring. The project team is currently performing the necessary calculations, engineering, and design to support the licensing as required by the US NRC. Pre-application meetings have been held to inform the regulator of the planned technical approach to ensure compliance with the applicable regulations. The current plan is to obtain the transportation C of C by the end of 2021. (authors)
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗