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At least 1,333 records · Page 74

Vaterite Optical Petrography in Lake Sturgeon Otoliths

Vaterite occurring in fish otoliths exhibits plumose and spherulitic habits, the latter being like those grown from aqueous solutions. Vaterite spherulites are known to have sheaf-like texture and can be up to 100 μm in size. In thin section, the spherulites typically show uniaxial positive interference figures between cross-polarizers using a polarizing light microscope but without conoscopic or Bertrand lenses because the spherulites mimic the effect of these lenses. Plumose vaterite can show both uniaxial (+) and biaxial (+) interference figures with a small 2V, which suggests that crystal structural models for vaterite should have the plane of the carbonate group parallel to the optic axis or acute bisectrix. Finally, vaterite spherulites grown from aqueous solution exhibit similar structure and growth habits.

58 GEOSCIENCES↗

A Search for Technosignatures from 14 Planetary Systems in the Kepler Field with the Green Bank Telescope at 1.15–1.73 GHz

Analysis of Kepler mission data suggests that the Milky Way includes billions of Earth-sized planets in the habitable zone of their host stars. Current technology enables the detection of technosignatures emitted from a large fraction of the Galaxy. We describe a search for technosignatures that is sensitive to Arecibo-class transmitters located within ∼420 ly of Earth and transmitters that are 1000 times more effective than Arecibo within ∼13000 ly of Earth. Our observations focused on 14 planetary systems in the Kepler field and used the L-band receiver (1.15–1.73 GHz) of the 100 m diameter Green Bank Telescope. Each source was observed for a total integration time of 5 minutes. We obtained power spectra at a frequency resolution of 3 Hz and examined narrowband signals with Doppler drift rates between ±9 Hz s{sup −1}. We flagged any detection with a signal-to-noise ratio in excess of 10 as a candidate signal and identified approximately 850,000 candidates. Most (99%) of these candidate signals were automatically classified as human-generated radio-frequency interference (RFI). A large fraction (>99%) of the remaining candidate signals were also flagged as anthropogenic RFI because they have frequencies that overlap those used by global navigation satellite systems, satellite downlinks, or other interferers detected in heavily polluted regions of the spectrum. All 19 remaining candidate signals were scrutinized and none were attributable to an extraterrestrial source.

79 ASTRONOMY AND ASTROPHYSICS↗

K2-79b and K2-222b: Mass Measurements of Two Small Exoplanets with Periods beyond 10 days that Overlap with Periodic Magnetic Activity Signals

We present mass and radius measurements of K2-79b and K2-222b, two transiting exoplanets orbiting active G-type stars observed with HARPS-N and K2. Their respective 10.99 day and 15.39 day orbital periods fall near periods of signals induced by stellar magnetic activity. The two signals might therefore interfere and lead to an inaccurate estimate of exoplanet mass. We present a method to mitigate these effects when radial velocity (RV) and activityindicator observations are available over multiple observing seasons and the orbital period of the exoplanet is known. We perform correlation and periodogram analyses on subsets composed of each target's two observing seasons, in addition to the full data sets. For both targets, these analyses reveal an optimal season with little to no interference at the orbital period of the known exoplanet. We make a confident mass detection of each exoplanet by confirming agreement between fits to the full RV set and the optimal season. For K2-79b, we measure a mass of 11.8 ± 3.6 M ⊕ and a radius of 4.09 ± 0.17 R ⊕ . For K2-222b, we measure a mass of 8.0 ± 1.8 M ⊕ and a radius of 2.35 ± 0.08 R ⊕ . According to model predictions, K2-79b is a highly irradiated Uranus analog and K2-222b hosts significant amounts of water ice. We also present a RV solution for a candidate second companion orbiting K2-222 at 147.5 days.

79 ASTRONOMY AND ASTROPHYSICS↗

General Model for Light Curves of Chromospherically Active Binary Stars

The starspots on the surface of many chromospherically active binary stars concentrate on long-lived active longitudes separated by 180°. Shifts in activity between these two longitudes, the “flip-flop” events, have been observed in single stars like FK Comae and binary stars like σ Geminorum. Recently, interferometry has revealed that ellipticity may at least partly explain the flip-flop events in σ Geminorum. This idea was supported by the double-peaked shape of the long-term mean light curve of this star. Here we show that the long-term mean light curves of 14 chromospherically active binaries follow a general model that explains the connection between orbital motion, changes in starspot distribution, ellipticity, and flip-flop events. Surface differential rotation is probably weak in these stars, because the interference of two constant period waves may explain the observed light curve changes. These two constant periods are the active longitude period (P{sub act}) and the orbital period (P{sub orb}). We also show how to apply the same model to single stars, where only the value of P {sub act} is known. Finally, we present a tentative interference hypothesis about the origin of magnetic fields in all spectral types of stars.

79 ASTRONOMY AND ASTROPHYSICS↗

Performance of DSRC V2V Communication Networks in an Autonomous Semi-Truck Platoon Application

Autonomy for multiple trucks to drive in a fixedheadway platoon formation is achieved by adding precision GPS and V2V communications to a conventional adaptive cruise control (ACC) system. The performance of the Cooperative ACC (CACC) system depends heavily on the reliability of the underlying V2V communications network. Using data recorded on precision-instrumented trucks at both ACM and NCAT test tracks, we provide an understanding of various effects on V2V network performance: Occlusions - non-line-of-sight (NLOS) between the Tx and Rx antenna may cause network signal loss. Rain - water droplets in the air may cause network signal degradation. Antenna position - antennas at higher elevation may have less ground clutter to deal with. RF interference - interference may cause network packet loss. GPS outage - outages caused by tree cover, tunnels, etc. may result in degraded performance. Road curvature - curves may affect antenna diversity. Road grade - antenna may have limited vertical coverage. Our results, which include multiple plots and graphs and their analysis, build on those reported by others and could be of interest to researchers, practitioners, and end-users in the broader autonomous-connected vehicle community.

V2V communications, GPS, truck platoon, semi-auton↗

Retrospective on Recent DOE-Funded Studies Concerning the Extraction of Rare Earth Elements & Lithium from Geothermal Brines (Final Report)

Rare earth elements (REE) and lithium are non-toxic metals that are considered critical materials due to their use in electronics, magnets, batteries, and a wide variety of industrial processes important for the economy and military preparedness. Demand for REE and lithium is increasing and these critical materials are imported, so identifying and exploiting domestic sources of REE and lithium is a national priority. The U.S. Department of Energy (DOE) Geothermal Technologies Office (GTO) has been in the forefront of sponsoring research investigating the potential recovery of REE, lithium, and other critical minerals from geothermal brines. It has been proposed that the future of geothermal energy should include “hybrid systems” that combine electricity generation with other revenue-generating activities, such as recovery of valuable and critical minerals, including REE and lithium. Two recent GTO funding opportunities have focused on the recovery of REE and other valuable minerals from geothermal brines. The research supported by the GTO’s mineral recovery program is focused on three areas: resource characterization, technology for the extraction of REE, and technology for the extraction of lithium (Tables 1 and 2). This report is a retrospective study examining the outcome of GTO’s two recent mineral recovery programs (DE-FOA-0001016 in FY 2014 and DE-FOA-0001376 in FY 2016). In this report, the knowledge, technology, and techniques that were developed by researchers funded by GTO are summarized and discussed. Four projects were funded to assess the concentrations and amounts of REE found in geothermal brines and oil field produced waters. The GTO-funded studies compiled publically available data on REE concentrations from brines and produced water from all over the USA. In addition, new samples were collected and characterized from major geothermal and hydrocarbon basins in the Western USA. The studies examined the relationship between lithology and REE concentrations and developed models examining the influence of geology on REE concentrations in produced brines. It was determined that REE are frequently found at higher concentrations in oil field produced water than geothermal brines, but that some geothermal areas had significant REE resources. Significant reservoirs of REE were identified in the Western USA. In some cases, concentrations of REE were more than 1000 times the concentrations found in seawater. Collectively, these studies represent a comprehensive picture of REE resources associated with geothermal and hydrocarbon systems in the USA. The studies did not examine lithium resources, but in some cases, lithium concentration data was collected. Data from these studies are housed in the Geothermal Data Repository (GDR) and represent a significant information resource and it is recommended that these data be further analyzed in a future study. Eight projects were funded to develop new technology for REE extraction from geothermal fluids. These projects investigated sorption as an approach for removal and recovery of REE from geothermal brines. The projects investigated cutting-edge technology for selective sorption of ions from complex solutions, including the application of metal-organic frameworks and biosorbent proteins. The REE sorption studies tested different combinations of metal-binding ligands and solid supports. The most promising metal-binding ligands for REE included phosphonic acid, thiol, and carboxylic acid functional groups. Ligands were attached or incorporated into a wide variety of solid supports. In most cases, attachment was via covalent bonding to organic resins, polymers, or silica-based supports. Most of the REE projects were conducted at a low technology readiness level (TRL) and showed promise, but direct comparison between technologies was not possible based on the available information. It is recommended that testing and reporting be standardized to the extent possible to facilitate comparisons between technologies. Two projects were directed at novel lithium extraction technology. Both projects investigated the use of inorganic sorbents, including manganese oxides. One study also examined the use of metal- ion imprinted polymers as selective ion-exchange resins for the separation of lithium and manganese from brines. Both approaches showed promise for the selective extraction of lithium from brines, including potentially geothermal brines. Results from these GTO studies indicated that selective REE and lithium extraction is possible, but interference from co-occurring solutes, such as calcium, magnesium, or heavy metals, will interfere with process efficiency and negatively impact process economics. Techno-economic analysis conducted as part of the resource and technology studies suggest extraction of REE from geothermal brines is unlikely to be economically viable, especially since non-geothermal produced waters frequently have higher REE concentrations. It is recommended that benchmarks for techno-economic analysis be established to the extent possible for future studies, to facilitate direct comparison of various technologies. Based on the collective results of this program, it appears that hybrid geothermal power would benefit more from recovery of lithium and other metals, rather than REE. It is recommended that future studies be conducted at a higher- TRL and that sorbents be tested against actual geothermal fluid samples. Prior higher-TRL efforts to extract metals from geothermal brines should be further evaluated for lessons learned.

36 MATERIALS SCIENCE↗

Synchrotron FTIR imaging of OH in quartz mylonites

Previous measurements of water in deformed quartzites using conventional Fourier transform infrared spectroscopy (FTIR) instruments have shown that water contents of larger grains vary from one grain to another. However, the non-equilibrium variations in water content between neighboring grains and within quartz grains cannot be interrogated further without greater measurement resolution, nor can water contents be measured in finely recrystallized grains without including absorption bands due to fluid inclusions, films, and secondary minerals at grain boundaries. Synchrotron infrared (IR) radiation coupled to a FTIR spectrometer has allowed us to distinguish and measure OH bands due to fluid inclusions, hydrogen point defects, and secondary hydrous mineral inclusions through an aperture of 10 µm for specimens > 40 µm thick. Doubly polished infrared (IR) plates can be prepared with thicknesses down to 4–8 µm, but measurement of small OH bands is currently limited by strong interference fringes for samples < 25 µm thick, precluding measurements of water within individual, finely recrystallized grains. By translating specimens under the 10 µm IR beam by steps of 10 to 50 µm, using a software-controlled x - y stage, spectra have been collected over specimen areas of nearly 4.5 mm 2 . This technique allowed us to separate and quantify broad OH bands due to fluid inclusions in quartz and OH bands due to micas and map their distributions in quartzites from the Moine Thrust (Scotland) and Main Central Thrust (Himalayas). Mylonitic quartzites deformed under greenschist facies conditions in the footwall to the Moine Thrust (MT) exhibit a large and variable 3400 cm -1 OH absorption band due to molecular water, and maps of water content corresponding to fluid inclusions show that inclusion densities correlate with deformation and recrystallization microstructures. Quartz grains of mylonitic orthogneisses and paragneisses deformed under amphibolite conditions in the hanging wall to the Main Central Thrust (MCT) exhibit smaller broad OH bands, and spectra are dominated by sharp bands at 3595 to 3379 cm -1 due to hydrogen point defects that appear to have uniform, equilibrium concentrations in the driest samples. The broad OH band at 3400 cm -1 in these rocks is much less common. The variable water concentrations of MT quartzites and lack of detectable water in highly sheared MCT mylonites challenge our understanding of quartz rheology. However, where water absorption bands can be detected and compared with deformation microstructures, OH concentration maps provide information on the histories of deformation and recovery, evidence for the introduction and loss of fluid inclusions, and water weakening processes.

36 MATERIALS SCIENCE↗

MELK is not necessary for the proliferation of basal-like breast cancer cells

Thorough preclinical target validation is essential for the success of drug discovery efforts. In this study, we combined chemical and genetic perturbants, including the development of a novel selective maternal embryonic leucine zipper kinase (MELK) inhibitor HTH-01-091, CRISPR/Cas9-mediated MELK knockout, a novel chemical-induced protein degradation strategy, RNA interference and CRISPR interference to validate MELK as a therapeutic target in basal-like breast cancers (BBC). In common culture conditions, we found that small molecule inhibition, genetic deletion, or acute depletion of MELK did not significantly affect cellular growth. This discrepancy to previous findings illuminated selectivity issues of the widely used MELK inhibitor OTSSP167, and potential off-target effects of MELK-targeting short hairpins. The different genetic and chemical tools developed here allow for the identification and validation of any causal roles MELK may play in cancer biology, which will be required to guide future MELK drug discovery efforts. Furthermore, our study provides a general framework for preclinical target validation.

Huang, Hai-Tsang↗

Two-Color Ultrafast Photoexcited Scanning Tunneling Microscopy

We report on two-color two-photon photoexcitation of a metal surface driven by ultrafast laser pulses and detected with a scanning tunneling microscope (STM) tip as a proximate anode. Results are presented for two cases: (i) where the tip is retracted from the surface far enough to prohibit tunneling, and (ii) where the tip is within tunneling range of the surface. A delay-modulation technique is implemented to isolate the two-color photoemission from concurrent one-color two-photon photoemission and provide subpicosecond time-resolved detection. When applied with the tip in tunneling range, this approach effectively isolates the two-photon photoexcited current signal from the conventional tunneling current and enables subpicosecond time-resolved detection of the photoexcited surface electrons. The advantage of the two-color approach is highlighted by comparison with the one-color case where optical interference causes thermal modulation of the STM tip length, resulting in tunneling current modulations that are orders of magnitude larger than the current due to photoexcitation of surface electrons. By completely eliminating this interference, and thereby avoiding thermal modulation of the STM tip length, the two-color approach represents an important step toward the ultimate goal of simultaneous subnanometer and subpicosecond measurements of surface electron dynamics by ultrafast-laser-excited STM.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Detector Noise Susceptibility Issues for the Future Generation of High Energy Physics Experiments

The front-end electronics (FEE) noise characterization to electromagnetic interference and the compatibility of the different subsystems are important topics to consider for the LHC calorimeter upgrades. A new power distribution scheme based on switching power converters is under study and will define a noticeable noise source very close to the detector's FEE. Knowledge and experience with both FFE noise and electromagnetic compatibility (EMC) issues from previous detectors are important conditions to guarantee the design goals and the good functionality of the upgraded LHC detectors. This paper shows an overview of the noise susceptibility studies performed in different CMS subdetectors. The impact of different FEE topologies in the final sensitivity to electromagnetic interference of the subsystem is analyzed and design recommendations are presented to increase the EMC of the detectors to the future challenging power distribution topologies.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

D_S Dalitz Plot Analysis From the B-Factories

The resonant sub-structure of three-body charm meson decays can be effectively studied with Dalitz plot analyses. By using coherent sums of amplitudes, interference between different intermediate states can be described. Such interference effects can yield information on states, such as the scalar resonances, that is difficult to obtain in other ways. In this summary, we report on BABAR collaboration Dalitz plot analyses of two modes: D{sub s}{sup +} {yields} K{sup +}K{sup -}{pi}{sup +} and D{sub s}{sup +} {yields} {pi}{sup +}{pi}{sup -}{pi}{sup +}.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Ultrafast laser based coherent control methods for explosives detection

The detection of explosives is a notoriously difficult problem, especially at stand-off, due to their (generally) low vapor pressure, environmental and matrix interferences, and packaging. We are exploring Optimal Dynamic Detection of Explosives (ODD-Ex), which exploits the best capabilities of recent advances in laser technology and recent discoveries in optimal shaping of laser pulses for control of molecular processes to significantly enhance the standoff detection of explosives. The core of the ODD-Ex technique is the introduction of optimally shaped laser pulses to simultaneously enhance sensitivity to explosives signatures while dramatically improving specificity, particularly against matrix materials and background interferences. These goals are being addressed by operating in an optimal non-linear fashion, typically with a single shaped laser pulse inherently containing within it coherently locked control and probe subpulses. Recent results will be presented.

47 OTHER INSTRUMENTATION↗

Optimization of the Coherent Intensity from Multi-Segment Undulators by Phase Matching

The use of inline insertion devices at third-generation synchrotron radiation sources can result in destructive interference effects if the relative phase between the devices is not properly adjusted. The destructive interference can strongly affect the emission spectrum and coherent wavefront of a compound insertion device. We simulate the photon source generated by a dual-inline elliptically polarizing undulator (EPU) situated in a low-{beta} straight section of the planned NSLS-II storage ring and show that a magnetic chicane with adjustable field integral can be used to phase-match the devices. Furthermore, we show that the maximum coherent intensity is delivered by a focusing x-ray beamline if the chicane is adjusted to phase-match the off-axis and red-shifted radiation. Such a system will be installed at the coherent soft x-ray (CSX) beamline of the NSLS-II in order to provide the highest possible coherent flux for coherent soft x-ray scattering experiments.

36 MATERIALS SCIENCE↗

Electrochemically Modulated Separation for Plutonium Safeguards

Accurate and timely analysis of plutonium in spent nuclear fuel is critical in nuclear safeguards for detection of both protracted and rapid plutonium diversions. Gamma spectroscopy is a viable method for accurate and timely measurements of plutonium provided that the plutonium is well separated from the interfering fission and activation products present in spent nuclear fuel. Electrochemically modulated separation (EMS) is a method that has been used successfully to isolate picogram amounts of Pu from nitric acid matrices. With EMS, Pu adsorption may be turned "on" and "off" depending on the applied voltage, allowing for collection and stripping of Pu without the addition of chemical reagents. In this work, we have scaled up the EMS process to isolate microgram quantities of Pu from matrices encountered in spent nuclear fuel during reprocessing. Several challenges have been addressed including surface area limitations, radiolysis effects, electrochemical cell performance stability, and chemical interferences. After these challenges were resolved, 6 µg Pu was deposited in the electrochemical cell with approximately an 800-fold reduction of fission and activation product levels from a spent nuclear fuel sample. Modeling showed that these levels of Pu collection and interference reduction may not be sufficient for Pu detection by gamma spectroscopy. The main remaining challenges are to achieve a more complete Pu isolation and to deposit larger quantities of Pu for successful gamma analysis of Pu. If gamma analyses of Pu are successful, EMS will allow for accurate and timely on-site analysis for enhanced Pu safeguards.

Pratt, Sandra H.↗

Optical phased arrays with evanescently-coupled antennas

An optical phased array formed of a large number of nanophotonic antenna elements can be used to project complex images into the far field. These nanophotonic phased arrays, including the nanophotonic antenna elements and waveguides, can be formed on a single chip of silicon using complementary metal-oxide-semiconductor (CMOS) processes. Directional couplers evanescently couple light from the waveguides to the nanophotonic antenna elements, which emit the light as beams with phases and amplitudes selected so that the emitted beams interfere in the far field to produce the desired pattern. In some cases, each antenna in the phased array may be optically coupled to a corresponding variable delay line, such as a thermo-optically tuned waveguide or a liquid-filled cell, which can be used to vary the phase of the antenna's output (and the resulting far-field interference pattern).

42 ENGINEERING↗

The Potosi Reservoir Model 2013

As a part of a larger project co-funded by the United States Department of Energy (US DOE) to evaluate the potential of formations within the Cambro-Ordovician strata above the Mt. Simon as potential targets for carbon sequestration in the Illinois and Michigan Basins, the Illinois Clean Coal Institute (ICCI) requested Schlumberger to evaluate the potential injectivity and carbon dioxide (CO2) plume size of the Cambrian Potosi Formation. The evaluation of this formation was accomplished using wireline data, core data, pressure data, and seismic data from the US DOE-funded Illinois Basin–Decatur Project (IBDP) being conducted by the Midwest Geological Sequestration Consortium in Macon County, Illinois. In 2010, technical performance evaluations on the Cambrian Potosi Formation were performed through reservoir modeling. The data included formation tops from mud logs, well logs from the VW1 and the CCS1 wells, structural and stratigraphic formation from three dimensional (3D) seismic data, and field data from several waste water injection wells for Potosi Formation. Intention was for two million tons per annum (MTPA) of CO2 to be injected for 20 years. In the preceding, the 2010 Potosi heterogeneous model (referred to as the "Potosi Dynamic Model 2010" in this topical report) was re-run using a new injection scenario; 3.2 MTPA for 30 years. The extent of the Potosi Dynamic Model 2010, however, appeared too small for the new injection target. It was not sufficiently large enough to accommodate the evolution of the plume. The new model, Potosi Dynamic Model 2013a, was built by extending the Potosi Dynamic Model 2010 grid to 30 miles x 30 miles (48.3km x48.3km), while preserving all property modeling workflows and layering. This model was retained as the base case of Potosi Dynamic Model 2013a. The Potosi reservoir model was updated to take into account the new data from the verification well VW2 which was drilled in 2012. The new porosity and permeability modeling was performed to take into account the log data from the new well. Revisions of the 2010 modeling assumptions were also done on relative permeability, capillary pressures, formation water salinity, and the maximum allowable well bottomhole pressure. Dynamic simulations were run using the injection target of 3.2 MTPA for 30 years. This new dynamic model was named Potosi Dynamic Model 2013b. Due to the major uncertainties on the vugs permeability, two models were built; the Pessimistic and Optimistic Cases. The Optimistic Case assumes vugs permeability of 9,000 mD, which is analog to the vugs permeability identified in the pressure fall off test of a waste water injector in the Tuscola site, approx. 40 miles (64.4km) away from the IBDP area. The Pessimistic Case assumes that the vugs permeability is equal to the log data, which does not take into account the permeability from secondary porosity. The probability of such case is deemed low and could be treated as the worst case scenario, since the contribution of secondary porosity to the permeability is neglected and the loss circulation events might correspond to a much higher permeability. It is considered important, however, to identify the range of possible reservoir performance since there are no rigorous data available for the vugs permeability. The Optimistic Case gives an average CO2 injection rate of 0.8 MTPA and cumulative injection of 26 MT in 30 years, which corresponds to 27% of the injection target. The injection rate is approx. 3.2 MTPA in the first year as the well is injecting into the surrounding vugs, and declines rapidly to 0.8 MTPA in year 4 once the surrounding vugs are full and the CO2 start to reach the matrix. This implies that according to this preliminary model, a minimum of four (4) wells could be required to achieve the injection target. This result is lower than the injectivity estimated in the Potosi Dynamic Model 2013a (43 MT in 30 years), since the permeability model applied in the Potosi Dynamic Model 2013b is more conservative. This revision was deemed necessary to treat the uncertainty in a more appropriate manner. As the CO2 follows the paths where vugs interconnection exists, a reasonably large and irregular plume extent was created. For the Optimistic Case, the plume extends 17 miles (27.4km) in E-W and 14 miles (22.5km) in N-S directions after 30 years. After injection is completed, the plume continues to migrate laterally, mainly driven by the remaining pressure gradient. After 100 years post injection, the plume extends 20 miles (32.2km) in E-W and 15.5 miles (24.9km) in N-S directions. Should the targeted cumulative injection of 96 MT be achieved; a much larger plume extent could be expected. For the Optimistic Case, the increase of reservoir pressure at the end of injection is approximately 1200 psia (8,274 kPa) around the injector and gradually decreases away from the well. The reservoir pressure increase is less than 30 psia (206.8 kPa) beyond 14 miles (22.5km) away from injector. Should the targeted cumulative injection of 96 MT be achieved; a much larger areal pressure increase could be expected. The initial reservoir pressure is nearly restored after approximately 100 years post injection. The presence of matrix slows down the pressure dissipations. The Pessimistic Case gives an average CO2 injection rate of 0.2 MTPA and cumulative injection of 7 MT in 30 years, which corresponds to 7% of the injection target. This implies that in the worst case scenario, a minimum of sixteen (16) wells could be required to achieve the injection target. The present evaluation is mainly associated with uncertainty on the vugs permeability, distribution, and interconnectivity. The different results indicated by the Optimistic and Pessimistic Cases signify the importance of vugs permeability characterization. Therefore, injection test and pressure interference test among the wells could be considered to evaluate the local vugs permeability, extent, and interconnectivity. Porosity mapping derived from the seismic inversion could also be used in the succeeding task to characterize the lateral porosity distribution within the reservoir. With or without seismic inversion porosity mapping, it is worth exploring whether increased lateral heterogeneity plays a significant role in Potosi injectivity. Investigations on vugular, dolomitic outcrops suggest that there may be significantly greater lateral heterogeneity than what has been modeled here. Facies modeling within the Potosi has yet to be thoroughly addressed. The carbonates during the time of deposition are believed to be regionally extensive. However, it may be worth delineating the reservoir with other regional wells or modern day analogues to understand the extent of the Potosi. More specifically, the model could incorporate lateral changes or trends if deemed necessary to represent facies transition. Data acquisitions to characterize the fracture pressure gradient, the formation water properties, the relative permeability, and the capillary pressure could also be considered in order to allow a more rigorous evaluation of the Potosi storage performance. A simulation using several injectors could also be considered to determine the required number of wells to achieve the injection target while taking into account the pressure interference.

Adushita, Yasmin↗

Potosi Reservoir Modeling; History and Recommendations

As a part of a larger project co-funded by the United States Department of Energy (US DOE) to evaluate the potential of formations within the Cambro-Ordovician strata above the Mt. Simon as potential targets for carbon sequestration in the Illinois and Michigan Basins, the Illinois Clean Coal Institute (ICCI) requested Schlumberger to evaluate the potential injectivity and carbon dioxide (CO₂) plume size of the Cambrian Potosi Formation. The evaluation of this formation was accomplished using wireline data, core data, pressure data, and seismic data from two projects: the US DOE-funded Illinois Basin–Decatur Project being conducted by the Midwest Geological Sequestration Consortium in Macon County, Illinois, as well as data from the Illinois – Industrial Carbon Capture and Sequestration (IL-ICCS) project funded through the American Recovery and Reinvestment Act. In 2010, technical performance evaluations on the Cambrian Potosi Formation were performed through reservoir modeling. The data included formation tops from mud logs, well logs from the Verification Well 1 (VW1) and the Injection Well (CCS1), structural and stratigraphic formation from three dimensional (3D) seismic data, and field data from several waste water injection wells for the Potosi Formation. The intention was for two million tonnes per annum (MTPA) of CO₂ to be injected for 20 years into the Potosi Formation. In 2013, updated reservoir models for the Cambrian Potosi Formation were evaluated. The data included formation tops from mud logs, well logs from the CCS1, VW1, and Verification Well 2 (VW2) wells, structural and stratigraphic formation from a larger 3D seismic survey, and field data from several waste water injection wells for Potosi Formation. The objective is to simulate the injection of CO₂ at a rate 3.5 million tons per annum (3.2 million tonnes per annum [MTPA]) for 30 years 106 million tons (96 MT total) into the Potosi Formation. The Potosi geomodeling efforts have evolved from using data from a single well in 2010 to the inclusion of data from three wells in 2013 which largely leverage the porosity and permeability logs plus knowledge of lost circulation zones. The first Potosi model (Potosi Geobody Model 2010) attempted to use the available seismic inversion data to inform the geomodel and predict vugular zones in advance of drilling VW1. Lost circulation zones in VW1 came in as the geologists predicted. The model was not implemented in subsequent simulation work. To date, reservoir models used for flow simulation work have relied predominately on Gaussian distributed properties (porosity and permeability) and have employed a single injection well. Potosi Model 2013b incorporated the new VW2 logs, and exhibited an extra level of sophistication by delineating the vugular intervals. This method added further realism that likely represents the best reservoir approximation to date. Where the 2010 reservoir models were 10 by 10 mi (16 by 16 km) in area, the 2013 models were expanded in size to 30 by 30 mi (48 by 48 km). The latest reservoir simulations show that a minimum of four injectors might be required to meet target injection rates. Still, there is data that requires further scrutiny and modeling methodologies that require testing for the Potosi Formation. This work is currently ongoing, and the next phase of the reservoir modeling intends to implement valuable data like porosity derived from seismic inversion, seismically derived geobodies, or a combination of both to further define vugular zones and the porosity distribution within the Potosi Formation. Understanding the dual porosity, dual permeability character of the Potosi remains the greatest challenge in representing this formation. Further analysis of the FMI* fullbore formation microimager data may aid in assessing this uncertainty. The Potosi Formation is indeed an interesting formation, and recommendations to further characterize it are included in the following list: - Data acquisition to identify the vugs permeability, distribution, and interconnectivity could be considered to perform a more rigorous evaluation of the Potosi Formation injectivity and capacity. This could be achieved by performing an injection test on a vugular interval to determine the vugs permeability, and an interference test between wells to evaluate the local vugs extent and interconnectivity. - A thorough study of the available FMI data may reveal specifics on estimating the vug to matrix ratio. This estimate could be used to further condition the porosity distribution. Porosity logs alone might underestimate the formation’s porosity associated with vugs. Porosity mapping derived from the seismic inversion could also be used in the succeeding task to characterize the lateral porosity distribution within the reservoir. This could involve the geobody methodology previously attempted in 2010. With or without seismic inversion porosity mapping, it is worth exploring whether increased lateral heterogeneity plays a significant role in Potosi injectivity. Investigations on vugular, dolomitic outcrops suggest that there may be significantly greater lateral heterogeneity than what has been modeled here. - The FMI data also reveals the presence of and helps describe open fractures. The presence of fractures will further enhance the formation’s permeability. The task of leveraging this data in the geomodeling effort still remains. Under the best of circumstances, this data describing open fractures may be combined with seismic attributes to delineate fracture corridors. Fracture modeling would certainly add another layer of sophistication to the model. Its contribution and applicability remain to be explored. - Facies modeling within the Potosi has yet to be thoroughly addressed. The carbonates during the time of deposition are believed to be regionally extensive. However, it may be worth delineating the reservoir with other regional wells or modern day analogues to understand the extent of the Potosi. More specifically, the model could incorporate lateral changes or trends if deemed necessary to represent facies transition. - Currently there is no fracture gradient data available for the Potosi in the Decatur project area. The acquisition of the fracture pressure data could be considered to determine an appropriate maximum allowable bottomhole injection pressure. This would allow the evaluation of injectivity and the required number of wells in a more precise manner. - Special core analysis (SCAL) to determine the relative permeability and capillary pressure of the vugs and matrix could be considered to have a better estimation of the reservoir injectivity and plume extent. - Formation water sampling and analysis could be considered for the Potosi to estimate the water salinity and properties. A vertical flow performance evaluation could be considered for the succeeding task to determine the appropriate tubing size, the required injection tubing head pressure, and to investigate whether the corresponding well injection rate falls within the tubing erosional velocity limit. - A simulation using several injectors could also be considered to determine the required number of wells to achieve the injection target while taking into account the pressure interference.

Smith, Valerie↗

The Potosi Reservoir Model 2013c, Property Modeling Update

As part of a larger project co-funded by the United States Department of Energy (US DOE) to evaluate the potential of formations within the Cambro-Ordovician strata above the Mt. Simon as potential targets for carbon sequestration in the Illinois and Michigan Basins, the Illinois Clean Coal Institute (ICCI) requested Schlumberger to evaluate the potential injectivity and carbon dioxide (CO2) plume size of the Cambrian Potosi Formation. The evaluation of this formation was accomplished using wireline data, core data, pressure data, and seismic data from this project as well as two other separately funded projects: the US DOE-funded Illinois Basin–Decatur Project (IBDP) being conducted by the Midwest Geological Sequestration Consortium (MGSC) in Macon County, Illinois, and the Illinois Industrial Carbon Capture and Sequestration (ICCS) project funded through the American Recovery and Reinvestment Act. In 2010, technical performance evaluations on the Cambrian Potosi Formation were performed through reservoir modeling. The data included formation tops from mud logs, well logs from the Verification Well #1 (VW1) and the Injection Well (CCS1), structural and stratigraphic formation from three dimensional (3D) seismic data, and field data from several waste water injection wells for Potosi Formation. The intention was for 2.2 million tons per annum (2 million tonnes per annum [MTPA]) of CO2 to be injected for 20 years. In the Task Error! Reference source not found., the 2010 Potosi heterogeneous model (referred to as the "Potosi Dynamic Model 2010") was re-run using a new injection scenario of 3.5 million tons per annum (3.2 MTPA) for 30 years. The extent of the Potosi Dynamic Model 2010, however, appeared too small for the new injection target. The models size was insufficient to accommodate the evolution of the plume. The new model, Potosi Dynamic Model 2013a, was built by extending the Potosi Dynamic Model 2010 grid to 30 by 30 mi (48 by 48 km), while preserving all property modeling workflows and layering. This model was retained as the base case. In the preceding Task [1], the Potosi reservoir model was updated to take into account the new data from the Verification Well #2 (VW2) which was drilled in 2012. The porosity and permeability modeling was revised to take into account the log data from the new well. Revisions of the 2010 modeling assumptions were also done on relative permeability, capillary pressures, formation water salinity, and the maximum allowable well bottomhole pressure. Dynamic simulations were run using the injection target of 3.5 million tons per annum (3.2 MTPA) for 30 years. This dynamic model was named Potosi Dynamic Model 2013b. In this Task, a new property modeling workflow was applied, where seismic inversion data guided the porosity mapping and geobody extraction. The static reservoir model was fully guided by PorosityCube interpretations and derivations coupled with petrophysical logs from three wells. The two main assumptions are: porosity features in the PorosityCube that correlate with lost circulation zones represent vugular zones, and that these vugular zones are laterally continuous. Extrapolation was done carefully to populate the vugular facies and their corresponding properties outside the seismic footprint up to the boundary of the 30 by 30 mi (48 by 48 km) model. Dynamic simulations were also run using the injection target of 3.5 million tons per annum (3.2 MTPA) for 30 years. This new dynamic model was named Potosi Dynamic Model 2013c. Reservoir simulation with the latest model gives a cumulative injection of 43 million tons (39 MT) in 30 years with a single well, which corresponds to 40% of the injection target. The injection rate is approx. 3.2 MTPA in the first six months as the well is injecting into the surrounding vugs, and declines rapidly to 1.8 million tons per annum (1.6 MTPA) in year 3 once the surrounding vugs are full and the CO2 start to reach the matrix. After, the injection rate declines gradually to 1.2 million tons per annum (1.1 MTPA) in year 18 and stays constant. This implies that a minimum of three (3) wells could be required in the Potosi to reach the injection target. The injectivity evaluated in this Task was higher compared to the preceding Task, since the current facies modeling (guided by the porosity map from the seismic inversion) indicated a higher density of vugs within the vugular zones. 5 As the CO2 follows the paths where vugs interconnection exists, a reasonably large and irregular plume extent was created. After 30 years of injection, the plume extends 13.7 mi (22 km) in E-W and 9.7 mi (16 km) in N-S directions. After injection finishes, the plume continues to migrate laterally, mainly driven by the remaining pressure gradient. After 60 years post-injection, the plume extends 14.2 mi (22.8 km) in E-W and 10 mi (16 km) in N-S directions, and remains constant as the remaining pressure gradient has become very low. Should the targeted cumulative injection of 106 million tons (96 MT) be achieved; a much larger plume extent could be expected. The increase of reservoir pressure at the end of injection is approximately 1,200 psia (8,274 kPa) around the injector and gradually decreases away from the well. The reservoir pressure increase is less than 10 psia (69 kPa) beyond 14 mi (23 km) away from injector. Should the targeted cumulative injection of 106 million tons (96 MT) be achieved; a much larger areal pressure increase could be expected. The reservoir pressure declines rapidly during the first 30 years post injection and the initial reservoir pressure is nearly restored after 100 years post-injection. The present evaluation is mainly associated with uncertainty on the vugs permeability and interconnectivity. The use of porosity mapping from seismic inversion might have reduced the uncertainty on the lateral vugs body distributions. However, major uncertainties on the Potosi vugs permeability remains. Therefore, injection test and pressure interference test among the wells could be considered to evaluate the local vugs permeability, extent, and interconnectivity. Facies modeling within the Potosi has yet to be thoroughly addressed. The carbonates during the time of deposition are believed to be regionally extensive. However, it may be worth delineating the reservoir with other regional wells or modern day analogues to understand the extent of the Potosi. More specifically, the model could incorporate lateral changes or trends if deemed necessary to represent facies transition. Data acquisitions to characterize the fracture pressure gradient, the formation water properties, the relative permeability, and the capillary pressure could also be considered in order to allow a more rigorous evaluation of the Potosi storage performance. A simulation using several injectors could also be considered to determine the required number of wells and appropriate spacing to achieve the injection target while taking into account the pressure interference.

Adushita, Yasmin↗