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At least 1,333 records · Page 74

Solution chemistry effects on the stress corrosion cracking behavior of alloy 2090 (Al-Li-Cu) and alloy 2024 (Al-Cu-Mg)

The SCC initiation behavior of alloys 2090 and 2024 is examined in various NaCl-based environments. The pre-exposure and bulk/local solution chemistry effects discovered by Holroyd et al. (1986) are investigated, with emphasis on the effect of bulk solution chemistries and atmospheric CO2 on the occluded cell environment and the role of the occluded environment in the crack initiation and early-stage propagation processes. It was found that constant immersion in NaCl does not promote SCC in alloy 2090 or alloy 2024. Upon removal from NaCl, SCC is quickly facilitated, but only in the presence of atmospheric CO2. The need for CO2 is attributed to an increase in carbonate concentrations, eventually allowing passivation of blunted fissures by precipitation of Li2CO3. It is inferred that any effects due to aging are small in magnitude, relative to the effects of subtle changes in the bulk/local solution chemistries.

Moran, James P.↗

Program Helps To Optimize Assembly Sequences

FAST project-management software tool designed to optimize sequence of assembly of Space Station Freedom. Assesses effects of detailed changes upon system and produces output metrics identifying preferred assembly sequences. Incorporates Space-Shuttle integration, Space-Station hardware, on-orbit operations, and governing programmatic considerations as either precedence relations or numerical data. Written in C language.

Borden, Chester S.↗

Sea ice-atmosphere interaction. Application of multispectral satellite data in polar surface energy flux estimates

Satellite data for the estimation of radiative and turbulent heat fluxes is becoming an increasingly important tool in large-scale studies of climate. One parameter needed in the estimation of these fluxes is surface temperature. To our knowledge, little effort has been directed to the retrieval of the sea ice surface temperature (IST) in the Arctic, an area where the first effects of a changing climate are expected to be seen. The reason is not one of methodology, but rather our limited knowledge of atmospheric temperature, humidity, and aerosol profiles, the microphysical properties of polar clouds, and the spectral characteristics of the wide variety of surface types found there. We have developed a means to correct for the atmospheric attenuation of satellite-measured clear sky brightness temperatures used in the retrieval of ice surface temperature from the split-window thermal channels of the advanced very high resolution radiometer (AVHRR) sensors on-board three of the NOAA series satellites. These corrections are specified for three different 'seasons' and as a function of satellite viewing angle, and are expected to be applicable to the perennial ice pack in the central Arctic Basin.

Steffen, Konrad↗

Effects of the low Earth orbit space environment on the surface chemistry of Kapton polyimide film: An XPS study

Kapton H (DuPont Trademark) polyimide specimens exposed to the low earth (LEO) space environment suffered significant weathering with surface erosions of approximately 8.0 microns. Despite these effects, no significant changes in bulk chemistry were observed. X-ray photoelectron spectroscopy (XPS) was used to determine local changes induced from approximately 25 percent in 1980 vintage ground control specimens to nearly 53 percent in space exposed specimens. The greatest increase was observed for the divalent oxygen moieties, although a slight increase in carbonyl oxygen was also measured. Furthermore, the chemical shifts of all XPS peaks of space-exposed Kapton are shifted to higher energy. This is consistent with a higher oxidation state of the space exposed surface. Finally, space exposed specimens had distinct silicon peaks (2p 100 eV and 2s 149 eV) in their XPS spectra in agreement with widespread reports of silicon contamination throughout the LDEF satellite. These results are discussed in terms of surface reactivity of the polyimide exposed to the LEO environment and the chemical nature of contaminants deposited on flight surfaces due to satellite outgassing.

Lee, Myung↗

Analysis, review, and documentation of the activation data from LDEF material

Samples removed from Long Duration Exposure Facility (LDEF-1) are being studied at various laboratories to determine the specific activity(pCi/kg) produced in orbit by exposure to protons and neutrons in near-Earth orbit. These activities are being corrected for efficiency, self-attenuation, and background. The activities and associated gamma-ray spectra are being collected, analyzed, documented and reviewed by faculty and graduate students at Eastern Kentucky University. The currently available activation results have been tabulated and reviewed in this report. Approximately 500 spectra have been accumulated for future archival and analysis. The effect of the changing satellite orbit on the activation is reported herein and was calculated using more recent estimates of the flux of Van Allen belt protons.

Laird, C. E.↗

The 10 January 1986 disconnection event in Comet Halley

The disconnection event (DE) in the plasma tail of Comet Halley on January 9-12, 1986 is examined. The distances between the comet head and the disconnected tail are measured for a series of images for that time period and then extrapolated to the nucleus to determine the disconnection time: January 9.60 +/- 0.2 days. The approximate solar-wind conditions at the time of the DE were obtained by corotation of IMP-8 satellite data in earth orbit to Comet Halley. At the time of the DE, Comet Halley is inferred to have been close to a magnetic-sector boundary and a high-speed stream-compression region. However, a heliographic latitude separation of 22 degrees (between the comet and IMP-8) and gaps in the IMP-8 data render a more definitive statement about the linkage of the DE to external conditions quite difficult. It is not possible to resolve the effects of magnetic changes associated with the sector boundary and plasma pressure in the compression region.

Niedner, Malcolm B., Jr.↗

Design and assessment of high performance fault-tolerant digital systems

This paper outlines a candidate design and assessment methodology that is targeted for the early to mid-level phases of the design cycle. This method allows alternate architectural configurations to be effectively assessed to evaluate the effects of design changes and to reduce the number of inherent design errors.

Elks, Carl R.↗

Shock drift acceleration of energetic protons at a planetary bow shock

Results are presented of numerical orbit integrations of the interaction of suprathermal charged particles (protons) with a planetary bow shock, performed in order to investigate the effect of the changing geometry of the shock, due to its curvature, on the kinematics of the particle/shock interaction. Results obtained for both the 2D and 3D bow-shock geometries show that the introduction of shock curvature to the shock in the simulations leads to an increase of the reflection probability of incident suprathermal protons. It was also found that the curvature of the planetary bow shock allows protons to enter at a given value of theta(Bn) (where theta(Bn) is the angle between the local shock normal and the incident magnetic field) and to exit at a different theta(Bn) value. The result has consequences in the characteristics of the energetic charged particle environment in the planetary foreshock.

Giacalone, Joe↗

Upscale integration of normalized difference vegetation index - The problem of spatial heterogeneity

An analysis is conducted of the correspondence between the normalized difference vegetation index (NDVI) calculated from average reflectances, or M(NDVI), and the I(NDVI) that is integrated from individual NDVIs, by simulating AVHRR data from high spatial resolution SPOT 1 radiometer and Landsat TM data. The West African and French sites analyzed at 300-1000 m scale show a strong correlation between the two types of index; the relationship is almost perfectly linear, with a slope that is somewhat dependent on vegetation cover. Effecting the scale change using M(NDVI) instead of I(NDVI) does not introduce significant errors.

Aman, Angora↗

Parametric Study Of A Ceramic-Fiber/Metal-Matrix Composite

Report describes computer-model parametric study of effects of degradation of constituent materials upon mechanical properties of ceramic-fiber/metal-matrix composite material. Contributes to understanding of weakening effects of large changes in temperature and mechanical stresses in fabrication and use. Concerned mainly with influences of in situ fiber and matrix properties upon behavior of composite. Particular attention given to influence of in situ matrix strength and influence of interphase degradation.

Murthy, P. L. N.↗

Tropospheric processes: Observations and interpretation

Three aspects of tropospheric chemical processes imposed by manmade emission of source gases will be discussed. First, the implications for the OH distribution and thereby for the lifetime of source gases which are controlled by reactions with OH in the troposphere (e.g., CH4 and HCFC) are investigated. This is of importance for stratosphere ozone and climate. Second, we will study the impact of source gas emission on tropospheric ozone and discuss the possibility to estimate indirect climate effects from the changes in ozone and other climate gases. Finally, the degradation of HFC and HCFC's is discussed.

Isaksen, Ivar S. A.↗

Reports to the Nation on our changing planet. Winter 1991 No. 1: The climate system

This pamphlet is a semi-annual report for the period April 1992 through September 1992 dealing with the study of climatology. This introductory pamphlet treats in the simplest of terms such topics as climate change, the greenhouse effect, the global heat engine, hydrology, oceanography, computers and climatology, ice ages, and global warming. Informative charts are included.

Source record↗

Diurnal variation of overdense meteor echo duration and ozone

The diurnal variation of the median duration of overdense sporadic radar meteor echoes is examined. The meteors recorded in August, December, and January by the Ondrejov meteor radar during the period 1958-1990 were used for the analysis. A maximum median echo duration 1-3 hours after the time of local sunrise in the meteor region confirms the already known sunrise effect. Minimum echo duration occurring at the time of sunset seems to be the most important point of diurnal variation of the echo duration, when ozone is no longer dissociated by solar UV radiation. The effect of diurnal changes of the echo duration should be considered when the mass distribution of meteor showers is analyzed.

Simek, Milos↗

Use of cyclic current reversal polarization voltammetry for investigating the relationship between corrosion resistance and heat-treatment induced variations in microstructures of 400 C martensitic stainless steels

Software for running a cyclic current reversal polarization voltammagram has been developed for use with a EG&G Princeton Applied Research Model 273 potentiostat/galvanostat system. The program, which controls the magnitude, direction and duration of an impressed galvanostatic current, will produce data in ASCII spreadsheets (Lotus, Quattro) for graphical representation of CCRPV voltammograms. The program was used to determine differences in corrosion resistance of 440 C martenstic stainless steel produced as a result of changes in microstructure effected by tempering. It was determined that tempering at all temperatures above 400 F resulted in increased polarizability of the material, with the increased likelihood that pitting would be initiated upon exposure to marine environments. These results will be used in development of remedial procedures for lowering the susceptibility of these alloys toward the stress corrosion cracking experienced in bearings used in high pressure oxygen turbopumps used in the main engines of space shuttle orbiters.

Ambrose, John R.↗

Soot agglomeration in isolated, free droplet combustion

Under the conditions of an isolated, free droplet experiment, hollow, carbonaceous structures, called soot spheres, were observed to form during the atmospheric pressure, low Reynolds number combustion of 1-methylnaphthalene. These structures which are agglomerates composed of smaller spheroidal units result from both thermophoretic effects induced by the envelope flame surrounding each drop and aerodynamic effects caused by changes in the relative gas/drop velocities. A chemically reacting flow model was used to analyze the process of sootshell formation during microgravity droplet combustion. The time-dependent temperature and gas property field surrounding the droplet was determined, and the soot cloud location for microgravity combustion of n-heptane droplets was predicted. Experiments showed that the sooting propensity of n-alkane fuel droplets can be varied through diluent substitution, oxygen-index variations, and ambient pressure reductions.

Choi, M. Y.↗

Multidisciplinary design of a rocket-based combined cycle SSTO launch vehicle using Taguchi methods

Results are presented from the optimization process of a winged-cone configuration SSTO launch vehicle that employs a rocket-based ejector/ramjet/scramjet/rocket operational mode variable-cycle engine. The Taguchi multidisciplinary parametric-design method was used to evaluate the effects of simultaneously changing a total of eight design variables, rather than changing them one at a time as in conventional tradeoff studies. A combination of design variables was in this way identified which yields very attractive vehicle dry and gross weights.

Olds, John R.↗

Cosmic ray proton spectra at low rigidities

The cosmic ray proton rigidity spectra have been investigated with data collected in the Low Energy Antiproton (LEAP) balloon flight experiment flown from Prince Albert, Canada in 1987. The LEAP apparatus was designed to measure antiprotons using a superconducting magnet spectrometer with ancillary scintillator, time-of-flight, and liquid Cherenkov detectors. After reaching float altitude the balloon drifted south and west to higher geomagnetic cutoffs. The effect of the changing geomagnetic cutoff on the observed spectra was observed during analysis of the proton data along the balloon trajectory. This is the first measurement of the primary and splash albedo spectra over a wide rigidity range (few hundred MV to about 100 GV) with a single instrument.

Seo, E. S.↗

A global model of carbon-nutrient interactions

The global biogeochemical model presented has two primary objectives. First, it characterizes natural elemental cycles and their linkages for the four elements significant to Earth's biota: C, N, S, and P. Second, it describes changes in these cycles due to human activity. Global nutrient cycles were studied within the drainage basins of several major world rivers on each continent. The initial study region was the Mississippi drainage basin, concentrating on carbon and nitrogen. The model first establishes the nutrient budgets of the undisturbed ecosystems in a study region. It then uses a data set of land use histories for that region to document the changes in these budgets due to land uses. Nutrient movement was followed over time (1800 to 1980) for 30 ecosystems and 10 land use categories. A geographically referenced ecological information system (GREIS) was developed to manage the digital global data bases of 0.5 x 0.5 grid cells needed to run the model: potential vegetation, drainage basins, precipitation, runoff, contemporary land cover, and FAO soil maps of the world. The results show the contributions of land use categories to river nutrient loads on a continental scale; shifts in nutrient cycling patterns from closed, steady state systems to mobile transient or open, steady state systems; soil organic matter depletion patterns in U.S. agricultural lands; changing nutrient ratios due to land use changes; and the effect of using heavy fertilizer on aquatic systems.

Moore, Berrien, III↗